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Keywords = silicon monitoring

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24 pages, 4004 KiB  
Article
Assessing the Impact of Solar Spectral Variability on the Performance of Photovoltaic Technologies Across European Climates
by Ivan Bevanda, Petar Marić, Ante Kristić and Tihomir Betti
Energies 2025, 18(14), 3868; https://doi.org/10.3390/en18143868 - 21 Jul 2025
Viewed by 125
Abstract
Precise photovoltaic (PV) performance modeling is essential for optimizing system design, operational monitoring, and reliable power forecasting—yet spectral correction is often overlooked, despite its significant impact on energy yield uncertainty. This study employs the FARMS-NIT model to assess the impact of spectral irradiance [...] Read more.
Precise photovoltaic (PV) performance modeling is essential for optimizing system design, operational monitoring, and reliable power forecasting—yet spectral correction is often overlooked, despite its significant impact on energy yield uncertainty. This study employs the FARMS-NIT model to assess the impact of spectral irradiance on eight PV technologies across 79 European sites, grouped by Köppen–Geiger climate classification. Unlike previous studies limited to clear-sky or single-site analysis, this work integrates satellite-derived spectral data for both all-sky and clear-sky scenarios, enabling hourly, tilt-optimized simulations that reflect real-world operating conditions. Spectral analyses reveal European climates exhibit blue-shifted spectra versus AM1.5 reference, only 2–5% resembling standard conditions. Thin-film technologies demonstrate superior spectral gains under all-sky conditions, though the underlying drivers vary significantly across climatic regions—a distinction that becomes particularly evident in the clear-sky analysis. Crystalline silicon exhibits minimal spectral sensitivity (<1.6% variations), with PERC/PERT providing highest stability. CZTSSe shows latitude-dependent performance with ≤0.7% variation: small gains at high latitudes and losses at low latitudes. Atmospheric parameters were analyzed in detail, revealing that air mass (AM), clearness index (Kt), precipitable water (W), and aerosol optical depth (AOD) play key roles in shaping spectral effects, with different parameters dominating in distinct climate groups. Full article
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38 pages, 5046 KiB  
Review
Photonics on a Budget: Low-Cost Polymer Sensors for a Smarter World
by Muhammad A. Butt
Micromachines 2025, 16(7), 813; https://doi.org/10.3390/mi16070813 - 15 Jul 2025
Viewed by 346
Abstract
Polymer-based photonic sensors are emerging as cost-effective, scalable alternatives to conventional silicon and glass photonic platforms, offering unique advantages in flexibility, functionality, and manufacturability. This review provides a comprehensive assessment of recent advances in polymer photonic sensing technologies, focusing on material systems, fabrication [...] Read more.
Polymer-based photonic sensors are emerging as cost-effective, scalable alternatives to conventional silicon and glass photonic platforms, offering unique advantages in flexibility, functionality, and manufacturability. This review provides a comprehensive assessment of recent advances in polymer photonic sensing technologies, focusing on material systems, fabrication techniques, device architectures, and application domains. Key polymer materials, including PMMA, SU-8, polyimides, COC, and PDMS, are evaluated for their optical properties, processability, and suitability for integration into sensing platforms. High-throughput fabrication methods such as nanoimprint lithography, soft lithography, roll-to-roll processing, and additive manufacturing are examined for their role in enabling large-area, low-cost device production. Various photonic structures, including planar waveguides, Bragg gratings, photonic crystal slabs, microresonators, and interferometric configurations, are discussed concerning their sensing mechanisms and performance metrics. Practical applications are highlighted in environmental monitoring, biomedical diagnostics, and structural health monitoring. Challenges such as environmental stability, integration with electronic systems, and reproducibility in mass production are critically analyzed. This review also explores future opportunities in hybrid material systems, printable photonics, and wearable sensor arrays. Collectively, these developments position polymer photonic sensors as promising platforms for widespread deployment in smart, connected sensing environments. Full article
(This article belongs to the Section A:Physics)
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24 pages, 3795 KiB  
Article
Ecological Effects of Sargassum fusiforme Cultivation on Coastal Phytoplankton Community Structure and Water Quality: A Study Based on Microscopic Analysis
by Yurong Zhang, Rijin Jiang, Qingxi Han, Zimeng Li, Zhen Mao and Haifeng Jiao
Biology 2025, 14(7), 844; https://doi.org/10.3390/biology14070844 - 10 Jul 2025
Viewed by 328
Abstract
This study used microscopy-based quantitative enumeration to investigate the effects of large-scale Sargassum fusiforme cultivation on coastal water quality and phytoplankton communities. Data from April (cultivation period) and June (non-cultivation period) in 2018 and 2019 showed that cultivation increased pH and dissolved oxygen [...] Read more.
