Search Results (603)

The FLEX-S3 mission by ESA will deliver key Level 2 products such as sun-induced chlorophyll fluorescence (SIF) and vegetation-reflected radiance. To validate these, the SpaFLEX project, funded by the Spanish Ministry of Science and Innovation, is developing a robust calibration and validation strategy in Spain. This includes test site setup, instrument characterization, and sampling protocols. A field campaign was conducted in two Holm Oak forests in Teruel, analyzing Sentinel-2 spatial heterogeneity and collecting ground, UAV, and airborne data. The results support scaling procedures to match the 300 m pixel resolution of FLEX-S3, ensuring product accuracy and compliance with ESA standards. Full article

Sun-induced chlorophyll fluorescence (SIF) is an important indicator of vegetation photosynthesis. While remote sensing enables large-scale monitoring of SIF, existing products face the challenge of trade-offs between temporal and spatial resolutions, limiting their applications. To select the optimal model for SIF data downscaling, we used a consistent dataset combined with vegetation physiological and meteorological parameters to evaluate four different regression methods in this study. The XGBoost model demonstrated the best performance during cross-validation (R² = 0.84, RMSE = 0.137 mW/m²/nm/sr) and was, therefore, selected to downscale GOME-2 SIF data. The resulting high-resolution SIF product (HRSIF) has a temporal resolution of 8 days and a spatial resolution of 0.05° × 0.05°. The downscaled product shows high fidelity to the original coarse SIF data when aggregated (correlation = 0.76). The reliability of the product was ensured through cross-validation with ground-based and satellite observations. Moreover, the finer spatial resolution of HRSIF better matches the footprint of eddy covariance flux towers, leading to a significant improvement in the correlation with tower-based gross primary productivity (GPP). Specifically, in the mixed forest vegetation type with the best performance, the R² increased from 0.66 to 0.85, representing an increase of 28%. This higher-precision product will support more effective ecosystem monitoring and research. Full article

Fatigue damage in steel–concrete composite structures frequently initiates at welded joints due to stress concentrations and inherent defects. This study investigates the stress intensity factors (SIFs) associated with fatigue cracks in the welds of steel longitudinal beams, employing the FRANC3D–ABAQUS interactive technique. A finite element model was developed and validated against experimental data, followed by the insertion of cracks at both the weld root and weld toe. The influences of stud spacing, initial crack size, crack shape, and lack-of-penetration defects on Mode I SIFs were systematically analyzed. Results show that both weld root and weld toe cracks are predominantly Mode I in nature, with the toe cracks exhibiting higher SIF values. Increasing the stud spacing, crack depth, or crack aspect ratio significantly raises the SIFs. Lack of penetration defects further amplifies the SIFs, especially at the weld root. Based on the computed SIFs, fatigue life predictions were conducted using a crack propagation approach. These findings highlight the critical roles of crack geometry and welding quality in fatigue performance, providing a numerical foundation for optimizing welded joint design in composite structures. Full article

IoT devices with sensors and actuators are frequently deployed in environments without access to the power grid. These devices are battery powered and might make use of energy harvesting if battery lifetime is too limited. This article focuses on automatically adapting the duty cycle frequency to the predicted available solar energy so that a continuous operation of IoT applications is guaranteed. The implementation is based on a low-cost solar control board that is integrated with the Serverless IoT Framework (SIF), which provides an event-based programming paradigm for microcontroller-based IoT devices. The paper presents a case study where the IoT device sleep time is pro-actively adapted to a predicted sequence of cloudy days to guarantee continuous operation. Full article

