Search Results (180)

Difficult, extreme operating conditions of parabolic antennas under precipitation and sub-zero temperatures require the creation of effective heating systems. The purpose of the research is to develop a multilayer coating containing two metal-ceramic layers, epoxy composite layers, carbon fabric, and an outer layer of basalt fabric, which allows for effective heating of the antenna, and to study the properties of this coating. The multilayer coating was formed on an aluminum base that was subjected to abrasive jet processing. The first and second metal-ceramic layers, Al₂O₃ + 5% Al, which were applied by high-speed multi-chamber cumulative detonation spraying (CDS), respectively, provide maximum adhesion strength to the aluminum base and high adhesion strength to the third layer of the epoxy composite containing Al₂O₃. On this not-yet-polymerized layer of epoxy composite containing Al₂O₃, a layer of carbon fabric (impregnated with epoxy resin) was formed, which serves as a resistive heating element. On top of this carbon fabric, a layer of epoxy composite containing Cr₂O₃ and SiO₂ was applied. Next, basalt fabric was applied to this still-not-yet-polymerized layer. Then, the resulting layered coating was compacted and dried. To study this multilayer coating, X-ray analysis, light and raster scanning microscopy, and transmission electron microscopy were used. The thickness of the coating layers and microhardness were measured on transverse microsections. The adhesion strength of the metal-ceramic coating layers to the aluminum base was determined by both bending testing and peeling using the adhesive method. It was established that CDS provides the formation of metal-ceramic layers with a maximum fraction of lamellae and a microhardness of 7900–10,520 MPa. In these metal-ceramic layers, a dispersed subgrain structure, a uniform distribution of nanoparticles, and a gradient-free level of dislocation density are observed. Such a structure prevents the formation of local concentrators of internal stresses, thereby increasing the level of dispersion and substructural strengthening of the metal-ceramic layers’ material. The formation of materials with a nanostructure increases their strength and crack resistance. The effectiveness of using aluminum, chromium, and silicon oxides as nanofillers in epoxy composite layers was demonstrated. The presence of structures near the surface of these nanofillers, which differ from the properties of the epoxy matrix in the coating, was established. Such zones, specifically the outer surface layers (OSL), significantly affect the properties of the epoxy composite. The results of industrial tests showed the high performance of the multilayer coating during antenna heating. Full article

Supercritical carbon dioxide (s-CO₂) Brayton cycles have emerged as a promising technology for high-efficiency power generation, owing to their compact architecture and favorable thermophysical properties. However, their performance degrades significantly under cold-climate conditions—such as those encountered in Greenland, Russia, Canada, Scandinavia, and Alaska—due to the proximity to the fluid’s critical point. This study investigates the behavior of the recompression Brayton cycle (RBC) under subzero ambient temperatures through the incorporation of low-critical-temperature additives to create CO₂-based binary mixtures. The working fluids examined include methane (CH₄), tetrafluoromethane (CF₄), nitrogen trifluoride (NF₃), and krypton (Kr). Simulation results show that CH₄- and CF₄-rich mixtures can achieve thermal efficiency improvements of up to 10 percentage points over pure CO₂. NF₃-containing blends yield solid performance in moderately cold environments, while Kr-based mixtures provide modest but consistent efficiency gains. At low compressor inlet temperatures, the high-temperature recuperator (HTR) becomes the dominant performance-limiting component. Optimal distribution of recuperator conductance (UA) favors increased HTR sizing when mixtures are employed, ensuring effective heat recovery across larger temperature differentials. The study concludes with a comparative exergy analysis between pure CO₂ and mixture-based cycles in RBC architecture. The findings highlight the potential of custom-tailored working fluids to enhance thermodynamic performance and operational stability of s-CO₂ power systems under cold-climate conditions. Full article

