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13 pages, 2675 KiB  
Article
Material Removal in Mycelium-Bonded Composites Through Laser Processing
by Maciej Sydor, Grzegorz Pinkowski and Agata Bonenberg
J. Compos. Sci. 2025, 9(8), 389; https://doi.org/10.3390/jcs9080389 - 23 Jul 2025
Viewed by 421
Abstract
Mycelium-bonded composites (MBCs), or myco-composites, represent a novel engineered material that combines natural lignocellulosic substrates with a fungal matrix. As a sustainable alternative to plastics, MBCs are gaining increasing interest; however, their large-scale industrial adoption remains limited, partly due to low social acceptance [...] Read more.
Mycelium-bonded composites (MBCs), or myco-composites, represent a novel engineered material that combines natural lignocellulosic substrates with a fungal matrix. As a sustainable alternative to plastics, MBCs are gaining increasing interest; however, their large-scale industrial adoption remains limited, partly due to low social acceptance resulting from their unattractive appearance. Laser engraving provides a promising method for fabricating intricate patterns and functional surfaces on MBCs, minimizing tool wear, material loss, and environmental impact, while enhancing esthetic and engineering properties. This study investigates the influence of CO2 laser parameters on the material removal rate during the engraving of myco-composites, focusing on the effects of variable laser power, beam defocus, and head feed rate on engraving outcomes. The results demonstrate that laser power and beam focus significantly impact material removal in mycelium-bonded composites. Specifically, increasing the laser power results in greater material removal, which is more pronounced when the beam is focused due to higher energy density. In contrast, a beam defocused by 1 mm produces less intense material removal. These findings highlight the critical role of beam focus—surpassing the influence of power alone—in determining engraving quality, particularly on irregular or uneven surfaces. Moreover, reducing the laser head feed rate at a constant power level increases the material removal rate linearly; however, it also results in excessive charring and localized overheating, revealing the low thermal tolerance of myco-composites. These insights are essential for optimizing laser processing techniques to fully realize the potential of mycelium-bonded composites as sustainable engineering materials, simultaneously maintaining their appearance and functional properties. Full article
(This article belongs to the Special Issue Advances in Laser Fabrication of Composites)
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19 pages, 4767 KiB  
Article
Risk Mitigation of a Heritage Bridge Using Noninvasive Sensors
by Ricky W. K. Chan and Takahiro Iwata
Sensors 2025, 25(12), 3727; https://doi.org/10.3390/s25123727 - 14 Jun 2025
Viewed by 348
Abstract
Bridges are fundamental components of transportation infrastructure, facilitating the efficient movement of people and goods. However, the conservation of heritage bridges introduces additional challenges, encompassing environmental, social, cultural, and economic dimensions of sustainability. This study investigates risk mitigation strategies for a heritage-listed, 120-year-old [...] Read more.
Bridges are fundamental components of transportation infrastructure, facilitating the efficient movement of people and goods. However, the conservation of heritage bridges introduces additional challenges, encompassing environmental, social, cultural, and economic dimensions of sustainability. This study investigates risk mitigation strategies for a heritage-listed, 120-year-old reinforced concrete bridge in Australia—one of the nation’s earliest examples of reinforced concrete construction, which remains operational today. The structure faces multiple risks, including passage of overweight vehicles, environmental degradation, progressive crack development due to traffic loading, and potential foundation scouring from an adjacent stream. Due to the heritage status and associated legal constraints, only non-invasive testing methods were employed. Ambient vibration testing was conducted to identify the bridge’s dynamic characteristics under normal traffic conditions, complemented by non-contact displacement monitoring using laser distance sensors. A digital twin structural model was subsequently developed and validated against field data. This model enabled the execution of various “what-if” simulations, including passage of overweight vehicles and loss of foundation due to scouring, providing quantitative assessments of potential risk scenarios. Drawing on insights gained from the case study, the article proposes a six-phase Incident Response Framework tailored for heritage bridge management. This comprehensive framework incorporates remote sensing technologies for incident detection, digital twin-based structural assessment, damage containment and mitigation protocols, recovery planning, and documentation to prevent recurrence—thus supporting the long-term preservation and functionality of heritage bridge assets. Full article
(This article belongs to the Special Issue Feature Papers in Physical Sensors 2025)
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17 pages, 3134 KiB  
Article
Hydrolyzed Chitin and Chitosan Blends as Reversible and Biocompatible Sorbents for Carbon Dioxide Sorption
by Preeti Sharma, Benjamin Barnes, Raekayla Johnson and Victoria V. Volkis
Compounds 2025, 5(2), 18; https://doi.org/10.3390/compounds5020018 - 15 May 2025
Viewed by 1196
Abstract
One of the most pressing issues confronting modern society is carbon dioxide pollution (CO2). The reliance of social progress on CO2-producing technologies such as power generation, automobiles, and specialized industrial processes exacerbates the problem. Due to this reliance, it [...] Read more.
