Search Results (419)

Heavy metal pollution from human activities is an increasing environmental concern. This study investigates the concentrations of Cu, Pb, Zn, Cd, Hg, and As in the coastal seawater offshore of Beihai, Guangxi, in April 2021, and explores their relationships with dissolved inorganic nitrogen, phosphate, and salinity. Our results reveal higher heavy metal concentrations in the northern nearshore waters and lower levels in southern offshore areas, with surface waters generally exhibiting greater enrichment than bottom waters. Surface concentrations show a decreasing trend from the northeast to the southwest, likely influenced by prevailing northeast monsoon winds. While bottom water concentrations decline from the northwest to the southeast, which indicates the influence of riverine runoff, particularly from the Qinzhou Bay estuary. Heavy metal levels in southern Beihai waters are comparable to those in the Beibu Gulf, except for Hg and Zn, which are significantly higher in the water of the Beibu Gulf. Notably, heavy metal concentrations in both Beihai and Beibu Gulf remain considerably lower than those observed in the coastal waters of Guangdong. Overall, Beihai’s coastal seawater meets China’s Class I quality standards. Nonetheless, continued monitoring is essential, especially of the potential ecological impacts of Hg and Zn on marine life. Full article

This study investigates the implications of sewage contamination in the coastal and riverine environments of Hout Bay, Cape Town, South Africa. Chemical analyses were applied to quantify the presence of pollutants such as pharmaceutical and personal care products (PPCPs) in sentinel marine organisms such as mussels, as well as microbial indicators of faecal contamination in river water and seawater, for estimating the extent of impact zones in the coastal environment of Hout Bay. This research investigated the persistent pharmaceuticals found in marine outfall wastewater effluent samples in Hout Bay, examining whether these substances were also detectable in marine biota, specifically focusing on Mytilus galloprovincialis mussels. The findings reveal significant levels of sewage-related pollutants in the sampled environments, with concentrations ranging from 32.74 to 43.02 ng/g dry weight (dw) for acetaminophen, up to 384.96 ng/g for bezafibrate, and as high as 338.56 ng/g for triclosan. These results highlight persistent PPCP contamination in marine organisms, with increasing concentrations observed over time, suggesting a rise in population and pharmaceutical use. Additionally, microbial analysis revealed high levels of E. coli in the Hout Bay River, particularly near stormwater from the Imizamo Yethu settlement, with counts exceeding 8.3 million cfu/100 mL. These findings underscore the significant impact of untreated sewage on the environment. This study concludes that current sewage treatment is insufficient to mitigate pollution, urging the implementation of more effective wastewater management practices and long-term monitoring of pharmaceutical levels in marine biota to protect both the environment and public health. Full article

7,12-Dimethylbenzo[a]anthracene (DMBA-7,12), a highly toxic and environmentally persistent polycyclic aromatic hydrocarbon (PAH), poses significant threats to marine biodiversity and human health due to its bioaccumulation through the food chain. Conventional chromatographic methods, while achieving comparable detection limits, are hindered by the need for expensive instrumentation and prolonged analysis times, rendering them unsuitable for rapid on-site monitoring of DMBA-7,12 in marine environments. Therefore, the development of novel, efficient detection techniques is imperative. In this study, we have successfully developed an electrochemical immunosensor based on a polydopamine (PDA)–chitosan (CTs) composite interface to overcome existing technical limitations. PDA provides a robust scaffold for antibody immobilization due to its strong adhesive properties, while CTs enhances signal amplification and biocompatibility. The synergistic integration of these materials combines the high efficiency of electrochemical detection with the specificity of antigen–antibody recognition, enabling precise qualitative and quantitative analysis of the target analyte through monitoring changes in the electrochemical properties at the electrode surface. By systematically optimizing key experimental parameters, including buffer pH, probe concentration, and antibody loading, we have constructed the first electrochemical immunosensor for detecting DMBA-7,12 in seawater. The sensor achieved a detection limit as low as 0.42 ng/mL. In spiked seawater samples, the recovery rates ranged from 95.53% to 99.44%, with relative standard deviations (RSDs) ≤ 4.6%, demonstrating excellent accuracy and reliability. This innovative approach offers a cost-effective and efficient solution for the in situ rapid monitoring of trace carcinogens in marine environments, potentially advancing the field of marine pollutant detection technologies. Full article

