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Search Results (381)

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Keywords = textile innovation

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9 pages, 1938 KiB  
Brief Report
Single-Component Silicon-Containing Polyurethane for High-Performance Waterproof and Breathable Nanofiber Membranes
by Dongxu Lu, Yanbing Li, Yake Chai, Ximei Wen, Liming Chen and Sanming Sun
Fibers 2025, 13(8), 105; https://doi.org/10.3390/fib13080105 - 5 Aug 2025
Abstract
High-performance waterproof and breathable nanofiber membranes (WBNMs) are in great demand for various advanced applications. However, the fabrication of such membranes often relies on fluorinated materials or involves complex preparation processes, limiting their practical use. In this study, we present an innovative approach [...] Read more.
High-performance waterproof and breathable nanofiber membranes (WBNMs) are in great demand for various advanced applications. However, the fabrication of such membranes often relies on fluorinated materials or involves complex preparation processes, limiting their practical use. In this study, we present an innovative approach by utilizing silicon-containing polyurethane (SiPU) as a single-component, fluorine-free raw material to prepare high-performance WBNMs via a simple one-step electrospinning process. The electrospinning technique enables the formation of SiPU nanofibrous membranes with a small maximum pore size (dmax) and high porosity, while the intrinsic hydrophobicity of SiPU imparts excellent water-repellent characteristics to the membranes. As a result, the single-component SiPU WBNM exhibits superior waterproofness and breathability, with a hydrostatic pressure of 52 kPa and a water vapor transmission rate (WVTR) of 5798 g m−2 d−1. Moreover, the optimized SiPU-14 WBNM demonstrates outstanding mechanical properties, including a tensile strength of 6.15 MPa and an elongation at break of 98.80%. These findings indicate that the single-component SiPU-14 WBNMs not only achieve excellent waterproof and breathable performance but also possess robust mechanical strength, thereby enhancing the comfort and expanding the potential applications of protective textiles, such as outdoor apparel and car seats. Full article
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15 pages, 439 KiB  
Article
The Internationalization of the Portuguese Textile Sector into the Chinese Market: Contributions to Destination Image
by Manuel José Serra da Fonseca, Bruno Barbosa Sousa, Tatiana Machado Carvalho and Andreia Teixeira
Tour. Hosp. 2025, 6(3), 146; https://doi.org/10.3390/tourhosp6030146 - 30 Jul 2025
Viewed by 190
Abstract
Globalization and market saturation have led Portuguese textile companies to seek international markets not only for growth but also to contribute to their country’s international image. This study aims to explore how the internationalization of the Portuguese textile sector into the Chinese market [...] Read more.
Globalization and market saturation have led Portuguese textile companies to seek international markets not only for growth but also to contribute to their country’s international image. This study aims to explore how the internationalization of the Portuguese textile sector into the Chinese market contributes to Portugal’s destination image and identify the critical success factors in this process. The research follows an inductive, qualitative methodology based on semi-structured interviews with two groups of companies: those already operating in China (n = 5) and those preparing to enter the market (n = 5). The interviews were thematically analyzed to extract key patterns and insights. The findings reveal that successful companies operate in the luxury segment, rely on prior international experience, and often use local intermediaries. Firms planning to internationalize highlight quality differentiation, brand authenticity, and innovation as strategic advantages. These insights support the role of niche positioning and cultural adaptation in building both commercial success and a refined international image of Portugal. This study contributes to the literature by linking internationalization and destination branding through industry-specific case evidence and offers practical implications for managers targeting emerging markets like China. Full article
(This article belongs to the Special Issue Innovations as a Factor of Competitiveness in Tourism, 2nd Edition)
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15 pages, 3980 KiB  
Article
Four-Dimensional-Printed Woven Metamaterials for Vibration Reduction and Energy Absorption in Aircraft Landing Gear
by Xiong Wang, Changliang Lin, Liang Li, Yang Lu, Xizhe Zhu and Wenjie Wang
Materials 2025, 18(14), 3371; https://doi.org/10.3390/ma18143371 - 18 Jul 2025
Viewed by 327
Abstract
Addressing the urgent need for lightweight and reusable energy-absorbing materials in aviation impact resistance, this study introduces an innovative multi-directional braided metamaterial design enabled by 4D printing technology. This approach overcomes the dual challenges of intricate manufacturing processes and the limited functionality inherent [...] Read more.
