Search Results (607)

Mechanical friction offers a frequent approach for sustainable energy harvesting, as it can be captured and transformed into electricity by means of the triboelectric phenomenon. Theoretically, this electricity may subsequently be employed to drive electrochemical water purification processes. Herein, the experimental results confirm that the SiC particles effectively trigger the tribocatalytic decomposition of Rhodamine B (RhB). During the tribocatalytic decomposition of dye, mechanical friction is generated at the contact surface between the tribocatalyst and a custom-fabricated polytetrafluoroethylene (PTFE) rotating disk, under varying conditions of stirring speed, temperature, and pH value. Hydroxyl radicals and superoxide radicals are confirmed as the dominant reactive species participating in tribocatalytic dye decomposition, as demonstrated by reactive species inhibition experiments. Furthermore, the SiC particles demonstrate remarkable reusability, even after being subjected to five consecutive recycling processes. The exceptional tribocatalytic performance of SiC particles makes them potentially applicable in water purification by harnessing environmental friction energy. Full article

Environmental risk assessment (ERA) for pesticide approval in the context of predatory insects remains inadequate as it often overlooks the influence of agricultural practices. An increasing number of studies have shown that prolonged and synergistic pesticide exposure can elevate insect mortality. However, such effects remain largely unstudied in non-target predatory carabid beetles. The carabid beetle Platynus assimilis was subjected to repeated oral and continuous contact exposure to low doses of prothioconazole (20 g ha⁻¹), lambda-cyhalothrin (0.4 g ha⁻¹), or their combination over a 64-day period. The food consumption rate, body mass, locomotor activity, and mortality were monitored throughout the experiment. All pesticide-treated groups showed significantly increased final mortality, with median lethal times (LT₅₀) of 51.6 days for prothioconazole, 60.3 days for lambda-cyhalothrin, and 12.2 days for their combination. A significant synergistic effect on mortality was observed in the combined treatment group, with the highest synergistic ratio detected 20 days after the first exposure. Pesticide-treated beetles exhibited significant abnormalities in locomotor activity and body mass compared to the untreated group. These findings demonstrate that both time-cumulative mortality and potential synergistic interactions, reflecting field-realistic conditions, must be considered in ERA. Failure to do so may lead to an underestimation of pesticide toxicity to predatory carabids. Full article

This paper examines Krivelj, a copper mining village in Serbia, as a critical yet overlooked node within global extractive networks. Despite supplying copper essential for renewable energy and sustainable architecture, Krivelj experiences severe ecological disruption, forced relocations, and socio-spatial destabilization, becoming a “sacrifice zone”—an area deliberately subjected to harm for broader economic interests. Employing a hybrid methodology that combines ethnographic fieldwork with Geographic Information Systems (GISs), this study spatializes narratives of extractive violence collected from residents through walking interviews, field sketches, and annotated aerial imagery. By integrating satellite data, legal documents, environmental sensors, and lived testimonies, it uncovers the concept of “slow violence,” where incremental harm occurs through bureaucratic neglect, ambient pollution, and legal ambiguity. Critiquing the abstraction of Planetary Urbanization theory, this research employs countertopography and forensic spatial analysis to propose a counter-cartographic framework that integrates geospatial analysis with local narratives. It demonstrates how global mining finance manifests locally through tangible experiences, such as respiratory illnesses and disrupted community relationships, emphasizing the potential of counter-cartography as a tool for visualizing and contesting systemic injustice. Full article

