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Keywords = sandstone-hosted uranium deposit

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25 pages, 22082 KB  
Article
The Formation Mechanism of Chlorite and Its Constraints on Uranium Mineralization: A Case Study from the Pengyang Sandstone-Hosted Uranium Deposit in the Southwestern Ordos Basin, North China
by Haoze Yang, Jin-Cheng Luo, Guifeng Yang, Yan Liang, Youwei Chen, Qing Lan, Qiang Zhu and Bo Zhang
Minerals 2026, 16(6), 633; https://doi.org/10.3390/min16060633 (registering DOI) - 14 Jun 2026
Abstract
The discovery of a super-large sandstone-hosted uranium ore field in the eolian sandstones of the Pengyang area (Ordos Basin, North China) represents a major breakthrough, yet the relationship between chlorite alteration and uranium mineralization in this deposit type remains unclear. This study conducted [...] Read more.
The discovery of a super-large sandstone-hosted uranium ore field in the eolian sandstones of the Pengyang area (Ordos Basin, North China) represents a major breakthrough, yet the relationship between chlorite alteration and uranium mineralization in this deposit type remains unclear. This study conducted detailed mineralogical and geochemical analyses of chlorite using SEM, TEM, and EPMA. Five distinct types of chlorite were identified from mineralized and non-mineralized sandstones from the Luohe Formation in the Pengyang area from the southwestern Ordos Basin. This study addresses the formation temperatures, material sources, and possible formation mechanisms of those chlorites. The chlorites closely associated with uranium minerals formed at temperatures ranging from 130 to 170 °C, which represent the true formation temperature of the uranium minerals in the Pengyang uranium deposit. Comparing chlorite from uranium deposits related to granitic and volcanic rocks hosted uranium deposits in South China and sandstone-hosted uranium deposits in northern Ordos, North China, it is revealed that the chlorites from the eolian sandstone depositional area of the Pengyang experienced multiple episodes of fluid alteration. In addition, the chlorites closely related to uranium mineralization were formed by relatively low-temperature and oxidizing fluids, which may indicate that the uranium-bearing oxidative fluids in this region were primarily derived from interlayer infiltration. Full article
(This article belongs to the Special Issue Genesis of Uranium Deposit: Geology, Geochemistry, and Geochronology)
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34 pages, 11347 KB  
Review
Core Spectral Technology in Sandstone-Type Uranium Deposits of Basins in Northern China: Applications and Challenges—A Review
by Wenyi Wu, Mingsen Fan, Pei Ni, Junyi Pan, Yihan Lin, Zhe Chi and Junying Ding
Minerals 2026, 16(5), 471; https://doi.org/10.3390/min16050471 - 30 Apr 2026
Viewed by 509
Abstract
Sandstone-type uranium deposits represent one of the most significant uranium deposit types in China, predominantly hosted in Meso-Cenozoic sedimentary basins in the northern part of the country. Due to characteristics such as deep burial of orebodies, fine grain size of ores, and strong [...] Read more.
Sandstone-type uranium deposits represent one of the most significant uranium deposit types in China, predominantly hosted in Meso-Cenozoic sedimentary basins in the northern part of the country. Due to characteristics such as deep burial of orebodies, fine grain size of ores, and strong heterogeneity, traditional geological logging methods have limitations in rapidly and accurately identifying alteration minerals and mineralization indicator information. Core spectral technology (wavelength range approximately 400–2500 nm), particularly short-wave infrared spectroscopy (SWIR, 1300–2500 nm), enables rapid, non-destructive, and quantitative extraction of alteration mineral information from drill cores. This provides robust technical support for reconstructing metallogenic environments, delineating oxidation–reduction zones, and prospecting and prediction in sandstone-type uranium deposits. This review systematically examines the spectral absorption characteristics and geological significance of key alteration minerals (e.g., clay minerals, carbonate minerals, iron oxides, and hydrocarbon substances) in sandstone-type uranium deposits. It elaborates on the current application status of core spectral technology in sandstone-type uranium exploration within typical basins in northern China, such as the Ordos, Songliao, Erlian, and Qaidam Basins. These applications include alteration mineral mapping, oxidation–reduction zone delineation, and metallogenic fluid tracing. Due to the unique characteristics of host rock lithology, alteration mineral assemblages, and fluid properties in sandstone-type uranium deposits, the application of this technology also faces certain challenges, such as difficulties in spectral interpretation and insufficient accuracy in quantitative inversion. Integrating this technique with multiple methods, including petrography and X-ray diffraction (XRD), will facilitate more effective applications in both metallogenic research and prospecting practices for sandstone-type uranium deposits in northern China. Full article
(This article belongs to the Special Issue Critical Metal Minerals, 2nd Edition)
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22 pages, 11013 KB  
Article
Mineralogical and Geochemical Characteristics of the Lower Xishanyao Formation in the Mengqiguer Uranium Deposit, Yili Basin, NW China
by Gui Wang, Hu-Jun Zhang, Hao-Hao Zhang and Yang-Quan Jiao
Minerals 2026, 16(5), 448; https://doi.org/10.3390/min16050448 - 25 Apr 2026
Viewed by 389
Abstract
The interlayer oxidation zone-type Mengqiguer uranium deposit in the southern Yili Basin is a typical sandstone-hosted uranium deposit in northwest China, and the lower member of the Jurassic Xishanyao Formation is its main ore-hosting stratum. However, mineralogical and geochemical responses to redox evolution [...] Read more.