One of the most pressing issues confronting modern society is carbon dioxide pollution (CO2). The reliance of social progress on CO2-producing technologies such as power generation, automobiles, and specialized industrial processes exacerbates the problem. Due to this reliance, it is critical to develop solutions to reduce CO2 emissions from these sources. One such solution is carbon capture and sequestration (CCS), which employs chemical methods to prevent CO2 emissions. The irreversibility of current CCS technology is its primary problem. Chitin, chitosan, and their derivatives, which were recovered from local seafood waste, are studied as reversible CO2 capture materials in this study in an effort to lessen this issue. Polysulfone (PSF) blends were employed to lessen chitosan edema, as chitosan’s hydrophilicity reduces its active sorption surface. Blends with only 20% chitosan have the same high sorption capacity as pure chitosan due to decreased swelling. Hydrolysis was used to boost the chitin sorption abilities. The CO2 sorption data were analyzed using an Intelligent Gravimetric Analyzer (IGA), Fourier-Transform Infrared (FTIR) spectroscopy, and Matrix-Assisted Laser Desorption/Ionization-Time of Flight (MALDI-TOF) spectroscopy. This study reveals that shrimp shells were the best source of chitin. This research led to the creation of eco-friendly, reversible, and reusable carbon sequestration sorbents. Full article
(This article belongs to the Special Issue Feature Papers in Compounds (2025))
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10 pages, 6671 KiB  
Communication
Thermo-Ablative Fractional CO2 Lasers Combined with 1540 nm Wavelengths Is a Promising Treatment Option in Stress Urinary Incontinence
by Maurizio Filippini, Sara Elmi, Jessica Sozzi, Laura Pieri, Irene Fusco, Tiziano Zingoni and Pablo González-Isaza
Med. Sci. 2025, 13(1), 25; https://doi.org/10.3390/medsci13010025 - 1 Mar 2025
Cited by 1 | Viewed by 1208
Abstract
Background/Objectives: Stress urinary incontinence (SUI) is a common and often under-reported condition that significantly impacts quality of life. SUI is more than just a physical issue; it can also affect social interactions, mental health, and emotional well-being due to the embarrassment and [...] Read more.