This study employs molecular dynamics (MD) simulations to investigate the mechanical response and fracture behavior of penta-graphene, a novel two-dimensional carbon allotrope composed entirely of pentagonal rings with mixed sp²–sp³ hybridization and pronounced mechanical anisotropy. Atomistic simulations are carried out to evaluate the impact of structural defects on mechanical performance and to elucidate crack propagation mechanisms. The results reveal that void defects involving sp³-hybridized carbon atoms cause a more significant degradation in mechanical strength compared to those involving sp² atoms. During fracture, local atomic rearrangements and bond reconstructions lead to the formation of energetically favorable ring structures—such as hexagons and octagons—at the crack tip, promoting enhanced energy dissipation and fracture resistance. A central focus of this work is the evaluation of the critical stress intensity factor (SIF) under mixed-mode (I/II) loading conditions. The simulations demonstrate that the critical SIF is influenced by the loading phase angle, with pure mode I exhibiting a higher SIF than pure mode II. Notably, penta-graphene shows a critical SIF significantly higher than that of graphene, indicating exceptional fracture toughness that is rare among ultra-thin two-dimensional materials. This enhanced toughness is primarily attributed to penta-graphene’s capacity for substantial out-of-plane deformation prior to failure, which redistributes stress near the crack tip, delays crack initiation, and increases energy absorption. Additionally, the study examines crack growth paths as a function of loading phase angle, revealing that branching and kinking can occur even under pure mode I loading. Full article

The integration of lithium-ion (Li-ion) battery energy storage systems (LiBESSs) with photovoltaic (PV) generation offers a promising solution for powering auxiliary services (ASs) in high-voltage power stations. This study conducts a systematic literature review (SLR) to evaluate the feasibility, benefits, and challenges of this integration. The proposed SLR complies with the PRISMA 2020 statement, and it is also registered on the international PROSPERO platform (ID 1073599). The selected methodology includes the following key steps: definition of the research questions; search strategy development; selection criteria of the studies; quality assessment; data extraction and synthesis; and discussion of the results. Through a comprehensive analysis of scientific publications from 2013 to 2024, trends, advancements, and research gaps are identified. The methodology follows a structured review framework, including data collection, selection criteria, and evaluation of technical feasibility. From 803 identified studies, 107 were eligible in accordance with the assessed inclusion criteria. Then, a custom study impact factor (SIF) framework selected 5 out of 107 studies as the most representative and assertive ones on the topics of this SLR. The findings indicate that Li-ion BESSs combined with PV systems enhance reliability, reduce reliance on conventional sources, and improve grid resilience, particularly in remote or constrained environments. The group of reviewed studies discuss optimization models and multi-objective strategies for system sizing and operation, along with practical case studies validating their effectiveness. Despite these advantages, challenges related to cost, regulatory frameworks, and performance variability remain. The study concludes that further experimental validations, pilot-scale implementations, and assessment of long-term economic impacts are necessary to accelerate the adoption of BESS-PV systems in high-voltage power substations. This study was funded by the R&D program of the Brazilian National Electric Energy Agency (ANEEL) via project number PD-07351-0001/2022. Full article

Background: Shirakiopsis indica (Willd.) (Family: Euphorbiaceae), a mangrove species found in the Asian region, is a popular folkloric plant. Locally, the plant is traditionally used to treat various types of ailments, especially for pain relief. Therefore, the current study investigates the neuropharmacological, antipyretic, thrombolytic, and anthelmintic properties of the S. indica fruit methanolic extract (SIF-ME). Methods: The neuropharmacological activity was evaluated using several bioactive assays, and the antipyretic effect was investigated using the yeast-induced pyrexia method, both in Swiss albino mice models. Human blood clot lysis was employed to assess thrombolytic activity, while in vitro anthelmintic characteristics were tested on Tubifex tubifex. Insights into phytochemicals from SIF-ME have also been reported from a literature review, which were further subjected to molecular docking, pass prediction, and ADME/T analysis and validated the wet-lab outcomes. Results: In the elevated plus maze test, SIF-ME at 400 mg/kg demonstrated significant anxiolytic effects (200.16 ± 1.76 s in the open arms, p < 0.001). SIF-ME-treated mice exhibited increased head dipping behavior and spent a longer time in the light box, confirming strong anxiolytic activity in the hole board and light–dark box tests, respectively. It (400 mg/kg) also significantly reduced depressive behavior during forced swimming and tail suspension tests (98.2 ± 3.83 s and 126.33 ± 1.20 s, respectively). The extract induced strong locomotor activity, causing mice’s mobility to gradually decrease over time in the open field and hole cross tests. The antipyretic effect of SIF-ME (400 mg/kg) was minimal using the yeast-induced pyrexia method, while it (100 μg/mL) killed T. tubifex in 69.33 ± 2.51 min, indicating a substantial anthelmintic action. SIF-ME significantly reduced blood clots by 67.74% (p < 0.001), compared to the control group’s 5.56%. The above findings have also been predicted by in silico molecular docking studies. According to the molecular docking studies, the extract’s constituents have binding affinities ranging from 0 to −10.2 kcal/mol for a variety of human target receptors, indicating possible pharmacological activity. Conclusions: These findings indicate that SIF-ME could serve as a promising natural source of compounds with neuropharmacological, anthelmintic, thrombolytic, and antipyretic properties. Full article