This study used microscopy-based quantitative enumeration to investigate the effects of large-scale Sargassum fusiforme cultivation on coastal water quality and phytoplankton communities. Data from April (cultivation period) and June (non-cultivation period) in 2018 and 2019 showed that cultivation increased pH and dissolved oxygen (DO). It also reduced nitrate–nitrogen (NO3–N), nitrite–nitrogen (NO2–N), phosphate–phosphorus (PO4–P), total phosphorus (TP), and silicate–silicon (SiO3–Si) concentrations. These changes indicate improved coastal water quality from S. fusiforme cultivation. Nutrient levels rose again during the non-cultivation period. This suggests that water purification decreased without cultivation. Cultivation also lowered the dominance of Skeletonema costatum. This led to a more diverse and stable phytoplankton community. Microscopic observation is valuable for quantifying larger phytoplankton species, and plays an important role in ecological monitoring. These findings provide insights for sustainable aquaculture and ecological restoration. Full article
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21 pages, 7797 KiB  
Article
On the Optimization of T6 Heat Treatment Parameters of a Secondary Al-Si-Cu-Mg Foundry Aluminum Alloy: A Microstructural and Mechanical Characterization
by Mattia Merlin, Lorenzo Antonioli, Federico Bin, Cindy Morales and Chiara Soffritti
Metals 2025, 15(7), 742; https://doi.org/10.3390/met15070742 - 30 Jun 2025
Viewed by 310
Abstract
Foundry aluminum-silicon (Al-Si) alloys, especially those containing Cu and/or Mg, are widely used in casting processes for fabricating lightweight parts. This study focuses on the optimization of the solution heat treatment parameters within the T6 heat treatment of an innovative AlSi7Cu0.5Mg0.3 secondary alloy, [...] Read more.
Foundry aluminum-silicon (Al-Si) alloys, especially those containing Cu and/or Mg, are widely used in casting processes for fabricating lightweight parts. This study focuses on the optimization of the solution heat treatment parameters within the T6 heat treatment of an innovative AlSi7Cu0.5Mg0.3 secondary alloy, aiming at achieving energy savings and reducing the environmental impact related to the production of foundry components for the automotive industry. Different combinations of solution times and temperatures lower than those typically adopted in industrial practice were evaluated, and their effects on tensile properties were investigated on samples machined from as-cast and T6-treated castings produced by pouring the alloy into a steel permanent mold. Thermal analysis (TA) and differential thermal analysis (DTA) were performed to monitor the solidification sequence of microstructural phases as well as their dissolution on heating according to the proposed solution heat treatments. Microstructural analysis by light microscopy (LM) and scanning electron microscopy (SEM), together with Brinell hardness testing, was also carried out to assess the effects of heat treatment parameters. The results suggested that a shorter solution heat treatment set at a temperature lower than that currently adopted for the heat treatment of the studied alloy can still ensure the required mechanical properties while improving productivity and reducing energy consumption. Full article
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20 pages, 3506 KiB  
Article
AuNP/Magnetic Bead-Enhanced Electrochemical Sensor Toward Dual Saliva Alzheimer’s Biomarkers Detection
by Pengcheng Zhao, Jieyu Wang, Hongju Mao, Lin Zhou, Zhenhua Wu, Yunxing Lu, Teng Sun, Jianan Hui and Guowu Ma
Sensors 2025, 25(13), 4088; https://doi.org/10.3390/s25134088 - 30 Jun 2025
Viewed by 338
Abstract
Alzheimer’s disease (AD) early screening requires non-invasive, high-sensitivity detection of low-abundance biomarkers in complex biofluids like saliva. In this study, we present a miniaturized, silicon-based electrochemical sensor for sequential detection of two AD salivary biomarkers, lactoferrin (Lf) and amyloid β-protein 1-42 (Aβ1-42 [...] Read more.
