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Keywords = silicon modules

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14 pages, 3863 KB  
Article
PN Junction Optimization for High-Speed Silicon Photonic Modulators
by Mahmoud Hamouda, Carine Mankarious, Aser El-Dahshan, Alaa Fathy, Eslam El-Fiky and Diaa Khalil
Photonics 2025, 12(11), 1079; https://doi.org/10.3390/photonics12111079 (registering DOI) - 31 Oct 2025
Abstract
PN-junction-based modulators are widely used in silicon photonic transceivers for different applications. Different junction shapes have been proposed in the literature. This work studies the optimization of the PN junction by tailoring the doping profile to achieve a high-efficiency modulator with sufficient bandwidth. [...] Read more.
PN-junction-based modulators are widely used in silicon photonic transceivers for different applications. Different junction shapes have been proposed in the literature. This work studies the optimization of the PN junction by tailoring the doping profile to achieve a high-efficiency modulator with sufficient bandwidth. For this purpose, a new N-shaped junction is proposed, which achieves superior performance compared to other junction shapes. The proposed junction has an efficiency that is 60% better than that of the lateral PN junction for the same doping condition, while maintaining a high bandwidth similar to other junctions such as the L-shaped and S-shaped designs. A junction design with an estimated RC bandwidth between 70 GHz and 94 GHz is also proposed. The impact of using the proposed junction in micro-ring modulators (MRMs) is also studied. N-shaped junctions in MRM demonstrated a 112% increase in electro-optic bandwidth over the vertical PN junction, with 60% and 140% improvements in extinction ratio (ER) and optical modulation amplitude (OMA), respectively, compared to the lateral PN junction. Full article
(This article belongs to the Special Issue Recent Advancement in Microwave Photonics)
14 pages, 2275 KB  
Article
Surface Charge and Size Evolution of Silica–Iron Colloidal Particles in Simulated Late-Archaean Seawater
by Weiming Jiang, Xiao Wu, Hongmei Yang, Juan Fu, Qirui Zeng, Sizhe Li, Ruiyao Luo, Yiping Yang, Xiaoju Lin and Jianxi Zhu
Minerals 2025, 15(11), 1123; https://doi.org/10.3390/min15111123 - 28 Oct 2025
Viewed by 143
Abstract
Late-Archean seawater functioned as a vast, redox-tuned colloidal system for which its kinetics were largely governed by the surface chemistry of silica–iron nanoparticles. By reproducing Archean seawater (≈0.7 M ionic strength, 25 °C) in laboratory anoxic-to-mildly oxic reactors, the ζ potential (zeta-potential(ζ)) of [...] Read more.
Late-Archean seawater functioned as a vast, redox-tuned colloidal system for which its kinetics were largely governed by the surface chemistry of silica–iron nanoparticles. By reproducing Archean seawater (≈0.7 M ionic strength, 25 °C) in laboratory anoxic-to-mildly oxic reactors, the ζ potential (zeta-potential(ζ)) of silica–iron nanoparticles was investigated, and we tracked how transient O2 pulses (≤9 mg L−1) regulated it. The zeta (ζ) potential was applied as the key diagnostic parameter to quantify both the sign of the ζ potential and the colloidal stability of simulated silica–iron particles in dispersion. Under strictly anoxic conditions, silica colloids (SiO2(aq)) exhibit a persistently negative ζ potential (ζ ≈ −25 mV) in the simulated seawater (pH 6.5), arising from deprotonated silanol groups (≡Si–O). Upon the addition of Fe2+, the inner-sphere complexation of ferrous ions on SiO2 colloids partially replaces ≡Si–O with ≡Si–O–Fe+/≡Si–O–Fe–OH sites; the net negative charge density at the outer Stern plane nevertheless increases, and the ζ potential shifts from −25 mV to −30 mV. As the simulated seawater was