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32 pages, 1939 KiB  
Review
A Review on Anaerobic Digestate as a Biofertilizer: Characteristics, Production, and Environmental Impacts from a Life Cycle Assessment Perspective
by Carmen Martín-Sanz-Garrido, Marta Revuelta-Aramburu, Ana María Santos-Montes and Carlos Morales-Polo
Appl. Sci. 2025, 15(15), 8635; https://doi.org/10.3390/app15158635 (registering DOI) - 4 Aug 2025
Viewed by 94
Abstract
Digestate valorization is essential for sustainable waste management and circular economy strategies, yet large-scale adoption faces technical, economic, and environmental challenges. Beyond waste-to-energy conversion, digestate is a valuable soil amendment, enhancing soil structure and reducing reliance on synthetic fertilizers. However, its agronomic benefits [...] Read more.
Digestate valorization is essential for sustainable waste management and circular economy strategies, yet large-scale adoption faces technical, economic, and environmental challenges. Beyond waste-to-energy conversion, digestate is a valuable soil amendment, enhancing soil structure and reducing reliance on synthetic fertilizers. However, its agronomic benefits depend on feedstock characteristics, treatment processes, and application methods. This study reviews digestate composition, treatment technologies, regulatory frameworks, and environmental impact assessment through Life Cycle Assessment. It analyzes the influence of functional unit selection and system boundary definitions on Life Cycle Assessment outcomes and the effects of feedstock selection, pretreatment, and post-processing on its environmental footprint and fertilization efficiency. A review of 28 JCR-indexed articles (2018–present) analyzed LCA studies on digestate, focusing on methodologies, system boundaries, and impact categories. The findings indicate that Life Cycle Assessment methodologies vary widely, complicating direct comparisons. Transportation distances, nutrient stability, and post-processing strategies significantly impact greenhouse gas emissions and nutrient retention efficiency. Techniques like solid–liquid separation and composting enhance digestate stability and agronomic performance. Digestate remains a promising alternative to synthetic fertilizers despite market uncertainty and regulatory inconsistencies. Standardized Life Cycle Assessment methodologies and policy incentives are needed to promote its adoption as a sustainable soil amendment within circular economy frameworks. Full article
(This article belongs to the Special Issue Novel Research on By-Products and Treatment of Waste)
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29 pages, 5505 KiB  
Article
Triaxial Response and Elastoplastic Constitutive Model for Artificially Cemented Granular Materials
by Xiaochun Yu, Yuchen Ye, Anyu Yang and Jie Yang
Buildings 2025, 15(15), 2721; https://doi.org/10.3390/buildings15152721 - 1 Aug 2025
Viewed by 159
Abstract
Because artificially cemented granular (ACG) materials employ diverse combinations of aggregates and binders—including cemented soil, low-cement-content cemented sand and gravel (LCSG), and concrete—their stress–strain responses vary widely. In LCSG, the binder dosage is typically limited to 40–80 kg/m3 and the sand–gravel skeleton [...] Read more.