Leveraging the sensitivity of long-period fiber grating (LPFG) to changes in the environmental refractive index, an LPFG-based seawater concentration monitoring sensor is proposed. Considering the highly saltine and alkali characteristics of the sensor’s operating environment, the proposed sensor is packaged by basalt fiber-reinforced polymer (BFRP), and the sensor’s sensitivities were studied by sodium chloride and calcium chloride solution concentration experiments and one real-time sodium chloride solution concentration monitoring experiment. The test results show the wavelength of LPFG, a 3 dB bandwidth and a peak loss of LPFG’s spectrogram change with changes in the concentration of sodium chloride or calcium chloride solutions, but only the wavelength has a good linear relationship with the change in solution concentration, and the sensing coefficient is −0.160 nm/% in the sodium chloride solution and −0.225 nm/% in the calcium chloride solution. The real-time monitoring test further verified the sensor’s sensing performance, with an absolute measurement error of less than 1.8%. The BFRP packaged sensor has good corrosion resistance and a simple structure, and it has a certain application value in the monitoring of salinity in the marine environment and coastal soil. Full article

Deep learning models have obvious advantages in detecting oil spills, but the training of deep learning models heavily depends on a large number of samples of high quality. However, due to the accidental nature, unpredictability, and urgency of oil spill incidents, it is difficult to obtain a large number of labeled samples in real oil spill monitoring scenarios. Surprisingly, few-shot learning can achieve excellent classification performance with only a small number of labeled samples. In this context, a new cross-domain few-shot SAR oil spill detection network is proposed in this paper. Significantly, the network is embedded with a hybrid attention feature extraction block, which consists of a coordinate attention module to perceive the channel information and spatial location information, as well as a global self-attention transformer module capturing the global dependencies and a multi-scale self-attention module depicting the local detailed features, thereby achieving deep mining and accurate characterization of image features. In addition, to address the problem that it is difficult to distinguish between the suspected oil film in seawater and real oil film using few-shot due to the small difference in features, this paper proposes a double loss function category determination block, which consists of two parts: a well-designed category-perception loss function and a traditional cross-entropy loss function. The category-perception loss function optimizes the spatial distribution of sample features by shortening the distance between similar samples while expanding the distance between different samples. By combining the category-perception loss function with the cross-entropy loss function, the network’s performance in discriminating between real and suspected oil films is thus maximized. The experimental results effectively demonstrate that this study provides an effective solution for high-precision oil spill detection under few-shot conditions, which is conducive to the rapid identification of oil spill accidents. Full article

Excessive levels of Pb²⁺ and Cd²⁺ in seawater pose significant combined toxicity to marine organisms, resulting in harmful effects and further threatening human health through biomagnification in the food chain. Traditional methods for detecting marine Pb²⁺ and Cd²⁺ rely on laboratory analyses, which are hindered by limitations such as sample degradation during transport and complex operational procedures. In this study, we present an electrochemical sensor based on intelligent mobile detection devices. By combining G-COOH-MWCNTs/ZnO with differential pulse voltammetry, the sensor enables the efficient, simultaneous detection of Pb²⁺ and Cd²⁺ in seawater. The G-COOH-MWCNTs/ZnO composite film is prepared via drop-coating and is applied to a glassy carbon electrode. The film is characterized using cyclic voltammetry, electrochemical impedance spectroscopy, and scanning electron microscopy, while Pb²⁺ and Cd²⁺ are quantified using differential pulse voltammetry. Using a 0.1 mol/L sodium acetate buffer (pH 5.5), a deposition potential of −1.1 V, and an accumulation time of 300 s, a strong linear correlation was observed between the peak response currents of Pb²⁺ and Cd²⁺ and their concentrations in the range of 25–450 µg/L. The detection limits were 0.535 µg/L for Pb²⁺ and 0.354 µg/L for Cd²⁺. The sensor was applied for the analysis of seawater samples from Maowei Sea, achieving recovery rates for Pb²⁺ ranging from 97.7% to 103%, and for Cd²⁺ from 97% to 106.1%. These results demonstrate that the sensor exhibits high sensitivity and stability, offering a reliable solution for the on-site monitoring of heavy metal contamination in marine environments. Full article