oxygenated, the dissolved and surface-bound Fe2+ ions were oxidized to Fe3+, causing the ζ potential to exceed −30 mV. This study demonstrates that Fe2+–silica interactions generate electrostatic destabilization, suspending micron-scale aggregates and thus modulating the solubility and speciation of SiO2 in early oceans. Also, transient micro-oxic pulses are shown to shift silica–iron colloids between metastable aggregation and dispersion by modulating their ζ potential. Subsequently, AFM and TEM were used to characterize the morphological changes in the colloidal particles from the liquid state to the dry state. Furthermore, infrared and XPS analyses were conducted on the colloidal samples. These findings provide certain reference significance for reconstructing the chemical evolution process of seawater in the Late-Archean period and for understanding the factors influencing the silicon–iron cycle of seawater in the Late-Archean era. Full article
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11 pages, 2245 KB  
Article
A Three-Terminal Si-Ge Avalanche Photodiode with a Breakdown Voltage of 6.8 V and a Gain Bandwidth Product of 1377 GHz
by Chao Cheng, Jintao Xue, Xishan Yu, Jifang Mu and Binhao Wang
Micromachines 2025, 16(11), 1222; https://doi.org/10.3390/mi16111222 - 27 Oct 2025
Viewed by 176
Abstract
Silicon–germanium (Si-Ge) avalanche photodiodes (APDs), fully compatible with complementary metal–oxide–semiconductor (CMOS) processes, are critical devices for high-speed optical communication. In this work, we propose a three-terminal Si-Ge APD on a silicon-on-insulator (SOI) substrate based on device simulation studies. The proposed APD employs a [...] Read more.
Silicon–germanium (Si-Ge) avalanche photodiodes (APDs), fully compatible with complementary metal–oxide–semiconductor (CMOS) processes, are critical devices for high-speed optical communication. In this work, we propose a three-terminal Si-Ge APD on a silicon-on-insulator (SOI) substrate based on device simulation studies. The proposed APD employs a separate absorption and multiplication structure, achieving an ultra-low breakdown voltage of 6.8 V. The device operates in the O-band, with optical signals laterally coupled into the Ge absorption layer via a silicon nitride (Si3N4) waveguide. At a bias of 2 V, the APD exhibits a responsivity of 0.85 A/W; under a bias of 6.6 V, it achieves a 3-dB optoelectronic (OE) bandwidth of 51 GHz, a direct current gain of 27, and a maximum gain–bandwidth product (GBP) of 1377 GHz. High-speed performance is further confirmed through eye-diagram simulations at 100 Gbps non-return-to-zero (NRZ) and 200 Gbps four-level pulse amplitude modulation (PAM4). These results clearly show the strong potential of the proposed APD for optical communication and interconnect applications under stringent power and supply voltage constraints. Full article
(This article belongs to the Special Issue Photonic and Optoelectronic Devices and Systems, Third Edition)
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19 pages, 2469 KB  
Article
Tuning Multi-Wavelength Reflection Properties of Porous Silicon Bragg Reflectors Using Silver-Nanoparticle-Assisted Electrochemical Etching
by Sheng-Yang Huang, Hsiao-Han Hsu, Amal Muhammed Musthafa, I-An Lin, Chia-Man Chou and Vincent K. S. Hsiao
Micromachines 2025, 16(11), 1198; https://doi.org/10.3390/mi16111198 - 22 Oct 2025
Viewed by 303
Abstract
This study proposes an innovative silver-nanoparticle-assisted electrochemical etching method for the fabrication of porous silicon Bragg reflectors with multi-wavelength reflection characteristics. By introducing silver nanoparticles at varying concentrations (0.1–10 mg/mL) into the conventional HF–ethanol electrolyte and applying periodically modulated current densities (40/100 mA/cm [...] Read more.