Because artificially cemented granular (ACG) materials employ diverse combinations of aggregates and binders—including cemented soil, low-cement-content cemented sand and gravel (LCSG), and concrete—their stress–strain responses vary widely. In LCSG, the binder dosage is typically limited to 40–80 kg/m3 and the sand–gravel skeleton is often obtained directly from on-site or nearby excavation spoil, endowing the material with a markedly lower embodied carbon footprint and strong alignment with current low-carbon, green-construction objectives. Yet, such heterogeneity makes a single material-specific constitutive model inadequate for predicting the mechanical behavior of other ACG variants, thereby constraining broader applications in dam construction and foundation reinforcement. This study systematically summarizes and analyzes the stress–strain and volumetric strain–axial strain characteristics of ACG materials under conventional triaxial conditions. Generalized hyperbolic and parabolic equations are employed to describe these two families of curves, and closed-form expressions are proposed for key mechanical indices—peak strength, elastic modulus, and shear dilation behavior. Building on generalized plasticity theory, we derive the plastic flow direction vector, loading direction vector, and plastic modulus, and develop a concise, transferable elastoplastic model suitable for the full spectrum of ACG materials. Validation against triaxial data for rock-fill materials, LCSG, and cemented coal–gangue backfill shows that the model reproduces the stress and deformation paths of each material class with high accuracy. Quantitative evaluation of the peak values indicates that the proposed constitutive model predicts peak deviatoric stress with an error of 1.36% and peak volumetric strain with an error of 3.78%. The corresponding coefficients of determination R2 between the predicted and measured values are 0.997 for peak stress and 0.987 for peak volumetric strain, demonstrating the excellent engineering accuracy of the proposed model. The results provide a unified theoretical basis for deploying ACG—particularly its low-cement, locally sourced variants—in low-carbon dam construction, foundation rehabilitation, and other sustainable civil engineering projects. Full article
(This article belongs to the Special Issue Low Carbon and Green Materials in Construction—3rd Edition)
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21 pages, 1456 KiB  
Article
Life Cycle Assessment of Land Use Trade-Offs in Indoor Vertical Farming
by Ana C. Cavallo, Michael Parkes, Ricardo F. M. Teixeira and Serena Righi
Appl. Sci. 2025, 15(15), 8429; https://doi.org/10.3390/app15158429 - 29 Jul 2025
Viewed by 239
Abstract
Urban agriculture (UA) is emerging as a promising strategy for sustainable food production in response to growing environmental pressures. Indoor vertical farming (IVF), combining Controlled Environment Agriculture (CEA) with Building-Integrated Agriculture (BIA), enables efficient resource use and year-round crop cultivation in urban settings. [...] Read more.
Urban agriculture (UA) is emerging as a promising strategy for sustainable food production in response to growing environmental pressures. Indoor vertical farming (IVF), combining Controlled Environment Agriculture (CEA) with Building-Integrated Agriculture (BIA), enables efficient resource use and year-round crop cultivation in urban settings. This study assesses the environmental performance of a prospective IVF system located on a university campus in Portugal, focusing on the integration of photovoltaic (PV) energy as an alternative to the conventional electricity grid (GM). A Life Cycle Assessment (LCA) was conducted using the Environmental Footprint (EF) method and the LANCA model to account for land use and soil-related impacts. The PV-powered system demonstrated lower overall environmental impacts, with notable reductions across most impact categories, but important trade-offs with decreased soil quality. The LANCA results highlighted cultivation and packaging as key contributors to land occupation and transformation, while also revealing trade-offs associated with upstream material demands. By combining EF and LANCA, the study shows that IVF systems that are not soil-based can still impact soil quality indirectly. These findings contribute to a broader understanding of sustainability in urban farming and underscore the importance of multi-dimensional assessment approaches when evaluating emerging agricultural technologies. Full article
(This article belongs to the Special Issue Innovative Engineering Technologies for the Agri-Food Sector)
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25 pages, 5461 KiB  
Article
Spaceborne LiDAR Reveals Anthropogenic and Biophysical Drivers Shaping the Spatial Distribution of Forest Aboveground Biomass in Eastern Himalayas
by Abhilash Dutta Roy, Abraham Ranglong, Sandeep Timilsina, Sumit Kumar Das, Michael S. Watt, Sergio de-Miguel, Sourabh Deb, Uttam Kumar Sahoo and Midhun Mohan
Land 2025, 14(8), 1540; https://doi.org/10.3390/land14081540 - 27 Jul 2025
Viewed by 424
Abstract
The distribution of forest aboveground biomass density (AGBD) is a key indicator of carbon stock and ecosystem health in the Eastern Himalayas, which represents a global biodiversity hotspot that sustains diverse forest types across an elevation gradient from lowland rainforests to alpine meadows [...] Read more.
