Search Results (13)

Compressed CO₂ energy storage (CCES) in deep sedimentary basins offers a promising option to integrate carbon management with long-duration energy storage. However, most existing subsurface energy-storage studies focus on salt caverns or generic porous reservoirs, while the potential of evaporite-bounded carbonate reservoirs remains insufficiently explored. This study presents the first application-oriented numerical assessment of CCES in Southern Ontario. It investigates the feasibility of CCES in the Upper Silurian Salina Group beneath offshore Lake Huron, focusing on a porous A-2 carbonate interval vertically confined by B and A-2 halite caprocks. A fully coupled three-dimensional thermo-hydro-mechanical model is developed in COMSOL Multiphysics 6.3 to simulate two-phase (brine-CO₂) Darcy flow, heat transfer, and poroelastic deformation under a realistic Michigan Basin stress, pressure and geothermal regime. After an initial cushion-gas stage at 8 kg/s that establishes a caprock-parallel supercritical CO₂ wedge beneath the B-salt, 24 h injection-production cycles are imposed for two years, followed by a five-month high-resolution window. Three well completion strategies are compared: full-length, upper-only, and split (upper + lower) perforations. Results indicate that in all simulations the CO₂ plume stabilizes as a persistent gas cap beneath the B-salt, far-field pressures remain close to hydrostatic, and reservoir deformations are very small, pointing to a substantial geomechanical safety margin. Among the three completion strategies, the split completion provides the best compromise: it maintains high and relatively stable CO₂ production while avoiding the stronger lower-zone depressurisation seen in the full-length case and the more limited working volume of the upper-only case. These findings suggest that a Salina A-2 carbonate reservoir bounded by B and A-2 salts can accommodate cyclic CCES under realistic basin conditions, and that appropriately designed split completions offer a practical balance between storage utilisation and operational robustness in this setting. Full article

Salt cavern CO₂ storage (SCCS) technology represents a crucial pathway for achieving large-scale carbon sequestration. However, its long-term operation faces the challenge of cavern shrinkage due to surrounding rock creep, which directly impacts storage safety and stability. Despite its importance, there is currently a lack of research focusing on the proactive control of SCCS cavern shrinkage and its collaborative optimization with operational economy. To fill this gap, this paper first investigated the effects of the stress state (f₁), height-to-diameter ratio (f₂), symmetry factor (f₃), and cavern volume (f₄) on the volumetric shrinkage rate through numerical simulations of regular caverns and univariate sensitivity analysis. The sensitivity ranking and quantitative relationships of these factors were clarified as $f_1(2.31)>f_4(0.309)>f_2(0.166)>f_3(0)$. Subsequently, a multi-objective nonlinear optimization model was established, and the primal-dual interior-point method was adopted as the solution algorithm. Using actual cavern data as a case study for the solution, the results demonstrate that the optimization model converges stably in approximately 1.1 s. The resulting optimal gas injection allocation scheme achieves a 14.77% improvement in the comprehensive score compared to the baseline scheme. This study provides a theoretical basis and a practical tool for the rapid generation of SCCS gas injection allocation schemes. Full article

The global energy sector is aiming to substantially reduce CO₂ emissions to meet the UN climate goals. Among the proposed strategies, underground storage solutions such as radioactive disposal, CO₂, NH₃, and underground H₂ storage (UHS) have emerged as promising options for mitigating anthropogenic emissions. These approaches require rigorous research and development (R&D), often involving laboratory-scale experiments to establish their feasibility before being scaled up to pilot plant operations. Microorganisms, which are ubiquitous in laboratory environments, can significantly influence geochemical reactions under variable experimental conditions of porous media and a salt cavern. We have selected a consortium composed of Bacillus sp., Enterobacter sp., and Cronobacter sp. bacteria, which are typically present in the laboratory environment. These microorganisms can contaminate the rock sample and develop experimental artifacts in UHS experiments. Hence, it is pivotal to sterilize the rock prior to conduct experimental research related to effects of microorganisms in the porous media and the salt cavern for the investigation of UHS. This study investigated the efficacy of various disinfection and sterilization methods, including ultraviolet irradiation, autoclaving, oven heating, ethanol treatments, and gamma irradiation, in removing the microorganisms from silica sand. Additionally, the consideration of their effects on mineral properties are reviewed. A total of 567 vials, each filled with 9 mL of acid-producing bacteria (APB) media were used to test killing efficacy of the cleaning methods. We conducted serial dilutions up to 10⁻⁸ and repeated them three times to determine whether any deviation occurred. Our findings revealed that gamma irradiation and autoclaving were the most effective techniques for eradicating microbial contaminants, achieving sterilization without significantly altering the mineral characteristics. These findings underscore the necessity of robust cleaning protocols in hydrogeochemical research to ensure reliable, reproducible data, particularly in future studies where microbial contamination could induce artifacts in laboratory research. Full article

