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Search Results (3,072)

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Keywords = temperature field distribution

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13 pages, 3051 KB  
Article
Leakage Current Equalization via Thick Semiconducting Coatings Suppresses Pin Corrosion in Disc Insulators
by Cong Zhang, Hongyan Zheng, Zikui Shen, Junbin Su, Yibo Yang, Heng Zhong and Xiaotao Fu
Energies 2025, 18(19), 5246; https://doi.org/10.3390/en18195246 - 2 Oct 2025
Abstract
In coastal hot and humid regions, the steel pin of AC porcelain insulators often suffers from severe electrochemical corrosion due to surface contamination and moisture, leading to insulator string breakage. Contrary to the common belief that AC corrosion is negligible, this study reveals [...] Read more.
In coastal hot and humid regions, the steel pin of AC porcelain insulators often suffers from severe electrochemical corrosion due to surface contamination and moisture, leading to insulator string breakage. Contrary to the common belief that AC corrosion is negligible, this study reveals the significant role of the DC component in leakage currents and the synergy of this DC component with localized high current densities in accelerating corrosion, based on field investigations and experiments. Using a simulation model based on the Suwarno equivalent circuit, it is shown that non-linear contamination causes highly non-sinusoidal leakage currents, with total harmonic distortion up to 40% and a DC component of approximately 22%. To mitigate this, a conductive silicone rubber coating is proposed to block moisture and distribute leakage current evenly, keeping surface current density below the critical threshold of 100 A/m2. Simulations indicate that a 2 mm thick coating with conductivity around 10−4 S/m effectively reduces current density to a safe level. Accelerated corrosion tests confirm that this conductive coating significantly suppresses pitting corrosion caused by high current densities, outperforming traditional insulating coatings. This study presents a practical and effective approach for protecting AC insulators in harsh environments, contributing to improved transmission line reliability in high-temperature and high-humidity regions. Full article
(This article belongs to the Special Issue Advances in High-Voltage Engineering and Insulation Technologies)
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21 pages, 5676 KB  
Article
Surface Deformation Monitoring and Spatiotemporal Evolution Analysis of Open-Pit Mines Using Small-Baseline Subset and Distributed-Scatterer InSAR to Support Sustainable Mine Operations
by Zhouai Zhang, Yongfeng Li and Sihua Gao
Sustainability 2025, 17(19), 8834; https://doi.org/10.3390/su17198834 - 2 Oct 2025
Abstract
Open-pit mining often induces geological hazards such as slope instability, surface subsidence, and ground fissures. To support sustainable mine operations and safety, high-resolution monitoring and mechanism-based interpretation are essential tools for early warning, risk management, and compliant reclamation. This study focuses on the [...] Read more.
Open-pit mining often induces geological hazards such as slope instability, surface subsidence, and ground fissures. To support sustainable mine operations and safety, high-resolution monitoring and mechanism-based interpretation are essential tools for early warning, risk management, and compliant reclamation. This study focuses on the Baorixile open-pit coal mine in Inner Mongolia, China, where 48 Sentinel-1 images acquired between 3 March 2017 and 23 April 2021 were processed using the Small-Baseline Subset and Distributed-Scatterer Interferometric Synthetic Aperture Radar (SBAS-DS-InSAR) technique to obtain dense and reliable time-series deformation. Furthermore, a Trend–Periodic–Residual Subspace-Constrained Regression (TPRSCR) method was developed to decompose the deformation signals into long-term trends, seasonal and annual components, and residual anomalies. By introducing Distributed-Scatterer (DS) phase optimization, the monitoring density in low-coherence regions increased from 1055 to 338,555 points (approximately 321-fold increase). Deformation measurements at common points showed high consistency (R2 = 0.97, regression slope = 0.88; mean rate difference = −0.093 mm/yr, standard deviation = 3.28 mm/yr), confirming the reliability of the results. Two major deformation zones were identified: one linked to ground compaction caused by transportation activities, and the other associated with minor subsidence from pre-mining site preparation. In addition, the deformation field exhibits a superimposed pattern of persistent subsidence and pronounced seasonality. TPRSCR results indicate that long-term trend rates range from −14.03 to 14.22 mm/yr, with a maximum periodic amplitude of 40 mm. Compared with the Seasonal-Trend decomposition using LOESS (STL), TPRSCR effectively suppressed “periodic leakage into trend” and reduced RMSEs of total, trend, and periodic components by 48.96%, 93.33%, and 89.71%, respectively. Correlation analysis with meteorological data revealed that periodic deformation is strongly controlled by precipitation and temperature, with an approximately 34-day lag relative to the temperature cycle. The proposed “monitoring–decomposition–interpretation” framework turns InSAR-derived deformation into sustainability indicators that enhance deformation characterization and guide early warning, targeted upkeep, climate-aware drainage, and reclamation. These metrics reduce downtime and resource-intensive repairs and inform integrated risk management in open-pit mining. Full article
(This article belongs to the Special Issue Application of Remote Sensing and GIS in Environmental Monitoring)
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18 pages, 2078 KB  
Article
Unraveling Belowground Community Assembly in Temperate Steppe Ecosystems
by Ping Wang, Shuai Shang, Zhengyang Rong, Jingkuan Sun, Jinzhao Ma, Zhaohua Lu, Fei Wang and Zhanyong Fu
Biology 2025, 14(10), 1350; https://doi.org/10.3390/biology14101350 - 2 Oct 2025
Abstract
The composition, architecture, and plant traits of temperate steppe communities are intricately associated with environmental factors. However, most studies primarily focus on aboveground observations, often overlooking the critical role of belowground root systems. Here we conducted a field survey at a large-regional scale [...] Read more.
The composition, architecture, and plant traits of temperate steppe communities are intricately associated with environmental factors. However, most studies primarily focus on aboveground observations, often overlooking the critical role of belowground root systems. Here we conducted a field survey at a large-regional scale to investigate the composition of temperate steppe communities and plant root traits. Cluster analysis, correspondence analysis and Pearson correlation coefficient matrix method were employed to classify vegetation associations based on plant community composition and root traits. The principal driving and limiting factors shaping plant root communities were systematically investigated. The results showed that the temperate steppe was categorized into three community subtypes: meadow steppe, typical steppe, and desert steppe, comprising five plant groups and thirteen plant associations. The RLFS analysis, based on belowground architectural and functional traits, demonstrated a spatial gradient differentiation with three ecological adaptations: tufted herbs, rhizome herbs, and non-tufted or rhizome herbs. Key environmental driving factors for meadow steppe included precipitation, soil carbon, nitrogen, and phosphorus content, while the average growing-season temperature as a limiting factor. The environmental driving factors for the typical steppe were not apparent, and the limiting factor was water. For the desert steppe, the environmental driving factors were altitude and average growing-season temperature. These findings reveal notable spatial heterogeneity and a distinct distribution pattern in community composition and vegetation classification based on belowground root traits in the Inner Mongolia steppes. Full article
(This article belongs to the Section Ecology)
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19 pages, 2976 KB  
Article
Numerical and Experimental Analyses of Flue Gas Emissions, from Biomass Pellet Combustion in a Domestic Boiler
by Nevena Mileva, Penka Zlateva, Martin Ivanov, Kalin Krumov, Angel Terziev and Adriana Comarla
Eng 2025, 6(10), 257; https://doi.org/10.3390/eng6100257 - 2 Oct 2025
Abstract
This study explores the combustion behavior of three biomass pellet types—wood (W), sunflower husk (SH), and a mixture of wood and sunflower husks (W/SH)—in a residential hot water boiler. Experiments were carried out under two air supply regimes (40%/60% and 60%/40% primary to [...] Read more.