Alzheimer’s disease (AD) early screening requires non-invasive, high-sensitivity detection of low-abundance biomarkers in complex biofluids like saliva. In this study, we present a miniaturized, silicon-based electrochemical sensor for sequential detection of two AD salivary biomarkers, lactoferrin (Lf) and amyloid β-protein 1-42 (Aβ1-42), on a single reusable electrode. The sensor features a three-electrode system fabricated by sputter-coating a quartz substrate with gold (Au) sensing electrodes, which are further modified with gold nanoparticles (AuNPs) to form 3D dendritic structures that enhance surface area and electron transfer. To improve specificity, immunomagnetic beads (MBs) are employed to selectively capture and isolate target biomarkers from saliva samples. These MB–biomarker complexes are introduced into a polydimethylsiloxane chamber aligned with Au sensing electrodes, where a detachable magnet localizes the complexes onto the electrode surface to amplify redox signals. The AuNPs/MBs sensor achieves detection limits of 2 μg/mL for Lf and 0.1 pg/mL for Aβ1-42, outperforming commercial ELISA kits (37.5 pg/mL for Aβ1-42) and covering physiological salivary concentrations. After the MBs capture the biomarkers, the sensor can output the result within one minute. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) measurements confirm enhanced electron transfer kinetics on AuNP-decorated surfaces, while linear correlations (R2 > 0.95) validate quantitative accuracy across biomarker ranges. The compact and integrated design eliminates reliance on bulky instrumentation and enables user-friendly operation, establishing a promising platform for portable, cost-effective AD screening and monitoring. Full article
(This article belongs to the Section Biomedical Sensors)
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15 pages, 6418 KiB  
Article
Multifunctional Sensor for Strain, Pressure, and UV Light Detections Using Polyaniline and ZnO Nanostructures on a Flexible Substrate
by Seung-Woo Lee, Ju-Seong Lee, Hyeon-Wook Yu, Tae-Hee Kim and Hyun-Seok Kim
Polymers 2025, 17(13), 1825; https://doi.org/10.3390/polym17131825 - 30 Jun 2025
Viewed by 296
Abstract
Wearable sensors have rapidly advanced, enabling applications such as human activity monitoring, electronic skin, and biomimetic robotics. To meet the growing demands of these applications, multifunctional sensing has become essential for wearable devices. However, most existing studies predominantly focus on enhancing single-function sensing [...] Read more.