Amidst escalating concerns about climate change, manufacturers are increasingly pressured to adopt a low-carbon supply chain (LCSC). Financial constraints deter numerous companies from embracing low-carbon initiatives in a competitive landscape. Inclusive internal financing (IIF) provides operational funds from capital-abundant members to capital-constrained members, resolving funding shortages internally within the system. However, when dominant members cannot support all such enterprises, selective internal financing (SIF) or hybrid financing (HF) becomes necessary. This paper studies the operation and financing strategies of a competitive LCSC. Within the framework of an LCSC where two capital-constrained retailers compete, using Stackelberg game theory and the backward induction method, three game-theoretical models are developed under IIF, SIF, and HF. The results indicate that increased competition intensity reduces product sales price, the manufacturer’s carbon emission reduction level, and profit. When competition intensity is high, SIF more effectively enhances carbon emission reduction level, product sales quantity, and profit acquisition. HF reduces profits for the allied retailer and diminishes its competitiveness, yet enhances the competitive strength of the rival retailer. Numerical analysis demonstrates that when equity financing in HF exceeds 0.546, the allied retailer becomes unprofitable and is driven out of the market. This study complements LCSC finance research and provides references for supply chain operations and financing strategy formulation. Full article

Despite the promising electronic properties of graphene, its lack of an intrinsic bandgap limits its applicability in semiconductor technologies. This has catalyzed the investigation of newly developed two-dimensional carbon materials, including tetragraphene (TG), a quasi-2D semiconducting material featuring a combination of hexagonal and tetragonal rings. This study aims to investigate the mechanical and fracture behaviors of TG using density functional theory (DFT) and molecular dynamics (MD) simulations, studying two distinct atomic configurations of tetragraphene. DFT simulations assess the mechanical properties, while MD simulations explore the fracture dynamics subjected to mixed mode I (opening mode) and mode II (in-plane shear mode) loading. Our analysis focuses on the influence of loading phase angle, crack edge chirality, crack tip configuration, and temperature on crack propagation paths and critical stress intensity factors (SIFs) in TG structures. Our results show that the critical SIF varies by 12.5–21% depending on the crack chirality. Across all loading conditions, increasing the temperature ranging from 300 K to 2000 K reduces the critical SIF by 10–45%, with the largest reductions observed under pure mode I loading. These outcomes offer important insights into the structural integrity of TG and inform its potential integration into flexible nanoelectronic devices, where mechanical reliability is essential. Full article

Ecosystems modulate Earth’s climate through the exchange of carbon and water fluxes. However, long-term trends in these terrestrial fluxes remain unclear due to the lack of continuous measurements on the global scale. This study combined flux data from 197 eddy covariance sites with satellite-retrieved solar-induced chlorophyll fluorescence (SIF) to investigate spatiotemporal variations in gross primary productivity (GPP), evapotranspiration (ET), and their coupling via water use efficiency (WUE) from 2001 to 2020. We developed six global GPP and ET products at 0.05° spatial and 8-day temporal resolution, using two machine learning models and three SIF products, which integrate vegetation physiological parameters with data-driven approaches. These datasets provided mean estimates of 128 ± 2.3 Pg C yr⁻¹ for GPP, 522 ± 58.2 mm yr⁻¹ for ET, and 1.8 ± 0.21 g C kg⁻¹ H₂O yr⁻¹ for WUE, with upward trends of 0.22 ± 0.04 Pg C yr⁻² in GPP, 0.64 ± 0.14 mm yr⁻² in ET, and 0.0019 ± 0.0005 g C kg⁻¹ H₂O yr⁻² in WUE over the past two decades. These high-resolution datasets are valuable for exploring terrestrial carbon and water responses to climate change, as well as for benchmarking terrestrial biosphere models. Full article