This study explores the combustion behavior of three biomass pellet types—wood (W), sunflower husk (SH), and a mixture of wood and sunflower husks (W/SH)—in a residential hot water boiler. Experiments were carried out under two air supply regimes (40%/60% and 60%/40% primary to secondary air) to measure flue gas concentrations of oxygen (O2), carbon monoxide (CO), and nitrogen oxides (NOx). The results indicate that SH pellets generate the highest emissions (CO: 1095.3 mg/m3, NOx: 679.3 mg/m3), while W pellets achieve the lowest (CO: 0.3 mg/m3, NOx: 194.1 mg/m3). The mixed W/SH pellets produce intermediate values (CO: 148.7 mg/m3, NOx: 201.8 mg/m3). Overall boiler efficiency for all tested fuels ranged from 90.3% to 91.4%. Numerical simulations using ANSYS CFX (2024 R2 (24.2)) were performed to analyze temperature distribution, flue gas composition, and flow fields, showing good agreement with experimental outlet temperature and emission trends. These findings emphasize that both pellet composition and air distribution significantly influence efficiency and emissions, offering guidance for optimizing small-scale biomass boiler operation. Full article
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16 pages, 5242 KB  
Article
Temperature Field Construction in Qinghai-Gonghe Basin Based on Integrated Geophysical Inversion Results
by Yuanyuan Ming, Zhaofa Zeng, Puyuan Tian, Zhengpu Cheng, Fang Lu, Linyou Zhang, Qiuchen Li, Xue Niu and Shujun Guo
Appl. Sci. 2025, 15(19), 10630; https://doi.org/10.3390/app151910630 - 1 Oct 2025
Abstract
As a clean and renewable energy source with huge reserves, hot dry rock geothermal resources have received wide attention. The geothermal field plays a crucial role in studying the heat source mechanism of hot dry rock, defining target areas, and evaluating resources. In [...] Read more.
As a clean and renewable energy source with huge reserves, hot dry rock geothermal resources have received wide attention. The geothermal field plays a crucial role in studying the heat source mechanism of hot dry rock, defining target areas, and evaluating resources. In this study, the three-dimensional structural inversion of the Gonghe Basin is carried out using magnetotelluric sounding, and the Curie isothermal surface is obtained by analyzing regional aeromagnetic data. By coupling low-resistance and high-conductivity zones with temperature distribution and integrating the Curie isothermal surface with high-temperature anomalies of some melts, we constructed an initial temperature field model based on comprehensive geophysical data. The temperature field model of the Gonghe Basin is established by using the adaptive finite-element temperature conduction control equation and the constraints of the temperature data from geothermal wells. The temperature field model provides a basis for the future exploration of hot dry rock resources in the Gonghe area. Full article
(This article belongs to the Section Earth Sciences)
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86 pages, 1368 KB  
Article
Nonlinear Quasi-Classical Model of Isothermal Relaxation Polarization Currents in Functional Elements of Microelectronics, Optoelectronics, and Fiber Optics Based on Crystals with Ionic-Molecular Chemical Bonds with Complex Crystalline Structure
by Valeriy Kalytka, Ali Mekhtiyev, Yelena Neshina, Aleksey Yurchenko, Aliya Аlkina, Felix Bulatbayev, Valeriy Issayev, Kanat Makhanov, Dmitriy Lukin, Damir Kayumov and Alexandr Zaplakhov
Crystals 2025, 15(10), 863; https://doi.org/10.3390/cryst15100863 - 30 Sep 2025
Abstract
In this article, the mechanism of relaxation polarization currents occurring at a constant temperature (isothermal process) in crystals with ionic-molecular chemical bonds (CIMBs) in an alternating electric field was investigated. Methods of the quasi-classical kinetic theory of dielectric relaxation, based on solutions of [...] Read more.