Halogenated flame retardants have been amongst the most widely used and effective solutions for enhancing fire resistance. However, their use is currently strictly regulated due to serious health and environmental concerns. In this context, phosphorus-based and mineral flame retardants have emerged as promising alternatives. Despite this, their combined use is neither straightforward nor guaranteed to be effective. This study scrutinizes the interactions between these two classes of flame retardants (FR) through a systematic analysis aimed at elucidating the antagonistic pathways that arise from their coexistence. Specifically, this study focuses on two inorganic fillers, mineral huntite and chemically precipitated magnesium hydroxide, both of which produce basic oxides upon thermal decomposition. These fillers were incorporated into a poly(butylene terephthalate) (PBT) matrix to be utilized as advanced-mattress FR coating fabric and were subjected to a series of flammability tests. The pyrolysis products of the prepared polymeric composite compounds were isolated and thoroughly characterized using a combination of analytical techniques. Thermogravimetric analysis (TGA) and differential thermogravimetric analysis (dTGA) were employed to monitor decomposition behavior, while the char residues collected at different pyrolysis stages were examined spectroscopically, using FTIR-ATR and Raman spectroscopy, to identify their structure and the chemical reactions that led to their formation. X-ray diffraction (XRD) experiments were also conducted to complement the spectroscopic findings in the chemical composition of the resulting char residues and to pinpoint the different species that constitute them. The morphological changes of the char’s structure were monitored by scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS). Finally, the Limited Oxygen Index (LOI) and UL94 (vertical sample mode) methods were used to assess the relative flammability of the samples, revealing a significant drop in flame retardancy when both types of flame retardants are present. This reduction is attributed to the neutralization of acidic phosphorus species by the basic oxides generated during the decomposition of the basic inorganic fillers, as confirmed by the characterization techniques employed. These findings underscore the challenge of combining organophosphorus with popular flame-retardant classes such as mineral or basic metal flame retardants, offering insight into a key difficulty in formulating next-generation halogen-free flame-retardant composite coatings. Full article

Based on a literature review, the present article aims to present ecotourism as a transformative factor in the economic, social, cultural, and environmental contexts, revealing key elements for the sustainable development of ecotourism. To ensure that this objective is met, the review combines the insights of classical authors and many recent authors who have best addressed the subject. The review carefully selected consensual and contradictory arguments, reflecting on the relevance of each group, particularly in aspects such as the influence of emotional experience on behaviour and satisfaction, strategy and competitive advantage, cooperation and sustainability, and the influence of resilience on ecotourism. The impact of each perspective was presented without ignoring the major constraints that ecotourism faces in its search for a position in the tourism industry. This led the study to accept the fact that the active participation of the community is indispensable in the formula for the success of ecotourism. Some statistical data were consulted and analysed, which enabled the study to determine the quantitative impact of ecotourism on economic, social, and environmental life. In terms of benefits to communities, the review clarifies the fact that ecotourism serves as an instrument that mobilizes not only the additional value of products and services traded in the process, but also the return on investments and job creation. The combination of visiting activities with the involvement of tour guides contributes to maximizing profits in the destinations, thus supporting solid economic, social, and environmental development for the benefit of both ecotourism promoters and local communities. However, the analysis makes it clear that the economic, social, and environmental benefit depends on the degree of involvement of the local population. In terms of usability, for other studies, this review can contribute to the understanding and positioning of ecotourism in the search for a balance between satisfying socioeconomic and environmental interests. Additionally, it can serve as an aid to policy makers in their decisions related to ecotourism. Full article

Loess, a typical soil widely distributed in China, exhibits engineering properties that are highly sensitive to environmental changes, leading to increased erosion and the development of surface cracks. This article examines the influence of initial moisture content, dry density, and thickness on crack formation in compacted loess subjected to wet–dry cycles, using both laboratory experiments and numerical simulation analysis. It quantitatively analyzes the process of crack evolution using digital image processing technology. The experimental results indicate that wet–dry cycles can cause cumulative damage to the soil, significantly encouraging the initiation and expansion of secondary cracks. New cracks often branch out and extend along the existing crack network, demonstrating that the initial crack morphology has a controlling effect over the final crack distribution pattern. Numerical simulations based on MultiFracS software further revealed that soil samples with a thickness of 0.5 cm exhibited more pronounced surface cracking characteristics than those with a thickness of 2 cm, with thinner layers of soil tending to form a more complex network of cracks. The simulation results align closely with the indoor test data, confirming the reliability of the established model in predicting fracture dynamics. The study provides theoretical underpinnings and practical guidance for evaluating the stability of engineering slopes and for managing and mitigating fissure hazards in loess. Full article