Plant phenology is closely related to plant function, ecosystem services, and climate balance. Solar-induced chlorophyll fluorescence (SIF) offers new perspectives on plant phenology at regional and global scales. However, the effect of SIF products at different scales on phenology extraction is still unclear. Understanding of the mechanisms underlying phenological responses to environmental factors remains incomplete. Therefore, in this study, two phenological metrics for the Start of Growing Season (SOS) and the End of Growing Season (EOS) were extracted from the phenology of deciduous forests in the middle and high latitudes of the Northern Hemisphere, utilizing SIF products at scales of 1 km, 5 km, and 50 km, and applying the Savitzky-Golay filtering method along with the dynamic threshold method. Our results showed that the 1-km resolution SIF had a significant advantage over the 5-km and 50-km resolution SIFs in terms of consistency with the extracted phenology results from the Gross Primary Productivity (GPP) sites, with mean absolute errors (MAEs) of 4.48 and 15.49 days for SOS and EOS, respectively. For the 5-km resolution SIF, the MAEs for the same phenological metrics were 9.2 and 21.07 days. For the 50-km resolution SIF, the MAEs were 58.94 and 42.73 days. Meanwhile, this study analyzed the trends of phenology utilizing the three scales of SIF products and found a general trend of advancement. The coarser spatial resolution of the SIF data made the trend of advancement more obvious. Using SHapley Additive exPlanations (SHAP) analysis, we investigated the phenological responses to environmental factors at different scales. We found that SOS/EOS were mainly regulated by soil and air temperature, whereas the scale effect on this analysis’ results was not significant. This study has implications for optimizing the use of data, understanding ecosystem changes, predicting vegetation dynamics under global change, and developing adaptive management strategies. Full article

Solar-induced chlorophyll fluorescence (SIF) is a powerful tool for the estimation of gross primary productivity (GPP), but the relationship between SIF and GPP under drought stress remains incompletely understood. Elucidating the response of the relationship between SIF and GPP to drought stress is essential in order to enhance the precision of GPP estimation in forests. In this study, we obtained SIF in the red (SIF₆₈₇) and far-red (SIF₇₆₀) bands and GPP data from tower flux observations in a Chinese cork oak plantation to explore the response of the diurnal GPP-SIF relationship to drought stress. The plant water stress index (PWSI) was used to quantify drought stress. The results show that drought reduced SIF and GPP, but GPP was more sensitive to drought stress than SIF. The diurnal non-linear relationship of GPP-SIF (R²) decreased with the increase in drought stress, but a significant non-linear correlation remained for GPP-SIF (R²_GPP-SIF₇₆₀ = 0.30, R²_GPP-SIF₆₈₇ = 0.23) under severe drought stress (PWSI_bin: 0.8–0.9). Physiological coupling strengthened the GPP-SIF relationship under drought, while canopy structure effects were negligible. Random forest and path analyses revealed that VPD was the key factor reducing the GPP-SIF correlation during drought. Incorporating VPD into the GPP-SIF relationship improved the GPP estimation accuracy by over 48% under severe drought stress. The red SIF allowed for more accurate GPP estimations than the far-red SIF under drought conditions. Our results offer important perspectives on the GPP-SIF relationship under drought conditions, potentially helping to improve GPP model predictions in the face of climate change. Full article