The coastal zone presents complex hydrodynamic interactions among inland groundwater, reservoir water, and intruding seawater, with important implications for ecosystem functioning and water quality. However, the relative roles of hydraulic connectivity and seawater-driven salinity gradients in shaping microbial communities at the aquifer–reservoir interface remain unclear. Here, we integrated hydrochemical analyses with high-throughput 16S rRNA gene sequencing to investigate bacterial community composition, assembly processes, and co-occurrence network patterns across groundwater_in (entering the reservoir), groundwater_out (exiting the reservoir), and reservoir water in a coastal system. Our findings reveal that seawater intrusion exerts a stronger influence on groundwater_out, leading to distinct chemical profiles and salinity-driven environmental filtering, whereas hydraulic connectivity promotes greater microbial similarity between groundwater_in and reservoir water. Groundwater samples exhibited higher alpha and beta diversity compared to the reservoir, with dominant taxa such as Comamonadaceae, Flavobacteriaceae, and Rhodobacteraceae serving as indicators of seawater intrusion. Community assembly analyses showed that homogeneous selection predominated, especially under strong salinity gradients, while dispersal limitation and spatial distance also contributed in areas of reduced connectivity. Key chemical factors, including TDS, Na⁺, Cl⁻, Mg²⁺, and K⁺, strongly shaped groundwater communities. Additionally, groundwater bacterial networks were more complex and robust than those in reservoir water, suggesting enhanced resilience to salinity stress. Collectively, this study demonstrates that salinity gradients can override the effects of hydraulic connectivity in structuring bacterial communities and their networks at coastal interfaces. Our findings provide novel microbial insights relevant for understanding biogeochemical processes and support the use of microbial indicators for more sensitive monitoring and management of coastal groundwater resources. Full article

The energy consumption of current vertical-lifting underwater monitoring devices mainly falls into two categories: one fully supplied by battery packs; and the other partially by battery packs, with the rest from ocean thermal energy. Constrained by battery capacity, their operation time is limited, making long-term remote operations difficult. This study focuses on a device powered entirely by ocean thermal energy, which realizes the absorption and storage of energy through a phase change heat-exchange system, significantly extending its operation cycle and working area. A composite phase change material of n-hexadecane and graphite with a volume ratio of 9:1 is used. The Fluent software 2022 R1, based on the enthalpy-porosity method, simulates the phase change process of the device to analyze the effects of different structures and seawater temperatures. Results show that with the same phase change material volume and inner diameter of the cylindrical heat exchanger, a smaller outer diameter yields better phase change performance. Lower seawater temperature facilitates solidification. Due to natural convection in the liquid phase, the melting time is 520 s and solidification time is 4800 s, with the melting rate far exceeding the solidification rate. Full article

This study investigates the salinization processes affecting the coastal aquifer within the Torre Guaceto State Nature Reserve, a Mediterranean coastal area characterized by a unique ecological value of a brackish wetland threatened by water-intensive agricultural activities. Groundwater salinization threatens biodiversity, agriculture, and water resource sustainability. This work integrates hydrogeological monitoring, geochemical and isotopic analyses, and geophysical surveys to understand salinity dynamics and identify key drivers, such as seawater intrusion, irrigation practices, and climate change. Data collected during monitoring campaigns from 2022 to 2024 reveal significant seasonal and spatial variations in groundwater salinity influenced by natural and human-induced factors. The results indicate that salt recycling from irrigation and marine spray deposition are important local contributors to groundwater salinity, in addition to seawater intrusion. These findings highlight the urgent need for integrated groundwater management approaches considering the combined effects of agricultural practices, irrigation water quality, and climate variability tailored to Mediterranean coastal ecosystems. Full article

