Search Results (102)

This study investigates the quasi-static equalbiaxial compression behavior of 3D-printed Miura-ori metamaterials incorporating both out-of-plane and in-plane gradient configurations. The Miura-ori structure, composed of tessellated parallelogram units, exhibits pronounced anisotropic behavior due to its unique folding geometry. To assess this behavior, specimens were fabricated using ABS resin and subjected to equalbiaxial compression in three orthogonal directions: the xy-direction (in-plane compression), the yz-direction (edge-on side loading), and the xz-direction (accordion-like profile loading). In the out-of-plane gradient design, the acute angle ϕ was varied across layers, significantly influencing both yield stress and specific energy absorption (SEA). Compared with the uniform design, gradient configurations exhibited reduced mechanical performance in the xy-direction and yz-direction, and enhanced properties in the xz-direction. In addition, in-plane (x-direction) gradient structures were evaluated under xy-, yz- and xz- direction compression. The results indicate that gradient configuration specimens exhibit significantly lower yield stress and specific energy absorption than uniform structure specimens, with deformation initiating preferentially in regions with smaller acute angles and lower local stiffness. The results highlight the strong influence of geometric gradation and loading direction on the mechanical performance of Miura-ori metamaterials. This work provides new insights into the design and optimization of origami-inspired energy-absorbing structures for use in advanced mechanical, aerospace, and protective engineering applications. Full article

The marketable viability of perovskite solar cells (PSCs) is currently hindered by challenges related to interfacial charge-carrier extraction and thermal degradation. This study presents a comprehensive finite element method (FEM) analysis using COMSOL Multiphysics to evaluate the efficacy of bi-layer electron transport layer (ETL) engineering in addressing these limitations. We developed a coupled optical–electrical model to investigate three planar architectures: a conventional TiO₂-based reference device, a ${\mathrm{TiO}}_2/{\mathrm{SnO}}_2$ bi-layer configuration, and a ${\mathrm{TiO}}_2/{\mathrm{SnO}}_2:\mathrm{Fe}$ (iron-doped) bi-layer device. Simulation results under AM1.5G illumination reveal that the bi-layer configurations significantly enhance optical absorption across the visible spectrum (350–700 nm) compared to the single-layer counterpart. The incorporation of Fe-doped SnO₂ resulted in optimized energy band alignment, creating a favourable conduction band offset that facilitates electron extraction. Consequently, the ${\mathrm{TiO}}_2/{\mathrm{SnO}}_2:\mathrm{Fe}$ device achieved a peak power conversion efficiency (PCE) of 18.3% at 300 K, outperforming the undoped bi-layer (18.0%) and the reference device (17.5%). Furthermore, thermal stress simulations indicated that the Fe-doped architecture exhibits superior stability, maintaining a PCE of 12.8% at 440 K compared to 12.3% for the reference. This enhanced performance is attributed to the passivation of interfacial defects and the formation of a stronger built-in electric field at the ETL/absorber junction, validating the strategic doping of metal oxides as a robust pathway for high-efficiency, thermally stable perovskite photovoltaics. Full article

The containment of internal explosions remains a critical challenge in the design of protective infrastructure for ammunition storage and hazardous industrial facilities. To address the limitations of conventional single-layer reinforced concrete (RC) structures, this study proposes a multi-layer composite confined structure comprising RC layers and energy-absorbing interlayers. A fluid–structure interaction (FSI) numerical model was developed and validated against experimental data from scaled blast tests on two multi-layer composite confined structures reported in our companion study. Comparative analyses were performed between the composite structures and an equivalent single-layer RC structure under varying charge masses. The results indicate that the energy-absorbing layer transforms the monolithic structural response into a progressive, layer-by-layer deformation mode, effectively decoupling the outer layer from the direct blast impulse. Foamed concrete demonstrated superior performance by limiting the transmitted stress to its yield plateau (~1.0 MPa) and reducing the outer-layer energy to 8.77% of that in the single-layer structure. Two distinct failure modes were identified for the first time: the desired Mode I, where the inner layer reaches its deformation limit while the outer layer remains elastic, and the undesired Mode II, characterized by premature plastic failure of the outer layer. These findings provide a rational basis for the design of blast-resistant composite structures, highlighting the efficacy of foamed concrete in ensuring containment integrity. Full article

