Search Results (164)

This study investigates the application of additive manufacturing (AM) in fabricating transverse thermoelectric (TTE) composites, demonstrating the feasibility of this methodology for TTE material synthesis. Zinc oxide (ZnO), a wide-bandgap semiconductor with moderate thermoelectric performance, and copper (Cu), a highly conductive metal, were selected as base materials. These were formulated into stable paste-like feedstocks for direct ink writing (DIW). A custom dual-nozzle 3D printer was developed to precisely deposit these materials in pre-designed architectures. The resulting structures exhibited measurable transverse Seebeck effects. Unlike prior TE research primarily focused on longitudinal configurations, this work demonstrates a novel AM-enabled strategy that integrates directional compositional anisotropy, embedded metal–semiconductor interfaces, and scalable multi-material printing to realize TTE behavior. The approach offers a cost-effective and programmable pathway toward next-generation energy harvesting and thermal management systems. Full article

Resistive gas sensors have attracted significant attention due to their simple architecture, low cost, and ease of integration, with widespread applications in environmental monitoring, industrial safety, and healthcare diagnostics. This review provides a comprehensive overview of recent advances in resistive gas sensors, focusing on their fundamental working mechanisms, sensing material design, device architecture optimization, and intelligent system integration. These sensors primarily operate based on changes in electrical resistance induced by interactions between gas molecules and sensing materials, including physical adsorption, charge transfer, and surface redox reactions. In terms of materials, metal oxide semiconductors, conductive polymers, carbon-based nanomaterials, and their composites have demonstrated enhanced sensitivity and selectivity through strategies such as doping, surface functionalization, and heterojunction engineering, while also enabling reduced operating temperatures. Device-level innovations—such as microheater integration, self-heated nanowires, and multi-sensor arrays—have further improved response speed and energy efficiency. Moreover, the incorporation of artificial intelligence (AI) and Internet of Things (IoT) technologies has significantly advanced signal processing, pattern recognition, and long-term operational stability. Machine learning (ML) algorithms have enabled intelligent design of novel sensing materials, optimized multi-gas identification, and enhanced data reliability in complex environments. These synergistic developments are driving resistive gas sensors toward low-power, highly integrated, and multifunctional platforms, particularly in emerging applications such as wearable electronics, breath diagnostics, and smart city infrastructure. This review concludes with a perspective on future research directions, emphasizing the importance of improving material stability, interference resistance, standardized fabrication, and intelligent system integration for large-scale practical deployment. Full article

The demand for a “green” approach to the synthesis of nanomaterials is becoming increasingly pressing. In response to this need, we present, for the first time, the use of spark ablation as an environmentally friendly deposition technique to obtain nanoparticles of copper nitride, a material that is gaining increasing attention in the field of photovoltaic advanced technologies. This method involves the ablation of pure copper electrodes in nitrogen atmosphere while a spark current is tuned. The overall result is the co-presence of nitride and oxide nanoparticle agglomerates with different sizes according to the spark current, as confirmed by X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy and energy-dispersive spectroscopy techniques. Scanning probe microscopy and scanning electron microscopy show an increase in the number and size of nanoparticle agglomerates with an increasing current, while the nanoparticle size is always about sub-10 nm. The findings of this work promote spark ablation as a simple, versatile, cost-effective, environmentally friendly deposition method to obtain nitride-based nanoparticles. Furthermore, it is compatible with many types of materials and substrates, increasing the possible combinations of metals/semiconductors and carrier gas types to obtain completely innovative materials with unique compositions and properties. Full article