Background/Objectives: Stress urinary incontinence (SUI) is a common and often under-reported condition that significantly impacts quality of life. SUI is more than just a physical issue; it can also affect social interactions, mental health, and emotional well-being due to the embarrassment and limitations it can cause. SUI is often acquired during pregnancy and childbirth as a result of pelvic floor muscle weakness. The aim of this study was to evaluate the effectiveness of an innovative dual-wavelength laser system (CO2 + 1540 nm) in SUI management. Methods: A total of 56 women affected by SUI were enrolled in this study. Half of the patients were treated with CO2 alone, while the other half were treated with the combination of CO2 + 1540 nm wavelengths. The patients were split into four groups based on the type of treatment they received and their menopausal status. Data were acquired at baseline and at various follow-ups (T1, T2, and T3, respectively, after the first, second, and third treatment). The Visual Analog Scale (VAS) (score 0–10) was used. Cystoscopic images were acquired before and at the end of the laser treatment cycle. Results: At the end of the treatment, the patients in each group were very satisfied, on average. In each group, the treatment led to a statistically significant improvement in the SUI VAS score between baseline and follow-up after the first treatment; in both groups 3 and 4, the treatment led to a significant change in the dryness score, both from baseline to T1 (p < 0.05) and also for T2 and T3 compared to baseline. Finally, cystoscopic photos showed an evident increase in mucosa epithelial thickness after the laser treatment cycle. Conclusions: The use of a dual-wavelength laser system (CO2 + 1540 nm) was proven to be well tolerated and safe, with promising outcomes in reducing SUI symptoms, especially in non-menopausal patients. Full article
(This article belongs to the Section Gynecology)
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21 pages, 1854 KiB  
Article
Therapeutic Impact of Gardasil® in Recurrent Respiratory Papillomatosis: A Retrospective Study on RRP Patients
by Jennifer Sieg, Asita Fazel, Elgar Susanne Quabius, Astrid Dempfle, Susanne Wiegand and Markus Hoffmann
Viruses 2025, 17(3), 321; https://doi.org/10.3390/v17030321 - 26 Feb 2025
Cited by 1 | Viewed by 1295
Abstract
Background: Recurrent respiratory papillomatosis (RRP) is a rare, non-malignant disease caused by human papillomavirus (HPV) types 6 and 11. The condition primarily affects the larynx, potentially leading to life-threatening airway obstruction. It is more aggressive in younger patients, necessitating frequent surgical interventions. This [...] Read more.
Background: Recurrent respiratory papillomatosis (RRP) is a rare, non-malignant disease caused by human papillomavirus (HPV) types 6 and 11. The condition primarily affects the larynx, potentially leading to life-threatening airway obstruction. It is more aggressive in younger patients, necessitating frequent surgical interventions. This study investigates the therapeutic potential of the prophylactic HPV vaccine Gardasil® in RRP patients, focusing on its impact on lesion size and the frequency of surgical interventions. Furthermore, a literature review was conducted to analyze the factors influencing the decision to vaccinate. Methods: A retrospective analysis was conducted on 63 RRP patients treated from 2008 to 2021. Disease burden was assessed using the Derkay score and the annual frequency of laser-surgical ablations. Comparisons were made between pre- and post-vaccination periods in vaccinated patients (n = 18), and between first and second halves of the disease’s course in unvaccinated patients (n = 14). Results: A reduction in the frequency of surgical interventions post-vaccination (p < 0.05) could be seen. The cumulated Derkay score per year decreased after second and third vaccination (p < 0.05). The decision to be vaccinated is influenced by multiple factors (e.g., potential side-effects, sociocultural factors, impact of social media, pre-existing conditions and the wider context of the recent pandemic). Conclusions: Gardasil® appears to reduce the frequency of surgery and lessen disease severity in RRP patients, supporting the potential role of HPV vaccination as a therapeutic option for RRP. Moreover, it is crucial to overcome skepticism towards vaccinations to prevent the development of HPV-associated diseases in the first place. Full article
(This article belongs to the Special Issue Human and Animal Papillomavirus: Infections, Genetics, and Vaccines)
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19 pages, 1530 KiB  
Review
Periocular Aging Across Populations and Esthetic Considerations: A Narrative Review
by Brendan K. Tao, Fahad R. Butt, Thanansayan Dhivagaran, Michael Balas, Navdeep Nijhawan, Georges Nassrallah, Ahsen Hussain and Edsel B. Ing
J. Clin. Med. 2025, 14(2), 535; https://doi.org/10.3390/jcm14020535 - 16 Jan 2025
Cited by 1 | Viewed by 2927
Abstract
As the face ages, the skin, fat, muscle, and fascia descend, and the underlying bone, cartilage, and teeth may lose mass. Oculofacial aging is a multifactorial process that is influenced by genetic, environmental, and lifestyle factors. This review summarizes the patterns of oculofacial [...] Read more.