This study investigated the effects of three mulch types (straw, vermicompost and “plastic”) plus an untreated control, and three irrigation regimes (RFD: rainfed conditions; SIF: one supplemental irrigation at the flowering stage; SIVF: two supplemental irrigations at the vegetative and flowering stages) on the growth, seed yield, oil composition, and biochemical status of linseed (Linum usitatissimum L.). Linseed plants were best affected by SIVF and straw mulch in terms of seed yield (300 and 222.4 g m⁻², respectively), biomass yield (887.9 and 703 g m⁻², respectively), and concentration of oleic and linoleic acids. Under rainfed conditions, “plastic” mulch application increased stearic acid concentrations, while SIF increased palmitic acid concentrations. Rainfed conditions promoted the accumulation of proline (10.1 μmol g⁻¹ fresh weight), total phenols (6.68 mg g⁻¹ fresh weight), and DPPH radical scavenging capacity (56.5%). Under RFD, plants grown in straw-mulched soil showed the highest total phenol content and DPPH radical scavenging capacity, while control (unmulched) plants displayed the highest proline concentration at this irrigation regime. Enzyme activities, including catalase and superoxide dismutase, were enhanced under straw and “plastic” mulch compared to control plants under rainfed conditions. Our findings suggest that straw mulch represents an effective, sustainable strategy to successfully manage linseed crops, mitigating the adverse effects of water deficit stress on plant performance. Full article

In the field of crack mechanics, predicting the direction of a crack is important because this will evaluate whether, when the crack propagates, it penetrates into important areas and whether the structure is dangerous or not. This paper will refer to three theories that predict the propagation direction of cracks: a theory of maximum tangential normal stress, a theory of maximum energy release, and a theory of minimum strain energy density. At the same time, the finite element method (FEM)–ANSYS program will be used to calculate stress intensity factors (SIFs), strain energy release rate (J-integral), stress field, displacement near a crack tip, and crack propagation phenomenon based on the above theories. The calculated results were compared with the results in other scientific papers and experimental results. This research used ANSYS program, an experimental method combined with FEM based on the above energy theories to simulate the J-integral, the SIFs, and the crack propagation. The errors of the SIFs of the FGM rectangular plate has a through-thickness center crack of 1.77%, J-integral of 4.49%, and crack propagation angle ${\theta }_c$ of 0.15%. The FEM gave good errors compared to experimental and exact methods. Full article

Objectives: This study characterised and evaluated the stability, solubility, and in vitro drug release of OA- and AA-loaded SLNs. Methods: The OA- and AA-SLNs were formulated using the emulsion solvent evaporation method and characterised based on particle size (PS), polydispersity index (PDI), zeta potential (ZP), and transmission electron microscopy (TEM). Solubility studies were conducted in PBS (pH 1.2 and 6.8) and dH₂O using HPLC, while in vitro drug release was assessed in simulated intestinal fluid (SIF) (pH 6.8). Results: The optimised OA-SLNs (1:1 drug-to-lipid ratio) showed PS, PDI, ZP, and EE% values of 312.9 ± 3.617 nm, 0.157 ± 0.014, −17.0 ± 0.513 mV, and 86.54 ± 1.818%, respectively. The optimised AA-SLNs (1:2 drug-to-lipid: ratio) had a PS of 115.5 ± 0.458 nm, PDI of 0.255 ± 0.007, ZP of −11.9 ± 0.321 mV, and EE% of 76.22 ± 0.436%. The SLNs remained stable for 60 days at 4 °C and room temperature (p < 0.05). The solubility study revealed that free OA and AA showed no measurable values in the three solvents. However, OA-SLNs showed the highest solubility in H₂O (16-fold) followed by PBS at pH 6.8 (10-fold) and pH 1.2 (10-fold). AA-SLNs significantly improved the solubility in PBS at pH 6.8 (88-fold), compared to dH₂O (6-fold) and PBS at pH 1.2 (26-fold). In vitro drug release studies showed that OA release from the SLNs was significantly increased within 300 min (p < 0.05) compared to the free drug. Similarly, AA release from the SLNs was significantly increased within 300 min (p < 0.05) compared to free AA. Conclusions: These results demonstrate that SLNs enhance OA and AA solubility and drug release, suggesting a promising strategy for improving oral bioavailability and therapeutic efficacy. Full article