Photocatalytic hydrogen (H₂) production offers a promising solution to energy shortages and environmental challenges by converting solar energy into chemical energy. Hydrogen, as a versatile energy carrier, can be generated through photocatalysis under sunlight or via electrolysis powered by solar or wind energy. However, the advancement of photocatalysis is hindered by the limited availability of effective visible light-responsive semiconductors and the challenges of charge separation and transport. To address these issues, researchers are focusing on the development of novel nanostructured semiconductors and composite materials that can enhance photocatalytic performance. In this paper, we provide an overview of the advanced photocatalytic materials prepared so far that can be activated by sunlight, and their efficiency in H₂ production. One of the key strategies in this research area concerns improving the separation and transfer of electron–hole pairs generated by light, which can significantly boost H₂ production. Advanced hybrid materials, such as organic–inorganic hybrid composites consisting of a combination of polymers with metal oxide photocatalysts, and the creation of heterojunctions, are seen as effective methods to improve charge separation and interfacial interactions. The development of Schottky heterojunctions, Z-type heterojunctions, p–n heterojunctions from nanostructures, and the incorporation of nonmetallic atoms have proven to reduce photocorrosion and enhance photocatalytic efficiency. Despite these advancements, designing efficient semiconductor-based heterojunctions at the atomic scale remains a significant challenge for the realization of large-scale photocatalytic H₂ production. In this review, state-of-the-art advancements in photocatalytic hydrogen production are presented and discussed in detail, with a focus on photocatalytic nanostructures, heterojunctions and hybrid composites. Full article

The importance and challenges of ethylene detection based on combustion-type low-cost commercial sensors for agricultural and industrial applications are well-established. This work summarizes the significant progress in ethylene detection based on an innovative Gas Metal Oxide Semiconductor (GMOS) sensor and a new catalytic composition of metallic nanoparticles. The paper presents a study on ethylene and ethanol sensing using a miniature catalytic sensor fabricated by Complementary Metal Oxide Semiconductor–Silicon-on-Insulator–Micro-Electro-Mechanical System (CMOS-SOI-MEMS) technology. The GMOS performance with bimetallic palladium–platinum (Pd-Pt) and monometallic palladium (Pd) and platinum (Pt) catalysts is compared. The synergetic effect of the Pd-Pt catalyst is observed, which is expressed in the shift of combustion reaction ignition to lower catalyst temperatures as well as increased sensitivity compared to monometallic components. The optimal catalysts and their temperature regimes for low and high ethylene concentrations are chosen, resulting in lower power consumption by the sensor. Full article

Automated and robotic welding have become standard practices in manufacturing, requiring precise control to maintain weld quality without relying on skilled welders. In Tungsten Inert Gas (TIG) welding, monitoring the weld pool is crucial for ensuring the necessary weld penetration, which is vital for maintaining weld integrity. Real-time observation is essential to prevent defects and improve weld quality. Various sensing technologies have been developed to address this need, with vision-based systems showing particular effectiveness in enhancing welding quality and productivity within the framework of Industry 4.0. This review looks at the latest technologies for monitoring weld pools and bead shapes. It covers methods like using Complementary Metal-Oxide Semiconductors (CMOS) to take clear images of the melt pool for better process identification, Active Appearance Model (AAM) to capture 3D images of the weld pool for accurate penetration measurement, and Charge-Coupled Devices (CCD) and Laser-Induced Breakdown Spectroscopy (LIBS) to analyze plasma spectra and create material composition graphs. Full article

The refractive index is an important optical property of materials which can be used to understand the composition of materials. Therefore, refractive index sensing plays a vital role in biological diagnosis and therapy, material analysis, (bio)chemical sensing, and environmental monitoring. Conventional optical refractive index sensors based on optical fibers and ridge waveguides have relatively large sizes of a few millimeters, making them unsuitable for on-chip integration. Photonic crystals (PCs) have been used to significantly improve the compactness of refractive index sensors for on-chip integration. However, PC structures suffer from defect-introduced strong scattering, resulting in low transmittance, particularly at sharp bends. Valley photonic crystals (VPCs) can realize defect-immune unidirectional transmission of topological edge states, effectively reducing the scattering loss and increasing the transmittance. However, optical refractive index sensors based on VPC structures have not been demonstrated. This paper proposes a refractive index sensor based on a VPC Mach–Zehnder interferometer (MZI) structure with a high forward transmittance of 0.91 and a sensitivity of 1534%/RIU at the sensing wavelength of λ = 1533.97 nm within the index range from 1.0 to 2.0, which is higher than most demonstrated optical refractive index sensors in the field. The sensor has an ultracompact footprint of 9.26 μm × 7.99 μm. The design can be fabricated by complementary metal–oxide semiconductor (CMOS) fabrication technologies. Therefore, it will find broad applications in biology, material science, and medical science. Full article

