Search Results (2,925)

Spatial openness affects the subjective evaluation of soundscape, landscape, and thermal perceptions, leading to various restoration effects and recreational behaviors. However, the literature lacks studies investigating the effects of multisensory interactions under different levels of spatial openness in plazas on users’ behaviors in urban greenways. Thus, this study contributes to the enhancement of recreational experiences and the environmental design of urban greenways by examining the interaction between multisensory evaluations and recreational behaviors in greenway plazas with different levels of spatial openness. Three types of plazas (enclosed, semi-enclosed, open) were selected along an urban greenway to analyze interactions through in situ measurements, questionnaires, and behavior observation. The results showed that people rated the environment as the quietest and coolest in enclosed plazas, although the sound pressure level of these plazas was the highest. Furthermore, the visual evaluation (VE) was mostly correlated with acoustic evaluation (AE) in plazas with high openness, while the correlation effect between AE and thermal evaluation (TE) was only significant in enclosed plazas. In other words, AE was the key factor targeting the improvement in comfort in greenway plazas. Secondly, improving AE was more effective for stimulating the frequency of interactive activities in enclosed plazas, compared to improving TE. However, AE had a negative effect on the time that people were willing to spend on interactive activities in semi-enclosed plazas. Finally, these findings provide corresponding strategies for creating comfortable audio, visual, and thermal environments in greenway plazas with different levels of openness, as well as strategies for enhancing the recreational experiences of visitors. Full article

By the year 2050, the United States aims to achieve net-zero carbon emissions. To achieve this target, the licensing of the Light Water Reactor (LWR) fleet has been extended for 20 more years. To stay economically competitive with other power sources such as renewable and fossil-fuel power plants, the U.S. Department of Energy has introduced a plan to modernize the existing LWR fleet and diversify the revenue stream. One of the plans is to dispatch thermal energy to endothermic industrial processes. SMART valves will play an important role in this initiative by efficiently balancing the load by regulating valves in a coordinated manner while monitoring the thermal-hydraulic systems to enhance safety and maintain the integrity of the power plant. This research aims to develop a facility to test the coordinated control algorithm and produce various test results for training the monitoring system. The constructed facility is capable of simulating various operational and accidental scenarios by coordinating all the valves (positions) and pump (flowrate). The facility is developed with an Internet of Things (IoT)-based custom system and a python-based valve position control and coordination mechanism. It has achieved stable sensor outputs, pump control, and coordinated valve regulation in all three valves with minimum obstruction in the system. Full article

To meet stringent efficiency and environmental targets, future gas turbines require increased turbine inlet temperatures while maintaining low NO${}_x$ emissions and accommodating hydrogen-blended fuels. Axially staged combustion has emerged as a key technology to address these challenges. This paper presents a mathematical model for the rapid prediction of NO emissions in axially staged combustors fueled with hydrogen-blended methane. The model integrates a simplified thermal NO mechanism with a set of dimensionless staging variables, providing a unified description of flow, mixing, and reaction processes. Its accuracy was validated against a detailed chemical reaction network (CRN). The model was applied to identify feasible low-emission staging windows across different hydrogen-blending ratios and to systematically analyze the effects of secondary-stage mixing quality, operating parameters, and fuel composition on optimal staging and emissions. Results demonstrate that coordinating the combustion strategies of the primary and secondary stages enables effective NO control across a wide fuel range. This work provides a theoretical foundation for the design of low-emission, fuel-flexible axially staged combustors. Full article