Addressing the urgent need for lightweight and reusable energy-absorbing materials in aviation impact resistance, this study introduces an innovative multi-directional braided metamaterial design enabled by 4D printing technology. This approach overcomes the dual challenges of intricate manufacturing processes and the limited functionality inherent to traditional textile preforms. Six distinct braided structural units (types 1–6) were devised based on periodic trigonometric functions (Y = A sin(12πX)), and integrated with shape memory polylactic acid (SMP-PLA), thereby achieving a synergistic combination of topological architecture and adaptive response characteristics. Compression tests reveal that reducing strip density to 50–25% (as in types 1–3) markedly enhances energy absorption performance, achieving a maximum specific energy absorption of 3.3 J/g. Three-point bending tests further demonstrate that the yarn amplitude parameter A is inversely correlated with load-bearing capacity; for instance, the type 1 structure (A = 3) withstands a maximum load stress of 8 MPa, representing a 100% increase compared to the type 2 structure (A = 4.5). A multi-branch viscoelastic constitutive model elucidates the temperature-dependent stress relaxation behavior during the glass–rubber phase transition and clarifies the relaxation time conversion mechanism governed by the Williams–Landel–Ferry (WLF) and Arrhenius equations. Experimental results further confirm the shape memory effect, with the type 3 structure fully recovering its original shape within 3 s under thermal stimulation at 80 °C, thus addressing the non-reusability issue of conventional energy-absorbing structures. This work establishes a new paradigm for the design of impact-resistant aviation components, particularly in the context of anti-collision structures and reusable energy absorption systems for eVTOL aircraft. Future research should further investigate the regulation of multi-stimulus response behaviors and microstructural optimization to advance the engineering application of smart textile metamaterials in aviation protection systems. Full article
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41 pages, 6695 KiB  
Review
Design Innovation and Thermal Management Applications of Low-Dimensional Carbon-Based Smart Textiles
by Yating Pan, Shuyuan Lin, Yang Xue, Bingxian Ou, Zhen Li, Junhua Zhao and Ning Wei
Textiles 2025, 5(3), 27; https://doi.org/10.3390/textiles5030027 - 9 Jul 2025
Viewed by 420
Abstract
With the rapid development of wearable electronics, traditional rigid thermal management materials face limitations in flexibility, conformability, and multi-physics adaptability. Low-dimensional carbon materials such as graphene and carbon nanotubes combine ultrahigh thermal conductivity with outstanding mechanical compliance, making them promising building blocks for [...] Read more.