The salt layer, characterized by its low permeability and excellent damage self-healing properties, is an ideal geological body for CO₂ geological storage. However, the relatively high permeability of mudstone interlayers may reduce the safety of CO₂ long-term storage in bedded salt caverns. This study establishes a thermal–hydraulic–mechanical (THM) coupled physical and mathematical model for CO₂ geological storage in the Huaian salt cavern, analyzes the factors affecting CO₂ flow behavior, and proposes measures to enhance the safety of CO₂ storage in salt caverns. The results indicate that the permeability of both salt layers and mudstone interlayers is influenced by stress-induced deformation within the salt cavern. From the salt cavern edge to the simulation boundary, the permeability and volume strain exhibit a trend of rapid decline, followed by a gradual increase, and an eventual stabilization or slight reduction. The seepage velocity, pore pressure, and flow distance of CO₂ in the mudstone interlayer are significantly higher than those in the salt layer, leading to CO₂ migration along the interfaces between the mudstone and salt layer. With the increase in storage time, the permeability of the mudstone interlayer gradually decreases, while the permeability of the salt layer shows a general tendency to increase. The elevated storage pressure reduces the permeability of the mudstone interlayer, while increasing the permeability of the salt layer, and enhances the seepage velocity in both the mudstone and salt layers. To enhance the safety of CO₂ long-term storage in bedded salt caverns, it is recommended to minimize the presence of mudstone interlayers during site selection and cavern construction, optimize the storage pressure, and strengthen monitoring systems for potential CO₂ leakage. Full article

Achieving net-zero greenhouse gas emissions by 2050 requires CO₂-neutral industrial process heat, with seasonal energy storage (SES) playing a crucial role in balancing supply and demand. This study reviews thermal energy storage (TES) and Power-to-X (P2X) technologies for applications without thermal grids, assessing their feasibility, state of the art, opportunities, and challenges. Underground TES (UTES), such as aquifer and borehole storage, offer 1–26 times lower annual heat storage costs than above-ground tanks. For P2X, hydrogen storage in salt caverns is 80% less expensive than in high-pressure tanks. Methane and methanol storage costs depend on CO₂ sourcing, while Renewable Metal Energy Carriers (ReMECs), such as aluminum and iron, offer high energy density and up to 580 times lower storage volume, with aluminum potentially achieving the lowest Levelized Cost of X Storage (LCOXS) at a rate of 180 EUR/MWh of energy discharged. Underground TES and hydrogen caverns are cost-effective but face spatial/geological constraints. P2X alternatives have established infrastructure but have lower efficiency, whereas ReMECs show promise for large-scale storage. However, economic viability remains a challenge due to very few annual cycles, which require significant reductions of investment cost and annual cost of capital (CAPEX), as well as improvements in overall system efficiency to minimize losses. These findings highlight the trade-offs between cost, space requirements, and the feasibility of SES deployment in industry. Full article