Wearable sensors have rapidly advanced, enabling applications such as human activity monitoring, electronic skin, and biomimetic robotics. To meet the growing demands of these applications, multifunctional sensing has become essential for wearable devices. However, most existing studies predominantly focus on enhancing single-function sensing capabilities. This study introduces a multifunctional sensor that combines high stretchability for strain and pressure detection with ultraviolet (UV) sensing capability. To achieve simultaneous detection of strain, pressure, and UV light, a multi-sensing approach was employed: a capacitive method for strain and pressure detections and a resistive method utilizing a pn-heterojunction diode for UV detection. In the capacitive method, polyaniline (PANI) served as parallel-plate electrodes, while silicon-based elastomer acted as the dielectric layer. This configuration enabled up to 100% elongation and enhanced operational stability through encapsulation. The sensor demonstrated a strong linear relationship between capacitance value changes reasonably based on the area of PANI, and showed a good linearity with an R-squared value of 0.9918. It also detected pressure across a wide range, from low (0.4 kPa) to high (9.4 kPa). Furthermore, for wearable applications, the sensor reliably captured capacitance variations during finger bending at different angles. For UV detection, a pn-heterojunction diode composed of p-type silicon and n-type zinc oxide nanorods exhibited a rapid response time of 6.1 s and an on/off ratio of 13.8 at −10 V. Durability under 100% tensile strain was confirmed through Von Mises stress calculations using finite element modeling. Overall, this multifunctional sensor offers significant potential for a variety of applications, including human motion detection, wearable technology, and robotics. Full article
(This article belongs to the Special Issue Polymer Thin Films: Synthesis, Characterization and Applications)
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18 pages, 8059 KiB  
Article
Monitoring Nasal Breathing Using an Adjustable FBG Sensing Unit
by Xiyan Yan, Yan Feng, Min Xu and Hua Zhang
Sensors 2025, 25(13), 4060; https://doi.org/10.3390/s25134060 - 29 Jun 2025
Viewed by 253
Abstract
We have developed an adjustable optical fiber Bragg grating (FBG) sensing unit for monitoring nasal breathing. The FBG sensing unit can accommodate individuals with varying facial dimensions by adjusting the connecting holes of the ear hangers. We employed two FBG configurations: an encapsulated [...] Read more.
We have developed an adjustable optical fiber Bragg grating (FBG) sensing unit for monitoring nasal breathing. The FBG sensing unit can accommodate individuals with varying facial dimensions by adjusting the connecting holes of the ear hangers. We employed two FBG configurations: an encapsulated FBG within a silicon tube (FBG1) and a bare FBG (FBG2). Calibration experiments show the temperature sensitivities of 6.77 pm/°C and 6.18 pm/°C, respectively, as well as the pressure sensitivities of 2.05 pm/N and 1.18 pm/N, respectively. We conducted breathe monitoring tests on male and female volunteers under the resting and the motion states. For the male volunteer, the breathing frequency is 13.48 breaths per minute during the rest state and increases to 23.91 breaths per minute during the motion state. For the female volunteer, the breathing frequency is 14.12 breaths per minute during rest and rises to 24.59 breaths per minute during motion. Experimental results show that the FBG sensing unit can effectively distinguish breathing rate for the same person in different states. In addition, we employed a random forest algorithm to assess the importance of two sensors in breathing monitoring applications. The findings indicate that FBG1 outperforms FBG2 in monitoring performance, highlighting that pressure plays a positive impact in enhancing the accuracy of breathing monitoring. Full article
(This article belongs to the Section Optical Sensors)
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13 pages, 4454 KiB  
Article
Proton Irradiation and Thermal Restoration of SiPMs for LEO Missions
by Alexis Luszczak, Lucas Finazzi, Leandro Gagliardi, Milagros Moreno, Maria L. Ibarra, Federico Golmar and Gabriel A. Sanca
Instruments 2025, 9(3), 15; https://doi.org/10.3390/instruments9030015 - 26 Jun 2025
Viewed by 232
Abstract
Silicon Photomultipliers (SiPMs) are optical sensors widely used in space applications due to their high photon detection efficiency, low power consumption, and robustness. However, in Low Earth Orbit (LEO), their performance degrades over time due to prolonged exposure to ionizing radiation, primarily from [...] Read more.