The distribution of forest aboveground biomass density (AGBD) is a key indicator of carbon stock and ecosystem health in the Eastern Himalayas, which represents a global biodiversity hotspot that sustains diverse forest types across an elevation gradient from lowland rainforests to alpine meadows and contributes to the livelihoods of more than 200 distinct indigenous communities. This study aimed to identify the key factors influencing forest AGBD across this region by analyzing the underlying biophysical and anthropogenic drivers through machine learning (random forest). We processed AGBD data from the Global Ecosystem Dynamics Investigation (GEDI) spaceborne LiDAR and applied filtering to retain 30,257 high-quality footprints across ten ecoregions. We then analyzed the relationship between AGBD and 17 climatic, topographic, soil, and anthropogenic variables using random forest regression models. The results revealed significant spatial variability in AGBD (149.6 ± 79.5 Mg ha−1) across the region. State-wise, Sikkim recorded the highest mean AGBD (218 Mg ha−1) and Manipur the lowest (102.8 Mg ha−1). Within individual ecoregions, the Himalayan subtropical pine forests exhibited the highest mean AGBD (245.5 Mg ha−1). Topographic factors, particularly elevation and latitude, were strong determinants of biomass distribution, with AGBD increasing up to elevations of 2000 m before declining. Protected areas (PAs) consistently showed higher AGBD than unprotected forests for all ecoregions, while proximity to urban and agricultural areas resulted in lower AGBD, pointing towards negative anthropogenic impacts. Our full model explained 41% of AGBD variance across the Eastern Himalayas, with better performance in individual ecoregions like the Northeast India-Myanmar pine forests (R2 = 0.59). While limited by the absence of regionally explicit stand-level forest structure data (age, stand density, species composition), our results provide valuable evidence for conservation policy development, including expansion of PAs, compensating avoided deforestation and modifications in shifting cultivation. Future research should integrate field measurements with remote sensing and use high-resolution LiDAR with locally derived allometric models to enhance biomass estimation and GEDI data validation. Full article
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23 pages, 2364 KiB  
Review
A Comprehensive Review of Applications and Environmental Risks of Waste Plastics in Asphalt Pavements
by Ju Pan, Jue Li, Bailin Shan, Yongsheng Yao and Chao Huang
Materials 2025, 18(15), 3441; https://doi.org/10.3390/ma18153441 - 22 Jul 2025
Viewed by 252
Abstract
The global plastic crisis has generated significant interest in repurposing waste plastics as asphalt modifiers, presenting both environmental and engineering advantages. This study offers a comprehensive review of the applications of waste plastics in asphalt, focusing on their types, modification mechanisms, incorporation techniques, [...] Read more.
The global plastic crisis has generated significant interest in repurposing waste plastics as asphalt modifiers, presenting both environmental and engineering advantages. This study offers a comprehensive review of the applications of waste plastics in asphalt, focusing on their types, modification mechanisms, incorporation techniques, and environmental impacts, alongside proposed mitigation strategies. Commonly utilized plastics include polyethylene (PE), polypropylene (PP), polystyrene (PS), polyvinyl chloride (PVC), and polyethylene terephthalate (PET), each affecting asphalt performance differently—enhancing high-temperature stability and fatigue resistance while exhibiting varying levels of compatibility and environmental risks. The incorporation techniques, namely wet and dry processes, differ in terms of efficiency, cost, and environmental footprint: the wet process enhances durability but requires more energy, whereas the dry process is more cost-effective but may lead to uneven dispersion. Environmental concerns associated with these practices include toxic emissions (such as polycyclic aromatic hydrocarbons and volatile organic compounds) during production, microplastic generation through abrasion and weathering, and ecological contamination of soil and water. Mitigation strategies encompass optimizing plastic selection, improving pre-treatment and compatibilization methods, controlling high-temperature processing, and monitoring the spread of microplastics. This review highlights the need for balanced adoption of waste plastic-modified asphalt, emphasizing sustainable practices to maximize benefits while minimizing risks. Full article
(This article belongs to the Section Construction and Building Materials)
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16 pages, 2469 KiB  
Article
Application of Gelatin for Sustainable Stabilization of Low-Compressible Silt–Clay Mixtures: Geotechnical Behavior and Carbon Emission Considerations
by Evangelin Ramani Sujatha, Veera Ragavan Pratheeba, Jair De Jesus Arrieta Baldovino and Yamid E. Nunez de la Rosa
Polymers 2025, 17(14), 1954; https://doi.org/10.3390/polym17141954 - 17 Jul 2025
Viewed by 299
Abstract
Biopolymers, owing to their environmentally friendly and sustainable characteristics, have become a promising alternative for soil stabilization in geotechnical engineering. The application of protein-based biopolymers as binders for soil stabilization is less prevalent in geotechnical engineering compared to polysaccharide-based biopolymers. This study explores [...] Read more.
