Search Results (48)

Geothermal resources in arid inland basins are important for clean energy development, yet their circulation and geochemical mechanisms remain insufficiently understood. This study investigates the hydrochemical characteristics and formation mechanisms of geothermal water in the Zhangye–Minle Basin, an arid inland region in northwestern China. A total of nine geothermal water samples were analyzed using major ion chemistry, stable isotopes (δ²H, δ¹⁸O), tritium (³H), and radiocarbon (¹⁴C) to determine recharge sources, flow paths, and geochemical evolution. The waters were predominantly of the Cl–Na and Cl·SO₄–Na types, with total dissolved solids ranging from 3432.00 to 5810.00 mg/L. Isotopic data indicated that recharge originated from atmospheric precipitation and snowmelt in the Qilian Mountains, with recharge altitudes between 2497 and 5799 m. Tritium and ¹⁴C results suggested that most samples were recharged before 1953, with maximum ages exceeding 40,000 years. Gibbs diagrams and ion ratio plots demonstrated that water–rock interaction was the primary geochemical process, while cation exchange was weak. Na⁺ was mainly derived from halite, albite, and mirabilite, while SO₄²⁻ originated largely from gypsum. The calculated reservoir temperatures using cation geothermometers ranged from 57 °C to 148 °C. The deep circulation of geothermal water was closely related to NNW-trending fault zones that facilitated infiltration and heat accumulation. These findings provide new insights into the recharge sources, circulation patterns, and geochemical processes of geothermal systems in fault-controlled basins, offering a scientific basis for their sustainable exploration and development. Full article

The hydrochemical characteristics and evolution mechanisms of groundwater are critical for accurately understanding the input–output budget of hydrochemical constituents in pristine groundwater. However, few studies have analyzed the changes in mineral precipitation and dissolution equilibrium along the groundwater flow path, especially in arid regions. This study integrated hydrochemical analysis, stable isotopes, and inverse hydrochemical modeling to identify groundwater recharge sources, hydrochemical evolution, and controlling mechanisms in an arid endorheic watershed, northwestern China. A stable isotope signature indicated that groundwater is primarily recharged by high-altitude meteoric precipitation and glacial snowmelt. The regional hydrochemical type evolved from HCO₃·Cl-Ca·Mg·Na types in phreatic aquifers to more complex HCO₃·Cl-Ca·Mg Na and HCO₃·Cl-Na Mg types in confined aquifers and a Cl-Mg·Na type in high-salinity groundwater. The dissolution of halite, gypsum, calcite, K-feldspar, and albite was identified as the primary source of dissolved substances and a key factor controlling the hydrochemical characteristics. Meanwhile, hydrochemical evolution is influenced by cation exchange, mineral dissolution–precipitation, and carbonate equilibrium mechanisms. Inverse hydrochemical modeling demonstrated that high-salinity groundwater has experienced intensive evaporation and quantified the transfer amounts of associated minerals. This study offers deeper insight into hydrochemical evolution in the Golmud River watershed and elucidates mineral transport and enrichment mechanisms, providing a theoretical basis for investigating hydrochemical metallogenic processes. Full article