Silicon Photomultipliers (SiPMs) are optical sensors widely used in space applications due to their high photon detection efficiency, low power consumption, and robustness. However, in Low Earth Orbit (LEO), their performance degrades over time due to prolonged exposure to ionizing radiation, primarily from trapped protons and electrons. The dominant radiation-induced effect in SiPMs is an increase in dark current, which can compromise detector sensitivity. This study investigates the potential of thermal annealing as a mitigation strategy for radiation damage in SiPMs. We designed and tested PCB-integrated heaters to selectively heat irradiated SiPMs and induce recovery processes. A PID-controlled system was developed to stabilize the temperature at 100 °C, and a remotely controlled experimental setup was implemented to operate under irradiation conditions. Two SiPMs were simultaneously irradiated with 9 MeV protons at the EDRA facility, reaching a 1 MeV neutron equivalent cumulative fluence of (9.5 ± 0.2) × 108 cm−2. One sensor underwent thermal annealing between irradiation cycles, while the other served as a control. Throughout the experiment, dark current was continuously monitored using a source measure unit, and I–V curves were recorded before and after irradiation. A recovery of more than 39% was achieved after only 5 min of thermal cycling at 100 °C, supporting this recovery approach as a low-complexity strategy to mitigate radiation-induced damage in space-based SiPM applications and increase device lifetime in harsh environments. Full article
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16 pages, 3131 KiB  
Article
Humidity Sensing in Graphene-Trenched Silicon Junctions via Schottky Barrier Modulation
by Akeel Qadir, Munir Ali, Afshan Khaliq, Shahid Karim, Umar Farooq, Hongsheng Xu and Yiting Yu
Nanomaterials 2025, 15(13), 985; https://doi.org/10.3390/nano15130985 - 25 Jun 2025
Viewed by 245
Abstract
In this study, we develop a graphene-trenched silicon Schottky junction for humidity sensing. This novel structure comprises suspended graphene bridging etched trenches on a silicon substrate, creating both free-standing and substrate-contacting regions of graphene that enhance water adsorption sensing. Suspended graphene is intrinsically [...] Read more.
In this study, we develop a graphene-trenched silicon Schottky junction for humidity sensing. This novel structure comprises suspended graphene bridging etched trenches on a silicon substrate, creating both free-standing and substrate-contacting regions of graphene that enhance water adsorption sensing. Suspended graphene is intrinsically insensitive to water adsorption, making it difficult for adsorbed H2O to effectively dope the graphene. In contrast, when graphene is supported on the silicon substrate, water molecules can effectively dope the graphene by modifying the silicon’s impurity bands and their hybridization with graphene. This humidity-induced doping leads to a significant modulation of the Schottky barrier at the graphene–silicon interface, which serves as the core sensing mechanism. We investigate the current–voltage (I–V) characteristics of these devices as a function of trench width and relative humidity. Our analysis shows that humidity influences key device parameters, including the Schottky barrier height, ideality factor, series resistance, and normalized sensitivity. Specifically, larger trench widths reduce the graphene density of states, an effect that is accounted for in our analysis of these parameters. The sensor operates under both forward and reverse bias, enabling tunable sensitivity, high selectivity, and low power consumption. These features make it promising for applications in industrial and home safety, environmental monitoring, and process control. Full article
(This article belongs to the Section 2D and Carbon Nanomaterials)
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22 pages, 9724 KiB  
Article
Study on the Mechanical Properties and Degradation Mechanisms of Damaged Rock Under the Influence of Liquid Saturation
by Bowen Wu, Jucai Chang, Jianbiao Bai, Chao Qi and Dingchao Chen
Appl. Sci. 2025, 15(13), 7054; https://doi.org/10.3390/app15137054 - 23 Jun 2025
Viewed by 256
Abstract
To investigate the degradation mechanisms of the surrounding rock in abandoned mine roadways used for oil storage, this study combined uniaxial compression tests with digital image correlation (DIC), scanning electron microscopy (SEM), and other techniques to analyze the evolution of the rock mechanical [...] Read more.