Coal-fired power plants exacerbate hazy weather under low winter temperatures, while sulphate ions (SO₄²⁻) in condensable particulate matter (CPM) emitted from ultra-low emission coal-fired power plants accelerate sulphate formation. The transformation of gaseous precursors (SO₂, NOx, NH₃) is the main pathway for sulphate formation by homogeneous or non-homogeneous reactions. For the sustainability of the world, in this paper, the effects of condensation temperature, H₂O, NO_X and NH₃ on the SO₄²⁻ generation characteristics under low-temperature rapid condensation conditions are investigated. With lower temperatures, especially from 0 °C cooling to −20 °C, the concentration of SO₄²⁻ was as high as 26.79 mg/m³. With a greater proportion of H₂SO₄ in the aerosol state, and a faster rate of sulphate formation, H₂O vapour condensation can provide a reaction site for sulphuric acid aerosol generation. SO₄²⁻ in CPM is mainly derived from the non-homogeneous reaction of SO₂. SO₃ is an important component of CPM and provides a reaction site for the formation of SO₄²⁻. SO₂ and SO₃, in combination with Stefan flow, jointly play a synergistic role in the generation of SO₄²⁻. The content of SO₄²⁻ was as high as 36.18 mg/m³. While NO_X sometimes inhibits the formation of SO₄²⁻, NH₃ has a key role in the nucleation process of CPM. NH₃, SO₂ and NO_X have been found to rapidly form sulphate with particle sizes up to 5 µm at sub-zero temperatures and promote the formation of sulphuric acid aerosols. Full article

This paper proposes a new functionalized oligosiloxane as a comonomer for polyester, designed to provide hydrophobic surface properties and enhance low-temperature impact resistance. The functionalization of polymer resin itself has attracted attention in the context of monomaterialization. Chemically designing the primary structure of not only polymers but also monomers is crucial for enhancing the intrinsic performance of the resin. However, little is known about oligosiloxane monomers for polyester that can provide oligosiloxane-like properties such as hydrophobicity and flexibility at low temperatures. Here, we report the functional design of a polyester material through silicone copolymerization. A novel comonomer was designed and synthesized to optimize both the molecular structure and the compatibility of the silicone segments, promoting uniform copolymer formation. Incorporating silicone into the polymer matrix reduced surface energy, thereby improving water repellency. Furthermore, the flexibility imparted by the silicone components effectively mitigated the brittleness of polyester at sub-zero temperatures, resulting in superior impact resistance. Structural analysis, contact angle measurements, and low-temperature impact tests were conducted on the copolymers. The results confirmed that optimizing comonomer design enables significant enhancement of both hydrophobicity and impact durability, contributing to the development of high-performance polyester materials suitable for demanding environments. Full article

Biochar has garnered considerable attention for its potential to improve soil properties due to its unique characteristics. However, the precise measurement of soil water content using electromagnetic sensors becomes challenging after biochar is incorporated. This study investigated the impact of biochar on soil water content measurement by adding biochar of varying dosages and particle sizes to a typical loess, under both room and subzero temperature conditions by using time domain reflectometry (TDR) and frequency domain reflectometry (FDR) techniques. The results demonstrate that biochar amendment significantly influenced the measurement accuracy of both TDR and FDR. A clear dosage-dependent relationship was observed, with measurement errors exhibiting progressive escalation as biochar addition rates increased. At room temperature, the root mean square error (RMSE) values for loess were remarkably low (TDR: 0.029; FDR: 0.093). In contrast, the 9% coarse-grained biochar-amended soil (BAS-9%C) showed substantially elevated RMSE values (TDR: 0.2006; FDR: 0.1468). Furthermore, comparative analysis revealed that particle size significantly affected measurement precision, with coarse-grained biochar demonstrating more pronounced interference effects than fine-grained biochar at equivalent application rates. At subzero temperatures, BAS-6%C exhibited significantly higher RMSE values (TDR: 0.1753; FDR: 0.2022) compared to BAS-6%F (TDR: 0.079; FDR: 0.1872). A dielectric mixing model was established for calculating the dielectric constant of BAS. In addition, calibration equations for accurately determining the water content of biochar-amended loess under both room and subzero temperature conditions were established. Furthermore, the mechanisms by which biochar influenced the performance of the TDR and FDR sensors are comprehensively discussed. These findings can provide valuable theoretical foundation and practical guidance for future soil improvement with biochar and accurate water content measurement in BAS. Full article