Groundwater is a critical resource in semi-arid regions like Morocco’s Guire Basin, yet pollution and overexploitation threaten its sustainability. This study evaluates the groundwater quality of the Guire aquifer (Eastern High Atlas) using an integrated approach combining hydrochemical, isotopic (δ¹⁸O, δ²H, δ¹³C), multivariate statistical, and Geographic Information System (GIS) analyses alongside the Water Quality Index (WQI). Sixteen wells were monitored for physicochemical parameters (pH: 7–7.9; EC: 480–3004 μS/cm; BOD5: 1.03–30.5 mg/L; COD: 10.2–45.75 mg/L) and major ions, revealing widespread exceedances of Moroccan standards for Cl⁻, HCO₃⁻, Mg²⁺, Ca²⁺, and NH₄⁺. WQI classified 81% of samples as “Poor” to “Unsuitable for drinking” (WQI: 51–537), driven by elevated Cl⁻, Na⁺, and SO₄²⁻ from Triassic evaporite dissolution and NO₃⁻ (up to 45 mg/L) from agricultural runoff. Stable isotopes (δ¹⁸O: −7.73‰ to −5.08‰; δ²H: −66.14‰ to −44.20‰) indicate Atlantic-influenced recharge at 900–2200 m altitudes, with a δ¹⁸O-δ²H slope of 5.93 reflecting evaporation during infiltration. Strontium (Sr²⁺/Ca²⁺: 0.0024–0.0236) and bromide (Br/Cl: 8.47 × 10⁻⁵–9.88 × 10⁻⁴) ratios further confirm evaporitic dominance over anthropogenic contamination. This work provides actionable insights for policymakers, advocating for targeted restrictions on fertilizers, enhanced monitoring near evaporite zones, and artificial recharge initiatives. By linking geogenic/anthropogenic contamination to governance strategies, this study advances sustainable groundwater management in semi-arid regions. Full article

This study elucidates soil–climate regulatory mechanisms on regional health baselines in China and hydrogeochemical roles in cardiovascular biomarker differentiation. Utilizing data from 26,759 healthy adult samples across 286 Chinese cities/counties, seven core factors were identified via Pearson correlation analysis from 25 indicators, including longitude (X₁, r = −0.192, p = 0.009), elevation (X₃, r = 0.377, p = 0.001), and precipitation (X₇, r = −0.200, p = 0.006). Ridge regression analysis (R² = 0.714) was subsequently applied to simulate predicted values for 2232 cities/counties. The synergistic effects of soil calcium sulfate content and salinity (X₂₅) on serum cardiac troponin I (cTnI) reference values were rigorously validated, explaining 25.5% of regional cTnI elevation (ΔR² = 0.183). The findings demonstrate that precipitation leaching and groundwater recharge processes collectively drive a 25.5% elevation in cTnI levels in northwestern regions (e.g., Nagqu, Tibet: altitude > 4500 m, annual sunshine > 3000 h) compared to southeastern areas. To mitigate salinity transport dynamics, optimization strategies targeting soil cation exchange capacity (X₁₈/X₁₉) were proposed, providing a theoretical foundation for designing gradient water treatment schemes in high-calcium-sulfate zones (CaSO₄ > 150 mg/L). Crucially, regression equations derived from the predictive model enable the construction of a geographically stratified reference framework for cTnI in Chinese adults, with spatial analysis delineating its latitudinal (R² = 0.83) and longitudinal (R² = 0.88) distribution patterns. We propose targeted strategies optimizing soil cation exchange capacity to mitigate sulfate transport in groundwater, informing geographically tailored water treatment and cardiovascular disease prevention efforts. Our findings provide localized empirical evidence critical for refining WHO drinking water sulfate guidelines, demonstrating direct integration of hydrogeochemistry, water quality management, and public health. Full article

The integration of different sources of geological and hydrogeological information and the application of interdisciplinary methods have informed the origin of the thermal springs of Alhama de Aragón and Jaraba, as well as other associated semi thermal springs (1200 L/s of combined flow, 711 L/s at over 30 °C), which is the main objective of this article. These springs come mainly from the autogenous recharge that occurs in the Cretaceous calcareous outcrops that border the Almazán Basin to the north, both in the Ebro Basin (Jalón Valley) and in the Duero Basin. The aquifer, shaped by upper Cretaceous limestones under the Palaeogene and Neogene rocks of the Almazán Basin, has extensive depths of more than 4000 m in the NE sector. This hydrostratigraphic unit has been affected by a generalized pre-Paleogene karstification that provides the main porosity to the aquifer. The underground flow moves in a NW–SE direction, crossing the Duero–Ebro divide, favoured by the topographic difference in elevation between the two basins. The regional flow is coherent with the progressive increase in temperature, infiltrating recharge water age (about 20–25 years in the semi-thermal springs, and more than 60 years in the Alhama and Jaraba springs), mineralization, and flow of the springs through which the system discharges. This issue is key to being able to design any sustainable conservation strategy in terms of quantity and quality of resources within the recharge area of the most important thermal springs in Spain. The Jaraba and Alhama de Aragón hot springs share the same or similar temperature, chemical composition, and geological contact of the spring. Their tritium isotopic composition and its evolution over time are practically the same. Their isotopic composition in D and ¹⁸O is also very similar. Both springs share the same recharge zone of similar altitude and constitute the end of flow tubes of similar length and flow rate. Full article