This study addresses a critical challenge in surface engineering: developing robust nanocomposite layers on high-performance thermoplastics without inducing macroscopic thermal degradation. While cold gas dynamic spraying (CGDS) of polymers is often described in the literature as a deposition process based on purely mechanical anchoring of particles into polymer surface, our work establishes a multi-scale, hybrid physical–chemical adhesion framework. Using a coupled 3D thermoplasticity finite element model with a Mie–Grüneisen equation of state and Johnson–Cook criteria, we evaluate the supersonic impact dynamics ($V_0=1000 \mathrm{m}/\mathrm{s}$) of single-walled (5,0) CNTs impacting a PEEK substrate at oblique angles (0–20°). The core scientific lies in bridging continuum mechanics with quantum-chemical statistics. By applying Weibull weakest-link theory to a 37-bond monomer model, we demonstrate that compliant $C_{arom}-O$ ether bonds selectively absorb impact energy, covering 8.37% of their dissociation barrier. This non-uniform energy sharing yields a 0.23% monomer activation probability, generating a high free-radical density of ~1100 ${\mathrm{\mu }\mathrm{m}}^{-2}$ beneath the particle plume. This localized “chemical nano-welding” network provides exceptional chemical adhesion, while the remaining 99.77% of intact chains ensure structural rigidity, reinforced by a mechanical “self-locking” field (residual compressive stresses up to 0.9 GPa). This study provides a scientific foundation for designing functional coatings tailored for engineering, aerospace, and biomedical applications. Full article

Colloidal processing provides a scalable non-vacuum route for fabricating CIGS and CZTSSe thin-film absorbers, but nanoparticle-derived films should be treated as constrained particulate green bodies rather than as simple chemically deposited semiconductor layers. This review reorganizes colloidal chalcogenide photovoltaics using ceramic-processing concepts: ink dispersion, green-body packing, capillary drying stress, ligand burnout, constrained shrinkage, reactive chalcogenization, transient liquid-assisted coarsening, secondary-phase control, defect chemistry, and interface reactions. The central argument is that film densification and grain growth are necessary but insufficient for high-performance CZTSSe devices. Residual carbon, Sn loss, Cu/Zn disorder, ZnSe or Cu_2−xSe secondary phases, excessive MoSe₂, and nonideal absorber/buffer band alignment can dominate open-circuit-voltage loss, fill factor, and carrier collection even when the absorber appears dense in cross-sectional microscopy. By linking ceramic-processing variables to photovoltaic loss mechanisms, this review identifies practical routes for improving colloidal chalcogenide solar cells: controlled ligand exchange and binder burnout, high-green-density precursor design, moderated chalcogen chemical potential, transient liquid management, depth-resolved phase analysis, and integrated front/back-interface engineering. Full article

Brittle geomaterials such as coal and rock are prone to unstable failure under high stress and dynamic disturbances, where rapid release of stored elastic strain energy can trigger dynamic disasters. Polyurea, a high-strength and high-ductility elastomer, can form a continuous flexible coating on the surface of coal/rock to regulate their deformation–fracture behavior. Here, uniaxial compression tests were performed on coal specimens coated with polyurea layers of different thicknesses (0–1.25 mm). Acoustic emission (AE) and digital image correlation (DIC) were jointly employed to characterize macroscopic deformation, microcrack evolution, fracture-mode transition, and energy partitioning. The results show that polyurea provides passive lateral confinement that suppresses lateral expansion and shifts macroscopic failure from brittle splitting to progressive ductile damage. AE-based AF–RA analysis indicates that thicker coatings increase the normal stress and shear resistance along potential fracture planes, promoting a microfracture transition from shear-dominated to tension-dominated cracking. Energy analysis demonstrates that the coating enhances pre-peak energy dissipation via coordinated deformation with the coal, while thicker coatings (≥1.00 mm) exhibit pronounced post-peak elastic tensile deformation to absorb and buffer fracture-released energy, impeding the instantaneous energy release typical of bare coal. Moreover, the elastic energy index shows that polyurea markedly reduces impact tendency, with an appropriate thickness stabilizing specimens from strong to weak/non-impact propensity. These findings clarify the coupled confinement–fracture–energy regulation mechanisms of polyurea coatings and provide quantitative guidance for coating-thickness design to mitigate dynamic failure hazards in brittle materials. Full article