The interlayer oxidation zone-type Mengqiguer uranium deposit in the southern Yili Basin is a typical sandstone-hosted uranium deposit in northwest China, and the lower member of the Jurassic Xishanyao Formation is its main ore-hosting stratum. However, mineralogical and geochemical responses to redox evolution in the deposit have not been systematically constrained. In this study, we carried out detailed petrographic observation, X-ray diffraction analysis, electron probe microanalysis, and whole-rock geochemical analyses on samples from the interlayer oxidation zone in the lower member of the Xishanyao Formation. Kaolinite and illite are the dominant clay minerals in the deposit, with higher contents in oxidation zones than in transition and unaltered zones, while the illite–smectite mixed-layer content shows the opposite trend. The main uranium minerals are uranium oxides and coffinite. U, S and organic carbon are enriched in the transition zone, while the Fe3+/Fe2+ ratio increases with the oxidation degree. Comprehensive analysis on clay minerals shows that the ore-forming fluids evolved from acidic oxidized meteoric fluids to weakly alkaline reduced fluids; the uranium was mainly derived from the leaching of uraniferous sandstone. The formation of the deposit is controlled by sedimentary facies, tectonic uplift, organic–inorganic fluid interaction and redox reaction. This study provides detailed mineralogical and geochemical evidence for the metallogenic mechanism of interlayer oxidation zone-type uranium deposits, and has important guiding significance for uranium prospecting in the Yili Basin. Full article
(This article belongs to the Special Issue Genesis of Uranium Deposit: Geology, Geochemistry, and Geochronology)
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24 pages, 5741 KB  
Article
Geochemistry and Sulfur Isotopes of Chalcopyrite in the Yuejin II Sandstone-Hosted Uranium Deposit, Qaidam Basin: Implications for Ore-Forming Fluid Sources and Processes
by Yi-Han Lin, Ming-Sen Fan, Pei Ni, Jun-Yi Pan, Jun-Ying Ding, Wen-Yi Wu, Chen Zhang, Zhe Chi, Bin Guo and Yi-Fan Gao
Minerals 2026, 16(5), 446; https://doi.org/10.3390/min16050446 - 24 Apr 2026
Viewed by 306
Abstract
Sandstone-hosted uranium deposits in the western Qaidam Basin are spatially associated with hydrocarbon-bearing structures, yet the specific roles of different sulfur sources in uranium mineralization remain poorly constrained. This study aims to distinguish the contributions of bacterial sulfate reduction and hydrocarbon-associated sulfate reduction [...] Read more.