This study proposes an innovative silver-nanoparticle-assisted electrochemical etching method for the fabrication of porous silicon Bragg reflectors with multi-wavelength reflection characteristics. By introducing silver nanoparticles at varying concentrations (0.1–10 mg/mL) into the conventional HF–ethanol electrolyte and applying periodically modulated current densities (40/100 mA/cm2), the transition from single-peak to multi-peak reflection spectra was successfully achieved. The results demonstrate that at a concentration of 10 mg/mL silver nanoparticles, up to four distinct reflection bands can be obtained. A systematic investigation was conducted on the influence of etching cycles (4–20 cycles) and silver nanoparticle concentration on the optical performance and microstructure. SEM analysis revealed well-defined periodic multilayer structures, while XPS analysis confirmed the presence of metallic silver on the porous silicon surface. This work provides a simple, controllable, and cost-effective approach to the development of multifunctional photonic devices, with promising applications in laser optics, solar cells, chemical sensing, and surface-enhanced Raman scattering. Full article
(This article belongs to the Special Issue Micro-Nano Photonics: From Design and Fabrication to Application)
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13 pages, 11106 KB  
Article
Quantification of Yield Gain from Bifacial PV Modules in Multi-Megawatt Plants with Sun-Tracking Systems
by Gabriele Malgaroli, Fabiana Matturro, Andrea Cagnetti, Aleandro Vivino, Ludovico Terzi, Alessandro Ciocia and Filippo Spertino
Solar 2025, 5(4), 49; https://doi.org/10.3390/solar5040049 - 21 Oct 2025
Viewed by 245
Abstract
Nowadays, bifacial photovoltaic (PV) technology has emerged as a key solution to enhance the energy yield of large-scale PV plants, especially when integrated with sun-tracking systems. This study investigates the quantification of bifaciality productivity for two multi-MW PV plants in southern Italy (Sicily) [...] Read more.
Nowadays, bifacial photovoltaic (PV) technology has emerged as a key solution to enhance the energy yield of large-scale PV plants, especially when integrated with sun-tracking systems. This study investigates the quantification of bifaciality productivity for two multi-MW PV plants in southern Italy (Sicily) equipped with monocrystalline silicon bifacial modules installed on single-axis east–west tracking systems and aligned in the north–south direction. An optimized energy model was developed at the stringbox level, employing a dedicated procedure including data filtering, clear-sky condition selection, and numerical estimation of bifaciality factors. The model was calibrated using on-field measurements acquired during the first operational months to minimize uncertainties related to degradation phenomena. The application of the model demonstrated that the rear-side contribution to the total energy output is non-negligible, resulting in additional energy gains of approximately 5.3% and 3% for the two plants, respectively. Full article
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11 pages, 3383 KB  
Article
All-Optically Controlled Terahertz Modulation by Silicon-Grown CdSe/CdZnS Colloidal Quantum Wells
by Reyihanguli Tudi, Zhongxin Zhang, Xintian Song, AbulimitiYasen, Bumaliya Abulimiti and Mei Xiang
Nanomaterials 2025, 15(20), 1597; https://doi.org/10.3390/nano15201597 - 20 Oct 2025
Viewed by 296
Abstract
The CdSe/CdZnS colloidal quantum wells, with their exceptionally high carrier mobility and ultrafast response characteristics, emerge as highly promising candidate material for high-performance active terahertz modulators—indispensable core components critical for next-generation communication technologies. A high-performance, cost-effective terahertz modulator was fabricated through spin-coating CdSe(4ML)/CdZnS [...] Read more.
The CdSe/CdZnS colloidal quantum wells, with their exceptionally high carrier mobility and ultrafast response characteristics, emerge as highly promising candidate material for high-performance active terahertz modulators—indispensable core components critical for next-generation communication technologies. A high-performance, cost-effective terahertz modulator was fabricated through spin-coating CdSe(4ML)/CdZnS nanosheets onto a silicon substrate. This all-optical device demonstrates broadband modulation capabilities (0.25–1.4 THz), achieving a remarkable modulation depth of 87.6% at a low power density of 2 W/cm2. Demonstrating pump-power-efficient terahertz modulation characteristics, this core–shell composite shows immediate applicability in terahertz communication systems and non-destructive testing equipment. Full article
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12 pages, 2252 KB  
Article
Ultra-High Spectral Contrast Nanobeam Photonic Crystal Cavity on Bending Waveguide
by Ping Yu, Peihong Cheng, Zhuoyuan Wang, Jingrui Wang, Fangfang Ge, Huiye Qiu and Daniel Kacik
Photonics 2025, 12(10), 1031; https://doi.org/10.3390/photonics12101031 - 17 Oct 2025
Viewed by 298
Abstract
In this article, one-dimensional photonic crystal cavities on bending waveguides (PCCoBW) used for achieving high-contrast spectra are proposed, analyzed, and experimentally verified on silicon on insulator (SOI). Both air and dielectric modes of the PCCoBW calculated by the finite-difference time-domain (FDTD) method show [...] Read more.