Future lunar missions, like the International Lunar Research Station (ILRS), demand single-launch multi-point operations, urgently requiring reusable energy-absorbing structures. Integrating shape memory alloy (SMA) into honeycombs offers a promising solution; however, deformation exceeding the SMA’s recoverable limit induces structural residual deformation, altering the configuration and degrading subsequent energy absorption. To address this, we propose a semi-analytical, data-calibrated hybrid model predicting SMA honeycomb residual deformation. A four-stage linear constitutive model is established capturing superelasticity and martensitic yielding. Cell walls are idealized as equivalent beams. Using layered fiber integration and numerical interpolation, a nonlinear moment–curvature relationship is constructed, enabling rapid structural residual deflection evaluation from material residual strains. Finite element results confirm that initial residual deformation stabilizes the honeycomb into a reusable configuration, governing subsequent plateau stresses. Calibrated by uniaxial test data, the proposed model accurately predicts residual deformation ratios and reusable plateau stresses with errors within 8%. By bridging material-level strain with structural-level deformation, this approach circumvents computationally expensive full-scale simulations and costly experimental trials, providing a highly efficient tool for designing reusable SMA absorbers. Full article

Additively manufactured cellular architectures frequently exhibit brittle failure under impact due to layer-induced stress concentrations. Through the programming of architectural and material design, specifically combining Fused Deposition Modeling (FDM) lattice topology with hyperelastic polyurea infiltration, this study achieves active control over the macroscopic transition from catastrophic structural fragmentation to stable progressive collapse. To evaluate this, auxetic and honeycomb specimens printed with ABS and glass-fiber-reinforced polyamide (PA-GF) were evaluated in unreinforced and polyurea-infiltrated states under quasi-static compression, three-point bending, and Charpy impact loading. Results show that the compressive response depends primarily on cellular topology; the pure auxetic (A-A) configuration provided the highest stiffness and energy absorption. Polyurea infiltration did not significantly alter elastic stiffness but increased post-yield stability, leading to a 96.6% elastic recovery in PA-GF A-A structures. In flexure, the base polymer governed stiffness, with ABS structures measuring 68% stiffer than PA-GF. Unreinforced ABS achieved 34% higher specific energy absorption (SEA) than PA-GF under compression, with the A-H topology maximizing SEA. Under dynamic impact, PA-GF absorbed an average of 70% more energy than ABS, and the H-A configuration recorded the highest impact resistance. The addition of polyurea shifted the failure mode from brittle fragmentation to stable elastomeric deformation, increasing absorbed impact energy by 52% for ABS and over 30% for PA-GF, preventing catastrophic structural failure. Integrating topological sequencing with elastomeric confinement provides a direct method to control energy dissipation and damage tolerance in 3D-printed cellular composites. Full article

To address the challenges posed by complex Cretaceous(K) deep structural deformation and the poorly understood decoupling mechanism between deep and shallow structural layers in the foreland thrust belt of the Kuqa depression, Tarim Basin, this study integrates high-precision 3D seismic interpretation with balanced cross-section restoration techniques to systematically elucidate the controlling role of rheological heterogeneity within the Shushanhe Formation (K₁s) mudstone on the stress–lithology–structure coupling mechanism. Our findings demonstrate that variations in thickness and rheological properties of the Shushanhe Formation mudstone govern the structural segmentation along the Zhongqiu–Dongqiu transect. In the Dongqiu area, an exceptionally thick and highly ductile mudstone layer induces principal stress deflection and horizontal shearing, effectively absorbing vertical strain transmitted from deep-seated tectonic wedges. This results in pronounced decoupling between deep and shallow strata, giving rise to broad, gentle anticlines and ramp-flat imbricate structures at depth. Conversely, in the Zhongqiu area, the mudstone thins significantly and becomes more brittle, increasing the friction coefficient and impeding vertical stress transmission. Consequently, near-vertical stacking occurs in the proximal compressional segment, leading to the development of high-angle thrust faults and strike-slip-modified fault-bend folds. This study clarifies the genetic mechanism of non-coaxial structures controlled by the mudstone detachment layer and confirms that the plastic flow of this layer not only enhances lateral sealing capacity but also acts as an effective rheological barrier, thereby preserving the deep overpressured hydrocarbon reservoirs in the Yageliemu Formation (K₁y). These insights provide a robust theoretical foundation for shifting exploration strategies from shallow structural traps to deep, subtle lithologic–structural composite plays, offering critical guidance for sweet spot prediction in ultra-deep settings. Full article