Sandstone-hosted uranium deposits in the western Qaidam Basin are spatially associated with hydrocarbon-bearing structures, yet the specific roles of different sulfur sources in uranium mineralization remain poorly constrained. This study aims to distinguish the contributions of bacterial sulfate reduction and hydrocarbon-associated sulfate reduction to uranium precipitation by integrating detailed petrography, in situ trace element analyses, and sulfur isotope measurements of chalcopyrite from the Yuejin II deposit. Chalcopyrite is restricted to high-grade uranium ores and occurs intergrown with uranium minerals, pyrite, baryte, and carbonate cements. Trace element patterns indicate that oxidizing brines acted as the main transport medium for both uranium and copper, as evidenced by positive correlations between U and brine-related elements (Ba, Sr, Na, K). Positive U-Th correlations with relatively constant Th/U ratios (0.027–0.225) reflect a combination of source composition, fluid transport capacity, and limited thorium remobilization in this near-source, hydrocarbon-rich environment. Correlations between U and high field strength elements (Sn, W) point to a highly evolved granitic origin, with Altyn granitoids likely supplying the copper. Sulfur isotopes show a clear bimodal distribution: one group exhibits heavy δ34S values (+6.9‰ to +18.5‰), while the other shows extremely light values (–36.0‰ to –44.6‰). The light group reflects bacterial sulfate reduction in shallow strata, supported by framboidal pyrite textures, whereas the heavy group corresponds to surface-derived sulfate reduced at hydrocarbon-associated redox fronts, rather than direct incorporation of deep H2S. The lack of intermediate δ34S values indicates that two discrete sulfur reduction mechanisms coexisted within the same deposit, refining genetic models for uranium mineralization in petroliferous basins and challenging frameworks that invoke a single dominant sulfur source. Full article
(This article belongs to the Special Issue Critical Metal Minerals, 2nd Edition)
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17 pages, 772 KB  
Article
Assessment of Rare Earth Elements Fractionation in Sandstone and Magmatic Uranium Ores: Implications for Deposit Typing
by Zhiger Kenzhetaev, Bolatbek Toksanbayev, Kuanysh Togizov, Kudaibergen Zhapabayev, Bagdara Mukatay, Madina Kurmangazhina and Karina Svetlakova
Minerals 2026, 16(4), 362; https://doi.org/10.3390/min16040362 - 30 Mar 2026
Cited by 1 | Viewed by 596
Abstract
This paper presents a comparative determination of rare earth elements (REEs) in sandstone-type uranium ore samples from Kazakhstan using a proposed rapid ICP-MS method following microwave digestion in a MARS 6 system with a mixed acid solution of HNO3, HCl, and [...] Read more.
This paper presents a comparative determination of rare earth elements (REEs) in sandstone-type uranium ore samples from Kazakhstan using a proposed rapid ICP-MS method following microwave digestion in a MARS 6 system with a mixed acid solution of HNO3, HCl, and HF. To validate the rapid REE determination method, comparative measurements were performed using a certified uranium ore reference material provided by Ore Research & Exploration, representing sandstone-hosted uranium mineralization from a Tanzanian deposit (OREAS 120). Fractionation patterns of chondrite-normalized REEs in uranium ores from Kazakhstan were evaluated. Comparative data on REE distribution in sandstone- and magmatic-type uranium deposits from Australia and Tanzania are presented. Uranium ores of magmatic- and sandstone-hosted types exhibit distinct REE distribution patterns, reflecting differences in the nature of ore-forming processes. This study provides chondrite-normalized REE distribution profiles for major uranium deposit types from three countries, which are subsequently used to assess uranium ore paragenesis through simple linear regression analysis. This study is intended as an applied comparative synthesis of REE fractionation patterns in genetically contrasting uranium deposits, with particular relevance to deposit classification. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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23 pages, 12467 KB  
Article
Key Ore-Controlling Factors and Genetic Model of the Tamusu Super-Large Sandstone-Type Uranium Deposit, Bayingobi Basin
by Chao Lu, Zhongyue Zhang, Yangquan Jiao, Zhao Li, Xiaoyi Yuwen, Yinan Zhuang, Chengyuan Jin, Chengcheng Zhang, Weihui Zhong and Qilin Wang
Minerals 2026, 16(4), 357; https://doi.org/10.3390/min16040357 - 27 Mar 2026
Viewed by 574
Abstract
Tamusu, the only identified super-large sandstone-hosted uranium deposit in the Bayingobi Basin, provides an important natural laboratory for evaluating ore-controlling factors and genetic models of sandstone-type uranium mineralization. Based on core descriptions from more than 200 boreholes, log facies analysis and geochemical environmental [...] Read more.