In this article, one-dimensional photonic crystal cavities on bending waveguides (PCCoBW) used for achieving high-contrast spectra are proposed, analyzed, and experimentally verified on silicon on insulator (SOI). Both air and dielectric modes of the PCCoBW calculated by the finite-difference time-domain (FDTD) method show finger-ring-like mode profiles with the achievement of high-quality factors (Q∼106), even when the bending radius is less than 50 times the lattice constant. Straight waveguides side-coupled to the cavity are used to access and measure mode resonances. The measured spectra show a high extinction ratio over 40 dB for dielectric modes and 20 dB for air modes, respectively. Both dielectric and air resonant modes are revealed with Q-factors over 3.3 × 104 and 7.9 × 104, respectively, for the coupled PCCoBWs. The proposed PCCoBW could be implemented as high-contrast notch filtering and would benefit a broad range of applications such as optical filters, modulators, sensors, or switches. Full article
(This article belongs to the Special Issue Recent Advancement in Microwave Photonics)
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20 pages, 4302 KB  
Article
Supplementation of Trimethylamine N-Oxide or Betaine in Semen Improves Quality of Boar Spermatozoa Stored at 17 °C Following Hydrostatic Pressure Stress
by Cheng Qin, Guangyuan Lu, Xiao Lin, Zhongkai Wang, Shiyu Yang, Liqiong Teng, Xin Lin, Fangfang Li, Shouping Huang and Chuanhuo Hu
Life 2025, 15(10), 1606; https://doi.org/10.3390/life15101606 - 15 Oct 2025
Viewed by 317
Abstract
HP, as an isotropic physical stress, has been widely applied in cell biology and reproductive research to simulate the effects of environmental pressure on cellular functions. In this study, the elastic silicone membrane of a novel bionic insemination catheter was employed as the [...] Read more.
HP, as an isotropic physical stress, has been widely applied in cell biology and reproductive research to simulate the effects of environmental pressure on cellular functions. In this study, the elastic silicone membrane of a novel bionic insemination catheter was employed as the pressure medium, with semen perfused into a sealed silicone chamber. As the silicone membrane underwent controlled deformation, the liquid inside the chamber generated a nearly uniform isotropic pressure, thereby maintaining spermatozoa in a stable HP environment. Boar sperm are susceptible to physiological and functional damage under HP stress, which can impair fertilization capacity. This study aimed to investigate the effects of TMAO, BET, or their combination on the quality of semen from eight Landrace boars under HP during storage at 17 °C (experiment repeated three times). Semen was collected using the manual collection method and treated with different concentrations of TMAO or BET. Sperm motility parameters were assessed using a CASA system to determine the optimal concentrations. Subsequently, experimental groups were established: the fresh group, HP control group, T group (optimal TMAO), B group (optimal BET), and H group (optimal TMAO + BET). The results showed that the optimal concentrations were 8 mmol/L for TMAO and 20 mmol/L for BET. Compared with the HP control group, the T, B, and H groups showed significantly improved sperm viability, mitochondrial membrane potential (MMP), and plasma membrane integrity (p < 0.05), and significantly reduced DFI, ROS, MDA, and NO contents (p < 0.05), while acrosome integrity showed no significant differences (p > 0.05). Additionally, the B group showed significantly increased T-AOC (p < 0.05). Non-targeted lipidomic analysis revealed 49 differential lipids in the T group, 262 in the B group, and 269 in the H group compared with the HP control. These differential lipids were mainly associated with PC, AcCa, and sphingolipid signaling pathways, with key sphingolipid pathway lipids including Cer, SM, and DG. These findings indicate that BET and TMAO + BET improve HP-induced sperm damage by modulating the sphingolipid signaling pathway and maintaining PC and AcCa levels, whereas TMAO alone may exert protective effects through additional mechanisms. In conclusion, TMAO, BET, or their combination effectively mitigates the detrimental effects of HP on boar sperm. Full article
(This article belongs to the Section Animal Science)
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21 pages, 7112 KB  
Article
A Two-Plane Proton Radiography System Using ATLAS IBL Pixel-Detector Modules
by Hendrik Speiser, Claus Maximillian Bäcker, Johannes Esser, Alina Hild, Marco Iampieri, Ann-Kristin Lüvelsmeyer, Annsofie Tappe, Helen Thews, Kevin Kröninger and Jens Weingarten
Instruments 2025, 9(4), 23; https://doi.org/10.3390/instruments9040023 - 14 Oct 2025
Viewed by 231
Abstract
Accurate knowledge of a patient’s anatomy during every treatment fraction in proton therapy is an important prerequisite to ensure a correct dose deposition in the target volume. Adaptive proton therapy aims to detect those changes and adjust the treatment plan accordingly. One way [...] Read more.
Accurate knowledge of a patient’s anatomy during every treatment fraction in proton therapy is an important prerequisite to ensure a correct dose deposition in the target volume. Adaptive proton therapy aims to detect those changes and adjust the treatment plan accordingly. One way to trigger a daily re-planning of the treatment is to take a proton radiograph from the beam’s-eye view before the treatment to check for possible changes in the water equivalent thickness (WET) along the path due to daily changes in the patient’s anatomy. In this paper, the Two-Plane Imaging System (TPIS) is presented, comprising two ATLAS IBL silicon pixel-detector modules developed for the tracking detector of the ATLAS experiment at CERN. The prototype of the TPIS is described in detail, and proof-of-principle WET images are presented, of two-step phantoms and more complex phantoms with bone-like inlays (WET 10 to 40 mm). This study shows the capability of the TPIS to measure WET images with high precision. In addition, the potential of the TPIS to accurately determine WET changes over time down to 1 mm between subsequently taken WET images of a changing phantom is shown. This demonstrates the possible application of the TPIS and ATLAS IBL pixel-detector module in adaptive proton therapy. Full article
(This article belongs to the Special Issue Medical Applications of Particle Physics, 2nd Edition)
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22 pages, 6557 KB  
Article
Modeling of Residual Stress, Plastic Deformation, and Permanent Warpage Induced by the Resin Molding Process in SiC-Based Power Modules
by Giuseppe Mirone, Luca Corallo, Raffaele Barbagallo and Giuseppe Bua
Energies 2025, 18(20), 5364; https://doi.org/10.3390/en18205364 - 11 Oct 2025
Viewed by 303
Abstract
A critical aspect in the design of power electronics packages is the prediction of their mechanical response under severe thermomechanical loads and the consequent structural damage. For this purpose, finite element (FE) simulations are used to estimate the mechanical performance and reliability under [...] Read more.