With the rapid development of wearable electronics, traditional rigid thermal management materials face limitations in flexibility, conformability, and multi-physics adaptability. Low-dimensional carbon materials such as graphene and carbon nanotubes combine ultrahigh thermal conductivity with outstanding mechanical compliance, making them promising building blocks for flexible thermal regulation. This review summarizes recent advances in integrating these materials into textile architectures, mapping the evolution of this emerging field. Key topics include phonon-dominated heat transfer mechanisms, strategies for modulating interfacial thermal resistance, and dimensional effects across scales; beyond these intrinsic factors, hierarchical textile configurations further tailor macroscopic performance. We highlight how one-dimensional fiber bundles, two-dimensional woven fabrics, and three-dimensional porous networks construct multi-directional thermal pathways while enhancing porosity and stress tolerance. As for practical applications, the performance of carbon-based textiles in wearable systems, flexible electronic packaging, and thermal coatings is also critically assessed. Current obstacles—namely limited manufacturing scalability, interfacial mismatches, and thermal performance degradation under repeated deformation—are analyzed. To overcome these challenges, future studies should prioritize the co-design of structural and thermo-mechanical properties, the integration of multiple functionalities, and optimization guided by data-driven approaches. This review thus lays a solid foundation for advancing carbon-based smart textiles toward next-generation flexible thermal management technologies. Full article
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26 pages, 389 KiB  
Review
Recent Advancements in Millimeter-Wave Antennas and Arrays: From Compact Wearable Designs to Beam-Steering Technologies
by Faisal Mehmood and Asif Mehmood
Electronics 2025, 14(13), 2705; https://doi.org/10.3390/electronics14132705 - 4 Jul 2025
Viewed by 936
Abstract
Millimeter-wave (mmWave) antennas and antenna arrays have gained significant attention due to their pivotal role in emerging wireless communication, sensing, and imaging technologies. With the rapid deployment of 5G and the transition toward 6G networks, the demand for compact, high-gain, and reconfigurable mmWave [...] Read more.
Millimeter-wave (mmWave) antennas and antenna arrays have gained significant attention due to their pivotal role in emerging wireless communication, sensing, and imaging technologies. With the rapid deployment of 5G and the transition toward 6G networks, the demand for compact, high-gain, and reconfigurable mmWave antennas has intensified. This article highlights recent advancements in mmWave antenna technologies, including hybrid beamforming using phased arrays, dynamic beam-steering enabled by liquid crystal and MEMS-based structures, and high-capacity MIMO architectures. We also examine the integration of metamaterials and metasurfaces for miniaturization and gain enhancement. Applications covered include wearable antennas with low-SAR textile substrates, conformal antennas for UAV-based mmWave relays, and high-resolution radar arrays for autonomous vehicles. The study further analyzes innovative fabrication methods such as inkjet and aerosol jet printing, micromachining, and laser direct structuring, along with advanced materials like Kapton, PDMS, and graphene. Numerical modeling techniques such as full-wave EM simulation and machine learning-based optimization are discussed alongside experimental validation approaches. Beyond communications, we assess mmWave systems for biomedical imaging, security screening, and industrial sensing. Key challenges addressed include efficiency degradation at high frequencies, interference mitigation in dense environments, and system-level integration. Finally, future directions, including AI-driven design automation, intelligent reconfigurable surfaces, and integration with quantum and terahertz technologies, are outlined. This comprehensive synthesis aims to serve as a valuable reference for advancing next-generation mmWave antenna systems. Full article
(This article belongs to the Special Issue Recent Advancements of Millimeter-Wave Antennas and Antenna Arrays)
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24 pages, 9971 KiB  
Article
Development of Bioactive Cotton, Wool, and Silk Fabrics Functionalized with Origanum vulgare L. for Healthcare and Medical Applications: An In Vivo Study
by Aleksandra Ivanovska, Anica Petrović, Tamara Lazarević-Pašti, Tatjana Ilic-Tomic, Katarina Dimić-Mišić, Jelena Lađarević and Jovana Bradić
Pharmaceutics 2025, 17(7), 856; https://doi.org/10.3390/pharmaceutics17070856 - 30 Jun 2025
Viewed by 461
Abstract
Background: This study presents an innovative approach to developing bioactive natural fabrics for healthcare and medical applications. Methods: An ethanol extract of Origanum vulgare L. (in further text: OE), exhibiting exceptional antioxidant (100%) and antibacterial activity (>99% against E.coli and S.aureus), was [...] Read more.