Hydrogel sensors show unique advantages in underwater detection, ocean monitoring, and human–computer interaction because of their excellent flexibility, biocompatibility, high sensitivity, and environmental adaptability. However, due to the water environment, hydrogels will dissolve to a certain extent, resulting in insufficient mechanical strength, poor long-term stability, and signal interference. In this paper, a double-network structure was constructed by polyvinyl alcohol (PVA) and poly([2-(methacryloyloxy) ethyl]7 dimethyl-(3-sulfopropyl) ammonium hydroxide) (PSBMA). The resultant PVA/PSBMA-PA hydrogel demonstrated notable swelling resistance, a property attributable to the incorporation of non-covalent interactions (electrostatic interactions and hydrogen bonding) through the addition of phytic acid (PA). The hydrogel exhibited high stretchability (maximum tensile strength up to 304 kPa), high conductivity (5.8 mS/cm), and anti-swelling (only 1.8% swelling occurred after 14 days of immersion in artificial seawater). Assembled as a sensor, it exhibited high strain sensitivity (0.77), a low detection limit (1%), and stable electrical properties after multiple tensile cycles. The utilization of PVA/PSBMA-PA hydrogel as a wearable sensor shows promise for detecting human joint movements, including those of the fingers, wrists, elbows, and knees. Due to the excellent resistance to swelling, the PVA/PSBMA-PA-based sensors are also suitable for underwater applications, enabling the detection of underwater mannequin motion. This study proposes an uncomplicated and pragmatic methodology for producing hydrogel sensors suitable for use within subaquatic environments, thereby concomitantly broadening the scope of applications for wearable electronic devices. Full article

This study addresses the microbial corrosion of cement-based materials in coastal urban sewer networks, systematically investigating the kinetic mechanisms of sulfur biogeochemical cycling under seawater infiltration conditions. Through dynamic monitoring of sulfide concentrations and environmental parameter variations in anaerobic pipelines, a multiphase coupled kinetic model integrating liquid-phase, gas-phase, and biofilm metabolic processes was developed. The results demonstrate that moderate salinity enhances the activity of sulfate-reducing bacteria (SRB) and accelerates sulfate reduction rates, whereas excessive sulfide accumulation inhibits SRB activity. At 35 °C, the mathematical model coefficient “a” for sulfate reduction in the reactor with 3 g/L salinity was significantly higher than those in reactors with 19 g/L and 35 g/L salinities, with no significant difference observed between the latter two. Overall, high sulfate concentrations do not act as limiting factors for sulfide oxidation under anaerobic conditions; instead, they enhance the reaction within specific concentration ranges. The refined kinetic model enables prediction of sulfur speciation in tropical coastal urban sewer pipelines, providing a scientific basis for corrosion risk assessment. Full article

Seawater desalination is considered the first option to meet the domestic and industrial requirements of freshwater in desert areas, such as the Atacama Desert (Chile). However, its environmental implications remain poorly characterized. This study evaluated the effects of brine discharge from a desalination plant located in Caldera Bay, where fishing and tourism coexist. Sampling was conducted at increasing distances from the outfall to assess physicochemical parameters, sediment metal content, and nutrient concentrations. The results revealed a clear spatial gradient: salinity decreased from 57.75 to 34.87 PSU and nitrate from 10.49 to 4.05 µM. The sediment samples near the outfall showed elevated concentrations of Al, Fe, and Cr(VI). These findings suggest that brine discharge alters water chemistry and sediment quality. This study highlights the need for long-term environmental monitoring and regulatory frameworks to ensure sustainable desalination in sensitive coastal systems. Full article