A critical aspect in the design of power electronics packages is the prediction of their mechanical response under severe thermomechanical loads and the consequent structural damage. For this purpose, finite element (FE) simulations are used to estimate the mechanical performance and reliability under operational conditions, typically alternate high voltages/currents resulting in thermal gradients. When simulations are performed, it is common practice to consider the as-received package to be in a stress-free state. Namely, residual stresses and plastic deformation induced by the manufacturing processes are neglected. In this study, an advanced FE modeling approach is proposed to assess the structural consequences of the encapsulating resin curing, typical in the production of silicon carbide (SiC)-based power electronics modules for electric vehicles. This work offers a general modeling framework that can be further employed to simulate the effects of thermal gradients induced by the production process on the effective shape and residual stresses of the as-received package for other manufacturing stages, such as metal brazing, soldering processes joining copper and SiC, and, to lower extents, the application of polyimide on top of passivation layers. The obtained results have been indirectly validated with experimental data from literature. Full article
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19 pages, 5557 KB  
Article
Formulation Strategies for High-Thermal-Conductivity Organosilicon Potting Adhesive
by Limin Chen, Sadaf Bashir Khan, Zhengjun Zhang and Weipeng Wang
Molecules 2025, 30(20), 4043; https://doi.org/10.3390/molecules30204043 - 10 Oct 2025
Viewed by 285
Abstract
In this study, we present a novel high-thermal-conductivity-organosilicon potting adhesive developed for use in power modules. The adhesive is designed to enhance power modules’ thermal properties and mechanical strength, addressing the need for more efficient and reliable encapsulation materials in electronic applications. By [...] Read more.
In this study, we present a novel high-thermal-conductivity-organosilicon potting adhesive developed for use in power modules. The adhesive is designed to enhance power modules’ thermal properties and mechanical strength, addressing the need for more efficient and reliable encapsulation materials in electronic applications. By optimizing the resin formulation, the adhesive exhibits improved tensile strength and elongation at break properties, making it particularly suitable for applications requiring high durability and resilience under thermal and mechanical stress. Herein, we propose a high-thermal-conductivity organosilicon electronic potting adhesive designed for power modules. The adhesive consists of two components: Component A and Component B. Component A is composed of a base polymer (0.5–10 parts), silicone resin (0.15–10 parts), plasticizer (0.5–5 parts), color paste (0.01–0.2 parts), thermally conductive filler (70–120 parts), filler treatment agent (2–8 parts), and a catalyst (0.1–2 parts). Component B includes a base polymer (0.5–10 parts), silicone resin (0.15–10 parts), plasticizer (0.5–5 parts), thermally conductive filler (70–120 parts), crosslinking agent (0.1–10 parts), chain extender (0.1–10 parts), and crosslinking inhibitor (0.01–1 part). The adhesive is designed to improve the tensile strength and elongation at break. These materials were engineered to facilitate easy repair and disassembly, ensuring cost-effective maintenance and reuse in power module systems. This work demonstrates the potential of the adhesive in advancing the performance and longevity of power electronics, providing valuable insights into its practical application for high-performance electronic devices. Full article
(This article belongs to the Special Issue Photoelectrochemical Properties of Nanostructured Thin Films)
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20 pages, 4835 KB  
Article
An Asymmetric SiC Power Module Directly Integrated with Vapor Chamber for Thermal Balancing in MMC
by Binyu Wang, Xiwei Zhou, Yawen Zhu, Mengfei Qi, Hai Lin, Bobin Yao, Shaohua Huang, Xuetao Wang, Qisheng Wu and Weiyu Liu
Appl. Sci. 2025, 15(20), 10869; https://doi.org/10.3390/app152010869 - 10 Oct 2025
Viewed by 325
Abstract
Power modules in silicon carbide (SiC)-based modular multilevel converters (MMCs) suffer from notably severe thermal imbalance and localized overheating. This paper puts forward an asymmetric SiC power module with direct integration of a vapor chamber (VC), designed to balance the thermal distribution inside [...] Read more.