Background: This study presents an innovative approach to developing bioactive natural fabrics for healthcare and medical applications. Methods: An ethanol extract of Origanum vulgare L. (in further text: OE), exhibiting exceptional antioxidant (100%) and antibacterial activity (>99% against E.coli and S.aureus), was employed to biofunctionalize cotton, wool, and silk fabrics. Results: All biofunctionalized fabrics demonstrated strong antioxidant activity (>99%), while antibacterial efficacy varied by fabric: cotton > 54%, wool > 99%, and silk > 89%. OE-biofunctionalized wool possessed the highest release of OE’s bioactive compounds, followed by silk and cotton, indicating substrate-dependent release behavior. This tunable fabrics’ OE release profile, along with their unique bioactivity, supports targeted applications: OE-functionalized silk for luxury or prolonged therapeutic use (skin-care textiles, post-surgical dressings, anti-aging products), cotton for disposable or short-term use (protective wipes, minor wound coverings), and wool for wound dressings. The biocompatibility and cytotoxicity of OE-biofunctionalized wool were evaluated via in vitro assays using healthy human keratinocytes and in vivo testing in Wistar albino male rats. The obtained results revealed that OE-functionalized wool significantly accelerated wound closure (97.8% by day 14), enhanced collagen synthesis (6.92 µg/mg hydroxyproline), and improved tissue and systemic antioxidant defense while reducing oxidative stress markers in skin and blood samples of rats treated with OE-biofunctionalized wool. Conclusions: OE-biofunctionalized wool demonstrates strong potential as an advanced natural solution for managing chronic wounds. Further clinical validation is recommended to confirm its performance in real-world healthcare settings. This work introduces an entirely new application of OE in textile biofunctionalization, offering alternatives for healthcare and medical textiles. Full article
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13 pages, 2657 KiB  
Article
Efficient Filtration Systems for Microplastic Elimination in Wastewater
by Jamal Sarsour, Benjamin Ewert, Bernd Janisch, Thomas Stegmaier and Götz T. Gresser
Microplastics 2025, 4(3), 36; https://doi.org/10.3390/microplastics4030036 - 30 Jun 2025
Viewed by 426
Abstract
This study presents the development of a textile-based cascade filter for the removal of microplastics from an industrial laundry effluent. The cascade microfilter consists of three stages of 3D textile sandwich composite filter media, which have successively finer pores and are aimed at [...] Read more.
This study presents the development of a textile-based cascade filter for the removal of microplastics from an industrial laundry effluent. The cascade microfilter consists of three stages of 3D textile sandwich composite filter media, which have successively finer pores and are aimed at filtering microplastic particles down to 1.5 µm. Polypropylene fabrics with pore sizes of 100, 50 and 20 µm and 3D warp-knitted fabrics with high porosity (96%) were used. Filtration tests were carried out with polyethylene model microplastic particles at a concentration of 167 mg/L. To regenerate the filter and restore its filtration performance, backwashing with filtered water and compressed air was applied. Field trials at an industrial laundry facility and a municipal wastewater treatment plant confirmed high removal efficiencies. The 3D textile sandwich structure promotes filter cake formation, allowing extended backwash intervals and the effective recovery of filtration capacity between 89.7% and 98.5%. The innovative use of 3D textile composites enables a high level of microplastic removal while extending the filter media lifetime. This makes a significant contribution to the reduction in microplastic emissions in the aquatic environment. The system is scalable, space and cost efficient and adaptable to various industrial applications and is thus a promising solution for advanced wastewater treatment. Full article
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14 pages, 2778 KiB  
Article
The Effect of Orientation Angle of Center Facing Arm on Elongation of 3D-Printed Auxetic-Structure Textiles
by Shahbaj Kabir, Yu Li and Young-A Lee
Textiles 2025, 5(3), 25; https://doi.org/10.3390/textiles5030025 - 30 Jun 2025
Viewed by 336
Abstract
This study aimed to examine the effect of the orientation angle of center facing arms on the elongation and strength of 3D-printed textiles with two different re-entrant cellular auxetic structures. An experimental research design, consisting of 6 (auxetic-structure textiles) × 3 (repetition), was [...] Read more.