China’s renewable energy sector is experiencing rapid growth, yet its inherent intermittency is creating significant challenges for balancing power supply and demand. Power-to-gas (PtG) technology, which converts surplus electricity into combustible gas, offers a promising solution. Salt caverns, due to their favorable geological properties, are among the best choices for large-scale underground energy storage in PtG systems. CO₂ leakage along the interlayer and salt rock–interlayer interfaces is a key constraint on the CO₂ tightness of subsurface salt caverns. This paper focuses on the critical issue of tightness within salt cavern CO₂ storage, particularly in the Jintan region. A coupled hydro-mechanics mathematical model is developed to investigate CO₂ transportation and leakage in bedded salt caverns, with key variables such as permeability range, pore pressure evolution, and permeability changes being analyzed. The results reveal that permeability plays a decisive role in determining the CO₂ transportation rate and leakage extent within the salt rock layer. Notably, the CO₂ transportation rate and influence range in the mudstone interlayer are significantly larger than those in the salt rock over the same period. However, with prolonged storage time, the CO₂ transportation rate and pressure increase in both salt rock and mudstone interlayer exhibit a decreasing trend, eventually stabilizing as the CO₂ pressure front reaches the boundary of the simulation domain. Furthermore, elevated operating pressure markedly expands the permeability range and results in higher cumulative leakage. For a specific salt cavern, the CO₂ leakage range can reach up to 142 m, and the leakage volume can reach 522.5 tonnes with the increase in operating pressure during 35 years of operation. Therefore, the setting of operational pressure should fully consider the influence of permeability and mechanical strength of the salt rock and mudstone interlayer. These findings provide valuable insights into optimizing the sealing performance of salt cavern CO₂ storage systems under varying conditions. Full article

Rising shares of variable wind and solar generation in decarbonized electricity systems motivate the development of novel power cycles employing unconventional fuels. Innovative designs must be highly flexible and profitable at low capacity factors, requiring a simple process layout and low capital costs. Fuel supply infrastructure represents a significant additional capital cost, which is often ignored in economic assessments of gas-fired power plants. When these capital costs are included, liquid fuels such as NH₃ or MeOH gain relevance despite their high production costs because they are cheap to store and distribute. In addition, chemically recuperated power cycle designs upgrade these fuels with waste heat from the gas turbine exhaust, avoiding a capital-intensive bottoming cycle while achieving high thermal efficiencies. This work presents an exergoeconomic benchmarking of different large-scale power plants and their fuel supply infrastructure. The results show that chemically recuperated cycles using MeOH become competitive relative to natural-gas-fired combined cycles with fuel storage in salt caverns at capacity factors below 32% if seven-day storage is required and plants are located 500 km from the fuel source. NH₃ can compete with H₂ at a higher capacity factor of 47% because of the high cost of storing H₂, while a CO₂ price of 140 EUR/ton is required for NH₃ to outperform MeOH as a fuel. In cases where salt cavern storage is unavailable, or the energy security of multi-week fuel storage is highly valued, liquid fuels present a clearly superior solution. Full article

The hydrogen economy is one of the possible directions of development for the European Union economy, which in the perspective of 2050, can ensure climate neutrality for the member states. The use of hydrogen in the economy on a larger scale requires the creation of a storage system. Due to the necessary volumes, the best sites for storage are geological structures (salt caverns, oil and gas deposits or aquifers). This article presents an analysis of prospects for large-scale underground hydrogen storage in geological structures. The political conditions for the implementation of the hydrogen economy in the EU Member States were analysed. The European Commission in its documents (e.g., Green Deal) indicates hydrogen as one of the important elements enabling the implementation of a climate-neutral economy. From the perspective of 2050, the analysis of changes and the forecast of energy consumption in the EU indicate an increase in electricity consumption. The expected increase in the production of energy from renewable sources may contribute to an increase in the production of hydrogen and its role in the economy. From the perspective of 2050, discussed gas should replace natural gas in the chemical, metallurgical and transport industries. In the longer term, the same process will also be observed in the aviation and maritime sectors. Growing charges for CO₂ emissions will also contribute to the development of underground hydrogen storage technology. Geological conditions, especially wide-spread aquifers and salt deposits allow the development of underground hydrogen storage in Europe. Full article

Hydrogen (H₂) is an attractive energy carrier to move, store, and deliver energy in a form that can be easily used. Field proven technology for underground hydrogen storage (UHS) is essential for a successful hydrogen economy. Options for this are manmade caverns, salt domes/caverns, saline aquifers, and depleted oil/gas fields, where large quantities of gaseous hydrogen have been stored in caverns for many years. The key requirements intrinsic of a porous rock formation for seasonal storage of hydrogen are: adequate capacity, ability to contain H₂, capability to inject/extract high volumes of H₂, and a reliable caprock to prevent leakage. We have carefully evaluated a commercial non-isothermal compositional gas reservoir simulator and its suitability for hydrogen storage and withdrawal from saline aquifers and depleted oil/gas reservoirs. We have successfully calibrated the gas equation of state model against published laboratory H₂ density and viscosity data as a function of pressure and temperature. Comparisons between the H₂, natural gas and CO₂ storage in real field models were also performed. Our numerical models demonstrated more lateral spread of the H₂ when compared to CO₂ and natural gas with a need for special containment in H₂ projects. It was also observed that the experience with CO₂ and natural gas storage cannot be simply replicated with H₂. Full article