Metallic glasses (MGs) with excellent mechanical properties have significant applications in frontier technological fields such as medical, energy and aerospace industries. Recently, MGs have been considered as ideal candidates for subzero engineering applications due to their disordered atomic structure array. However, the mechanical properties and wear behaviors of MGs at subzero temperatures have rarely been explored. In this work, the wear properties and wear mechanisms of Zr-based MG were systematically evaluated at a subzero temperature of −50 °C. Compared to the wear results at room temperature, MG in a subzero environment shows a ~60% reduction in wear rate. The main contributing factor is that MG at room temperature will easily forms a thin, brittle oxide layer at the sliding interface, which will lead to oxidation, adhesive and abrasive wear on its surface, whereas these wear behaviors do not occur in subzero conditions where only abrasive wear occurs. Meanwhile, MG at subzero temperatures has a higher elastic modulus. These properties make MG more wear-resistant in subzero environments. The current study will provide new perspectives on the wear mechanisms and subsurface deformation of MG in subzero environments and valuable insights into the use of MG in subzero engineering applications, such as deep space and polar exploration. Full article

Polymer electrolyte membrane fuel cells (PEMFCs) are emerging as the next-generation powertrain for unmanned aerial vehicles (UAVs) due to their high energy density and long operating duration. PEMFCs are subject to icing and performance degradation problems at sub-zero temperatures, especially at high altitudes. Therefore, an effective preheating system is required to ensure stable PEMFC operation in high-altitude environments. This study aimed to mathematically model a shell-and-tube heat exchanger that utilizes waste heat recovery to prevent internal and external PEMFC damage in cold, high-altitude conditions. The waste heat from the PEMFC is estimated based on the thrust of the MQ-9 Reaper, and the proposed heat exchanger must be capable of heating air to −5 °C. As the heat exchanger utilizes only waste heat, the primary energy consumption arises from the coolant pumping process. Calculation results indicated that the proposed heat exchanger design improved the overall system efficiency by up to 15.7%, demonstrating its effectiveness in utilizing waste heat under aviation conditions. Full article

Winter concrete construction in cold regions faces significant challenges due to extreme subzero temperatures, and the harsh environment presents new requirement for cement-based materials to resist this hostile external condition. To address this gap, this study proposes gradient Joule heating (GJH) curing for steel-fiber-reinforced high-performance concrete (SFR-HPC) in subzero environments (−20 °C to −60 °C). Compared to room-temperature (RT) curing, GJH enabled specimens at −20 °C to −50 °C to achieve equivalent mechanical properties within a short curing duration; the compressive strength of the specimens cured at such low environmental temperature still reached up to that of the specimen cured by RT curing. Moreover, the compressive strength of the specimens cured at −60 °C retained >60 MPa despite reduced performance. Specifically, the specimens cured at −20 °C, −30 °C, −40 °C, and −50 °C for 2 days exhibited compressive strengths of 75.8 MPa, 79.2 MPa, 77.6 MPa, and 75.4 MPa, respectively. FTIR/XRD confirmed that the specimens cured by GJH showed hydration product integrity akin to RT-cured specimens. Moreover, it should be noted that early pore structure deteriorated with decreasing temperatures, but prolonged curing mitigated these differences. These results validate GJH as a viable method for in situ HPC production in extreme cold, addressing critical limitations of conventional winter construction techniques. Full article