This study aimed to examine the effect of the orientation angle of center facing arms on the elongation and strength of 3D-printed textiles with two different re-entrant cellular auxetic structures. An experimental research design, consisting of 6 (auxetic-structure textiles) × 3 (repetition), was employed. Star-shaped re-entrant auxetic structures (star re-entrant) with orientation angles of 25°, 30°, and 35° and floral-based star-shaped re-entrant auxetic structures (floral re-entrant) with orientation angles of 55°, 60°, and 65° were developed using the fused deposition modeling 3D-printing method through identifying commonly used auxetic structures in the 3D-printed textiles’ development. A statistically significant relationship was found between load and elongation of both star re-entrant and floral re-entrant. The findings indicated that 3D-printed textiles with both star re-entrant and floral re-entrant structures exhibited an enhanced elongation with the increase in orientation angle, making the textile products more flexible and potentially providing better wear comfort. However, the strength of both star re-entrant and floral re-entrant textiles was not significantly affected by the orientation angle of center facing arms. The findings demonstrated the potential to enhance the elongation of 3D-printed auxetic-structure textiles without compromising their strength for ensuing comfort by adjusting the orientation angle of center facing arms. Full article
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56 pages, 16805 KiB  
Review
Lightweight Textile and Fiber-Reinforced Composites for Soft Body Armor (SBA): Advances in Panel Design, Materials, and Testing Standards
by Mohammed Islam Tamjid, Mulat Alubel Abtew and Caroline Kopot
J. Compos. Sci. 2025, 9(7), 337; https://doi.org/10.3390/jcs9070337 - 28 Jun 2025
Viewed by 751
Abstract
Soft body armor (SBA) remains an essential component of first responder protection. However, most SBA design concepts do not adequately address the unique performance, morphological, and psychological needs of women as first responders. In this review, female-specific designs of ballistic-resistant panels, material systems, [...] Read more.
Soft body armor (SBA) remains an essential component of first responder protection. However, most SBA design concepts do not adequately address the unique performance, morphological, and psychological needs of women as first responders. In this review, female-specific designs of ballistic-resistant panels, material systems, and SBA performance testing are critically examined. The paper also explores innovations in shaping and design techniques, including darting, dartless shape construction, modular assembly, and body scanning with CAD integration to create contoured and structurally stable panels with improved coverage, reduced bulk, and greater mobility. In addition, the review addresses broadly used and emerging dry textile fabrics and fiber-reinforced polymers, considering various innovations, such as 3D warp interlock weave, shear thickening fluid (STF) coating, nanomaterials, and smart composites that improve energy dissipation and impact tolerance without sacrificing flexibility. In addition, the paper also examines various emerging ballistic performance testing standards and their revisions to incorporate gender-specific standards and measures their ability to decrease trauma effects and maintain flexibility and practical protection. Finally, it identifies existing challenges and areas of future research, such as optimizing multi-layer systems, addressing fatigue behavior, and improving multi-angle and low-velocity impact performance while providing avenues for future sustainable, adaptive, and performance-optimized body armor. Full article
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24 pages, 7913 KiB  
Review
From Waste to Value: Advances in Recycling Textile-Based PET Fabrics
by Fatemeh Mohtaram and Peter Fojan
Textiles 2025, 5(3), 24; https://doi.org/10.3390/textiles5030024 - 28 Jun 2025
Viewed by 940
Abstract
The environmental burden of textile waste has become a critical challenge for sustainable development. This review explores recent developments in the recycling of textiles, especially polyethylene tereph-2 thalate (PET)-based fabrics, with a focus on fiber-to-fiber regeneration as a pathway toward circular textile production. [...] Read more.