As the face ages, the skin, fat, muscle, and fascia descend, and the underlying bone, cartilage, and teeth may lose mass. Oculofacial aging is a multifactorial process that is influenced by genetic, environmental, and lifestyle factors. This review summarizes the patterns of oculofacial aging that are observed across populations, including variations in periorbital hollowing, eyelid ptosis, and skin elasticity. Evidence indicates significant variability in aging patterns between sex- and race-based subgroups. Nonetheless, there remains a paucity of research on the progression of aging in some under-studied demographic groups. Signs of oculofacial aging often become apparent to patients well before these changes reach full maturity in later years, leading many to seek early esthetic interventions. Others may present with more advanced signs of aging, motivating a diverse range of therapeutic options. We discuss minimally invasive esthetic interventions to mitigate the signs of aging, which may include botulinum toxin injections, dermal fillers, applied energy-based treatments (e.g., lasers), and emerging techniques such as micro-focused ultrasound and platelet-rich plasma therapies. We review evidence on outcomes related to patient satisfaction and quality of life following esthetic interventions for oculofacial aging. Finally, we outline ethical considerations and challenges faced with the delivery of esthetic surgery, including treatment complications and the influence of social media. This review provides a comprehensive overview of oculofacial aging patterns, its management, and important considerations for the provision of esthetic oculofacial treatment. Full article
(This article belongs to the Special Issue Advances in Ophthalmic Plastic and Reconstructive Surgery)
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8 pages, 509 KiB  
Article
The Glasgow Benefit Inventory—Assessment of Patients Who Underwent Laser-Assisted Dacryocystorhinostomy (LDCR)
by Radosław Różycki, Katarzyna Ulaszewska and Łukasz Skrzypiec
J. Clin. Med. 2024, 13(23), 7130; https://doi.org/10.3390/jcm13237130 - 25 Nov 2024
Viewed by 742
Abstract
Background/Objectives: Disruptions in lacrimal function can lead to various conditions, including chronic nasolacrimal duct obstruction and dacryocystitis, which may cause symptoms like excessive tearing, pain, and recurrent infections. In cases where pharmacological treatments are insufficient, surgical intervention becomes essential, which is widely used [...] Read more.
Background/Objectives: Disruptions in lacrimal function can lead to various conditions, including chronic nasolacrimal duct obstruction and dacryocystitis, which may cause symptoms like excessive tearing, pain, and recurrent infections. In cases where pharmacological treatments are insufficient, surgical intervention becomes essential, which is widely used to restore effective tear drainage. Methods: This study evaluated postoperative outcomes of laser-assisted dacryocystorhinostomy (LDCR) in 48 patients, totaling 56 treated eyes, over a follow-up period of 6 months to 3.5 years. During the follow-up examination, patients completed the Glasgow Benefit Inventory questionnaire. Results: The outcomes demonstrated significant improvements, particularly in the GBI total score (+35.07) and general subscale (+44.36), with minimal effects on social support and physical health subscales. Conclusions: LDCR proves to be an effective, minimally invasive alternative to traditional dacryocystorhinostomy, offering significant patient satisfaction, faster recovery, and reduced complications in treating nasolacrimal duct obstruction. Full article
(This article belongs to the Section Ophthalmology)
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11 pages, 1455 KiB  
Review
Factors Contributing to Early Recovery of Urinary Continence Following Radical Prostatectomy: A Narrative Review
by Bara Barakat, Boris Hadaschik, Mulham Al-Nader and Samer Schakaki
J. Clin. Med. 2024, 13(22), 6780; https://doi.org/10.3390/jcm13226780 - 11 Nov 2024
Cited by 3 | Viewed by 1675
Abstract
Stress urinary incontinence (SUI) is a common condition in patients following radical prostatectomy (RP), which has a significant impact on all aspects of quality of life and is associated with significant social stigma. The factors that improve urinary incontinence in patients following surgery [...] Read more.