Biopolymers, owing to their environmentally friendly and sustainable characteristics, have become a promising alternative for soil stabilization in geotechnical engineering. The application of protein-based biopolymers as binders for soil stabilization is less prevalent in geotechnical engineering compared to polysaccharide-based biopolymers. This study explores the potential of gelatin, a protein-based biopolymer derived from animal collagen, for stabilizing silty sand and improving its geotechnical properties. Gelatin was mixed into the soil at concentrations ranging from 0.25% to 2% of the dry weight of soil, and its effects on various soil characteristics were evaluated. The tests conducted include liquid limit, plastic limit, compaction behavior, and unconfined compressive strength (UCS); the addition of 1% gelatin led to an approximate 1.69 times increase in the strength of the unamended soil. After 28 days of curing, the UCS improved by approximately 5.03 times compared to the untreated soil, and the treated soil exhibited increased resistance to deformation under load. Microstructural analysis using scanning electron microscopy (SEM) revealed that gelatin facilitated the formation of a cohesive matrix, enhancing particle bonding and reducing void spaces within the soil. Carbon footprint analysis (CFA) conducted on an isolated footing stabilized with gelatin showed that the carbon emissions were reduced by 99.8% and 99% compared to traditional stabilizers such as lime and cement. Additionally, the interaction between the biopolymer and the fine-grained soil is distinctly evident in the FTIR and XRD analysis through hydrogen bonding and the formation of cementitious compounds. Full article
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20 pages, 5507 KiB  
Article
Variable-Rate Nitrogen Application in Wheat Based on UAV-Derived Fertilizer Maps and Precision Agriculture Technologies
by Alexandros Tsitouras, Christos Noulas, Vasilios Liakos, Stamatis Stamatiadis, Miltiadis Tziouvalekas, Ruijun Qin and Eleftherios Evangelou
Agronomy 2025, 15(7), 1714; https://doi.org/10.3390/agronomy15071714 - 16 Jul 2025
Viewed by 1201
Abstract
Variable-rate nitrogen (VR-N) application allows farmers to optimize nitrogen (N) input site-specifically within field boundaries, enhancing both economic efficiency and environmental sustainability. In this study, VR-N technology was applied to durum wheat in two small-scale commercial fields (3–4 ha each) located in distinct [...] Read more.
Variable-rate nitrogen (VR-N) application allows farmers to optimize nitrogen (N) input site-specifically within field boundaries, enhancing both economic efficiency and environmental sustainability. In this study, VR-N technology was applied to durum wheat in two small-scale commercial fields (3–4 ha each) located in distinct agro-climatic zones of Thessaly, central Greece. A real-time VR-N application algorithm was used to calculate N rates based on easily obtainable near-real-time data from unmanned aerial vehicle (UAV) imagery, tailored to the crop’s actual needs. VR-N implementation was carried out using conventional fertilizer spreaders equipped to read prescription maps. Results showed that VR-N reduced N input by up to 49.6% compared to the conventional uniform-rate N (UR-N) application, with no significant impact on wheat yield or grain quality. In one of the fields, the improved gain of VR-N when compared to UR-N was 7.2%, corresponding to an economic gain of EUR 163.8 ha−1, while in the second field—where growing conditions were less favorable—no considerable VR-N economic gain was observed. Environmental benefits were also notable. The carbon footprint (CF) of the wheat crop was reduced by 6.4% to 22.0%, and residual soil nitrate (NO3) levels at harvest were 13.6% to 36.1% lower in VR-N zones compared to UR-N zones. These findings suggest a decreased risk of NO3 leaching and ground water contamination. Overall, the study supports the viability of VR-N as a practical and scalable approach to improve N use efficiency (NUE) and reduce the environmental impact of wheat cultivation which could be readily adopted by farmers. Full article
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18 pages, 1777 KiB  
Review
Biochar in Agriculture: A Review on Sources, Production, and Composites Related to Soil Fertility, Crop Productivity, and Environmental Sustainability
by Md. Muzammal Hoque, Biplob Kumar Saha, Antonio Scopa and Marios Drosos
C 2025, 11(3), 50; https://doi.org/10.3390/c11030050 - 11 Jul 2025
Viewed by 870
Abstract
Due to soil nutrient depletion and rising food demand from an increasing global population, it is essential to find sustainable ways to boost crop yields, improve soil health, and address the environmental issues induced by agriculture. The most appropriate approach is to consider [...] Read more.