Indium, widely used as indium-tin oxide (ITO), has been recognized as a strategical metal for audiovisual, optoelectronic systems, semiconductors and photovoltaic fields. An increasing shortage and unflexible mineral supply have led indium to be recovered from secondary sources, such as waste electrical and electronic equipment (WEEE). The main step for indium hydrometallurgical recovery from WEEE is the electrowinning process using sulfate baths, giving lower environmental impact and improved workplace safety conditions. In this investigation, a titanium cathode has been employed for the study of the indium electrowinning process in a sulfate-based bath. This study was focused on analyzing current efficiency (CE), specific energy consumption (SEC) and deposit morphology and structure as the temperature, current density, pH and electrolyte composition were varied. Prior to conducting electrowinning tests, a conventional three-electrode cell was used to perform cyclic voltametric assessments of the electrodeposition reactions on the Ti electrode at room temperature. The indium electrowinning tests on Ti cathodes presented CE values higher than 90%, with low energy consumption at low current densities, showing a negligible influence of additive agents in the bath, different from results obtained with other cathodes in other works. Moreover, the increase of the current density beyond 75 A/m² produced significant effects by etching the electrode surface with 1M HF. In particular, at the conclusion of this investigation, good results are obtained without additives, by etching the titanium cathode and operating at higher current density between 100 and 200 A/m² at pH 2.3 and different temperatures (40 °C and 60 °C). Finally, indium deposits were analyzed by XRD and SEM in order to determine the influence of operative conditions on the structure and surface morphology. Full article

The S-Scheme heterojunction design offers a promising pathway to enhance the photocatalytic activity of semiconductors for antibiotic degradation in aquatic environments. Graphitic carbon nitride (g-C₃N₄) stands out due to its robust visible light absorption, exceptional charge separation efficiency, and abundant active sites, rendering it an ideal candidate for sustainable and energy-efficient photocatalysis. This review delves into the potential of g-C₃N₄-based S-Scheme heterojunctions in antibiotic degradation, with a particular emphasis on the photocatalytic principles, inherent advantages, and application prospects. We discuss various semiconductor materials, including metal oxides, multicomponent metal oxides, magnetic oxides, multicomponent magnetic oxides, metal sulfides, and multicomponent metal sulfides, which can be paired with g-C₃N₄ to fabricate S-Scheme heterojunctions. Furthermore, we explore common preparation techniques for synthesizing g-C₃N₄-based S-Scheme heterojunction composites, such as the hydrothermal method, solvothermal method, calcination method, self-assembly method, in situ growth, etc. Additionally, we summarize the applications of these g-C₃N₄-based S-Scheme heterojunctions in the degradation of antibiotics, focusing specifically on quinolones and tetracyclines. By providing insights into the development of these heterojunctions, we actively contribute to the ongoing exploration of innovative technologies in the field of photocatalytic antibiotic degradation. Our findings underscore the vast potential of g-C₃N₄-based S-Scheme heterojunctions in addressing the challenge of antibiotic contamination in water sources. Full article