Stress urinary incontinence (SUI) is a common condition in patients following radical prostatectomy (RP), which has a significant impact on all aspects of quality of life and is associated with significant social stigma. The factors that improve urinary incontinence in patients following surgery remain controversial. The aim of our narrative review was to identify and synthesise the latest evidence on pre-, intra- and post-operative factors and predictors that contribute to early continence recovery after RP. In this narrative review, primary resources were identified by searching PubMed, EMBASE and Medline, and secondary resources were collected by cross-referencing citations in the relevant articles. We started our review by searching for systematic reviews of factors and predictors that contribute to early recovery of urinary continence after RP. We then reviewed societal guidelines such as the American Urological Association and European Urological Association guidelines on male urinary incontinence. This review focuses on the pre-, intra and postoperative factors that influence postoperative SUI after RP, as well as highlighting modifications in surgical techniques that lead to early continence recovery. Increasing age, higher BMI, shorter membranous urethral length (MUL), and larger PV are independent prognostic factors for SUI within 3 months after RP. Factors such as modified surgical technique preservation of anatomical structure lead to influence postoperative early continence recovery. SUI after RP is influenced by various factors. These factors include not only anatomical landmarks and patient-related factors such as age, BMI, length of MUL and prostate volume, but also prior transurethral resection or laser enucleation of the prostate, the surgeon’s expertise, the surgical approach and NS technique. Full article
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24 pages, 7040 KiB  
Article
Virtual Obstacle Avoidance Strategy: Navigating through a Complex Environment While Interacting with Virtual and Physical Elements
by Fabiana Machado, Matheus Loureiro, Marcio Bezerra, Carla Zimerer, Ricardo Mello and Anselmo Frizera
Sensors 2024, 24(19), 6212; https://doi.org/10.3390/s24196212 - 25 Sep 2024
Cited by 1 | Viewed by 1547
Abstract
Robotic walking devices can be used for intensive exercises to enhance gait rehabilitation therapies. Mixed Reality (MR) techniques may improve engagement through immersive and interactive environments. This article introduces an MR-based multimodal human–robot interaction strategy designed to enable shared control with a Smart [...] Read more.
Robotic walking devices can be used for intensive exercises to enhance gait rehabilitation therapies. Mixed Reality (MR) techniques may improve engagement through immersive and interactive environments. This article introduces an MR-based multimodal human–robot interaction strategy designed to enable shared control with a Smart Walker. The MR system integrates virtual and physical sensors to (i) enhance safe navigation and (ii) facilitate intuitive mobility training in personalized virtual scenarios by using an interface with three elements: an arrow to indicate where to go, laser lines to indicate nearby obstacles, and an ellipse to show the activation zone. The multimodal interaction is context-based; the presence of nearby individuals and obstacles modulates the robot’s behavior during navigation to simplify collision avoidance while allowing for proper social navigation. An experiment was conducted to evaluate the proposed strategy and the self-explanatory nature of the interface. The volunteers were divided into four groups, with each navigating under different conditions. Three evaluation methods were employed: task performance, self-assessment, and observational measurement. Analysis revealed that participants enjoyed the MR system and understood most of the interface elements without prior explanation. Regarding the interface, volunteers who did not receive any introductory explanation about the interface elements were mostly able to guess their purpose. Volunteers that interacted with the interface in the first session provided more correct answers. In future research, virtual elements will be integrated with the physical environment to enhance user safety during navigation, and the control strategy will be improved to consider both physical and virtual obstacles. Full article
(This article belongs to the Special Issue Mobile Robots for Navigation: 2nd Edition)
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27 pages, 27600 KiB  
Article
New Insights into the Materials and Painting Techniques of Ancient Wall Paintings from the Roman Province of Dacia: A Minimally Invasive Multi-Method Approach
by Ioana Maria Cortea, Luminița Ghervase, Lucian Ratoiu, Ovidiu Țentea and Monica Dinu
Heritage 2024, 7(9), 5268-5294; https://doi.org/10.3390/heritage7090248 - 21 Sep 2024
Cited by 2 | Viewed by 2616
Abstract
A group of wall painting fragments discovered at Ulpia Traiana Sarmizegetusa, an important Roman archeological site located in the former Roman province of Dacia (Romania), have been investigated with the aim of defining the material composition of their pictorial layers and exploring the [...] Read more.