This study investigates the hydrological dynamics of the Pativilca Basin in the Southern Hemisphere using the SWAT (Soil and Water Assessment Tool) model. Seventy-seven watersheds across a mountainous region were analyzed using elevation data, land cover, soil type, and gridded meteorological products (RAIN4PE and PISCO) for hydrological simulations. Watershed delineation, aided by a Digital Elevation Model, enabled the identification of critical drainage points and the definition of Hydrological Response Units (HRUs). The model calibration and validation, performed using the SWAT-CUP with the SUFI-2 algorithm, achieved Nash–Sutcliffe Efficiency (NSE) values of 0.69 and 0.72, respectively. Cluster analysis categorized the watersheds into six distinct groups with unique hydrological and climatic characteristics. The results showed significant spatial variability in the precipitation and temperature, with pronounced seasonality influencing the daily flow patterns. The higher-altitude watersheds exhibited greater soil water storage and more effective aquifer recharge, whereas the lower-altitude watersheds, despite receiving less precipitation, displayed higher flows due to runoff from the upstream areas. These findings emphasize the importance of incorporating seasonality and spatial variability into water resource planning in mountainous regions and demonstrate the SWAT model’s effectiveness in predicting hydrological responses in the Pativilca Basin, laying the groundwork for future research in mountain hydrology. Full article

This study aims to investigate the intricate relationship between geological structures, water chemistry, and isotopic composition in order to gain a deeper understanding of the origins and recharge mechanisms of thermal–mineral waters in the Kyllini region. The research integrates tectonic analysis, hydrochemical data, and stable isotope measurements to delineate recharge zones and trace the origin of these unique water sources. The methods used for delineation are the geological and tectonic study of the area, as well as hydrochemical and isotopic data analysis. The findings highlight that tectonic activity creates preferential flow paths and consequently influences the hydrogeological framework, facilitating deep circulation and the upwelling of thermal waters. Monthly analyses of groundwater samples from the Kyllini thermal spring were conducted over one hydrological year (2019–2020) and compared with data from the area collected in 2009. The hydrochemical profiles of major and minor ions reveal distinct signatures corresponding to various water–rock interactions, while stable isotope analysis provides insights into the climatic conditions and altitudes of recharge areas. Hydrochemical analyses reveal the composition of thermal–mineral waters, aiding in the identification of potential sources and their evolution. The conceptualization of Kyllini contributes to the deeper understanding of the intricate interplay between tectonics, hydrochemistry, and stable isotopes. During a hydrological year, the water type of Kyllini’s spring groundwater remains the same (Na-Cl-HCO₃), presenting only slight alterations. Full article