Due to soil nutrient depletion and rising food demand from an increasing global population, it is essential to find sustainable ways to boost crop yields, improve soil health, and address the environmental issues induced by agriculture. The most appropriate approach is to consider sustainable amendments, such as biochar and its derivatives, which are vital constituents of soil health due to their affordability, low reactivity, large surface area, and reduced carbon footprint. In this context, biochar and its derivatives in farming systems focus on improving soil structure, nutrient holding capacity, microbial activities, and the perpetuation of soil fertility. Despite its benefits, biochar, if it is used in high concentration, can sometimes become highly toxic, causing soil erosion due to reducing surface area, increasing pH levels, and altering soil properties. This review highlights the production methods and sources of feedstocks, emphasizing their important contribution to the soil’s physicochemical and biological properties. Furthermore, it critically evaluates the environmental applications and their impacts, providing data built upon the literature on contaminant removal from soil, economic factors, heavy metal immobilization, carbon sequestration, and climate resilience. This review emphasizes the main challenges and future prospects for biochar use in comparison to modified biochar (MB) to propose the best practices for sustainable farming systems. Full article
(This article belongs to the Special Issue Carbons for Health and Environmental Protection (2nd Edition))
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32 pages, 1575 KiB  
Review
A Review of Reject Brine Disposal, Management, and Construction Applications
by Pranita Banerjee, Essam K. Zaneldin, Ali H. Al-Marzouqi and Waleed K. Ahmed
Buildings 2025, 15(13), 2317; https://doi.org/10.3390/buildings15132317 - 2 Jul 2025
Viewed by 933
Abstract
Desalination is becoming crucial to meet the increasing global demand for potable water. Despite its benefits, desalination produces reject brine, a highly concentrated saline byproduct, which poses substantial environmental risks if not managed properly. It contains high levels of salts and other potentially [...] Read more.
Desalination is becoming crucial to meet the increasing global demand for potable water. Despite its benefits, desalination produces reject brine, a highly concentrated saline byproduct, which poses substantial environmental risks if not managed properly. It contains high levels of salts and other potentially harmful compounds, which, when discharged into oceans or land, can disrupt habitats, degrade soil quality, and harm biodiversity, creating serious environmental challenges. In response to these challenges, this study investigated various uses for reject brine, aiming to reduce its environmental footprint and explore its potential applications. This review paper synthesizes findings from previous studies on the disposal, management, and applications of reject brine in fields such as concrete production, road construction, and ground stabilization. In addition, this review highlights the potential cost savings and resource efficiency resulting from the utilization of reject brine, as well as the mitigation of environmental impacts associated with traditional disposal methods. This paper also provides a comprehensive overview of existing technologies and approaches used to utilize reject brine in various industries, including construction. This review contributes to the growing body of knowledge on environmentally friendly solutions for reject brine, emphasizing its potential role in supporting sustainable development goals through resource reutilization and waste minimization. The study also highlights current research gaps that are still unaddressed, hindering the complete realization of the full potential of reject brine as a sustainable resource. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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18 pages, 11466 KiB  
Article
Water Footprint Through an Analysis of Water Conservation Policy: Comparative Analysis of Water-Intensive and Water-Efficient Crops Using IoT-Driven ML Models
by Mahdi Moudi, Dan Xie, Lin Cao, Hehuai Zhang, Yunchu Zhang and Bahador Bahramimianrood
Water 2025, 17(13), 1964; https://doi.org/10.3390/w17131964 - 30 Jun 2025
Viewed by 462
Abstract
Although economic profitability and food security often outweigh water conservation priorities in arid and semi-arid regions, this study investigates irrigation practices by evaluating water footprint and economic feasibility through a comparative analysis of water-intensive and water-efficient crops. In this context, an optimal irrigation [...] Read more.