A group of wall painting fragments discovered at Ulpia Traiana Sarmizegetusa, an important Roman archeological site located in the former Roman province of Dacia (Romania), have been investigated with the aim of defining the material composition of their pictorial layers and exploring the pictorial technology used. In order to preserve the integrity of the murals and minimize sampling, an array of non- and micro-invasive techniques has been employed, including X-ray fluorescence, laser-induced breakdown spectroscopy, Fourier transform infrared spectroscopy, and hyperspectral imaging. In accordance with previous studies, the identified color palette was mainly based on iron-rich earth pigments (red and yellow ochres, green earth) and carbon-based blacks (soot/charcoal, bone black). Egyptian blue, lazurite, some lead-based pigments, and potentially indigo were also identified (in complex mixtures) on the uppermost paint layers, typically applied a secco over the a fresco background. The presence of expensive pigments and the existence of a red preparatory drawing, documented for the first time in the region, indicate that the original wall paintings had elaborate schemes and, secondly, reflect the patron’s wealth and social status. Hyperspectral imaging was able to retrieve some faded paint layers in certain cases, helping to recover lost decorative details, an indicator of a more complex polychromy compared to what we see today. The obtained results add important contributions to the limited corpus of data regarding the technical know-how of decorative polychrome painting on plaster found in Roman archeological sites in Romania. Full article
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19 pages, 7115 KiB  
Article
Iron Tailings as Mineral Fillers and Their Effect on the Fatigue Performance of Asphalt Mastic
by Yaning Cui, Chundi Si, Song Li, Yanshun Jia and Bin Guo
Materials 2024, 17(12), 2927; https://doi.org/10.3390/ma17122927 - 14 Jun 2024
Cited by 6 | Viewed by 1111
Abstract
Incorporating iron tailings (ITs) into asphalt represents a new method for waste-to-resource conversion. The objective of this study is to evaluate the fatigue performance of ITs as fillers in asphalt mastic and investigate the interaction and interfacial adhesion energy between asphalt and ITs. [...] Read more.
Incorporating iron tailings (ITs) into asphalt represents a new method for waste-to-resource conversion. The objective of this study is to evaluate the fatigue performance of ITs as fillers in asphalt mastic and investigate the interaction and interfacial adhesion energy between asphalt and ITs. To achieve that, the particle size distributions of two ITs and limestone filler (LF) were tested through a laser particle size analyzer; the morphology and structure characteristics were obtained by scanning electronic microscopy (SEM), the mineral compositions were conducted through X-ray diffraction (XRD), and the chemical compositions were tested through X-ray Fluorescence Spectrometer (XRF). Furthermore, the fatigue properties of asphalt mastic and the interaction between asphalt binder and mineral fillers (ITs and LFs) were evaluated by Dynamic Shear Rheometer (DSR). The interfacial adhesion energy between ITs and asphalt binder were calculated through molecular dynamics simulation. In the end, the correlation between the test results and the fatigue life is established based on the gray correlation analysis, the environmental and economic benefits of iron tailings asphalt pavement are further evaluated. The results show that the particle size distribution of ITs is concentrated between 30 μm and 150 μm, and the main component is quartz. ITs have rich angularity and a higher interaction ability with asphalt. The adhesion energy of iron tailings filler to asphalt is less than that of limestone. The correlation degree of the interfacial adhesion energy and interaction between asphalt and mineral filler with asphalt mastic fatigue life is close to 0.58. Under the combined action of interaction ability and interfacial adhesion energy, the fatigue life of IT asphalt mastic meets the requirements. ITs as a partial replacement for mineral fillers in asphalt pavement have great environmental and social effectiveness. Full article
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18 pages, 24888 KiB  
Article
Miniaturized Multi-Platform Free-Space Laser-Communication Terminals for Beyond-5G Networks and Space Applications
by Alberto Carrasco-Casado, Koichi Shiratama, Dimitar Kolev, Fumie Ono, Hiroyuki Tsuji and Morio Toyoshima
Photonics 2024, 11(6), 545; https://doi.org/10.3390/photonics11060545 - 7 Jun 2024
Cited by 7 | Viewed by 4811
Abstract
Beyond-5G (B5G) technology plays a pivotal role in the next generation of communication infrastructure to support the future Society 5.0, a concept introduced in the 5th Basic Plan for Science and Technology by the Japanese Cabinet to define the long-term growth strategy for [...] Read more.