The environmental burden of textile waste has become a critical challenge for sustainable development. This review explores recent developments in the recycling of textiles, especially polyethylene tereph-2 thalate (PET)-based fabrics, with a focus on fiber-to-fiber regeneration as a pathway toward circular textile production. Recent developments in PET recycling, such as mechanical and chemical recycling methods, are critically examined, highlighting the potential of chemical depolymerization for recovering high-purity monomers suitable for textile-grade PET synthesis. Special attention is given to electrospinning as an emerging technology for converting recycled PET into high-value nanofibers, offering functional properties suitable for advanced applications in filtration, medical textiles, and smart fabrics. The integration of these innovations, alongside improved sorting technologies and circular design strategies, is essential for overcoming current limitations and enabling scalable, high-quality recycling systems. This review aims to support the development of a more resource efficient textile industry by outlining key challenges, technologies, and future directions in PET recycling. Full article
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48 pages, 6397 KiB  
Review
Advancements in Electrochromic Technology for Multifunctional Flexible Devices
by Alice Marciel, Joel Borges, Luiz Pereira, Rui F. Silva and Manuel Graça
Materials 2025, 18(13), 2964; https://doi.org/10.3390/ma18132964 - 23 Jun 2025
Viewed by 673
Abstract
The design and investigation of electrochromic devices have advanced significantly, including distinct applications such as self-charged smart windows, aerospace interactive windows, low power flexible and ecofriendly displays, automatic dimming rearview, wearable smart textiles, military and civilian camouflage systems, electrochromic sensors, among others. Although [...] Read more.
The design and investigation of electrochromic devices have advanced significantly, including distinct applications such as self-charged smart windows, aerospace interactive windows, low power flexible and ecofriendly displays, automatic dimming rearview, wearable smart textiles, military and civilian camouflage systems, electrochromic sensors, among others. Although significant progress has been made in related fields, achieving the full potential of electrochromic devices to meet the standards of maturity and practical applications remains a persistent challenge. Electrochromic devices are typically multilayered structures that can be designed as either rigid or flexible systems, depending on the type of substrate employed. Conventional electrochromic devices comprise layered structures that include transparent electrodes, electrochromic materials, ionic conductors, and ion storage materials. On the other hand, multifunctional systems integrate bifunctional materials or distinct functional layers to simultaneously achieve optical modulation and additional capabilities such as energy storage. The development of advanced materials, comprehensive electrochemical kinetic analysis, the optimization and advancement of process techniques and deposition methods, and innovative device designs are active areas of extensive global research. This review focuses on the recent advances in multifunctional electrochromic materials and devices with particular emphasis on the integration of electrochromic technology with other functional technologies. It further identifies current challenges, proposes potential solutions, and outlines future research directions focused on advancing this technology in both niche and scalable applications. Full article
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17 pages, 284 KiB  
Entry
The Health Impact of Fast Fashion: Exploring Toxic Chemicals in Clothing and Textiles
by Vivian Christine Dourado Pinto and Meital Peleg Mizrachi
Encyclopedia 2025, 5(2), 84; https://doi.org/10.3390/encyclopedia5020084 - 18 Jun 2025
Viewed by 3028
Definition
The fashion industry is widely recognized for its environmental challenges, but the health impacts related to textile toxicity remain significantly underexplored. Beyond the well-known issues of pollution and resource depletion, modern clothing often harbors a hidden threat: hazardous chemicals embedded within fabrics. These [...] Read more.