In this article, the mechanism of relaxation polarization currents occurring at a constant temperature (isothermal process) in crystals with ionic-molecular chemical bonds (CIMBs) in an alternating electric field was investigated. Methods of the quasi-classical kinetic theory of dielectric relaxation, based on solutions of the nonlinear system of Fokker–Planck and Poisson equations (for the blocking electrode model) and perturbation theory (by expanding into an infinite series in powers of a dimensionless small parameter) were used. Generalized nonlinear mathematical expressions for calculating the complex amplitudes of relaxation modes of the volume-charge distribution of the main charge carriers (ions, protons, water molecules, etc.) were obtained. On this basis, formulas for the current density of relaxation polarization (for transient processes in a dielectric) in the k-th approximation of perturbation theory were constructed. The isothermal polarization currents are investigated in detail in the first four approximations (k = 1, 2, 3, 4) of perturbation theory. These expressions will be applied in the future to compare the results of theory and experiment, in analytical studies of the kinetics of isothermal ion-relaxation (in crystals with hydrogen bonds (HBC), proton-relaxation) polarization and in calculating the parameters of relaxers (molecular characteristics of charge carriers and crystal lattice parameters) in a wide range of field parameters (0.1–1000 MV/m) and temperatures (1–1550 K). Asymptotic (far from transient processes) recurrent formulas are constructed for complex amplitudes of relaxation modes and for the polarization current density in an arbitrary approximation k of perturbation theory with a multiplicity r by the polarizing field (a multiple of the fundamental frequency of the field). The high degree of reliability of the theoretical results obtained is justified by the complete agreement of the equations of the mathematical model for transient and stationary processes in the system with a harmonic external disturbance. This work is of a theoretical nature and is focused on the construction and analysis of nonlinear properties of a physical and mathematical model of isothermal ion-relaxation polarization in CIMB crystals under various parameters of electrical and temperature effects. The theoretical foundations for research (construction of equations and working formulas, algorithms, and computer programs for numerical calculations) of nonlinear kinetic phenomena during thermally stimulated relaxation polarization have been laid. This allows, with a higher degree of resolution of measuring instruments, to reveal the physical mechanisms of dielectric relaxation and conductivity and to calculate the parameters of a wide class of relaxators in dielectrics in a wide experimental temperature range (25–550 K). Full article
(This article belongs to the Section Inorganic Crystalline Materials)
11 pages, 6376 KB  
Article
Study of Electro-Chemical Properties and Conditions of Flame Stabilization of Promising Fuel Mixtures CH4/H2 and NH3/H2
by Vladimir Lukashov, Andrey Tupikin, Yuriy Dubnishchev and Olga Zolotukhina
Energies 2025, 18(19), 5198; https://doi.org/10.3390/en18195198 - 30 Sep 2025
Abstract
This paper investigates the combustion characteristics of promising decarbonized fuel mixtures—methane/hydrogen (CH4/H2) and ammonia/hydrogen (NH3/H2)—with a focus on how they interact with external electric fields. The key findings are that these flames possess significant electrochemical [...] Read more.
This paper investigates the combustion characteristics of promising decarbonized fuel mixtures—methane/hydrogen (CH4/H2) and ammonia/hydrogen (NH3/H2)—with a focus on how they interact with external electric fields. The key findings are that these flames possess significant electrochemical properties, allowing for non-intrusive control over their stabilization, shape, and structure using relatively weak electric fields. The research combines experimental techniques like volt-ampere characteristic (VAC) measurement and advanced Hilbert visualization to analyze flame deformation, temperature distribution, and species concentration. Two orientations of the electric field were considered: transverse and longitudinal. For the transverse field, an assessment of the degree of flame deformation was made, indicating the preservation of the laminar combustion regime. In the longitudinal electric field, a change in the combustion stabilization mode was observed, which was detected through visualization and current-voltage characteristics (CVC). Full article
(This article belongs to the Special Issue Science and Technology of Combustion for Clean Energy)
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14 pages, 2003 KB  
Article
Changes in Camelina sativa Yield Based on Temperature and Precipitation Using FDA
by Małgorzata Graczyk, Danuta Kurasiak-Popowska and Grażyna Niedziela
Agriculture 2025, 15(19), 2051; https://doi.org/10.3390/agriculture15192051 - 30 Sep 2025
Abstract
Camelina (Camelina sativa) is an oilseed crop of increasing importance, valued not only for its adaptability to diverse environmental conditions and potential for sustainable agriculture but also for its economic advantages, including low input requirements and suitability for biofuel production and [...] Read more.