Beyond-5G (B5G) technology plays a pivotal role in the next generation of communication infrastructure to support the future Society 5.0, a concept introduced in the 5th Basic Plan for Science and Technology by the Japanese Cabinet to define the long-term growth strategy for reconciling economic development with the resolution of social issues through the promotion of science and technologies. Free-space laser communication is a key element in boosting the data transmission capabilities required for B5G applications. The NICT will complete in 2024 the first fully functional prototypes of a series of miniaturized laser-communication terminals for multiple platforms. These terminals are designed to adapt to a wide range of requirements to address scenarios where laser communications can offer a competitive, enhanced solution compared to existing technologies. This paper provides an overview of these terminals’ capabilities and the plans for their functional validation, as well as preliminary data from the first full-system tests. A number of innovations integrated into the terminals are introduced, such as the manufacture of the smallest miniaturized EDFA with integrated HPA and LNA and full space qualification to date, the first-ever integration of a beam-divergence control system in a practical communication terminal, the development of the most compact Tbit/s-class modem prototype documented in the literature, and the smallest gimbal design integrated in a lasercom terminal. Furthermore, this paper outlines the mid-term plans for demonstration in the most significant realistic scenarios, emphasizing the use of High-Altitude Platform Stations (HAPSs) and ultra-small satellites. Full article
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20 pages, 11538 KiB  
Article
Analytical Evaluation of Laser Cleaning Effectiveness in the Context of Contemporary Muralism
by Yezi Zhang, Francesca Zenucchini, Chiara Ricci, Paola Croveri and Dominique Scalarone
Appl. Sci. 2024, 14(11), 4799; https://doi.org/10.3390/app14114799 - 1 Jun 2024
Viewed by 1483
Abstract
Contemporary murals and street art play a critical role in urban culture, serving as platforms for social activism and reflecting the vibrancy of city life. This study within the SuperStaAr project framework examines the challenge of graffiti removal while safeguarding the original synthetic [...] Read more.
Contemporary murals and street art play a critical role in urban culture, serving as platforms for social activism and reflecting the vibrancy of city life. This study within the SuperStaAr project framework examines the challenge of graffiti removal while safeguarding the original synthetic paint layers. Through a detailed investigation using Q-Switch and Long Q-Switch lasers (Nd:YAG), we evaluate the effectiveness and safety of laser cleaning techniques on both unaged and artificially aged mural mock-ups. The initial findings highlight the Q-Switch and Long Q-Switch lasers as promising for removing graffiti without compromising the paint integrity. Our assessment criteria—encompassing residue presence, surface roughness, color changes, cleaning effectiveness, and pigment pickup—were validated through empirical evaluation and supported by colorimetric, micro–ATR–FTIR, and Py–GC/MS analyses. Notably, the incorporation of a passive sampling system for Py–GC/MS analysis facilitates a deeper understanding of the ablated materials without direct sampling from the artwork. This research contributes a foundational framework for the evaluation of laser cleaning in mural conservation, emphasizing the importance of tailored strategies to enhance the sustainability of urban art conservation efforts. Full article
(This article belongs to the Special Issue Advances in Analytical Methods for Cultural Heritage)
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15 pages, 4901 KiB  
Article
Surface-Enhanced Raman Spectroscopy of Ammonium Nitrate Using Al Structures, Fabricated by Laser Processing of AlN Ceramic
by Petar Atanasov, Anna Dikovska, Rosen Nikov, Genoveva Atanasova, Katarzyna Grochowska, Jakub Karczewski, Naoki Fukata, Wipakorn Jevasuwan and Nikolay Nedyalkov
Materials 2024, 17(10), 2254; https://doi.org/10.3390/ma17102254 - 10 May 2024
Cited by 5 | Viewed by 1619
Abstract
This work presents results on laser-induced surface structuring of AlN ceramic and its application in Surface-Enhanced Raman Spectroscopy (SERS). The laser processing is performed by nanosecond pulses in air and vacuum. Depending on the processing conditions, different surface morphology can be obtained. The [...] Read more.