This paper presents a comprehensive investigation into the quantum efficiency (QE) of metallic photocathodes used in modern high-performance radio frequency (RF) and superconducting radio frequency (SRF) guns. The study specifically examines how laser cleaning treatment impacts the QE of these photocathodes, providing detailed insights into their performance and potential improvements for accelerator applications, and assesses the chemical and environmental factors affecting the surface composition of metallic laser-photocathodes used in modern high-performance radio frequency (RF) and superconducting radio frequency (SRF) electron guns. This paper overviews the photocathode rejuvenation effects of laser cleaning treatment. Laser cleaning removes the oxides and hydrides responsible for the deterioration of photocathodes, increases the photoelectron emission quantum efficiency (QE) and extends the operational lifetime of high-brightness electron injectors. QE enhancement is analyzed with the aim of parametric cleaning process optimization. This study excludes semiconductor and thermionic cathodes, focusing solely on the widely used bulk and thin-film photocathodes of Cu, Mg, Y, Pb and Nb. Laser cleaning enhancement of QE in Cu from 5 × 10⁻⁵ to 1.2 × 10⁻⁴, in Mg from 5.0 × 10⁻⁴ to 1.8 × 10⁻³, in Y from 10⁻⁵ to 3.3 × 10⁻⁴, in Pb from 3 × 10⁻⁵ to 8 × 10⁻⁵, and in Nb from 2.1 × 10⁻⁷ to 2.5 × 10⁻⁵ is demonstrated. The analysis concludes with a specialized practical guide for improving photocathode efficacy and lifetime in RF and SRF guns. Full article

The increasing rate of environmental pollution and the emergence of new infectious diseases have drawn much attention toward the area of gas sensors for air quality monitoring and early-stage disease diagnosis, respectively. Polyaniline (PANI) has become one of the extensively studied polymers in the area of chemical sensing due to its good conductivity and sensitivity at room temperature. The development of room-temperature gas sensors represents a significant leap forward in air quality monitoring by conserving energy and enhancing the feasibility of the commercial development of sensing technologies. New research shines a light on the advantages of using PANI with materials such as semiconductor metal chalcogenides, metal oxides, metal nanoparticles, and graphitic carbon materials to form composites that can sense chemicals selectively at room temperature. This review focuses on the advancements in PANI-based gas sensors, exploring the materials, mechanisms, and applications that make these sensors a promising solution for modern air quality monitoring challenges. By examining the latest research and innovations, we aim to highlight this critical technology’s potential and future directions, instilling hope and optimism in safeguarding public health and the environment. Full article

Mycotoxins are highly toxic secondary metabolites that can pose a serious threat to food safety, human health, and the environment. As a promising detoxification method, photocatalysis has shown great potential for mycotoxin degradation due to its high efficiency, low cost, and green advantages. Heterogeneous photocatalysis using a semiconductor as a mediator is now regarded as an effective approach for mycotoxin degradation. The aim of this study was to review the recent developments, mainly in the photocatalytic degradation of mycotoxin (e.g., AFB1, FB1, DON, and ZEN). The principle, feasibility, and main semiconducting catalysts of mycotoxin photodegradation are introduced and discussed, including metal oxides (transition, noble, and rare earth metals), carbons (graphene, carbon nitride, and biochar) and other composites (MOFs and LDHs). This review will contribute to the development of semiconductor photocatalysts and photocatalytic degradation for mycotoxins decontamination. Full article