Power modules in silicon carbide (SiC)-based modular multilevel converters (MMCs) suffer from notably severe thermal imbalance and localized overheating. This paper puts forward an asymmetric SiC power module with direct integration of a vapor chamber (VC), designed to balance the thermal distribution inside MMC SMs. Specifically, the chips on the lower side of the HBSM are soldered onto a VC, which is additionally mounted on the direct bonding copper (DBC). Endowed with merits such as favorable temperature uniformity, exceptional thermal conductivity, compact size, flexible design, high integration level, and reasonable cost, the VC serves as an outstanding heat diffuser significantly expanding the effective thermal conduction area and reducing thermal resistance. Moreover, in this structure, the VC also functions as a conductor for device current. Finite element method (FEM) simulation results reveal that the proposed structure can notably reduce the hotspot temperature (from 109 °C to 71.8 °C), the maximum temperature difference among chips (from 45 °C to 13.89 °C), and the low-frequency temperature swing (TSL) (from 68 °C to 38 °C). Consequently, the issues of localized overheating and thermal imbalance in SiC-MMC SMs are effectively addressed. Lifetime analysis further indicates that the proposed structure can reduce the annual damage rate of the chip solder layer by 92.6%. Full article
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24 pages, 669 KB  
Review
Nutrient-Element-Mediated Alleviation of Cadmium Stress in Plants: Mechanistic Insights and Practical Implications
by Xichao Sun, Liwen Zhang, Yingchen Gu, Peng Wang, Haiwei Liu, Liwen Qiang and Qingqing Huang
Plants 2025, 14(19), 3081; https://doi.org/10.3390/plants14193081 - 6 Oct 2025
Viewed by 685
Abstract
Cadmium (Cd), a pervasive and highly phytotoxic metal pollutant, poses severe threats to agricultural productivity, ecosystem stability, and human health through its entry into the food chain. Plants have evolved intricate defense mechanisms, among which the strategic manipulation of nutrient elements emerges as [...] Read more.
Cadmium (Cd), a pervasive and highly phytotoxic metal pollutant, poses severe threats to agricultural productivity, ecosystem stability, and human health through its entry into the food chain. Plants have evolved intricate defense mechanisms, among which the strategic manipulation of nutrient elements emerges as a critical physiological and biochemical strategy for mitigating Cd stress. This comprehensive review delves deeply into the multifaceted roles of essential macronutrient elements (nitrogen, phosphorus, potassium, calcium, magnesium, sulfur), essential micronutrient elements (zinc, iron, manganese, copper) and non-essential beneficial elements (silicon, selenium) in modulating plant responses to Cd toxicity. We meticulously dissect the physiological, biochemical, and molecular underpinnings of how these nutrients influence Cd bioavailability in the rhizosphere, Cd uptake and translocation pathways, sequestration and compartmentalization within plant tissues, and the activation of antioxidant defense systems. Nutrient elements exert their influence through diverse mechanisms: competing with Cd for root uptake transporters, promoting the synthesis of complexes that reduce Cd mobility, stabilizing cell walls and plasma membranes to restrict apoplastic flow and symplastic influx, modulating redox homeostasis by enhancing antioxidant enzyme activities and non-enzymatic antioxidant pools, regulating signal transduction pathways, and influencing gene expression profiles related to metal transport, chelation, and detoxification. The complex interactions between nutrients themselves further shape the plant’s capacity to withstand Cd stress. Recent advances elucidating nutrient-mediated epigenetic regulation, microRNA involvement, and the role of nutrient-sensing signaling hubs in Cd responses are critically evaluated. Furthermore, we synthesize the practical implications of nutrient management strategies, including optimized fertilization regimes, selection of nutrient-efficient genotypes, and utilization of nutrient-enriched amendments, for enhancing phytoremediation efficiency and developing low-Cd-accumulating crops, thereby contributing to safer food production and environmental restoration in Cd-contaminated soils. The intricate interplay between plant nutritional status and Cd stress resilience underscores the necessity for a holistic, nutrient-centric approach in managing Cd toxicity in agroecosystems. Full article
(This article belongs to the Special Issue Plant Ecotoxicology and Remediation Under Heavy Metal Stress)
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19 pages, 2745 KB  
Article
Mechanistic Insights into Silicon-Enhanced Cadmium Detoxification in Rice: A Spatiotemporal Perspective
by Hongmei Lin, Miaohua Jiang, Shaofei Jin and Songbiao Chen
Agronomy 2025, 15(10), 2331; https://doi.org/10.3390/agronomy15102331 - 2 Oct 2025
Viewed by 361
Abstract
The spatiotemporal regulatory mechanism underlying silicon (Si)-mediated cadmium (Cd) detoxification in rice (Oryza sativa L.) was investigated using non-invasive micro-test technology (NMT), combined with physiological and biochemical analyses. The results revealed the following: (1) Si significantly inhibited Cd2+ influx into rice [...] Read more.