GaN-on-Si light-emitting devices have been widely studied in the field of opto-electronics, while their optical performance and characterization accessibility are severely limited by the strong visible light absorption of the native silicon substrate. Conventional substrate transfer technologies often suffer from inherent thermal, optical, or mechanical bottlenecks. In this study, we developed a robust wafer-level substrate transfer strategy for 8-inch green GaN-on-Si light-emitting device wafers, utilizing a hybrid planarization process combined with SiO₂–SiO₂ direct bonding. The hybrid planarization precisely eliminated the 900 nm macroscopic steps, achieving sub-nanometer surface roughness for high-yield wafer bonding. We systematically investigated the physical evolution during substrate removal. Results indicate that the removal of the thick native silicon and high-stress buffer layers effectively released the additional in-plane biaxial compressive stress within the multiple quantum wells (MQWs), thereby mitigating the quantum-confined Stark effect (QCSE). Benefiting from the elimination of the light-absorbing silicon substrate and the incorporation of a built-in back-surface reflector (BSR), the transferred devices achieved a remarkable 1.9-fold enhancement in relative optical performance, albeit with an inherent trade-off of increased reverse leakage current while preserving basic diode functionality. Furthermore, optothermal dynamic analysis at high injection levels suggests a potential localized thermal bottleneck at the thick SiO₂ bonding interface, where a hypothesized heat-induced spectral red shift may counteract the carrier-screening blue shift. This work provides a feasible wafer-level substrate transfer process for GaN-on-Si devices and offers systematic experimental insights into stress relaxation and optothermal behaviors during the substrate transfer process. Full article

Hot extrusion tools operate under severe thermal and mechanical conditions, which significantly limit their service life. During operation, the punch and die absorb large amounts of heat from the hot billet while being subjected to high pressures and intense friction, leading to severe abrasive wear and progressive hardness reduction. In practice, the punch generally exhibits a shorter service life than the die. The present study proposes a technological solution for reconditioning worn extrusion punches using vibration-assisted welding (VAW). A wear-resistant layer was deposited by MIG welding using DUR 600 filler material, while mechanical vibrations were introduced through a vibrating welding table. The applied vibration regime consisted of a frequency of 50 Hz–108 Hz and acceleration components of a_x = 30–60 m/s² and a_z = 35–70 m/s². The experimental investigations included macroscopic analysis, hardness and microhardness measurements, microstructural observations, and SEM-EDS line scanning analysis of the dilution zone between the cladding material and the base metal. The results suggest that vibration-assisted welding may influence the microstructural characteristics, hardness distribution, and dilution behavior of the cladded layer. The vibrated specimens exhibited higher hardness values in the range of 702 to 908 HV5–10. Under the investigated conditions, the process did not require additional hardening treatment, and only a stress-relief annealing stage was applied. The proposed VAW approach appears to be a promising option for the reconditioning of hot extrusion tools; however, further investigations are required to validate its performance under industrial conditions. Full article

Background: Mechanical trauma during pregnancy from motor vehicle accidents, falls, and maternal seizures poses significant risks to fetal development. The fetus is protected by multiple hierarchical layers including the uterine wall, amniotic fluid, and cerebrospinal fluid surrounding the brain. Despite the clinical significance of maternal trauma occurring in approximately six to eight percent of pregnancies, previous computational studies have focused primarily on amniotic fluid protection while treating the fetus as a homogeneous structure, without examining the nested protective architecture comprising both amniotic fluid and cerebrospinal fluid as an integrated system. Methods: This investigation implements a nested fluid–structure interaction framework simultaneously capturing three hierarchically organized systems: the uterine wall interacting with amniotic fluid, amniotic fluid interacting with the fetal body, and the cranial system comprising skull, cerebrospinal fluid, and brain tissue. The computational architecture employs smoothed particle hydrodynamics for fluid domains coupled with finite element methods for solid structures. Boundary conditions representing traumatic forces were obtained through experimental protocols using an instrumented medical simulation mannequin performing seizure movements. Results: Computational simulations predicted that amniotic fluid absorbed the majority of impact forces through hydraulic cushioning, while cerebrospinal fluid provided additional stress reduction through pressure redistribution, with model predictions suggesting total stress reduction exceeding ninety percent. Peak fetal brain stress values predicted by the model were below injury thresholds reported in adult neural tissue literature, though direct applicability of these thresholds to fetal tissue remains uncertain. The fetal brain exhibited minimal movement relative to the skull despite complex force cascades. Stress distributions showed elevated values in the frontal lobe and brainstem, though magnitudes remained within ranges that the model suggests may be tolerable. Conclusions: Computational modeling suggests that the nested fluid protection architecture operates as an integrated hierarchical system providing potential mechanical protection through sequential energy dissipation. These findings represent model predictions requiring experimental and clinical validation before translation to clinical practice. Full article