High electrostrain, excellent thermal stability, and low hysteresis are critical requirements for advanced high-precision actuators. However, simultaneously achieving these synergistic properties in lead-free ferroelectric ceramics remains a significant challenge. In this work, a targeted B-site doping strategy was employed to develop novel lead-free (0.99-x)BaTiO₃-xBaZrO₃-0.01Bi(Zn_2/3Nb_1/3)O₃ (BT-xBZ-BZN, x = 0–0.2) ceramics. Systematic investigation identified optimal Zr⁴⁺ substitution at x = 0.1, which yielded an outstanding combination of electromechanical properties. For this optimal composition, a high unipolar electrostrain (S_max = 0.11%) was achieved at 50 kV/cm, accompanied by an ultra-low hysteresis (H_S = 1.9%). Concurrently, a large electrostrictive coefficient (Q₃₃ = 0.0405 m⁴/C²) was determined, demonstrating excellent thermal robustness with less than 10% variation across a broad temperature range of 30–120 °C. This superior comprehensive performance is attributed to a composition-driven evolution from a long-range ferroelectric to a pseudocubic relaxor state. In this state, the dominant electrostrictive effect, propelled by reversible dynamics of polar nanoregions (PNRs), minimizes irreversible domain switching. These findings not only present BT-xBZ-BZN (x = 0.1) as a highly promising lead-free candidate for high-precision, low-loss actuator devices, but also provide a viable design strategy for developing high-performance electrostrictive materials with synergistic large strain and superior thermal stability. Full article

This study critically examines the sectoral dynamics of renewable energy (RE) adoption across the EU-27 from 1990 to 2023, addressing the persistent gap between electricity generation and end-use sectors. Utilizing Eurostat energy balance data, the research employs a robust multi-methodological framework. We apply the Logarithmic Mean Divisia Index (LMDI) decomposition to isolate driving factors, and the Self-Organizing Maps (SOM) of Kohonen to cluster countries with similar transition structures. Furthermore, the Method of Moments Quantile Regression (MMQR) is used to estimate heterogeneous drivers across the distribution of RE shares. The empirical findings reveal a sharp dichotomy: while the share of renewables in the electricity generation mix (RES-E-Renewable Energy Share in Electricity) reached approximately 53.8% in leading member states, the aggregated share in the transport sector (RES-T) remains significantly lower at 9.1%. This distinction highlights that while power generation is decarbonizing rapidly, end-use electrification lags behind. The MMQR analysis indicates that economic growth drives renewable adoption more effectively in countries with already high renewable shares (upper quantiles) due to established market mechanisms and grid flexibility. Conversely, in lower-quantile countries, regulatory stability and direct infrastructure investment prove more critical than market-based incentives, highlighting the need for differentiated policy instruments. While EU policy milestones (RED I–III-) align with progress in power generation, they have failed to accelerate transitions in lagging sectors. This study concludes that achieving climate neutrality requires moving beyond aggregate targets to implement distinct, sector-specific interventions that address the unique structural barriers in transport and thermal applications. Full article

This study presents a gradient-based topology optimisation framework for heat sinks embedded with phase-change material (PCM) that targets the mitigation of temperature oscillations under cyclic thermal loads. The approach couples transient thermal diffusion modelling in FEniCS with automatic adjoint sensitivities and GCMMA, and uses a simple analytical homogenisation to parametrise a composite of PCM and conductive material. With latent-heat buffering using PCM, the optimised layouts reduce the temperature variance by 41% when the full time history is used and by 32% when only the quasi-steady-state cycle is used. To improve physical manufacturability, explicit penalisation yields near-discrete designs with only ∼10% performance loss, preserving most oscillation reduction benefits. The results demonstrate that adjoint-driven PCM topology optimisation can systematically suppress thermal oscillations. Full article

Using additive manufacturing for the design of inserts in injection moulding (IM) offers advantages in product development and customization. However, challenges related to operating temperature and mechanical resistance remain. This article presents a systematic screening methodology to evaluate the suitability of materials for specific applications. Ten commercial Material Extrusion (MEX) filaments were selected to produce test samples. Moldex3D simulation software was employed to model the IM process using two thermoplastics and to determine the temperature and pressure conditions that the printed inserts must withstand. Simulation results were critically interpreted and cross-referenced with the experimental material characterisations to evaluate material suitability. Nine of the ten MEX materials were suitable for IM with LDPE, and five with PP. Dimensional assessments revealed that six insert solutions required further post-processing for assembly, while three did not. All of the selected materials successfully survived 10 injection cycles without encountering any significant issues. The simulation results were validated by comparing temperature data from a thermal imaging camera during IM, revealing only minor deviations. The study concludes that combining targeted material characterization with CAE simulation provides an effective and low-cost strategy for selecting MEX filaments for injection moulding inserts, supporting rapid tooling applications in niche production. Full article