Tamusu, the only identified super-large sandstone-hosted uranium deposit in the Bayingobi Basin, provides an important natural laboratory for evaluating ore-controlling factors and genetic models of sandstone-type uranium mineralization. Based on core descriptions from more than 200 boreholes, log facies analysis and geochemical environmental proxies, this study constrains the sedimentary–mineralization architecture and key controlling factors of the deposit. Uranium orebodies are mainly hosted in the upper member of the Lower Cretaceous Bayingobi Formation (Sq2) within a gravity flow-dominated fan-delta–lacustrine system. Braided distributary channel sands on the fan-delta plain and subaqueous distributary channel sands on the delta front constitute the principal uranium reservoirs, controlling both the migration pathways and storage space for U-bearing fluids. Mineralization is jointly governed by fan-delta architecture, interlayer oxidation zonation and reducing agents. The interlayer oxidation zone displays a north-thick–south-thin geometry, and uranium orebodies are concentrated at redox transition positions, with grades of 0.01–0.33 wt%. The metallogenic evolution can be summarized in three stages: syndepositional uranium pre-enrichment, interlayer oxidation mineralization, and a late hydrothermal/diagenetic overprint that mainly modified reservoir properties, favored ore preservation, and did not contribute to the primary uranium budget. Accordingly, a genetic model of “fan-delta architecture + interlayer oxidation control + late overprint and preservation” is proposed to guide exploration in the Bayingobi Basin and analogous sandstone-type uranium systems. Full article
(This article belongs to the Special Issue Genesis of Uranium Deposit: Geology, Geochemistry, and Geochronology)
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17 pages, 11160 KB  
Article
Mineralogical Characteristics and Leaching Behavior of Sandstone-Hosted Uranium Ore: Implications for In Situ Recovery in the Zhenyuan Deposit, SW Ordos Basin, China
by Chunru Hou, Shihai Chen, Ying Zhang, Zhengbang Liu, Xiansheng Xie, Jinxun Deng, Yuhan Zou and Wensheng Liao
Minerals 2026, 16(4), 340; https://doi.org/10.3390/min16040340 - 24 Mar 2026
Viewed by 508
Abstract
The mineralogical composition, textural characteristics, and uranium occurrence of sandstone-hosted uranium ores significantly influence the leaching performance during in situ recovery. This study investigates ore samples from the Zhenyuan uranium deposit, China, utilizing SEM, EPMA, XRD, and XRF to characterize their texture and [...] Read more.
The mineralogical composition, textural characteristics, and uranium occurrence of sandstone-hosted uranium ores significantly influence the leaching performance during in situ recovery. This study investigates ore samples from the Zhenyuan uranium deposit, China, utilizing SEM, EPMA, XRD, and XRF to characterize their texture and mineralogy. Combined with thin-section leaching tests, batch stirring experiments, and pressurized column leaching experiments, the leaching behavior of pitchblende, associated gangue minerals, and the whole rocks were evaluated. The results indicate that: Uranium mainly occurs as nano-spherical and film-like pitchblende distributed along the edges of detrital grains and Ti-oxides. Minor uranium is incorporated into Ti-oxides and dolomite lattices via isomorphic substitution or adsorbed by chlorite. Under CO2 + O2 leaching conditions, pitchblende was almost completely dissolved, while U-bearing Ti-oxides experienced slight corrosion. Dolomite underwent partial dissolution, providing bicarbonate ions and improving rock permeability. Pyrite dissolution was limited during the early stage of leaching. The high dolomite content, low clay abundance, favorable pore structure, and easily leachable pitchblende suggest that the Zhenyuan deposit is well suited for CO2 + O2 in situ recovery. Increasing CO2 pressure is recommended to enhance dolomite dissolution and improve uranium recovery efficiency. Full article
(This article belongs to the Section Mineral Processing and Extractive Metallurgy)
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21 pages, 23634 KB  
Review
The Role of OM in the Formation of Sandstone-Type Uranium Ore—A Review
by Zhiyang Nie, Shefeng Gu, Aihong Zhou, Changqi Guo, Hu Peng, Hongyu Wang, Lei Li, Qilin Wang, Yan Hao, Haozhan Liu and Chao Liu
Minerals 2025, 15(12), 1326; https://doi.org/10.3390/min15121326 - 18 Dec 2025
Cited by 1 | Viewed by 1123
Abstract
Sandstone-hosted uranium deposits represent one of the most critical global uranium resources suitable for in situ recovery, with their formation closely associated with organic matter (OM). We conducted a systematic literature review to synthesize over 100 published studies sourced from authoritative databases (Elsevier, [...] Read more.