Camelina (Camelina sativa) is an oilseed crop of increasing importance, valued not only for its adaptability to diverse environmental conditions and potential for sustainable agriculture but also for its economic advantages, including low input requirements and suitability for biofuel production and niche markets. This study examines the relationship between camelina yield and climatic variables—specifically temperature and precipitation—based on a ten-year field experiment conducted in Poland. To capture the temporal dynamics of weather conditions, Functional Data Analysis (FDA) was applied to daily temperature and precipitation data. The analysis revealed that yield variability was strongly influenced by the length of the vegetative period and specific weather patterns in April and July. Higher yields were recorded in years characterized by moderate spring temperatures, elevated temperatures in July, and evenly distributed rainfall during the early generative growth stages. The Maximal Information Coefficient (MIC) confirmed the relevance of these variables, with the duration of the vegetative phase showing the strongest correlation with yield. Cluster analysis further distinguished high- and low-yield years based on functional weather profiles. The FDA-based approach provided clear, interpretable insights into climate–yield interactions and demonstrated greater effectiveness than traditional regression models in capturing complex, time-dependent relationships. These findings enhance our understanding of camelina’s response to climatic variability and support the development of predictive tools for resilient, climate-smart crop management. Full article
(This article belongs to the Section Ecosystem, Environment and Climate Change in Agriculture)
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36 pages, 2307 KB  
Review
Ecological Synthesis of Precious Metal Nanoparticles: Harnessing the Potential of Marine Algae Biomass
by Laura Bulgariu
Nanomaterials 2025, 15(19), 1492; https://doi.org/10.3390/nano15191492 - 30 Sep 2025
Abstract
The synthesis of precious metal nanoparticles (PM-NPs) is an important field of research that has expanded significantly in recent decades due to their numerous applications. Therefore, research has been directed toward developing green methods for the synthesis of such nanoparticles that are simple, [...] Read more.
The synthesis of precious metal nanoparticles (PM-NPs) is an important field of research that has expanded significantly in recent decades due to their numerous applications. Therefore, research has been directed toward developing green methods for the synthesis of such nanoparticles that are simple, safe, eco-friendly, efficient, and sustainable. In this context, the use of marine algae biomass for the green synthesis of PM-NPs can be a viable large-scale alternative, as algae are easy to cultivate, have a rapid growth rate, and are widely distributed across many regions of the globe. The reduction of precious metal ions takes place at the surface of algae biomass particles, and the characteristics of the resulting precious metal nanoparticles depend on the experimental conditions (pH, amount of algae biomass, contact time, etc.), as well as on the type of algae biomass and the speciation form of the metal ions in the solution. All these factors significantly influence the properties of precious metal nanoparticles, and their understanding allows the development of synthesis strategies that can be applied on a large scale. The aim of this review is to provide a comprehensive overview of the way in which PM-NPs can be synthesized using algae biomass. The importance of experimental conditions (such as pH, contact time, amount of biomass, type of algal biomass, temperature, etc.) on the synthesis efficiency, as well as the elementary steps involved in the synthesis, is also discussed in this study. Particular attention has been paid to the analytical methods used for characterizing PM-NPs, as they provide crucial data regarding their structure and composition. These aspects are essential for identifying the practical applications of PM-NPs. Full article
(This article belongs to the Section Environmental Nanoscience and Nanotechnology)
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14 pages, 3978 KB  
Article
Research on the Solidification Structure, Properties and Composition Segregation of GCr15 Bearing Steel Under Double-Electrode Regulation
by Qinghe Xiao, Shengli Li, Siyao Liu, Jiyu Zhao, Xingang Ai, Ye Zhou, Xincheng Miao and Min Wang
Metals 2025, 15(10), 1086; https://doi.org/10.3390/met15101086 - 29 Sep 2025
Abstract
To explore the influence of double-electrode regulation technology on the solidification microstructure and properties of GCr15 bearing steel, the double-electrode insertion process was employed in this study, combined with metallographic analysis, mechanical property testing, and electron probe composition characterization. We analyzed the mechanisms [...] Read more.