This work presents results on laser-induced surface structuring of AlN ceramic and its application in Surface-Enhanced Raman Spectroscopy (SERS). The laser processing is performed by nanosecond pulses in air and vacuum. Depending on the processing conditions, different surface morphology can be obtained. The ablation process is realized by ceramic decomposition as the formation of an aluminium layer is detected. The efficiency of the fabricated structures as active substrates in SERS is estimated by the ability of the detection of ammonium nitrate (NH4NO3). It is conducted for Raman spectrometer systems that operate at wavelengths of 514 and 785 nm where the most common commercial systems work. The obtained structures contribute to enhancement of the Raman signal at both wavelengths, as the efficiency is higher for excitation at 514 nm. The limit of detection (LOD) of ammonium nitrate is estimated to be below the maximum allowed value in drinking water. The analysis of the obtained results was based on the calculations of the near field enhancement at different conditions based on Finite Difference Time Domain simulation and the extinction spectra calculations based on Generalized Mie scattering theory. The structures considered in these simulations were taken from the SEM images of the real samples. The oxidation issue of the ablated surface was studied by X-ray photoelectron spectroscopy. The presented results indicated that laser structuring of AlN ceramics is a way for fabrication of Al structures with specific near-field properties that can be used for the detection of substances with high social impact. Full article
(This article belongs to the Special Issue Advances in Laser Processing Technology of Materials)
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16 pages, 5338 KiB  
Article
3D Point Cloud and GIS Approach to Assess Street Physical Attributes
by Patricio R. Orozco Carpio, María José Viñals and María Concepción López-González
Smart Cities 2024, 7(3), 991-1006; https://doi.org/10.3390/smartcities7030042 - 25 Apr 2024
Cited by 3 | Viewed by 2466
Abstract
The present research explores an innovative approach to objectively assessing urban streets attributes using 3D point clouds and Geographic Information Systems (GIS). Urban streets are vital components of cities, playing a significant role in the lives of their residents. Usually, the evaluation of [...] Read more.
The present research explores an innovative approach to objectively assessing urban streets attributes using 3D point clouds and Geographic Information Systems (GIS). Urban streets are vital components of cities, playing a significant role in the lives of their residents. Usually, the evaluation of some of their physical attributes has been subjective, but this study leverages 3D point clouds and digital terrain models (DTM) to provide a more objective perspective. This article undertakes a micro-urban analysis of basic physical characteristics (slope, width, and human scale) of a representative street in the historic centre of Valencia (Spain), utilizing 3D laser-scanned point clouds and GIS tools. Applying the proposed methodology, thematic maps were generated, facilitating the objective identification of areas with physical attributes more conducive to suitable pedestrian dynamics. This approach provides a comprehensive understanding of urban street attributes, emphasizing the importance of addressing their assessment through advanced digital technologies. Moreover, this versatile methodology has diverse applications, contributing to social sustainability by enhancing the quality of urban streets and open spaces. Full article
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