Governance of abandoned mines has become a pressing issue for China. The utilization of abandoned mines is a technology that can solve the problem of governance and recreate the value of mines, which is in line with the current strategic goals of ecological protection and double carbon in China. In this paper, the various utilization models and the advances in rock mechanics of abandoned mines across the globe are summarized and reviewed. The utilization models of abandoned mines can be categorized into four aspects: Energy storage, Waste treatment, Ecological restoration, and carbon dioxide (CO₂) sequestration. There are a number of applications and uses of abandoned mines, such as pumped storage, compressed air storage, salt cavern gas/oil storage construction, carbon dioxide storage and utilization, radioactive waste disposal and treatment, and tourism development. Various progress practices of abandoned mines are discussed in detail with emphasis on the national conditions of China. The basic rock mechanics problems and advances involved in the construction of the facilities related to the utilization of abandoned mines are discussed and evaluated. The establishment of relevant research and experimental platforms will contribute to the sustainable development of China’s mining industry and the improvement of clean technologies. Full article

In the context of green energy and decarbonization, carbon dioxide storage in underground facilities, such as salt caverns, is one promising technical solution that has aroused attention. However, the thermodynamic behavior of CO₂ and the geomechanical response of salt cavities have not been studied comprehensively. In this study, we proposed a thermomechanical model that integrated a salt cavity and wellbore and implemented a series of simulations for carbon dioxide storage in a salt cavern. The model was verified by gas capacity calculations using field testing data. The thermodynamic behaviors of CO₂ were determined and compared to methane. The results showed that the critical point coordinates of carbon dioxide were within the storage operation conditions, a phase transition could occur, and the thermodynamic properties around the critical point varied dramatically. For a short CO₂ withdrawal operation, the salt cavity remained stable, while the near-wellbore area (NWA) was prone to fracture due to tensile stress concentration. Thus, we concluded that the proposed thermomechanical coupling numerical simulation method provided a comprehensive and quantitative tool for the feasibility analysis of CO₂ storage in underground salt caverns. Full article

Although subsurface traps have been regularly explored for hydrocarbon exploration, natural gas and CO₂ storage has drawn industrial attention over the past few decades, thanks to the increasing demand for energy resources and the need for greenhouse gas mitigation. With only one depleted hydrocarbon field in Greece, saline aquifers, salt caverns and sedimentary basins ought to be evaluated in furtherance of the latter. Within this study the potential of the Greek subsurface for underground storage is discussed. An overview and re-evaluation of the so-far studied areas is implemented based on the available data. Lastly, a pragmatic approach for the storage potential in Greece was created, delineating gaps and risks in the already proposed sites. Based on the above details, a case study for CO₂ storage is presented, which is relevant to the West Katakolo field saline aquifer. Full article

The increasing integration of large-scale electricity generation from renewable energy sources in the grid requires support through cheap, reliable, and accessible bulk energy storage technologies, delivering large amounts of electricity both quickly and over extended periods. Compressed air energy storage (CAES) represents such a storage option, with three commercial facilities using salt caverns for storage operational in Germany, the US, and Canada, with CAES now being actively considered in many countries. Massively bedded halite deposits exist in the UK and already host, or are considered for, solution-mined underground gas storage (UGS) caverns. We have assessed those with proven UGS potential for CAES purposes, using a tool developed during the EPSRC-funded IMAGES project, equations for which were validated using operational data from the Huntorf CAES plant. From a calculated total theoretical ‘static’ (one-fill) storage capacity exceeding that of UK electricity demand of ≈300 TWh in 2018, filtering of results suggests a minimum of several tens of TWh exergy storage in salt caverns, which when co-located with renewable energy sources, or connected to the grid for off-peak electricity, offers significant storage contributions to support the UK electricity grid and decarbonisation efforts. Full article