Today, PHB and its copolymers—potential plastic substitutes—are produced by fermenting sugar, which is not scalable to the volumes of plastic consumption. PHB from CH₄ can offer a sustainable process route, with CH₄ potentially produced from a variety of waste biomass streams through anaerobic digestion, gasification, and methanation. The high molar mass (M_w) of PHB is a key determinant of its mechanical properties, and strain, culture conditions and downstream processing influence it. In this work, the strain Methylocystis sp. GB 25 (DSMZ 7674) was grown on natural gas as the sole carbon and energy source and air (1:1) in a loop reactor with 350 L active fermentation volume, at 35 °C and ambient pressure. After two days of continuous growth, the bacteria were limited in P and N for 1, 2, and 2.5 days to determine the optimal conditions for PHB accumulation and the highest Mw as the target. The biomass was then centrifuged and spray-dried. For downstream processing, chloroform solvent extraction and selected enzymatic treatment were deployed, yielding ~40% PHB from the biomass. The PHB obtained by solvent extraction exhibited high average weight molar masses of M_w ~1.1–1.5 × 10⁶ g mol⁻¹. The highest M_w was obtained after one day of limitation, whereas enzyme treatment resulted in partially degraded PHB. Cold chloroform maceration, interesting due to energy savings, did not achieve sufficient extraction efficiency because it was unable to extract high-molar-mass PHB fractions. The extracted PHB has a high molar mass, more than double that of standard commercial PHB, and was characterized by DSC, which showed a high degree of crystallinity of up to 70% with a melting temperature of close to 180 °C. Mechanical tensile properties measurements, as well as dynamic mechanical thermal analysis (DMTA), were performed. Degradation of the PHB by enzymes was also determined. Methanotrophic PHB is a promising bioplastics material. The high M_w can limit and delay polymer degradation in practical processing steps, making the material more versatile and robust. Full article

Ulcerative colitis (UC) is an inflammatory bowel disease associated with oxidative stress. Pogostemon oil (PO) exhibits potent antioxidant and anti-inflammatory activities but is limited by high volatility and poor gastrointestinal stability. In this study, sporopollenin exine capsules (SECs) were engineered as natural micro-carriers for PO, achieving efficient encapsulation (η > 69%) and a high adsorption capacity (27.64 g/g). A pH-sensitive calcium alginate shell was subsequently applied to construct colon-targeted microspheres (Ca-Alg@PO-SECs). The resulting system improved the thermal and photostability of PO. In vitro dissolution assays confirmed the system’s pH-responsiveness, maintaining integrity under simulated gastric conditions while enabling localized release at intestinal pH. In a DSS-induced acute UC mouse model, Ca-Alg@PO-SECs effectively alleviated clinical symptoms, as evidenced by improved body weight, colon length, and disease activity index. At the inflammatory level, the formulation modulated key cytokines (IL-1β, IL-6, and IL-10). Overall, Ca-Alg@PO-SECs provides a biocompatible, colon-targeted delivery strategy that preserves the bioactivity of essential oils and offers a promising preclinical approach for localized UC therapy. Full article