This work proposes the doping of bi-electron transport layers consisting of TiO₂/SnO₂ with iron to facilitate electron movement and recombination reduction, which results in increases in power conversion efficiency and stability enhancement. Two different PSC structures are used: device 1—FTO/TiO₂/SnO₂/MAPbI₃/Spiro-OMETAD/Ag; device 2, a modified device—FTO/TiO₂/SnO₂ + Fe/MAPbI₃/Spiro-OMETAD/Ag. Characterization analysis revealed an improvement in perovskite crystallinity in the modified device; this leads to reductions in trap state density and the recombination of charges that enhance charge extraction. UV-vis absorbance enhancement in the modified device revealed an enhancement in the perovskite layer morphology and good coverage. As a result, PSCs with a short circuit current of 23.35 mA/cm², open circuit voltage of 1.07 V, fill factor of 0.73, and high PCE of 18.17% are obtained from device 2, compared to PSCs with only 22.13 mA/cm², 1.03 V, 0.7, and 16.053% for device 1 without Fe doping, respectively. The results reveal that the device based on Fe doping is more stable than the pristine one under stability tests with regard to aging, thermal, stress and prolonged light. Full article

In this study, the nonlocal theory of peridynamics (PD) is adopted to simulate elastic wave propagation in an infinite plate. To realistically represent an unbounded domain and suppress artificial wave reflections at computational boundaries, the perfectly matched layer (PML) technique is incorporated into the peridynamic framework. A refined non-ordinary state-based peridynamic (RNOSB-PD) formulation is developed in which the peridynamic differential operator is employed to accurately capture wave kinematics and stress responses. The proposed model is validated through numerical simulations of wave propagation, where displacement field is examined within both the physical domain and the absorbing layers. The results demonstrate that the peridynamic PML effectively attenuates outgoing waves without generating spurious reflections, leading to responses that closely replicate those of an infinite plate. This study confirms the robustness and accuracy of the RNOSB-PD–PML approach and highlights its potential for simulating wave phenomena in unbounded or large-scale solid mechanics problems involving nonlocal effects. Full article

Additive manufacturing enables the fabrication of personalized protective equipment with locally tailored mechanical properties. In this work, a low-cost scan-to-print workflow is proposed for the fused filament fabrication (FFF) of personalized dual-zone shin guards combining a stiff outer load-distribution layer with a compliant inner energy-absorbing layer. Subject-specific leg geometry was acquired via structured-light 3D scanning and used to design a shin guard with two 3.5 mm thick zones (total thickness 7 mm). Foamable filaments of PLA, ASA, and TPU were employed to manufacture unfoamed and foamed regions by controlling extrusion temperature. Mechanical performance was assessed through three-point bending tests and dynamic finite element impact simulations. Unfoamed PLA and ASA exhibited flexural strengths of approximately 88 MPa and 72 MPa, respectively, while foaming reduced these values by about 74%. Dual-zone configurations partially restored stiffness, reaching 41 MPa for PLA and 29 MPa for ASA. TPU showed lower flexural stresses with a smaller reduction of 23% upon foaming. Impact simulations revealed maximum deformations of 1.97 mm and 2.02 mm for PLA and ASA outer zones, respectively, while TPU exhibited large deformations leading to penetration of the 3.5 mm thick inner layer. The results demonstrate that dual-zone designs manufactured via foaming-enabled FFF can effectively balance stiffness, weight, and impact response for personalized shin guard applications. Full article