Sandstone-hosted uranium deposits represent one of the most critical global uranium resources suitable for in situ recovery, with their formation closely associated with organic matter (OM). We conducted a systematic literature review to synthesize over 100 published studies sourced from authoritative databases (Elsevier, Google Scholar, Web of Science, Scopus, CNKI, etc.). This study systematically summarizes the types and geological characteristics of OM in sandstone reservoirs and thoroughly analyzes the geochemical mechanisms by which OM regulates the transport and precipitation of aqueous uranium. By integrating case studies of representative sandstone uranium deposits globally, three major OM-related metallogenic models are proposed with distinct core characteristics: the humic-dominated model is driven by the complexation and direct reduction of uranium by humic substances/coal-derived OM; the roll-front model relies on reactions between oxidized uranium-bearing fluids and scattered OM, as well as microbially generated sulfides at the migration front; and the seepage-related model is fueled by upward-migrating deep hydrocarbon fluids (petroleum, methane) that act as both uranium carriers and reductants. Furthermore, this review explores the spatial coupling relationships between OM distribution and uranium mineralization in typical geological settings, evaluates the guiding significance of OM for uranium exploration, and outlines key unresolved scientific issues. The findings refine the genetic theoretical framework of sandstone-hosted uranium deposits and provide important technical support and theoretical guidance for future uranium exploration deployment and resource potential evaluation. Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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20 pages, 5056 KB  
Article
Prediction of Sandstone-Type Uranium Deposits Based on Data from Oilfield Drilling and Its Mineralization Regularity: A Case Study of Jingchuan Uranium Deposit, SW Ordos Basin
by Bo Zhang, Yinhang Cheng, Keyan Xiao, Rengan Yu, Yin Chen, Qiang Zhu and Sibo Wen
Appl. Sci. 2025, 15(20), 11268; https://doi.org/10.3390/app152011268 - 21 Oct 2025
Cited by 2 | Viewed by 1334
Abstract
A large-scale sandstone-type uranium deposit, recently discovered within the petroleum field of the Jingchuan area on the southwestern margin of the Ordos Basin, exemplifies a classic case of uranium exploration success achieved through the analysis of petroleum geological data including borehole logs. By [...] Read more.
A large-scale sandstone-type uranium deposit, recently discovered within the petroleum field of the Jingchuan area on the southwestern margin of the Ordos Basin, exemplifies a classic case of uranium exploration success achieved through the analysis of petroleum geological data including borehole logs. By synthesizing borehole radioactive logs and seismic surveys, we delineated target sandstone geometry, connectivity, and ore-controlling structures (e.g., paleochannels, redox interfaces). This study establishes a novel methodology for sandstone-type uranium exploration in petroliferous basins, unifying geophysical and geochemical datasets to define drill-validated targets. We integrated detailed core logging, petrography, and assay data to delineate the deposit’s geology. This included the host strata composition, ore-body morphology, mineralogy, and alteration assemblages. Our analysis identified the critical controls on mineralization: sandbody architecture, structural framework, and redox zonation. Based on these constraints, we constructed a genetic metallogenic model. Furthermore, we elucidated the mechanistic role of hydrocarbons in uranium mineralization and demonstrated the strategic potential of repurposing legacy oilfield data for synergistic uranium targeting. The Jingchuan uranium deposit provides both an exploration blueprint and theoretical foundations for uranium targeting in analogous sedimentary basins. Full article
(This article belongs to the Special Issue New Insights into Mineralization and Mining)
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28 pages, 5462 KB  
Article
Provenance and Uranium Sources in the Lower Cretaceous Huanhe Formation of Northern Ordos Basin: Constraints from Detrital Zircon U–Pb Geochronology and Hf Isotopes
by Xin Zhang, Junfan Che, Fengjun Nie, Aisheng Miao, Zhaobin Yan, Chengyong Zhang and Yujie Hu
Minerals 2025, 15(10), 1079; https://doi.org/10.3390/min15101079 - 16 Oct 2025
Cited by 1 | Viewed by 1149
Abstract
The Ordos Basin is a key district for sandstone-hosted uranium, yet host-rock controls and uranium sources remain debated. We integrate measured sections, whole-rock geochemistry, and detrital zircon U-Pb-Lu-Hf data from the Cretaceous Huanhe Formation (Yihewusu, northern Ordos) to resolve provenance, transport, and enrichment [...] Read more.