The fashion industry is widely recognized for its environmental challenges, but the health impacts related to textile toxicity remain significantly underexplored. Beyond the well-known issues of pollution and resource depletion, modern clothing often harbors a hidden threat: hazardous chemicals embedded within fabrics. These include dyes containing heavy metals, antimicrobial agents that foster bacterial resistance, and synthetic fibers that release microplastics. Unlike environmental discussions, the dialogue around the direct and long-term health effects of these substances is still limited. This entry addresses critical yet often-overlooked concerns, such as how chemicals in textiles contribute to chronic skin conditions, hormonal disruptions, and even carcinogenic risks. It also examines the proliferation of bacteria in synthetic garments, leading to dermatological infections and rapid fabric degradation. Furthermore, the globalized nature of production masks the contamination risks transferred from producer to consumer countries. Through an interdisciplinary approach, this entry highlights the urgent need for integrating scientific innovation, stringent regulation, and consumer awareness to mitigate health hazards in fashion. It calls for the adoption of safer textile technologies, sustainable materials, and transparent production practices, paving the way for a fashion future that prioritizes human health as much as environmental sustainability. Full article
(This article belongs to the Section Chemistry)
22 pages, 6159 KiB  
Article
Symmetrical Traditional Patterns and User Perception: A Study on Innovation in Home Textile Design
by Mengqi Qin, Jianfang Wang, Xueying Ding and Haihong Zhang
Symmetry 2025, 17(6), 960; https://doi.org/10.3390/sym17060960 - 17 Jun 2025
Viewed by 396
Abstract
With the increasing diversification of modern home textile design (HTD), the integration of traditional cultural elements has become an important trend. This study investigates the impact of symmetry in traditional patterns on the optimization of home textile product design and examines its role [...] Read more.
With the increasing diversification of modern home textile design (HTD), the integration of traditional cultural elements has become an important trend. This study investigates the impact of symmetry in traditional patterns on the optimization of home textile product design and examines its role in consumer acceptance. First, the affinity diagram method was employed to collect core affective vocabularies. Based on a selection of home textile products incorporating traditional patterns available in the market, a questionnaire was developed to solicit consumers’ evaluations of these affective descriptors. Principal component analysis (PCA) was conducted to extract key perceptual dimensions, with particular emphasis on the influence of pattern symmetry on consumer perception. Subsequently, the Fuzzy Analytic Hierarchy Process (FAHP) was applied to determine the relative weights of the affective terms. Incorporating expert input, five representative traditional patterns from the Homespun Fabric of Jiangnan (HFoJ) were selected and reinterpreted with a focus on symmetrical design. Through the Quality Function Deployment (QFD) method, the effective vocabularies were mapped to the redesigned patterns, leading to the identification of the scheme that most effectively embodied the symmetrical principle for integration into HTD. Finally, the Grey Relation Analysis (GRA) was used to conduct a comprehensive evaluation of multiple design alternatives. The optimal design was selected and subsequently validated through consumer feedback to assess its market feasibility. This study contributes a symmetric approach to the application of symmetry in traditional pattern design, offering both traditional insights and practical guidance for the modernization and innovative transformation of cultural elements in HTD. Full article
(This article belongs to the Special Issue Symmetry/Asymmetry in Computer-Aided Industrial Design)
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17 pages, 3264 KiB  
Article
Potential of Textile Wastewater Decolorization Using Cation Exchange Membrane Electrolysis Coupled with Magnesium Salt Precipitation (CEM-MSP)
by Yujing Zhao, Nuo Cheng, Ruihan Jiang, Jian Jiao, Chen Chen, Jiahao Liang, Longfeng Hu, Hesong Wang and Jinlong Wang
Water 2025, 17(12), 1785; https://doi.org/10.3390/w17121785 - 14 Jun 2025
Viewed by 364
Abstract
To overcome the low efficiency, high cost and less environmentally friendly limitations in existing textile wastewater disposal technology, an innovative approach of cation exchange membrane electrolysis coupled with magnesium salt precipitation (CEM-MSP) was implemented. This method simultaneously achieved the high-efficiency adsorption decolorization of [...] Read more.