Investigations of the geochemical compositions of geothermal water, as well as their movements and geneses, are of great significance for the exploration and exploitation of hydrothermal resources. In Zhongshan City, a southern city in Guangdong Province, large amounts of geothermal heat have been discovered. The results of investigations show that the hydrochemical types of geothermal water in the study area are Cl-Na·Ca and Cl-Na. H-O isotopes are basically near the atmospheric precipitation line, and the calculated recharge elevation of geothermal water ranges from 716 to 822 m, which is close to the altitude of the North Peak Mountain in Taishan City. The deep thermal storage temperature ranges from 95.32 to 149.71 °C, and the depth of the thermal cycle ranges from 2638.57 m to 4581.07 m. The genetic model of the geothermal water in this area is that, at favorable structural positions with satisfied water storage conditions, the mixture of atmospheric precipitation and seawater that circulates deep in Earth is heated by terrestrial heat flow under actions such as deep heat exchange and water–rock reactions to leach the salt, finally forming the highly mineralized geothermal water that uplifts out of the surface along faults and crops. The formation of the genetic model of geothermal water will provide a geological basis and technical support for the efficient development and utilization of geothermal resources in Zhongshan City and the coastal area of Southeast China. Full article

The aim of this paper is to describe the surveys performed in order to update the interpretive conceptual circulation model of the Ladeira de Envendos hyposaline hydromineral system (Central Portugal). The geology of the Ladeira de Envendos region is strongly controlled by the Amêndoa-Carvoeiro synform, of Ordovician-Silurian age, presenting continuous and aligned quartzite ridges on the NE flank, that form the basic structure of a set of inselbergs. The physico-chemical analysis of the Ladeira de Envendos natural mineral spring and borehole waters was provided by the Super Bock Group Enterprise (Concessionaire of the Ladeira de Envendos). Furthermore, two sampling campaigns took place to increase knowledge on the isotopic composition of the studied natural mineral waters. The stable (δ²H, δ¹⁸O) isotopic data indicate that local meteoric waters infiltrate around 400 m altitude and evolve to the natural mineral waters (of Cl-Na facies) through a NW–SE underground flow path ascribed to the highly fractured and permeable quartzite rocks. From recharge to discharge, the infiltrated meteoric waters acquire silica (±9 mg/L) due to water–quartzite rock interaction. These natural mineral waters emerge at temperatures around 21 °C, being the up flow of these waters controlled by the rock fractures and local faults. The natural mineral waters mean residence time range between 25 and 40 years, as indicated by the ³H content of these waters, enhancing an active recharge of this hydromineral system. The results obtained indicate existence of three hydrogeological subsystems, ascribed to three inselbergs, with similar groundwater circulation paths. These multi and interdisciplinary studies should be seen as an important contribution to the sustainable management of this type of natural mineral water resources. Full article

In this article we present the first investigation of the stable isotope composition of groundwater in Romania, East-Central Europe, with a focus on the karst areas. Our aim is twofold: (1) to provide a countrywide map with the distribution of stable oxygen and hydrogen isotope ratios in groundwater, and (2) to assess the recharge patterns of karst water. We collected more than 600 water samples from springs and wells across Romania for stable isotope analyses and monitored in detail the stable isotope composition of the waters as they pass through five cave systems. Our data show a spatial distribution of the stable isotope composition of the groundwater with low values in the mountainous area and high values in the surrounding lowlands and the central Transylvanian Depression. However, waters in karst areas induce departures from this distribution, resulting from the fast (hours to days) transfer of waters from high (ponor) to low (spring) altitudes. Water emerging from the karst springs has generally lower δ values than before sinking through the ponors, thus indicating a substantial contribution of winter recharge through diffuse infiltration and seepage. This contribution results in overall dilution of the water entering through ponors, likely resulting in changes in the chemical composition of the water and diluting potential pollutants. Our data call for careful separation between karst and non-karst spring/well waters, as indiscriminate common treatment might lead to erroneous interpretations. Full article