Although economic profitability and food security often outweigh water conservation priorities in arid and semi-arid regions, this study investigates irrigation practices by evaluating water footprint and economic feasibility through a comparative analysis of water-intensive and water-efficient crops. In this context, an optimal irrigation disparity framework integrated with Internet of Things (IoT) and Machine Learning (ML) mechanisms is proposed to evaluate the effectiveness of water conservation, thereby assessing the potential for enhancing economic profitability. IoT-enabled components are employed to monitor real-time environmental—soil moisture, temperature, and weather—conditions between March and November 2023. This data is processed using a hybrid modeling approach that integrates KNN, GBT, and LSTM algorithms to predict both the duration of cultivation and the water requirements. Finally, the predicted parameters are incorporated into a multi-objective framework aimed at minimizing the disparity in water allocation per net benefit. The final results indicate that saffron required substantially less water—ranging from (19.87 to 28.65 ∗ 106 m3)—compared to watermelon, which consumed (34.61 to 47.07 ∗ 106 m3), while achieving a higher average net profit (33 ∗ 109 IRR) relative to watermelon (31 ∗ 109 IRR). Moreover, saffron consistently approached optimal values across disparity-based objective functions, averaging (0.404). These findings emphasize the dual advantages of saffron as a value-added, water-efficient crop in achieving substantial water conservation while enhancing profitability, offering actionable insights for authorities to incentivize water-efficient crop adoption through subsidies, market mechanisms, or regulatory frameworks. These strategies operationalize technical insights into actionable pathways for balancing food security, economic growth, and environmental resilience. Full article
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28 pages, 3748 KiB  
Article
Carob–Thyme Intercropping Systems Can Improve Yield Efficiency and Environmental Footprint Compared to Conservation Tillage
by Sofia Matsi, Dimitrios Sarris and Vassilis Litskas
Agronomy 2025, 15(7), 1560; https://doi.org/10.3390/agronomy15071560 - 26 Jun 2025
Viewed by 319
Abstract
Living mulch intercropping systems are considered as nature-based solutions with a low environmental footprint for managing weeds, improving biodiversity and agroecosystem sustainability. In drylands, however, they may increase intra/inter-specific competition for water, reducing crop productivity. We tested conservation tillage (TLG) carob plots with [...] Read more.
Living mulch intercropping systems are considered as nature-based solutions with a low environmental footprint for managing weeds, improving biodiversity and agroecosystem sustainability. In drylands, however, they may increase intra/inter-specific competition for water, reducing crop productivity. We tested conservation tillage (TLG) carob plots with and without irrigation (TLGirr; TLGdry) vs. rainfed intercropping systems of carob and (i) thyme (Thymbra capitata; T-System) or (ii) clover (Trifolium squarrosum; C-System), strategically planted on the south (sun)-exposed soil side (SES) of carobs, to reduce soil temperature/evaporation. Carob water relations, productivity and environmental footprints were examined for three years under semi-arid, low weed-competition (Skarinou-SKR) and arid high weed-competition (Vrysoules-VRY) conditions in Cyprus. Carob yield efficiency (kg/m3) in SKR, was >27% higher for the T-System (p < 0.05; SES cover ca. 85%; year-3), matching a higher leaf water content (p < 0.001) compared to TLGdry. The T-System reached 28% and 56% of TLGirr yields during very dry and normal rainfall years; TLGdry yields approached zero. For VRY, no negative impacts on carob leaf water, at 25% SES cover, were found. SKR’s C-System improved leaf water content (p < 0.05) for only one year. The T-System also outperformed TLGirr and TLGdry in terms of reducing irrigation needs and energy consumption, breaking new grounds for dryland agroforestry. Full article
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17 pages, 7728 KiB  
Article
Comparative Effects of Nitrogen Fertigation and Granular Fertilizer Application on Pepper Yield and Soil GHGs Emissions
by Antonio Manco, Matteo Giaccone, Luca Vitale, Giuseppe Maglione, Maria Riccardi, Bruno Di Matteo, Andrea Esposito, Vincenzo Magliulo and Anna Tedeschi
Horticulturae 2025, 11(6), 708; https://doi.org/10.3390/horticulturae11060708 - 19 Jun 2025
Viewed by 749
Abstract
Quantitative greenhouse gas (GHG) budgets for Mediterranean pepper cultivation are still missing, limiting evidence-based nitrogen management. Furthermore, mitigation value of fertigation respect to granular fertilization in vegetable systems remains uncertain. This study therefore compared the GHG footprint and productivity of ‘papaccella’ pepper under [...] Read more.