To overcome the low efficiency, high cost and less environmentally friendly limitations in existing textile wastewater disposal technology, an innovative approach of cation exchange membrane electrolysis coupled with magnesium salt precipitation (CEM-MSP) was implemented. This method simultaneously achieved the high-efficiency adsorption decolorization of dyes and the recovery of lye. The results indicated that cation exchange membrane electrolysis with MgSO4 added to the anode chamber (CEM-EA) exhibited excellent decolorization performance on DB86 dye and achieved low residual Mg2+ concentration. Furthermore, the adsorption mechanism of Mg(OH)2 on DB86 was systematically investigated. The adsorption process fitted with the first-order kinetic, where the adsorption of DB86 by Mg(OH)2 was dominated by electrostatic attraction. Detailed comparison of the four systems demonstrated that CEM-EA was superior to the single magnesium addition method (85.24%) or the stand-alone membrane electrolysis method (10.36%), with 99% decolorization efficiency. In comparison to the cation exchange membrane electrolysis with MgSO4 added to the cathode chamber (CEM-EC), the CEM-EA could diminish the Mg2+ concentration in the effluent to facilitate the lye recovery while guaranteeing the decolorization efficiency. In addition, the DB86 adsorption behavior during the formation of Mg(OH)2 in the cathode chamber was investigated. The Mg(OH)2 particles were relatively dense copper-blue agglomerates with a thin lamellar layer on the surface. Notably, only slight mass contamination was observed on the cation exchange membrane (CEM) surface after multiple cycles. Minor CEM contamination illustrated the stable treatment efficiency of the CEM-EA after several cycles. This study constructed a novel approach integrating membrane electrolysis with magnesium salt precipitation, delivering valuable technical solutions for textile wastewater disposal. Full article
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17 pages, 4206 KiB  
Article
Fluorescent Hyperbranched Polymers and Cotton Fabrics Treated with Them as Innovative Agents for Antimicrobial Photodynamic Therapy and Self-Disinfecting Textiles
by Desislava Staneva, Paula Bosch, Petar Grozdanov, Ivanka Nikolova and Ivo Grabchev
Macromol 2025, 5(2), 26; https://doi.org/10.3390/macromol5020026 - 11 Jun 2025
Viewed by 560
Abstract
The results of this study, which involved treating cotton fabrics with three fluorescent hyperbranched polymers modified with 1,8-naphthalamide (P1), acridine (P2), and dansyl (P3) groups, could have applications in the development of antimicrobial textiles with self-disinfecting ability. The polymers, dissolved in DMF/water solution, [...] Read more.
The results of this study, which involved treating cotton fabrics with three fluorescent hyperbranched polymers modified with 1,8-naphthalamide (P1), acridine (P2), and dansyl (P3) groups, could have applications in the development of antimicrobial textiles with self-disinfecting ability. The polymers, dissolved in DMF/water solution, were deposited on the cotton fabric using the exhaustion method. The fabrics were thoroughly analyzed by reflection spectra, CIEL*a*b* coordinates, and color difference (∆E). The release of the polymers from the cotton surface was studied in a phosphate buffer with pH = 7.4 and an acetate buffer with pH = 4.5 at 37 °C for 10 h. It is shown that at pH = 7.4, the release of the three polymers occurs slowly (about 4–5%). In contrast, in an acidic medium, due to protonation of the tertiary amino group of 1,8-naphthalimide, P1 passes significantly more readily into the aqueous solution (35%). The possibility of singlet oxygen (1O2) generation by the polymers and the cotton fabrics treated with them under sunlight irradiation was followed using an iodometric method. The microbiological activity was investigated against Gram-positive Bacillus cereus and Gram-negative Pseudomonas aeruginosa as model bacterial strains in the dark and after irradiation with sunlight. The antimicrobial activity of the polymers increased after light irradiation, as 1O2 attacks and destroys the bacterial cell membrane. Scanning electron microscopy showed that a stable bacterial biofilm had formed on the untreated cotton surface, but treatment with hyperbranched polymers prevented its formation. However, many bacteria were still observed on the fiber surface when the microbial test was performed in the dark, whereas only a few single bacteria were noticed after the illumination. A virucidal effect against respiratory viruses HRSV-2 and AAdV-5 was observed only after irradiation with sunlight. Full article
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