This review explores the variety of diamond-based sensing applications, emphasizing their material properties, such as high Young’s modulus, thermal conductivity, wide bandgap, chemical stability, and radiation hardness. These diamond properties give excellent performance in mechanical, pressure, thermal, magnetic, optoelectronic, radiation, biosensing, quantum, and other applications. In vibration sensing, nano/poly/single-crystal diamond resonators operate from MHz to GHz frequencies, with high quality factor via CVD growth, diamond-on-insulator techniques, and ICP etching. Pressure sensing uses boron-doped piezoresistive, as well as capacitive and Fabry–Pérot readouts. Thermal sensing merges NV nanothermometry, single-crystal resonant thermometers, and resistive/diode sensors. Magnetic detection offers FeGa/Ti/diamond heterostructures, complementing NV. Optoelectronic applications utilize DUV photodiodes and color centers. Radiation detectors benefit from diamond’s neutron conversion capability. Biosensing leverages boron-doped diamond and hydrogen-terminated SGFETs, as well as gas targets such as NO₂/NH₃/H₂ via surface transfer doping and Pd Schottky/MIS. Imaging uses AFM/NV probes and boron-doped diamond tips. Persistent challenges, such as grain boundary losses in nanocrystalline diamond, limited diamond-on-insulator bonding yield, high temperature interface degradation, humidity-dependent gas transduction, stabilization of hydrogen termination, near-surface nitrogen-vacancy noise, and the cost of high-quality single-crystal diamond, are being addressed through interface and surface chemistry control, catalytic/dielectric stack engineering, photonic integration, and scalable chemical vapor deposition routes. These advances are enabling integrated, high-reliability diamond sensors for extreme and quantum-enhanced applications. Full article

Existing office buildings in Australia contribute to 24% of the nation’s electricity consumption and 10% of greenhouse gas emissions, with energy use projected to rise by 84%. Meeting the 2050 sustainability target and United Nations (UN) 17 Sustainable Development Goals (SDGs) requires improving sustainability within existing office buildings. This systematic review examines net zero energy and climate resilience strategies in these buildings by analysing 74 studies from scholarly literature, government reports, and industry publications. The literature search was conducted across Scopus, Google Scholar, and Web of Science databases, with the final search in early 2025. Studies were selected based on keywords and research parameters. A narrative synthesis identified key technologies, evaluating the integration of net zero principles with climate resilience to enhance energy efficiency through HVAC modifications. Technologies like heat pumps, energy recovery ventilators, thermal energy storage, and phase change materials (PCMs) have been identified as crucial in reducing HVAC energy usage intensity (EUI). Lighting control and plug load management advancements are examined for reducing electricity demand. This review highlights the gap between academic research and practical applications, emphasising the need for comprehensive field studies to provide long-term performance data. Current regulatory frameworks influencing the net zero transition are discussed, with recommendations for policy actions and future research. This study links net zero performance with climate adaptation objectives for existing office buildings and provides recommendations for future research, retrofit planning, and policy development. Full article

In regions with hot summers and cold winters, elderly care buildings face the dual challenges of high energy consumption and stringent thermal comfort requirements. Using Nanchang as a case study, this research presents an optimization approach that integrates phase change material (PCM) walls with the window-to-wall ratio (WWR). PCM wall performance was tested experimentally, and EnergyPlus simulations were conducted to assess building energy use for WWR values ranging from 0.25 to 0.50, with and without PCM. The phase change material (PCM) used in this study is paraffin (an organic phase change material), which has a melting point of 26 °C and can store and release heat during temperature fluctuations. The experimental results show that PCM walls effectively reduce heat transfer, lowering the surface temperatures of external, central, and internal walls by 3.9 °C, 3.8 °C, and 3.7 °C, respectively, compared to walls without PCM. The simulation results predict that the PCM wall can reduce air conditioning energy consumption by 8.2% in summer and total annual energy consumption by 14.2%. The impact of WWR is orientation-dependent: east and west façades experience significant cooling penalties as WWR increases and should be maintained at or below 0.30; the south façade achieves optimal performance at a WWR of 0.40, with the lowest total energy load (111.2 kW·h·m-2); and the north façade performs best at the lower bound (WWR = 0.25). Under the combined strategy (south wall with PCM and WWR = 0.40), annual total energy consumption is reduced by 9.8% compared to the baseline (no PCM), with indoor temperatures maintained between 18 and 26 °C. This range is selected based on international thermal comfort standards (e.g., ASHRAE) and comfort research specifically targeting the elderly population, ensuring comfort for elderly occupants. These findings offer valuable guidance for energy-efficient design in similar climates and demonstrate that the synergy between PCM and WWR can reduce energy consumption while maintaining thermal comfort. Full article