In high-elevation or high-latitude permafrost areas, persistent subzero temperatures significantly impact the freeze–thaw durability of concrete structures. Traditional methods for studying the frost resistance of concrete in permafrost regions do not provide a complete picture for predicting properties, and new approaches are needed using, for example, machine learning algorithms. This study utilizes four machine learning models—Support Vector Machine (SVM), extreme learning machine (ELM), long short-term memory (LSTM), and radial basis function neural network (RBFNN)—to predict freeze–thaw damage factors in concrete under low and subzero temperature conservation conditions. Building on the prediction results, the optimal model is refined to develop a new machine learning model: the Sparrow Search Algorithm-optimized Extreme Learning Machine (SSA-ELM). Furthermore, the SHapley Additive exPlanations (SHAP) value analysis method is employed to interpret this model, clarifying the relationship between factors affecting the freezing resistance of concrete and freeze–thaw damage factors. In conclusion, the empirical formula for concrete freeze–thaw damage is compared and validated against the prediction results from the SSA-ELM model. The study results indicate that the SSA-ELM model offers the most accurate predictions for concrete freeze–thaw resistance compared to the SVM, ELM, LSTM, and RBFNN models. SHAP value analysis quantitatively confirms that the number of freeze–thaw cycles is the most significant input parameter affecting the freeze–thaw damage coefficient of concrete. Comparative analysis shows that the accuracy of the SSA-ELMDE prediction set is improved by 15.46%, 9.19%, 21.79%, and 11.76%, respectively, compared with the prediction results of SVM, ELM, LSTM, and RBF. This parameter positively influences the prediction results for the freeze–thaw damage coefficient. Curing humidity has the least influence on the freeze–thaw damage factor of concrete. Comparing the prediction results with empirical formulas shows that the machine learning model provides more accurate predictions. This introduces a new approach for predicting the extent of freeze–thaw damage to concrete under low and subzero temperature conservation conditions. Full article

This study introduced and evaluated a new Carbon Nanotube (CNT) sheet-based method for battery temperature management, aimed at enhancing the performance of Li-ion batteries in subzero environments. This method addressed critical challenges such as startup failures, capacity loss, and the poor performance of the Li-ion battery in extreme cold conditions, particularly for industrial applications like forklifts operating at temperatures as low as −30 °C. Without CNT heating, the battery performance dropped significantly in low-temperature environments. At −20 °C, the battery delivered only 63.4% of its capacity, with minimal self-heating. At −30 °C, it failed almost entirely, shutting down after just 45 s. In contrast, CNT heating greatly enhanced performance. The CNT sheet quickly warmed the battery to 0 °C—within 97 s at −20 °C and 141 s at −30 °C—allowing it to recover up to 90% of its capacity. These improvements resulted in enhanced capacity and energy output compared to batteries without CNT heating, which suffered from severe performance losses, including a negligible capacity and energy output under −30 °C. It can be concluded that the CNT sheet-based approach provides superior thermal conductivity, rapid heating, and exceptional energy conversion efficiency, enabling extended battery life and enhanced operational reliability in subzero environments. Its scalability and affordability position it as a transformative innovation for industrial applications reliant on efficient battery performance in extreme cold environments. Full article

Ferroelectric liquid crystals (FLCs) are key materials for high-speed electro-optical applications, yet achieving optimal properties over a broad temperature range down below room temperature remains a challenge. This study presents a novel series of systematically designed FLC mixtures, incorporating components with three degrees of chirality—achiral systems, with one center of chirality and with two centers of chirality—to optimize the mesomorphic stability, electro-optical response, and physicochemical properties. The strategic doping by chiral components up to a 0.2 weight fraction extends the temperature range of the ferroelectric phase while lowering the melting temperature. Notably, mixtures containing two chiral centers exhibit shorter helical pitches, while increasing chirality enhances the tilt angle of the director and spontaneous polarization. However, in a mixture containing all three types of chirality (CchM), spontaneous polarization decreases due to opposing vector contributions. Switching time analysis reveals that a system with achiral components and those with two centers of chirality (A-BchM) exhibits the fastest response, while CchM demonstrates only intermediary behavior, caused by its high rotational viscosity. Among all formulations, those containing compounds with two centers of chirality display the most favorable balance of functional properties for deformed helix ferroelectric liquid crystal (DHFLC) applications. One such mixture achieves the lowest melting temperature reported for DHFLC-compatible FLCs, enabling operation at sub-zero temperatures. These findings pave the way for next-generation electro-optical devices with enhanced performance and appropriate environmental stability. Full article