Metal oxide semiconductor (MOS) hydrogen sensors offer advantages, such as high sensitivity and fast response, but their challenges remain in achieving low-cost fabrication and stable operation at room temperature. This study investigates Nb-doped TiO₂ (NTO) thin films prepared via a one-step micro-arc oxidation (MAO) with the addition of Nb₂O₅ nanoparticles into the electrolyte for room-temperature hydrogen sensing. The characterization results revealed that the incorporation of Nb₂O₅ altered the film’s morphology and phase composition, increasing the Nb content and forming a homogeneous composite thin film. Hydrogen sensing tests demonstrated that the NTO samples exhibited significantly improved sensitivity, selectivity, and stability compared to undoped TiO₂. Among the fabricated samples, NTO thin film prepared at Nb₂O₅ concentration of 6 g/L (NTO-6) showed the best performance, with a broad detection range, excellent sensitivity, rapid response, and good specificity to hydrogen. A strong linear relationship between response values and hydrogen concentration (10–1000 ppm) highlights its potential for precise hydrogen detection. The enhanced hydrogen sensing mechanism of NTO thin films primarily stems from the influence of Nb₂O₅; nanoparticles doping in the anatase-phase TiO₂ structure on the semiconductor surface depletion layer, as well as the improved charge transfer and additional adsorption sites provided by the Nb/Ti composite metal oxides, such as TiNb₂O₇ and Ti_0.95Nb_0.95O₄. This study demonstrates the potential of MAO-fabricated Nb-doped TiO₂ thin films as efficient and reliable hydrogen sensors operating at room temperature, offering a pathway for novel gas-sensing technologies to support clean energy applications. Full article

The increasing concentration of antibiotics in natural water poses a significant threat to society’s sustainable development due to water pollution. Photocatalytic technology is an efficient and environmentally friendly approach to environmental purification, offering great potential for addressing pollution and attracting significant attention from scholars worldwide. TiO₂, as a representative semiconductor photocatalytic material, exhibits strong oxidation ability and excellent biocompatibility. However, its wide band gap and the rapid recombination of photo-generated electron–hole pairs significantly limit its photocatalytic applications. Recent studies indicate that constructing heterojunctions with synergistic plasmonic effects is an effective strategy for developing high-performance photocatalysts. In this study, Bi metal nanoparticles and (BiO)₂CO₃ nanosheets were simultaneously grown on TiO₂ nanofibers via an in situ hydrothermal method, successfully forming a Bi@(BiO)₂CO₃/TiO₂ composite fiber photocatalyst with synergistic plasmonic effects. The surface plasmon resonance (SPR) effect of Bi nanoparticles combined with the (BiO)₂CO₃/TiO₂ heterojunction enhances sunlight absorption, facilitates efficient separation of photo-generated carriers, and significantly strengthens the photo-oxidation and reduction abilities. This system effectively generates abundant hydroxyl (·OH) and superoxide (·O²⁻) radicals under sunlight excitation. Consequently, Bi@(BiO)₂CO₃/TiO₂ exhibited outstanding photocatalytic performance. Under simulated sunlight for 60 min, the photodegradation efficiencies of the quinolone antibiotics lomefloxacin, ciprofloxacin, and norfloxacin reached 93.2%, 97.5%, and 100%, respectively. Bi@(BiO)₂CO₃/TiO₂ also demonstrates excellent stability and reusability. This study represents a significant step toward the application of TiO₂-based photocatalyst materials in environmental purification. Full article

To solve the energy crisis and environmental issues, it is essential to create effective and sustainable energy conversion and storage technologies. Traditional materials for energy conversion and storage however have several drawbacks, such as poor energy density and inadequate efficiency. The advantages of MOF-based materials, such as pristine MOFs, also known as porous coordination polymers, MOF composites, and their derivatives, over traditional materials, have been thoroughly investigated. These advantages stem from their high specific surface area, highly adjustable structure, and multifunctional nature. MOFs are promising porous materials for energy storage and conversion technologies, according to research on their many applications. Moreover, MOFs have served as sacrificial materials for the synthesis of different nanostructures for energy applications and as support substrates for metals, metal oxides, semiconductors, and complexes. One of the most intriguing characteristics of MOFs is their porosity, which permits space on the micro- and meso-scales, revealing and limiting their functions. The main goals of MOF research are to create high-porosity MOFs and develop more efficient activation techniques to preserve and access their pore space. This paper examines the porosity tunable mixed and hybrid MOF, pore architecture, physical and chemical properties of tunable MOF, pore conditions, market size of MOF, and the latest development of MOFs as precursors for the synthesis of different nanostructures and their potential uses. Full article