Urbanization poses mental health risks for urban dwellers, whereas natural environments offer mental health benefits by providing restorative experiences through visual stimuli. While urban waterfront spaces are recognized for their mental restorative potential, the specific environmental features and individual visual behaviors that drive these benefits remain inadequately understood. Grounded in restorative environments theory, this study investigates how these factors jointly influence restoration. Employing a controlled laboratory experiment, subjects viewed real-life images of nine representative spatial locations from the waterfront space of Guangzhou Long Bund. Data collected during the multimodal experiments included subjective scales data (SRRS), physiological measurement data (SCR; LF/HF), and eye-tracking data. Key findings revealed the following: (1) The element visibility rate and visual characteristics of plant and building elements significantly influence restorative benefits. (2) Spatial configuration attributes (degree of enclosure, spatial hierarchy, and depth perception) regulate restorative benefits. (3) Visual behavior patterns (attributes of fixation points, fixation duration, and moderate dispersion of fixations) are significantly associated with restoration benefits. These findings advance the understanding of the mechanisms linking environmental stimuli, visual behavior, and psychological restorative benefits. They translate into evidence-based design principles for urban waterfront spaces. This study provides a refined perspective and empirical foundation for enhancing the restorative benefits of urban waterfront spaces through design. Full article

The increasingly severe ecological and environmental problems in rural areas pose a serious threat to agricultural sustainability and human well-being. Protecting the ecological environment of cultivated land is fundamental to ensuring food security and achieving sustainable development goals. The effective integration of digital technology into farmers’ production and daily life is a key driver for transforming farming practices and advancing the ecological protection of cultivated land. This study draws on data from the 2020 China Rural Revitalization Survey (CRRS) to systematically examine the impact of farmers’ digital participation on the ecological protection of cultivated land. The main findings are as follows: (1) Digital participation significantly promotes ecological conservation of cultivated land, with each unit increase associated with a 7.8% reduction in fertilizer use intensity; (2) the results are robust across various empirical strategies, including instrumental variable estimation, the ERM approach, residual analysis, and alternative indicator specifications; (3) mechanism analysis indicates that digital participation reduces fertilizer use through three main channels: expansion of social networks (accounting for 7.10%), enhancement of subjective cognition (29.66%), and adoption of agricultural technologies (10.18%); and (4) heterogeneity analysis shows that the protective effects on cultivated land are more pronounced among households with off-farm employment experience, in villages where leaders have higher educational attainment, and in regions with more advanced digital environments. Based on these findings, the following policy recommendations are proposed: enhancing digital infrastructure in rural areas, strengthening the training of agricultural practitioners, and developing localized digital environments tailored to local conditions. Full article

Cockpit noise, as a critical environmental factor affecting flight safety, may impair pilots’ cognitive functions, leading to a decreased operational performance and decision-making errors, thereby posing potential threats to aviation safety. In order to reveal the relationship between the cockpit noise sound pressure level and pilot physiological indicators, and provide a scientific basis for cockpit noise airworthiness standards, this experiment takes pilot trainees as the research subject. Based on the principle of multimodal data synchronization, a sound field reconstruction system is used to reconstruct the cockpit sound field. Electroencephalogram (EEG), electrocardiogram (ECG), and electrodermal activity (EDA) measurements are carried out in different sound pressure level noise operating environments. The results show that with the increase in the sound pressure level, the significant suppression of α-wave activity in the occipital and parietal regions suggests that the cortical resting state is lifted and visual attention is enhanced; the enhancement of the β-wave in the frontal regions reflects the enhancement of alertness and prefrontal executive control, and the suppression of θ-wave activity in the frontal and temporal regions may indicate that cognitive tuning is suppressed, which reflects the brain’s rapid adaptive response to external noise stimuli in a high-noise environment; noise exposure triggers sustained sympathetic nerve hyperactivity, which is manifested by a significant acceleration of the heart rate and a significant increase in the mean value of skin conductance when the noise sound pressure level exceeds 70 dB(A). The correlation analysis between physiological indicators shows that cockpit noise has a multi-system synergistic effect on human physiological indicators. The experimental results indicate that noise has a significant impact on EEG, ECG, and EDA indicators. Full article