Quantitative greenhouse gas (GHG) budgets for Mediterranean pepper cultivation are still missing, limiting evidence-based nitrogen management. Furthermore, mitigation value of fertigation respect to granular fertilization in vegetable systems remains uncertain. This study therefore compared the GHG footprint and productivity of ‘papaccella’ pepper under two nitrogen fertilization methods: granular fertilization versus low-frequency fertigation with urea, each supplying about 63 kg N ha−1. Eight automated static chambers coupled to a cavity ring-down spectrometer monitored soil CO2 and N2O fluxes throughout the season. Cumulative emissions did not differ between treatments (CO2: 811 ± 6 g m−2 vs. 881 ± 4 g m−2; N2O: 0.038 ± 0.008 g m−2 vs. 0.041 ± 0.015 g m−2, fertigation vs. granular), and marketable yield remained at ~11 t ha−1, leaving product-scaled global warming potential (GWP) unchanged. Although representing less than 2% of measured fluxes, “hot moments,” burst emissions exceeding four standard deviations (SD) from the mean, accounted for up to 4% of seasonal CO2 and 19% of N2O. Fertigation doubled the frequency of these events but reduced their peak magnitude, whereas granular application produced fewer but more extreme bursts (>11 SD). Results showed that fertigation did not mitigate GHGs emission nor improve productivity for Mediterranean pepper, mainly due to the low application frequency and the use of a urea fertilizer. Moreover, we can highlight that in horticultural systems, omitting ‘hot moments’ leads to systematic underestimation of emissions. Full article
(This article belongs to the Section Plant Nutrition)
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17 pages, 1809 KiB  
Review
Biodegradable Microplastics: Environmental Fate and Persistence in Comparison to Micro- and Nanoplastics from Traditional, Non-Degradable Polymers
by Paolo Costa and Maximilian Lackner
Macromol 2025, 5(2), 29; https://doi.org/10.3390/macromol5020029 - 18 Jun 2025
Cited by 1 | Viewed by 1207
Abstract
The escalating production of virgin plastics has resulted in an unprecedented generation of microplastics (MPs), posing significant environmental and health risks. Biodegradable plastics have emerged as an alternative, but their degradation also releases microplastic-sized particles, referred to as biodegradable microplastics (BMPs). This review [...] Read more.
The escalating production of virgin plastics has resulted in an unprecedented generation of microplastics (MPs), posing significant environmental and health risks. Biodegradable plastics have emerged as an alternative, but their degradation also releases microplastic-sized particles, referred to as biodegradable microplastics (BMPs). This review evaluates the current understanding of BMPs, focusing on their environmental fate, degradation kinetics, and comparative persistence relative to conventional MPs. The degradation process of biodegradable plastics involves sequential abiotic and biotic mechanisms, with factors such as polymer chemistry, geometry, and environmental conditions influencing BMPs’ formation and mineralization. Studies highlight the temporal advantage of BMPs, which exhibit significantly shorter lifetimes than traditional MPs; however, their environmental impact remains context-dependent, particularly in soil and aquatic systems. Despite promising results under controlled conditions, challenges in standardizing biodegradation assessments and discrepancies between laboratory and real-world scenarios complicate evaluations of the temporal fate and the effects of BMPs. This work underscores the need for long-term studies and improved modeling approaches to accurately predict BMP behavior and mitigate their ecological impact. Poly(hydroxyalkanoates) are a class of fully biodegradable polymers that do not leave behind persistent microplastics. Biodegradable plastics should be prioritized over non-degradable, traditional polymers, as they can replace them in a large fraction of applications, yet with a significantly reduced footprint and without leaving behind persistent micro- and nanoplastics. They can also be recycled. Full article
(This article belongs to the Collection Advances in Biodegradable Polymers)
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18 pages, 3882 KiB  
Review
Sustainable Soil–Cement Composites with Rice Husk Ash and Silica Fume: A Review of Performance and Environmental Benefits
by Xiaosan Yin, Md Mashiur Rahman, Yuzhou Sun, Yi Zhao and Jian Wang
Materials 2025, 18(12), 2880; https://doi.org/10.3390/ma18122880 - 18 Jun 2025
Viewed by 535
Abstract
The construction industry urgently requires sustainable alternatives to conventional cement to mitigate its environmental footprint, which includes 8% of global CO2 emissions. This review critically examines the potential of rice husk ash (RHA) and silica fume (SF)—industrial and agricultural byproducts—as high-performance supplementary [...] Read more.