To investigate the degradation mechanisms of the surrounding rock in abandoned mine roadways used for oil storage, this study combined uniaxial compression tests with digital image correlation (DIC), scanning electron microscopy (SEM), and other techniques to analyze the evolution of the rock mechanical properties under the coupled effects of oil–water soaking and initial damage. The results indicate that oil–water soaking induces the loss of silicon elements and the deterioration of microstructure, leading to surface peeling, crack propagation, and increased porosity of the sample. The compressive strength decreases linearly with the soaking time. Acoustic emission (AE) monitoring showed that after 24 h of soaking, the maximum ringing count rate and cumulative count decreased by 81.7% and 80.4%, respectively, compared to the dry state. As the liquid saturation increases, the failure mode transitions from tension dominated to shear failure. The synergistic effect of initial damage and oil–water erosion weakens the rock’s energy storage capacity, with the energy storage limit decreasing by 45.6%, leading to reduced resistance to external forces. Full article
(This article belongs to the Special Issue Novel Technologies in Intelligent Coal Mining)
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13 pages, 2599 KiB  
Article
Fiber-Coupled Multipass NIR Sensor for In Situ, Real-Time Water Vapor Outgassing Monitoring
by Logan Echeveria, Yue Hao, Michael C. Rushford, Gerardo Chavez, Sean Tardif, Allan Chang, Sylvie Aubry, Maxwell Murialdo, J. Chance Carter, Brandon Foley, Pratanu Roy, S. Roger Qiu and Tiziana Bond
Sensors 2025, 25(12), 3824; https://doi.org/10.3390/s25123824 - 19 Jun 2025
Viewed by 471
Abstract
This work presents the recent development of a fiber-coupled multipass near-infrared (NIR) gas sensor used to monitor water vapor desorption of small material coupons. The gas sensor design employs a White cell topology to maximize the optical path length over a compact, hand-size [...] Read more.
This work presents the recent development of a fiber-coupled multipass near-infrared (NIR) gas sensor used to monitor water vapor desorption of small material coupons. The gas sensor design employs a White cell topology to maximize the optical path length over a compact, hand-size footprint. Water vapor concentrations are quantified over a large dynamic range by simultaneously applying wavelength modulation and tunable diode laser absorption spectroscopy techniques. A custom headspace optimized for material desorption experiments is assembled using commercially available vacuum chamber components. We provide in situ measurements of water vapor desorption from two geometries of the industrially important silicone elastomer Sylgard-184 as a case study for sensor viability. To corroborate the results, the gas sensor data are compared to numerical simulations based on a triple-mode diffusion–sorption model, consisting of Henry, Langmuir, and Pooling modes. Full article
(This article belongs to the Special Issue Optical Sensors for Industrial Applications)
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16 pages, 497 KiB  
Article
Numerical Analysis of a SiN Digital Fourier Transform Spectrometer for a Non-Invasive Skin Cancer Biosensor
by Miguel Ángel Nava Blanco and Gerardo Antonio Castañón Ávila
Sensors 2025, 25(12), 3792; https://doi.org/10.3390/s25123792 - 18 Jun 2025
Viewed by 444
Abstract
Early detection and continuous monitoring of diseases are critical to improving patient outcomes, treatment adherence, and diagnostic accuracy. Traditional melanoma diagnosis relies primarily on visual assessment and biopsy, with reported accuracies ranging from 50% to 90% and significant inter-observer variability. Among emerging diagnostic [...] Read more.