To address the insufficient early strength development of steel-fiber-reinforced high-performance concrete (SF-HPC) under subzero temperatures, this study proposes an electric-induced heating curing method for SF-HPC fabrication at −20 °C. The effects of mix parameters, including steel fiber content, water-to-binder ratio, silica fume dosage, and fine aggregate gradation, on the curing temperature and mechanical properties of SF-HPC were systematically investigated. The optimal mix proportion was identified through the curing temperature and compressive strength development for the specimens. Results revealed that compressive strength initially increased and then decreased with higher silica fume content and fine aggregate replacement ratios, while increased water-to-binder ratios positively influenced curing efficiency and strength development. The optimal mix comprised 2.0 vol% steel fibers, a water-to-binder ratio of 0.22, 20% silica fume, and 60% fine aggregate replacement. Further, comparative analyses of electric-induced heating curing, room-temperature curing, and high-temperature steam curing revealed that electric-induced heating curing can promote the strength formation of SF-HPC in a negative-temperature environment. Microstructural characterization via BET analysis demonstrated that electric-induced heating curing refined the pore structure of SF-HPC. These findings highlight the benefits of electric-induced heating as an efficient strategy for fabricating SF-HPC in cold climates, providing theoretical and practical insights for winter construction. Full article

In this work, we studied the thermal behavior and infrared fingerprint of anhydrous and hydrated DL-tartaric acid via conventional and modulated Differential Scanning Calorimetry (DSC), Thermogravimetry (TGA), Fourier Transform Infrared Spectroscopy (FTIR), nuclear magnetic resonance (NMR), pH measurements, and ab initio density functional theory (DFT) calculations. Six samples were examined in total (raw, recrystallized from D₂O solution, freeze-dried, and three heated samples). The results reveal that both forms (anhydrous and hydrated) do not exhibit melting prior to decomposition. It is also shown that the so-called DL-tartaric acid does not exist in the solid state in pure form, but it contains water and a tartaric acid oligomer, which is produced through esterification. Alteration of the chemical structure (reflected through decomposition) is initiated at quite low temperatures and is more pronounced for the hydrated form. Up to 75 °C, decomposition proceeds through esterification, while at higher temperatures it seems to be reversed due to the increase in water and decrease in COOH groups emerging through anhydride formation. Either upon heating or at sub-zero temperatures during freeze-drying, the hydrated form decomposes, and although some water is removed, new water is produced due to esterification. The conclusions are also supported by DFT calculations. Full article

Construction in cold regions faces significant challenges due to delayed cement hydration and frost damage caused by sub-zero temperatures. This study investigated the effects of three antifreeze agents on the performance of composite cement under sub-zero temperatures. The setting time, compressive strength, freezing point, and hydration mechanisms were evaluated. The results revealed that CaCl₂ optimally accelerated hydration, while achieving the continuous development of compressive strengths through freezing-point depression and dense microstructure formation. NaNO₂ exhibited the lowest freezing point but delayed setting at high dosages, while Li₂CO₃ showed limited impact due to insufficient freezing point depression. Li₂CO₃ showed limited efficacy under continuous low temperatures but enabled strength recovery after the temperature transition from sub-zero to ambient conditions. This research provides a basis for the application of antifreeze agents in the composite cement system for construction in cold environments. Full article

The performance of lithium-ion batteries deteriorates significantly under extreme-cold conditions due to increased internal resistance and decreased electrochemical activity. This study presents an experimental analysis of a battery thermal management system (BTMS) incorporating electromagnetic induction heating and a fluid-based heat transfer mechanism to alleviate these problems. The experimental setup utilizes a closed-loop circulation system where ethylene glycol-based fluid flows through induction-heated copper tubes, ensuring efficient heat transfer to an 18650-cell battery. This study evaluates heating performance under varying ambient temperatures (−15 °C and −5 °C), fluid flow rates (0.22, 0.3, and 0.5 L/min), and induction power levels (150 W, 225 W, 275 W, and 400 W). The results indicate that lower flow rates (e.g., 0.22 L/min) provide faster heating due to longer thermal interaction time with the battery; however, localized boiling points were observed at these low flow rates, potentially leading to efficiency losses and thermal instability. At −15 °C and 400 W, the battery temperature reached 25 °C in 383 s at 0.22 L/min, while at 0.5 L/min, the same temperature was achieved in 463 s. Higher flow rates improved temperature uniformity but slightly reduced heating efficiency due to increased heat dissipation. Internal resistance measurements revealed a substantial decrease as battery temperature increased, further validating the effectiveness of the system. These findings present a viable alternative for heating electric vehicle batteries in sub-zero environments, thereby optimizing battery performance and extending operational lifespan. Full article