The production of solid biofuels from torrefied biomass holds significant potential for renewable energy applications. Durable pellet formation from severely torrefied biomass is hindered by the loss of natural binding properties, yet studies on mild torrefaction that preserves sufficient binding capacity for pellet production without external binders or changes to die conditions remain scarce. This paper investigated the production of fuel pellets from torrefied biomass without using external binders or adjusting pelletization parameters. Experiments were conducted using a mild torrefaction temperature (230 °C and 250 °C) and shorter residence time (10, 15, and 30 min). The torrefied materials were then subjected to pelletization using a single-pellet press; and the influence of torrefaction on the mechanical durability, hydrophobicity, and fuel characteristics of the pellets was examined. Results indicated that the mass loss ranging from 10 to 20% among the mild torrefaction treatments was less than the typical extent of mass loss due to severe torrefaction. Pellets made from torrefied biomass (torrefied pellets) had improvement in the hydrophobicity (moisture resistance) when compared to pellets made from untreated biomass (untreated pellets). Improved hydrophobicity is important for storage and transportation of pellets that are exposed to humid environmental conditions, as it reduces the risk of pellet degradation and spoilage. Thermogravimetric analysis of the pyrolysis and combustion behaviour of torrefied pellets indicated the improvement of fuel characteristics in terms of a much higher comprehensive pyrolysis index and greater thermal stability compared to untreated pellets, as evidenced by the prolonged burnout time and reduced combustion characteristics index. Residence time had a more significant impact on pellet durability than temperature, but the durability of the torrefied pellets was lower than that of the untreated pellets. Further research is required to explore the feasibility of producing binder-free durable pellets under mild torrefaction conditions. Overall, the study demonstrated that mild torrefaction could enhance the fuel quality and moisture resistance of biomass pellets, offering promising advantages for energy applications, despite some trade-offs in mechanical durability. Full article

Background/Objectives: Duchenne muscular dystrophy (DMD) is often discussed in the literature with regard to physical impairments. This narrative review aims to show that living with DMD involves psychological, psychosocial, and cognitive aspects in addition to the well-known physical complications. Methods: Firstly, this review examines the main cognitive functions affecting subjects with DMD and the possible role of dystrophin gene mutations on the central nervous system. Secondly, it analyzes the comorbidity between DMD, neurodevelopmental disorders (autism spectrum disorders, attention-deficit/hyperactivity disorder, obsessive–compulsive disorder) and psychopathological traits (anxiety and/or depressive symptoms). Finally, the review addresses the relatively sparse literature investigating the positive aspects associated with the experience of DMD, like psychosocial resources, resilience, subjective well-being, positive individual and social functioning, and social support. Results: DMD has a significant impact on cognitive areas, probably due to dystrophin deficiency in the brain. The prevalence of neurodevelopmental comorbidities and psychopathological symptoms is also higher in people with DMD than in the general population. Despite these challenges, emerging studies highlight the role of psychosocial and environmental resources, including resilience and supportive social relations, in promoting a good quality of life and successful adaptation to disease progression. Conclusions: Early recognition of the above difficulties and strengths could ensure better care and promote an overall better quality of life for people with DMD and their families, physically, psychologically, and socially. Preclinical and clinical research is moving in the direction of finding new therapies, treatments, and psychosocial interventions to pursue these goals. Full article

In this paper, a sliding-mode control strategy incorporating prescribed features was systematically designed, resolving the dual challenges of trajectory tracking precision maintenance and disturbance attenuation for an AUV subjected to dynamic model inaccuracies and disturbances. To neutralize the impact of parametric uncertainties and environmental disturbances on the controlled plant, an adaptive finite-time sliding-mode disturbance observer (AFTSMDO), the upper bound of perturbations was not required for the proposed observer. Subsequently, by embedding error transformations and prescribed performance functions, we designed a novel sliding-mode surface. This surface ensured that tracking errors and their derivatives converge to specified regions within predefined temporal bounds, irrespective of initial configurations. This overcomes the longstanding limitations of traditional prescribed performance control methods and contributes to enhancing system performance. Finally, we conducted comparative simulation experiments with existing sliding-mode control methods to prove the practical viability and comparative advantage of the synthesized control methodology. Full article