The Ordos Basin is a key district for sandstone-hosted uranium, yet host-rock controls and uranium sources remain debated. We integrate measured sections, whole-rock geochemistry, and detrital zircon U-Pb-Lu-Hf data from the Cretaceous Huanhe Formation (Yihewusu, northern Ordos) to resolve provenance, transport, and enrichment pathways. Uranium enrichment is concentrated in feldspathic-lithic sandstones deposited in proximal fluvial-lacustrine settings. Detrital zircon ages define three clusters—Phanerozoic (500–200 Ma), Paleoproterozoic (2000–1700 Ma), and Neoarchean (2600–2300 Ma)—with Proterozoic grains >60%, indicating derivation from Archean–Paleoproterozoic TTG gneisses, granulites, and khondalites of the Yinshan Block and the northern Central Orogenic Belt. Zircon εHf(t) values (−10.84 to +7.76) and crustal model ages (3.2–2.1 Ga) record substantial Meso- to Neoarchean crustal growth in the source terranes. Critically, Permian-Cretaceous intermediate-felsic igneous rocks along the northern margin of the Western North China Block—marked by elevated U, Th/U > 5 (indicative of U loss), pervasive feldspar micro-fractures, and proximity to basin-margin uranium belts—are identified as the principal uranium reservoirs. We propose a dual uranium supply: soluble uranium mobilized from leached igneous rocks during weathering and fluid-rock interaction, and U-enriched detritus delivered to the basin. Uranium concentrated in redox-sensitive, feldspathic-lithic sandstones of the Huanhe Formation, which effectively trapped advected uranium at proximal facies transitions. These findings establish a direct genetic link between basin-margin uranium sources and in-basin mineralization, providing a predictive framework for regional uranium exploration in North China. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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25 pages, 12285 KB  
Article
Integrated Geophysical Hydrogeological Characterization of Fault Systems in Sandstone-Hosted Uranium In Situ Leaching: A Case Study of the K1b2 Ore Horizon, Bayin Gobi Basin
by Ke He, Yuan Yuan, Yue Sheng and Hongxing Li
Processes 2025, 13(10), 3313; https://doi.org/10.3390/pr13103313 - 16 Oct 2025
Cited by 2 | Viewed by 938
Abstract
This study presents an integrated geophysical and hydrogeological characterization of fault systems in the sandstone-hosted uranium deposit within the K1b2 Ore Horizon of the Bayin Gobi Basin. Employing 3D seismic exploration with 64-fold coverage and advanced attribute analysis techniques (including [...] Read more.
This study presents an integrated geophysical and hydrogeological characterization of fault systems in the sandstone-hosted uranium deposit within the K1b2 Ore Horizon of the Bayin Gobi Basin. Employing 3D seismic exploration with 64-fold coverage and advanced attribute analysis techniques (including coherence volumes, ant-tracking algorithms, and LOW_FRQ spectral attenuation), the research identified 18 normal faults with vertical displacements up to 21 m, demonstrating a predominant NE-oriented structural pattern consistent with regional tectonic features. The fracture network analysis reveals anisotropic permeability distributions (31.6:1–41.4:1 ratios) with microfracture densities reaching 3.2 fractures/km2 in the central and northwestern sectors, significantly influencing lixiviant flow paths as validated by tracer tests showing 22° NE flow deviations. Hydrogeological assessments indicate that fault zones such as F11 exhibit 3.1 times higher transmissivity (5.3 m2/d) compared to non-fault areas, directly impacting in situ leaching (ISL) efficiency through preferential fluid pathways. The study establishes a technical framework for fracture system monitoring and hydraulic performance evaluation, addressing critical challenges in ISL operations, including undetected fault extensions that caused lixiviant leakage incidents in field cases. These findings provide essential geological foundations for optimizing well placement and leaching zone design in structurally complex sandstone-hosted uranium deposits. The methodology combines seismic attribute analysis with hydrogeological validation, demonstrating how fault systems control fluid flow dynamics in ISL operations. The results highlight the importance of integrated geophysical approaches for accurate structural characterization and operational risk mitigation in uranium mining. Full article
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23 pages, 5217 KB  
Article
Constraints from Geochemistry of Mineralization-Hosting Sandstone and Sulfur Isotopes of Pyrite on Uranium Mineralization in the Liuhuanggou Area, Southern Junggar Basin
by Junyang Li, Yu Zhou, Chunji Xue, Shizhong Chen, Guoxiong Ma, Zuohuai Yang, Min Liu, Le Yang and Jie Gong
Minerals 2025, 15(6), 575; https://doi.org/10.3390/min15060575 - 28 May 2025
Cited by 1 | Viewed by 1344
Abstract
A combination of microstructural, fluid inclusion, and in situ sulfur isotopic analyses of pyrite, along with major and trace element studies of the mineralization-hosting sandstone, reveals the complexity of its genesis from the Jurassic Toutunhe Formation in the Liuhuanggou sandstone-hosted uranium deposit, Southern [...] Read more.