Carbon capture is pivotal for achieving carbon neutrality; however, its high energy consumption severely limits the operational flexibility of power plants and remains a key challenge. This study, targeting a full flue gas carbon capture scenario for a 1000 MW coal-fired power plant, identified the dual-element (“steam” and “power generation”) coupling convergence mechanism. Based on this mechanism, a comprehensive set of mathematical model equations for the “carbon–electricity–heat” coupling process is established. This model quantifies the dynamic relationship between key operational parameters (such as unit load, capture rate, and thermal consumption level) and system performance metrics (such as power output and specific power penalty). To address the challenge of flexible operation, this paper further proposes two innovative coupled modes: steam thermal storage and chemical solvent storage. Model-based quantitative analysis indicated the following: (1) The power generation impact rate under full THA conditions (25.7%) is lower than that under 30% THA conditions (27.7%), with the specific power penalty for carbon capture decreasing from 420.7 kW·h/tCO₂ to 366.7 kW·h/tCO₂. (2) Thermal consumption levels of the capture system are a critical influencing factor; each 0.1 GJ/tCO₂ increase in thermal consumption leads to an approximate 2.83% rise in unit electricity consumption. (3) Steam thermal storage mode effectively reduces peak-period capture energy consumption, while the chemical solvent storage mode almost fully eliminates the impact on peak power generation and provides optimal deep peak-shaving capability and operational safety. Furthermore, these modeling results provide a basis for decision-making in plant operations. Full article

Understanding how global climate drivers manifest at regional scales is critical for designing targeted adaptation strategies, particularly in vulnerable mountainous countries. This study provides an integrated assessment of atmospheric CO₂ concentrations, surface temperature, and precipitation trends at both global and Armenian levels from the early 20th century to 2024. Using long-term observational datasets and ordinary least squares regression models with HAC-robust errors, this study quantifies the magnitude and statistical significance of historical climate shifts. Results confirm pronounced global warming (+0.021 °C/year) alongside a moderate rise in global precipitation (+1.13 mm/year). Armenia, however, exhibits substantially accelerated warming (+0.052 °C/year) coupled with a non-significant and spatially heterogeneous precipitation trend, including notable declines in humid regions. CO₂ emissions per capita strongly predict temperature change both globally (0.59 °C/ton) and, even more prominently, in Armenia (1.33 °C/ton), indicating heightened regional climate sensitivity. These findings align closely with Armenia’s Fourth National Communication to the UNFCCC, reinforcing the robustness of the analysis. By revealing how global climate forcings translate into region-specific outcomes—and by discussing the emerging thermal contribution of digital infrastructure—this study underscores the urgency of localized climate adaptation, water resource planning, and agricultural resilience measures. Full article

This study investigates thermal stress and energy-related anxiety as lived, multidimensional manifestations of energy poverty in Western Macedonia, Greece, a coal phase-out region undergoing just transition. Using a 261-household survey, we construct a thermal stress index from four Likert-type items capturing seasonal thermal adequacy, energy anxiety, and restricted use of rooms. High thermal stress is defined as the upper quartile of the index. Descriptive results indicate that high thermal stress affects 27.2% of households, exceeding a 20% threshold, while energy-related anxiety and restricted room use are widespread. We then estimate logistic regression models to examine whether vulnerability characteristics (disability-related thermal/electric needs, single parenthood, dependent children, benefit receipt, elderly presence), financial stress indicators (arrears, energy debt, frequent forced reductions in consumption), and socio-economic controls (income, employment, tenure, age, gender) predict high thermal stress. Adjusted models show that vulnerability markers do not retain statistically independent associations once controls are included. In contrast, tenure and energy-related financial stress are significantly associated with the probability of high thermal stress. The findings highlight the importance of measurement choices and suggest that experiential indicators capture energy-poverty dynamics that are not reducible to income-based targeting, with implications for just-transition policy design and energy justice. Full article