This article discusses and compares approaches to the visualization of the danger zone formed as a result of spreading toxic substances during a fire at an industrial enterprise, to create predictive models and scenarios for evacuation and environmental protection measures. The purpose of this study is to analyze the features and conditions for the application of algorithms for predicting the spread of a danger zone, based on the Gauss equation and the probabilistic algorithm of a cellular automaton. The research is also aimed at the analysis of the consequences of a fire at an industrial enterprise, taking into account natural and climatic conditions, the development of the area, and the scale of the fire. The subject of this study is the development of software and algorithmic support for the visualization of the danger zone and analysis of the consequences of a fire, which can be confirmed by comparing a computational experiment and actual measurements of toxic substance concentrations. The main research methods include a Gaussian model and probabilistic, frontal, and empirical cellular automation. The results of the study represent the development of algorithms for a cellular automation model for the visual forecasting of a dangerous zone. They are characterized by taking into consideration the rules for filling the dispersion ellipse, as well as determining the effects of interaction with obstacles, which allows for a more accurate mathematical description of the spread of a cloud of toxic combustion products in densely built-up areas. Since the main problems of the cellular automation approach to modeling the dispersion of pollutants are the problems of speed and numerical diffusion, in this article the frontal cellular automation algorithm with a 16-point neighborhood pattern is used, which takes into account the features of the calculation scheme for finding the shortest path. Software and algorithmic support for an integrated system for the visualization and analysis of fire consequences at an industrial enterprise has been developed; the efficiency of the system has been confirmed by computational analysis and actual measurement. It has been shown that the future development of the visualization of dangerous zones during fires is associated with the integration of the Bayesian approach and stochastic forecasting algorithms based on Markov chains into the simulation model of a dangerous zone for the efficient assessment of uncertainties associated with complex atmospheric processes. Full article

This study explores the impact of microclimatic variations on thermal perception and walking experience in Béjaïa, Algeria, focusing on two contrasting urban areas: the compact historic medina and the modern lower city. A mixed-method approach combined microclimatic measurements (Ta, Ts, Va, RH) with subjective evaluations from 70 participants. After urban morphological analysis, walking itineraries were designed and studied through accompanied walks. Participants reported their thermal sensations and walking comfort via questionnaires and mental maps, while environmental data were simultaneously collected (21–28 July 2022). Results show that transitions between urban fabrics significantly affect thermal sensation and walking thermal comfort (WTC). Strong correlations were observed between surface temperature (Ts) and sky view factor (SVF), and between ASV and WTC (Kendall’s τᵦ = 0.79, 95% CI [0.70, 0.88]). Beyond physical factors, perceptual variables like vegetation (OR = 1.50), maintenance (OR = 1.40), and views (OR = 1.30) significantly increased WTC, while fatigue (OR = 0.70) and safety concerns (OR = 0.80) reduced it. The findings highlight strong contrasts between the two areas and support planning strategies emphasizing vegetation, spatial optimization, and the integration of perceptual thermal factors in urban design. Full article

Precision spraying technology has attracted increasing attention in orchard production management. Traditional chemical pesticide application relies on subjective judgment, leading to fluctuations in pesticide usage, low application efficiency, and environmental pollution. This study proposes a machine vision-based precision spraying control system for orchards. First, a canopy leaf wall area calculation method was developed based on a multi-iteration GrabCut image segmentation algorithm, and a spray volume calculation model was established. Next, a fuzzy adaptive control algorithm based on an extended state observer (ESO) was proposed, along with the design of flow and pressure controllers. Finally, the precision spraying system’s performance tests were conducted in laboratory and field environments. The indoor experiments consisted of three test sets, each involving six citrus trees, totaling eighteen trees arranged in two staggered rows, with an interrow spacing of 3.4 m and an intra-row spacing of 2.5 m; the nozzle was positioned approximately 1.3 m from the canopy surface. Similarly, the field experiments included three test sets, each selecting eight citrus trees, totaling twenty-four trees, with an average height of approximately 1.5 m and a row spacing of 3 m, representing a typical orchard environment for performance validation. Experimental results demonstrated that the system reduced spray volume by 59.73% compared to continuous spraying, by 30.24% compared to PID control, and by 19.19% compared to traditional fuzzy control; meanwhile, the pesticide utilization efficiency increased by 61.42%, 26.8%, and 19.54%, respectively. The findings of this study provide a novel technical approach to improving agricultural production efficiency, enhancing fruit quality, reducing pesticide use, and promoting environmental protection, demonstrating significant application value. Full article