Early detection and continuous monitoring of diseases are critical to improving patient outcomes, treatment adherence, and diagnostic accuracy. Traditional melanoma diagnosis relies primarily on visual assessment and biopsy, with reported accuracies ranging from 50% to 90% and significant inter-observer variability. Among emerging diagnostic technologies, Raman spectroscopy has demonstrated considerable promise for non-invasive disease detection, particularly in early-stage skin cancer identification. A portable, real-time Raman spectroscopy system could significantly enhance diagnostic precision, reduce biopsy reliance, and expedite diagnosis. However, miniaturization of Raman spectrometers for portable use faces significant challenges, including weak signal intensity, fluorescence interference, and inherent trade-offs between spectral resolution and the signal-to-noise ratio. Recent advances in silicon photonics present promising solutions by facilitating efficient light collection, enhancing optical fields via high-index-contrast waveguides, and allowing compact integration of photonic components. This work introduces a numerical analysis of an integrated digital Fourier transform spectrometer implemented on a silicon-nitride (SiN) platform, specifically designed for Raman spectroscopy. The proposed system employs a switch-based digital Fourier transform spectrometer architecture coupled with a single optical power meter for detection. Utilizing a regularized regression method, we successfully reconstructed Raman spectra in the 800 cm−1 to 1800 cm−1 range, covering spectra of both benign and malignant skin lesions. Our results demonstrate the capability of the proposed system to effectively differentiate various skin cancer types, highlighting its feasibility as a non-invasive diagnostic sensor. Full article
(This article belongs to the Section Optical Sensors)
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18 pages, 4023 KiB  
Article
Synergistic Effects of Silicon and Ferrous Sulfate on Reducing Arsenic and Cadmium Accumulation in Rice from Co-Contaminated Soil
by Yanlin You, Xiaodong Guo, Jianyu Chen, Zhiqin Liu, Qiuying Cai, Jinyong Yu, Wanli Zhu, Yuna Wang, Hanyue Chen, Bo Xu, Yanhui Chen and Guo Wang
Agronomy 2025, 15(6), 1422; https://doi.org/10.3390/agronomy15061422 - 10 Jun 2025
Viewed by 1211
Abstract
The co-contamination of arsenic (As) and cadmium (Cd) in paddy soils threatens rice safety, yet synergistic mitigation strategies using silicon (Si) and ferrous sulfate (FeSO4) remain underexplored. This study integrated hydroponic and soil pot experiments to evaluate Si-FeSO4 interactions on [...] Read more.
The co-contamination of arsenic (As) and cadmium (Cd) in paddy soils threatens rice safety, yet synergistic mitigation strategies using silicon (Si) and ferrous sulfate (FeSO4) remain underexplored. This study integrated hydroponic and soil pot experiments to evaluate Si-FeSO4 interactions on As/Cd accumulation and rice growth. Hydroponic trials employed 21-day-old rice seedlings exposed to 0.5 mg As(III)/Cd(II) L−1 with/without 70 mg Si L−1 and 30–70 mg Fe L−1, followed by sequential harvesting at 14 and 21 days. Soil experiments utilized co-contaminated paddy soil (50 mg As kg−1 and 1.2 mg Cd kg−1) amended with Si (80 or 400 mg kg−1) and Fe (100 or 1000 mg kg−1), with pore water dynamics monitored over 120 days. Hydroponic results demonstrated that 70 mg Si L−1 combined with 30 or 70 mg Fe L−1 enhanced shoot biomass by 12–79% under As stress, while simultaneously reducing shoot As concentrations by 76–87% and Cd concentrations by 14–33%. Iron plaque induced by FeSO4 exhibited contrasting adsorption behaviors: hydroponic roots immobilized both As and Cd (p < 0.01), whereas roots in soil primarily retained Cd (p < 0.05). In soil experiments, the optimal treatment of 100 mg Fe kg−1 and 400 mg Si kg−1 (Fe1 + Si2) increased grain biomass by 54%, while reducing As and Cd concentrations by 37% and 42%, respectively. However, a higher Fe dosage (Fe2: 1000 mg kg−1 Fe) paradoxically increased grain Cd concentrations. Mechanistically, Si amendment elevated soil pH (Δ + 0.72), facilitating Cd immobilization, while FeSO4 lowered pH (Δ−0.07–0.53), increasing Cd mobility. A strong correlation between soluble Cd and plant uptake was observed (p < 0.01), while changes in As accumulation were unrelated to aqueous behavior. The optimized Si/Fe molar ratio of 7.95:1 effectively mitigated As and Cd co-accumulation, offering a dual-functional strategy for safe rice cultivation in contaminated soils. Full article
(This article belongs to the Special Issue Heavy Metal Pollution and Prevention in Agricultural Soils)
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15 pages, 9452 KiB  
Article
Thermal Fatigue Behaviors of BGA Packages with an Optimized Solder Joint Layout
by Mohammed Abdel Razzaq, Michael Meilunas, Xian A. Cao, Jim Wilcox and Abdallah Ramini
Electronics 2025, 14(11), 2286; https://doi.org/10.3390/electronics14112286 - 4 Jun 2025
Viewed by 679
Abstract
Ball Grid Array (BGA) failures are often dominated by stress concentrations at the outer solder joints, particularly under thermomechanical loading. To mitigate this issue, this study investigates the mechanical and reliability implications of optimizing the BGA solder joint array by removing the outermost [...] Read more.