A combination of microstructural, fluid inclusion, and in situ sulfur isotopic analyses of pyrite, along with major and trace element studies of the mineralization-hosting sandstone, reveals the complexity of its genesis from the Jurassic Toutunhe Formation in the Liuhuanggou sandstone-hosted uranium deposit, Southern Junggar Basin. Based on field geological investigations and the geochemical characteristics, it is concluded that the source of the ore-bearing sandstones originates from felsic igneous rocks in the Northern Tianshan and Central Tianshan regions. Through optical microscopy and scanning electron microscopy (SEM), three generations of pyrite were identified: framboidal pyrite, concentric overgrown pyrite, and sub-idiomorphic to idiomorphic cement pyrite. The sulfur isotopes of the pyrite were analyzed using laser ablation multi-collector inductively coupled plasma mass spectrometry (LA-MC-ICP-MS). The results indicate that each type of pyrite has distinct sulfur isotope compositions (the framboidal pyrite: −16.85‰ to +2.16‰, the concentric overgrown pyrite: −7.86‰ to +10.32‰, the sub-idiomorphic to idiomorphic cement pyrite: +9.16‰ to +16.77‰). The framboidal pyrite and the sub-idiomorphic to idiomorphic cement pyrite were formed through bacterial sulfate reduction (BSR), while the concentric overgrown pyrite was formed through thermochemical sulfate reduction (TSR) triggered by the upward migration of hydrocarbons. The discovery of hydrocarbon inclusions provides evidence for the involvement of deep-seated reducing fluids in uranium mineralization. Uranium mineralization occurred in two distinct stages: (1) The early stage involved the interaction of uranium-bearing fluids with reductants in the mineralization-hosting strata under the influence of groundwater dynamics, leading to initial uranium enrichment. (2) The later stage involved the upward migration of deep-seated hydrocarbons along faults, which enhanced the reducing capacity of the sandstone and resulted in further uranium enrichment and mineralization. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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21 pages, 22649 KB  
Article
Epigenetic Alteration of the Hailijin Sandstone-Hosted Uranium Deposit and Its Indications on Uranium Metallogenesis in the Songliao Basin, NE China
by Mingming Tian, Ziying Li, Licheng Jia, Jungang Liu, Jun Ning and Jimu Li
Minerals 2025, 15(4), 393; https://doi.org/10.3390/min15040393 - 8 Apr 2025
Cited by 3 | Viewed by 1198
Abstract
This study focuses on the Hailijing sandstone-hosted uranium deposit in the Songliao Basin. Through a combination of petrographic analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), and geochemical analysis, the epigenetic alteration of the deposit was systematically investigated, and the alteration zonation was [...] Read more.
This study focuses on the Hailijing sandstone-hosted uranium deposit in the Songliao Basin. Through a combination of petrographic analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), and geochemical analysis, the epigenetic alteration of the deposit was systematically investigated, and the alteration zonation was delineated. On this basis, the metallogenic mechanisms were further explored. The results indicate that six major types of alteration can be identified in the ore-bearing strata of the Hailijing uranium deposit: hematitization, limonitization, carbonatization, pyritization, clay mineralization (including kaolinite, illite, and illite-smectite mixed-layer), and baritization. The mineral assemblages at different stages of alteration vary: during the sedimentary diagenetic stage, the assemblage consists of “hematite + clay minerals + II-type pyrite (framboidal pyrite) + III-type pyrite (euhedral granular pyrite)”; during the uranium mineralization stage, it transitions to “ankerite + barite + I-type pyrite (colloidal pyrite) + minor kaolinite”; and in the post-ore stage, alteration is characterized by calcite cementation in red sandstones. Based on petrological, mineralogical, and geochemical characteristics, as well as the spatial distribution of the host gray sandstones, it is inferred that during uranium mineralization stage, the ore-bearing strata underwent reduction by uranium-rich reducing fluids sourced from the Lower Cretaceous Jiufotang Formation. The primary red sandstones of the Lower Yaojia Formation, formed under arid to semi-arid conditions, experienced varying degrees of reduction, resulting in a color transition from light red, brownish red, and yellowish brown to grayish-yellow and gray. Accordingly, four alteration zones are distinguished in the Hailijing uranium deposit: the primary red zone, weakly reduced pink zone, moderately reduced grayish-yellow zone, and strongly reduced gray zone. Furthermore, as the uranium-rich reducing fluids migrated from a high-temperature, high-pressure deep system to the low-temperature, low-pressure ore-bearing sandstone strata near the surface, uranium was unloaded, precipitated, and enriched, ultimately forming multi-layered and tabular-shaped uranium orebodies within the gray sandstone. This study elucidates the epigenetic alteration processes and metallogenic mechanisms of the Hailijing uranium deposit, providing a critical theoretical basis for further uranium exploration in the southern Songliao Basin. Full article
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19 pages, 4569 KB  
Article
Comprehensive Study on Hydrogeological Conditions and Suitability Evaluation of In Situ Leaching for Sandstone-Hosted Uranium Deposit in Erlian Basin
by Lishan Meng, Hang Ning, Wanjun Jiang, Yizhi Sheng, Wei Wang and Chao Tang
Water 2024, 16(19), 2785; https://doi.org/10.3390/w16192785 - 30 Sep 2024
Cited by 3 | Viewed by 1883
Abstract
As a strategic mineral and energy resource, the enrichment and metallogenic mechanism of sandstone-hosted uranium deposits are highly dependent on hydrogeological conditions. However, the relationship between sandstone uranium mineralization and hydrogeological conditions has not received sufficient attention yet. The pumping test, hydrogeological parameters [...] Read more.