The spatiotemporal regulatory mechanism underlying silicon (Si)-mediated cadmium (Cd) detoxification in rice (Oryza sativa L.) was investigated using non-invasive micro-test technology (NMT), combined with physiological and biochemical analyses. The results revealed the following: (1) Si significantly inhibited Cd2+ influx into rice roots, with the most pronounced reductions in ion flux observed under moderate Cd stress (Cd50, 50 μmol·L−1), reaching 35.57% at 7 days and 42.30% at 14 days. Cd accumulation in roots decreased by 34.03%, more substantially than the 28.27% reduction observed in leaves. (2) Si application enhanced photosynthetic performance, as evidenced by a 14.21% increase in net photosynthetic rate (Pn), a 32.14% increase in stomatal conductance (Gs), and a marked restoration of Rubisco activity. (3) Si mitigated oxidative damage, with malondialdehyde (MDA) and hydrogen peroxide (H2O2) levels reduced by 11.29–21.88%, through the upregulation of antioxidant enzyme activities (SOD, APX, CAT increased by 15.34–38.33%) and glutathione metabolism (GST activity and GSH content increased by 60.78% and 51.35%, respectively). (4) The mitigation effects of Si were found to be spatiotemporally specific, with stronger responses under Cd50 than Cd100 (100 μmol·L−1), at 7 days (d) compared to 14 d, and in roots relative to leaves. Our study reveals a coordinated mechanism by which Si modulates Cd uptake, enhances photosynthetic capacity, and strengthens antioxidant defenses to alleviate Cd toxicity in rice. These findings provide a scientific basis for the application of Si in mitigating heavy metal stress in agricultural systems. Full article
(This article belongs to the Special Issue Rice Cultivation and Physiology)
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21 pages, 6329 KB  
Review
Degradation Progress of Metallized Silicon Nitride Substrate Under Thermal Cycling Tests by Digital Image Correlation
by Minh Chu Ngo, Hiroyuki Miyazaki, Kiyoshi Hirao, Tatsuki Ohji and Manabu Fukushima
J. Compos. Sci. 2025, 9(10), 536; https://doi.org/10.3390/jcs9100536 - 2 Oct 2025
Viewed by 500
Abstract
Thermal cycling test is one of the reliability tests, which are important for metal-ceramic layered composites (metallized ceramic substrates), a part in power modules. Since thermal cycles are within a large range of temperature, the test has only been performed using a thermal [...] Read more.
Thermal cycling test is one of the reliability tests, which are important for metal-ceramic layered composites (metallized ceramic substrates), a part in power modules. Since thermal cycles are within a large range of temperature, the test has only been performed using a thermal chamber. It limited the understanding of degradation mechanism in metallized ceramics substrates. Among NDE techniques, Digital Image Correlation (DIC) is a simple and effective method, enhanced by modern digital imaging technologies, enabling precise measurements of displacement, strain, deformation, and defects with a simple setup. In this paper, we combined some of our previous work to make a review to present a full analysis of a silicon metallized substrate under thermal cycling test (from beginning to fail) using DIC method. The main content is the application of DIC in evaluating the reliability of metallized silicon nitride (AMB-SN) substrates under thermal cycling with temperatures from −40 °C to 250 °C. Three key aspects of the AMB-SN substrate are presented, including (i) thermal strain characteristics before and after delamination, (ii) warpage and dynamic bending behavior across damage states, and (iii) stress–strain behavior of constituent materials. The review provides insights into degradation progress of the substrate and the role of Cu in substrate failure, and highlights DIC’s potential in ceramic composites, offering a promising approach for improving reliability test simulations and advancing digital transformation in substrate evaluation, ultimately contributing to enhanced durability in high-power applications. Full article
(This article belongs to the Special Issue Characterization and Modeling of Composites, 4th Edition)
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