To explore the influence of double-electrode regulation technology on the solidification microstructure and properties of GCr15 bearing steel, the double-electrode insertion process was employed in this study, combined with metallographic analysis, mechanical property testing, and electron probe composition characterization. We analyzed the mechanisms of solidification microstructure evolution and mechanical property improvement, as well as the composition segregation control effect, of GCr15 steel under double-electrode regulation. The results show that the double-electrode technology significantly refines the microstructure and improves the internal quality of the ingot by optimizing the temperature field and electromagnetic field distribution in the molten pool and enhancing the internal flow of the melt. The tensile strengths in the upper and middle parts were increased by 84.6% and 29.6%, respectively, which can be attributed to the uniform distribution of carbides at the grain boundaries and the reduction of segregation. Composition analysis indicates that the macroscopic segregation index of C element was decreased under the dual-electrode process. This research provides a theoretical basis and process optimization direction for the high-quality preparation of high-carbon chromium bearing steel. Full article
(This article belongs to the Special Issue Green Super-Clean Steels)
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21 pages, 3393 KB  
Article
Predicting the Potential Spread of Diabrotica virgifera virgifera in Europe Using Climate-Based Spatial Risk Modeling
by Ioana Grozea, Diana Maria Purice, Snejana Damianov, Levente Molnar, Adrian Grozea and Ana Maria Virteiu
Insects 2025, 16(10), 1005; https://doi.org/10.3390/insects16101005 - 27 Sep 2025
Abstract
Diabrotica virgifera virgifera Le Conte, 1868 (Coleoptera: Chrysomelidae), known as the western corn rootworm, is one of the most important alien insect pests affecting maize crops globally. It causes significant economic losses by feeding on the roots, which affects plant stability and nutrient [...] Read more.
Diabrotica virgifera virgifera Le Conte, 1868 (Coleoptera: Chrysomelidae), known as the western corn rootworm, is one of the most important alien insect pests affecting maize crops globally. It causes significant economic losses by feeding on the roots, which affects plant stability and nutrient absorption, as well as by attacking essential aerial organs (leaves, silk, pollen). Since its accidental introduction into Europe, the species has expanded its range across maize-growing regions, raising concerns about future distribution under climate change. This study aimed to estimate the risk of pest establishment across Europe over three future time frames (2034, 2054, 2074) based on geographic coordinates, climate data, and maize distribution. Spatial simulations were performed in QGIS using national centroid datasets, risk classification criteria, and temperature anomaly maps derived from Copernicus and ECA&D databases for 1992–2024. The results indicate consistently high risk in southern and southeastern regions, with projected expansion toward central and western areas by 2074. Risk zones showed clear spatial aggregation and directional spread correlated with warming trends and maize availability. The pest’s high reproductive potential, thermal tolerance, and capacity for human-assisted dispersal further support these predictions. The model emphasizes the need for expanded surveillance in at-risk zones and targeted policies in areas where D. v. virgifera has not yet established. Future work should refine spatial predictions using field validation, genetic monitoring, and dispersal modeling. The results contribute to anticipatory pest management planning and can support sustainable maize production across changing agroclimatic zones in Europe. Full article
(This article belongs to the Section Insect Pest and Vector Management)
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18 pages, 2763 KB  
Article
Study on Numerical Simulation of Blast Furnace Injection of Low-Rank Coal by Hydrothermal Carbonization
by Yu Zeng, Nan Zhang, Andrey Karasev, Xiaojun Ning, Guangwei Wang, Jianliang Zhang and Chuan Wang
Energies 2025, 18(19), 5141; https://doi.org/10.3390/en18195141 - 27 Sep 2025
Abstract
This study carried out a detailed investigation into the potential application of hydrothermally treated bituminous coal (hydrochar) as an injectant in blast furnace (BF) ironmaking. A tuyere model was constructed through simulation methods, and the influence of hydrochar injection on the thermal conditions [...] Read more.