The construction industry urgently requires sustainable alternatives to conventional cement to mitigate its environmental footprint, which includes 8% of global CO2 emissions. This review critically examines the potential of rice husk ash (RHA) and silica fume (SF)—industrial and agricultural byproducts—as high-performance supplementary cementitious materials (SCMs) in soil–cement composites. Their pozzolanic reactivity, microstructural enhancement mechanisms, and durability improvements (e.g., compressive strength gains of up to 31.7% for RHA and 250% for SF) are analyzed. This study highlights the synergistic effects of RHA/SF blends in refining pore structure, reducing permeability, and enhancing resistance to chemical attacks. Additionally, this paper quantifies the environmental benefits, including CO2 emission reduction (up to 25% per ton of cement replaced) and resource recovery from agricultural/industrial waste streams. Challenges such as material variability, optimal dosage (10–15% RHA, 5–8% SF), and regulatory barriers are discussed, alongside future directions for scalable adoption. This work aligns with SDGs 9, 11, and 12, offering actionable insights for sustainable material design. Full article
(This article belongs to the Section Construction and Building Materials)
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14 pages, 1966 KiB  
Article
Evaluation of Water Security in a Water Source Area from the Perspective of Nonpoint Source Pollution
by Jun Yang, Ruijun Su, Yanbo Wang and Yongzhong Feng
Sustainability 2025, 17(11), 4998; https://doi.org/10.3390/su17114998 - 29 May 2025
Viewed by 545
Abstract
Water security is a basic requirement of a region’s residents and also an important point of discussion worldwide. The middle route of the south-to-north water diversion project (MR-SNWDP) represents the most extensive inter-basin water allocation scheme globally. It is the major water resource [...] Read more.
Water security is a basic requirement of a region’s residents and also an important point of discussion worldwide. The middle route of the south-to-north water diversion project (MR-SNWDP) represents the most extensive inter-basin water allocation scheme globally. It is the major water resource for the Beijing–Tianjin–Hebei region, and its security is of great significance. In this study, 28 indicators including society, nature, and economy were selected from the water sources of the MR-SNWDP from 2000 to 2017. According to the Drivers-Pressures-States-Impact-Response (DPSIR) framework principle, the entropy weight method was used for weight calculation, and the comprehensive evaluation method was used for evaluating the water security of the water sources of the MR-SNWDP. This study showed that the total loss of nonpoint source pollution (NPSP) in the water source showed a trend of slow growth, except in 2007. Over the past 18 years, the proportion of pollution from three NPSP sources, livestock, and poultry (LP) breeding industry, planting industry, and living sources, were 44.56%, 40.33%, and 15.11%, respectively. The main driving force of water security in all the areas of the water source was the total net income per capita of farmers. The main pressure was the amount of LP breeding and the amount of fertilizer application. The largest impact indicators were NPSP gray water footprint and soil erosion area, and water conservancy investment was the most effective response measure. Overall, the state of the water source safety was relatively stable, showing an overall upward trend, and it had remained at Grade III except for in 2005, 2006, and 2011. The state of water safety in all areas except Shiyan City was relatively stable, where the state of water safety had fluctuated greatly. Based on the assessment findings, implications for policy and decision-making suggestions for sustainable management of the water sources of the MR-SNWDP resources are put forward. Agricultural cultivation in water source areas should reduce the application of chemical fertilizers and accelerate the promotion of agricultural intensification. Water source areas should minimize retail livestock and poultry farming and promote ecological agriculture. The government should increase investment in water conservancy and return farmland to forests and grasslands, and at the same time strengthen the education of farmers’ awareness of environmental protection. The evaluation system of this study combined indicators such as the impact of agricultural nonpoint source pollution on water bodies, which is innovative and provides a reference for the water safety evaluation system. Full article
(This article belongs to the Special Issue Hydrosystems Engineering and Water Resource Management)
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