As a strategic mineral and energy resource, the enrichment and metallogenic mechanism of sandstone-hosted uranium deposits are highly dependent on hydrogeological conditions. However, the relationship between sandstone uranium mineralization and hydrogeological conditions has not received sufficient attention yet. The pumping test, hydrogeological parameters and hydrochemical characteristics were employed to analyze the change characteristics of hydrogeological conditions and evaluate the suitability of in situ leaching (ISL). The results showed that the study area in the Inner Mongolia Autonomous Region could be divided into two groundwater subsystems, namely Quanzha-Engeriyin and Luhai-Zhendai. The latter with relatively high water richness is confined and a main ore-bearing aquifer, which consists of four orebodies. The well discharge (Q) and hydraulic conductivity (K) of Orebody II ranged from 98.40 to 867.36 m3/d and 0.25 to 5.64 m/d, respectively, indicating the aquifer is suitable for the migration, enrichment and mineralization of uranium due to relatively high permeability and fast flow rate. The water storage of Orebodies III-IV gradually deteriorated from east to west in a stepped pattern. And the highest values of Q and K in Orebodies III-IV decreased from 1200 m3/d to 120 m3/d and 1.75 m/d to 0.035 m/d, respectively, suggesting these were conducive to a reduction in and accumulation of uranium under poor hydrodynamic conditions. Additionally, the study area would be defined as three grades, including favorable, relatively favorable and unfavorable areas of ISL according to a comprehensive evaluation. This study provided a scientific basis for evaluating the possibility of in situ leaching for sandstone-hosted uranium deposit. Full article
(This article belongs to the Special Issue Soil and Groundwater Quality and Resources Assessment)
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Article
The Role of Hydrocarbons in the Formation of Uranium Mineralization, Louzhuangzi District, Southern Junggar Basin (China)
by Zhong-Bo He, Bao-Qun Hu, Lin-Fei Qiu, Yun Wang, Hong Chen, Wei-Wei Jia, Yi-Fei Li, Hua-Li Ji and Man-Huai Zhu
Minerals 2024, 14(7), 709; https://doi.org/10.3390/min14070709 - 12 Jul 2024
Cited by 3 | Viewed by 2090
Abstract
In recent years, there have been important breakthroughs in the exploration for sandstone-hosted uranium (U) deposits in the Louzhuangzi district of the southern Junggar Basin. Between 2020 and 2023, a medium-sized sandstone-hosted uranium deposit production area was identified in the region. Only a [...] Read more.
In recent years, there have been important breakthroughs in the exploration for sandstone-hosted uranium (U) deposits in the Louzhuangzi district of the southern Junggar Basin. Between 2020 and 2023, a medium-sized sandstone-hosted uranium deposit production area was identified in the region. Only a few investigations have been conducted at the Louzhuangzi U deposit, including those analyzing its geological–tectonic evolution, basic geological features, hydrogeology, and ore-controlling factors. It is generally believed that uranium mineralization at the Louzhuangzi U deposit is controlled by a redox zone. Organic matter (referred to as OM hereafter) consisting of bitumen and carbonaceous debris is very common in the uranium ores (especially in high-grade ores) at the Louzhuangzi U deposit. However, the characteristics of the OM and its contribution to uranium’s mineralization have not been studied in detail. In this study, OM-rich U-ores, altered sandstone, and barren sandstone samples were collected for petrography, mineralogical, micro-spectroscopy, carbon, and sulfur isotope studies. The results of this study show that the distribution of U minerals and metal sulfides (pyrite, sphalerite, etc.) was strictly controlled by bitumen at the Louzhuangzi U deposit. The bitumen may have been formed by hydrocarbon-rich and U-rich ore-forming fluids, which were formed after hydrocarbon generation and expulsion in the underlying Jurassic coal-bearing source rocks. The fluids contained U, Zn, Fe, and other metal elements, which migrated together and then precipitated into the oxidized Toutunhe Formation sandstone through cracking and differentiation processes. Therefore, the results indicate that migrated hydrocarbons were involved in U mineralization, in addition to oxidation–reduction processes, in the Louzhuangzi district, south of the Junggar Basin (China). Full article
(This article belongs to the Special Issue Uranium: Geochemistry and Mineralogy)
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