This study carried out a detailed investigation into the potential application of hydrothermally treated bituminous coal (hydrochar) as an injectant in blast furnace (BF) ironmaking. A tuyere model was constructed through simulation methods, and the influence of hydrochar injection on the thermal conditions within the BF hearth was also thoroughly analyzed. The results show that the gas flow velocity at the lower part of the tuyere of hydrochar injection increases, and the residual carbon mass fraction of the tuyere decreases. As the oxygen-enriched concentration increases, the CO concentration decreases. The CO concentration in the swirl zone after hydrochar injection is the highest, reaching 43.93%. The distributions of CO and CO2 exhibit opposite tendencies. Following hydrochar injection, a marked rise in temperature is observed. At an oxygen enrichment level of 30%, the tuyere zone temperature associated with hydrochar injection peaks, surpassing 2700 K. The corresponding pulverized coal burnout rate is also the highest. Thus, the injection of hydrochar has a positive impact on the air flow and temperature field, which can effectively maintain the heat balance and is conducive to strengthening BF smelting. Full article
(This article belongs to the Section I1: Fuel)
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20 pages, 4247 KB  
Article
Numerical Analysis of Thermal–Structural Coupling for Subsea Dual-Channel Connector
by Feihong Yun, Yuming Du, Dong Liu, Xiaofei Wu, Minggang Tang, Qiuying Yan, Peng Gao, Yu Chen, Xu Zhai, Hanyu Sun, Songlin Zhang, Shuqi Lin and Haiyang Xu
J. Mar. Sci. Eng. 2025, 13(10), 1867; https://doi.org/10.3390/jmse13101867 - 26 Sep 2025
Abstract
In deep-sea oil and gas development scenarios, deep-sea dual-channel connectors often face the risk of seal failure due to internal and external temperature difference loads. To address this issue, this paper systematically establishes equivalent heat transfer models for the key parts of the [...] Read more.
In deep-sea oil and gas development scenarios, deep-sea dual-channel connectors often face the risk of seal failure due to internal and external temperature difference loads. To address this issue, this paper systematically establishes equivalent heat transfer models for the key parts of the connector based on the third-type boundary condition. On this basis, the quantitative correlation between the equivalent thermal conductivity, composite heat transfer coefficient and temperature of each part is explored. Using the finite element numerical simulation method, the transient temperature field of the connector under three working conditions (heating, cooling and temperature shock) is simulated and analyzed, revealing the temperature distribution characteristics and temperature change trends of the maximum temperature difference of each key component of the connector; combined with thermal–structural coupling simulation, the temperature field is converted into static load, to determine the behavior of the contact stress on the sealing surface under different temperature–pressure coupling working conditions; in addition, by placing the test prototype in a high-low temperature cycle chamber, the seal performance tests under pressurized and non-pressurized working conditions are carried out to verify the reliable sealing performance of the connector under variable temperature conditions. The results of this paper provide comprehensive theoretical support and an experimental basis for the thermodynamic optimization design of deep-sea connectors and the improvement of the reliability of the sealing system. Full article
(This article belongs to the Section Ocean Engineering)
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15 pages, 3809 KB  
Article
Co-Polymerized P(AN-co-IA)-Derived Electrospun Nanofibers with Improved Graphitization via Dual-Metallocene Integration at Low Temperature
by Taewoo Kim, Tae Hoon Ko, Byoung-Suhk Kim, Yong-Sik Chung and Hak Yong Kim
Inorganics 2025, 13(10), 318; https://doi.org/10.3390/inorganics13100318 - 26 Sep 2025
Abstract
In this study, COOH-functionalized co-polymer of acrylonitrile and itaconic acid (P(AN-co-IA)) is synthesized via free radical copolymerization using DMSO as solvent. The continuous non-aligned carbon nanofibers (CNFs) with different amounts of metallocene (zirconocene and ferrocene) are fabricated through electrospinning, followed by a series [...] Read more.