Composite materials have the advantages of high strength and low weight, and are therefore used in many areas. However, in humid and marine environments, mechanical properties may deteriorate due to moisture diffusion, especially in glass fiber reinforced polymers (GFRP) and carbon fiber reinforced polymers (CFRP). This study investigated the damage formation and changes in mechanical properties of single-layer adhesive-bonded GFRP and CFRP connections under the effect of sea water. In the experiment, 0/90 orientation, twill-woven GFRP (7 ply) and CFRP (8 ply) plates were produced as prepreg using the hand lay-up method in accordance with ASTM D5868-01 standard. CNC Router was used to cut 36 samples were cut from the plates produced for the experiments. The samples were kept in sea water taken from the Aegean Sea, at 3.3–3.7% salinity and 23.5 °C temperature, for 1, 2, 3, 6, and 15 months. Moisture absorption was monitored by periodic weighings; then, the connections were subjected to three-point bending tests according to the ASTM D790 standard. The damages were analyzed microscopically with SEM (ZEISS GEMINI SEM 560). As a result of 15 months of seawater storage, moisture absorption reached 4.83% in GFRP and 0.96% in CFRP. According to the three-point bending tests, the Young modulus of GFRP connections decreased by 25.23% compared to dry samples; this decrease was 11.13% in CFRP. Moisture diffusion and retention behavior were analyzed according to Fick’s laws, and the moisture transfer mechanism of single-lap adhesively bonded composites under the effect of seawater was evaluated. Full article

Seawater transparency provides critical insight into marine ecological dynamics and serves as a foundational indicator for fisheries management, environmental monitoring, and coastal resource development. Among various indicators, the Secchi disk depth (SDD) is widely used to quantify seawater transparency in marine environmental monitoring. This study develops a remote sensing inversion model for estimating the SDD in the coastal waters of Qinhuangdao, utilizing Sentinel-3 OLCI satellite imagery and in situ measurements. The model is based on the CIE hue angle and demonstrates high accuracy (R² = 0.93, MAPE = 7.88%, RMSE = 0.25 m), outperforming traditional single-band, band-ratio, and multi-band approaches. Using the proposed model, we analyzed the monthly and interannual variations of SDD in Qinhuangdao’s coastal waters from 2018 to 2024. The results reveal a clear seasonal pattern, with SDD values generally increasing and then decreasing throughout the year, primarily driven by the East Asian monsoon and other natural factors. Notably, the average annual SDD in 2018 was significantly lower than in subsequent years (2019–2024), which is closely associated with comprehensive water management and pollution reduction initiatives in the Bohai Sea region. These findings highlight marked improvements in the coastal marine environment and underscore the benefits of China’s ecological civilization strategy, particularly the principle that “lucid waters and lush mountains are invaluable assets.” Full article

In China’s coastal regions, severe seawater eutrophication has led to frequent occurrences of red tides, causing significant damage to marine fisheries and aquatic resources. Therefore, red tide detection and prediction are of great research importance. Although current deep learning-based red tide detection methods perform well in detecting single-day red tides, they struggle with continuous multi-day detection due to insufficient mining of temporal features and difficulties in accurately capturing dynamic variations, limiting further improvements in detection accuracy. To address these issues, this study proposes a time-series fusion network model (CSF-RTDNet) for red tide detection using time-continuous GOCI data from the East China Sea. By integrating multi-temporal GOCI data, the model comprehensively captures spatiotemporal characteristics of red tides, enhancing dynamic process modeling. The CSF-RTDNet method improves feature discrimination by introducing NDVI to enhance red tide characteristics and increase separability between red tides and seawater. Additionally, an ECA channel attention mechanism is employed to fully exploit spectral features across different bands for deeper feature extraction. A novel feature extraction module, ASPC-DSC, combines atrous spatial pyramid convolution with depthwise separable convolution to effectively fuse multi-scale contextual features while improving computational efficiency. Furthermore, ConvLSTM is introduced to integrate temporal and spatial features, effectively addressing the insufficient mining of sequential characteristics in multi-day red tide detection. Experimental results demonstrate that CSF-RTDNet achieves robust detection of red tides with complex boundaries and continuous temporal patterns, attaining an accuracy of 95.89%, precision of 93.03%, recall of 96.34%, and a Kappa coefficient of 0.95. This method significantly enhances red tide detection accuracy and provides valuable technical support for marine environmental monitoring. Full article