Ball Grid Array (BGA) failures are often dominated by stress concentrations at the outer solder joints, particularly under thermomechanical loading. To mitigate this issue, this study investigates the mechanical and reliability implications of optimizing the BGA solder joint array by removing the outermost rows and columns, positioning all connections directly beneath the silicon die. Two commonly used solder alloys—SAC305 and Sn37Pb—were selected to evaluate the effects of this optimized array design. A combined experimental and numerical approach was employed, including accelerated thermal cycling (–40 °C to 125 °C), in situ resistance monitoring, cross-sectional failure analysis, and finite element modeling (FEM) to assess fatigue behavior under the altered layout. The optimized array significantly improved performance for SAC305, yielding a 1.67× increase in mean cycles-to-failure and a 29% reduction in peak von Mises stress, with failure locations shifting from the corners to more evenly distributed areas beneath the die. Sn37Pb assemblies showed only a 1.01× improvement despite an 11% stress reduction, attributed to persistent shear-dominated failures at second-row joints. These results highlight the critical influence of joint array architecture and solder alloy selection on reliability, offering design-level guidance for applications prioritizing thermomechanical robustness with reduced I/O counts. Full article
(This article belongs to the Section Electronic Materials, Devices and Applications)
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24 pages, 9032 KiB  
Article
A Gate Oxide Degradation and Junction Temperature Evaluation Method for SiC MOSFETs Based on an On-State Resistance Model
by Peng Wang and Zhigang Zhao
Electronics 2025, 14(11), 2278; https://doi.org/10.3390/electronics14112278 - 3 Jun 2025
Viewed by 504
Abstract
In situ estimations of gate oxide degradation and junction temperature are critical for SiC MOSFETs, as these parameters are key for device-level health management. However, the indicators used in existing evaluation methods primarily focus on one aspect and do not effectively integrate the [...] Read more.
In situ estimations of gate oxide degradation and junction temperature are critical for SiC MOSFETs, as these parameters are key for device-level health management. However, the indicators used in existing evaluation methods primarily focus on one aspect and do not effectively integrate the assessment of both targets, as they require different indicators. To address this problem, this paper proposes a unified evaluation method that uses a single indicator to simultaneously estimate both gate oxide degradation and junction temperature. An on-state resistance (RON) model is used as the indicator. The RON model is first proposed to characterize the influence of temperature and gate degradation on RON. An iterative approach is introduced to determine the RON model parameters, utilizing RON measurements across various temperatures and gate degradation levels, while accounting for the physical characteristics of the parameters. Furthermore, an in situ estimation method for gate degradation and junction temperature is developed based on a two-level turn-on strategy. By analyzing RON before and after gate voltage changes, the gate degradation level and junction temperature can be simultaneously estimated. The proposed method’s effectiveness is demonstrated in a DC-DC converter application. Full article
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