In this study, COOH-functionalized co-polymer of acrylonitrile and itaconic acid (P(AN-co-IA)) is synthesized via free radical copolymerization using DMSO as solvent. The continuous non-aligned carbon nanofibers (CNFs) with different amounts of metallocene (zirconocene and ferrocene) are fabricated through electrospinning, followed by a series of heat treatments under an inert atmosphere. The influence of metallocenes on electrospun carbon nanofiber diameter, alignment, and structural ordering was systematically investigated using FESEM, XRD, Raman spectroscopy, and TEM. Incorporation of dual metallocenes significantly alters the fiber diameter, improves orientation, and promotes graphitic domain formation at 1100 °C, a much lower temperature than conventional graphitization. The optimized sample (Zr-Fe)1-P(AN-co-IA)-eGNF) exhibited the lowest ID/IG ratio compared to pristine and all prepared samples, indicating an improved degree of graphitization due to the uniform distribution of metallocene nanofiber matrix. Furthermore, the electrical conductivity of optimized (Zr-Fe)1-P(AN-co-IA)-eGNF reached the highest value (1654.5 S/m) due to the high degree of graphitization of carbon nanofibers. These results show that integrating dual metallocene is an efficient pathway for tailoring nanofiber morphology and achieving conductive, structurally ordered electrospun eGNFs at reduced temperatures, with potential applications in various fields. Full article
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23 pages, 4868 KB  
Article
Design and Experiment of Drying Equipment for Alfalfa Bales
by Jianqiang Du, Zhiwen Sun and Zeqi Chen
Agriculture 2025, 15(19), 2000; https://doi.org/10.3390/agriculture15192000 - 24 Sep 2025
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Abstract
Inefficient drying of alfalfa round bales causes significant nutrient loss (up to 50%) and quality degradation due primarily to uneven drying in existing processing methods. To address this challenge requiring dedicated equipment and optimized processes, this study developed a specialized hot-air drying test [...] Read more.
Inefficient drying of alfalfa round bales causes significant nutrient loss (up to 50%) and quality degradation due primarily to uneven drying in existing processing methods. To address this challenge requiring dedicated equipment and optimized processes, this study developed a specialized hot-air drying test bench (CGT-1). A coupled heat and mass transfer model was established, and 3D dynamic simulations of temperature, humidity, and wind speed distributions within bales were performed using COMSOL multiphysics to evaluate drying inhomogeneity. Single-factor experiments and multi-factor response surface methodology (RSM) based on Box–Behnken design were employed to investigate the effects of hot air temperature (50–65 °C), wind speed (2–5 m/s), and air duct opening diameter (400–600 mm) on moisture content, drying rate, and energy consumption. Results demonstrated that larger duct diameters (600 mm) and higher wind speeds (5 m/s) significantly enhanced field uniformity. RSM optimization identified optimal parameters: temperature at 65 °C, wind speed of 5 m/s, and duct diameter of 600 mm, achieving a drying time of 119.2 min and a drying rate of 0.62 kg/(kg·min). Validation experiments confirmed the model’s accuracy. These findings provide a solid theoretical foundation and technical support for designing and optimizing alfalfa round-bale drying equipment. Future work should explore segmented drying strategies to enhance energy efficiency. Full article
(This article belongs to the Section Agricultural Technology)
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