The stability of irrigation water is critical for the sustainability of alpine agriculture. Based on monthly precipitation and terraced field water and spring water samples obtained between 2015 and 2016, the study used the mean residence time and isotope mixing model to analyze the influence of spring water residence time on irrigation water stability in the Hani Rice Terraces. The results indicate that: (1) The mean residence time of precipitation and terraced field water in spring water was 2.46 years and 1.55 years, respectively, implying that the terraced field’s irrigation water source could be refilled by spring water recharged 1.5–2.5 years ago. (2) The mean residence time of precipitation in ascending and descending springs was 2.73 years and 1.95 years, respectively. The mean residence time of terraced field water in ascending and descending springs was 1.54 years and 1.04 years, respectively. The ascending spring’s recharge water residence time is 0.5–0.8 years longer than that of the descending spring, indicating that the spring water exhibits intra-seasonal and inter-seasonal staggered peak recharging. At the same time, the total recharge period of the ascending–descending spring is extended to 1–3 years, which means the terraced fields have a drought resistance of three years. (3) The mean residence time of precipitation and terraced field water at higher altitudes in the ascending spring is 2.52 times and 3.73 times, respectively, while in the descending spring, it is 3.36 times and 6.49 times to the lower altitude region. This means that the mean residence time of the recharge water source in the lower terraced fields was shorter, and the elevation difference between ascending and descending springs was smaller, thereby regulating the spatial homogeneous distribution of recharge water sources in the terraced fields. Full article

Stable water isotopes are widely recognised as essential tools to trace processes within the hydrological cycle and to disentangle complex phenomena, such as regional–local atmospheric patterns, infer water balances or characterise the aquifer recharge. In this work, we characterised two post-summer precipitation events over the western sector of Sierra de Gádor through the analysis of the rainwater δ¹⁸O and δ²H ratios, ionic composition and, complementarily, remote sensing products to define the atmospheric circulation during the rainfall episodes. This information enabled us to discern the moisture source, formation conditions and orographic influence on the rain episodes, and to better define the origin of the groundwater recharge and its dynamics in the study area. Although the samples share a common moisture source (W Mediterranean), they display substantial differences in their isotopic compositions. Such differences are attributable to sub-cloud evaporation processes that mask their Mediterranean origin, and to the strong influence of the orography on the hydrochemical and isotopic characteristics of the rainfall at the local level. The groundwater presents a very stable isotopic content and is strongly depleted in heavy isotopes, evidencing that most of the aquifer recharge takes place at very high altitudes and primarily during winter, when the influence of evaporation is attenuated. Full article

The Perrot Spring (1300 m a.s.l.), located to the right of the Chalamy valley in the Monte Avic Natural Park (Valle d’Aosta, Italy), is an important source of drinking water for the municipality of Champdepraz. This spring is located on a large slope characterised by the presence of a Quaternary cover of various origins (glacial, glaciolacustrine, and landslide) above the bedrock (essentially serpentinite referred to the Zermatt–Saas Zone, Penninic Domain). Water emerges at the contact between the landslide bodies and impermeable or semi-permeable glaciolacustrine deposits. The aim of this study is to define the processes and recharge zones of this spring. The analysis of the data revealed the presence of two contributions to the Perrot Spring input: a spring thaw contribution defined by a small increase in flow and an autumn contribution from rainwater infiltration. The low average temperature and low variation of the annual temperature (4.8–6.5 °C) suggest a sufficiently deep flow circuit. Chemical analyses showed a groundwater chemistry consistent with the regional geology: the hydrochemical facies is calcium–magnesium bicarbonate and isotopic analyses (δ²H and δ¹⁸O) of rainfall and spring water suggested a recharge altitude of about 2100 m a.s.l. In conclusion, this study makes it possible to recognize the water inputs to the spring discharge and to delineate its recharge area, which can be proposed to implement strategies to protect the resource. Full article

Worldwide, there are great challenges for meteorological monitoring and glacier ablation monitoring in high-altitude mountain areas. It is often difficult to capture fine-scale climate and glacial changes in high-altitude mountainous areas due to the harsh natural environment and the extreme lack of observational sites. Based on high-altitude meteorological stations erected on the eastern shore of Aqikkule Lake (AQK) and at the terminus of Shenshechuan Glacier (SSG), as well as on mass balance data from SSG, the characteristics and correlation of temperature, solar radiation, relative humidity, precipitation, wind speed and direction of the two regions, and the mass balance in the ablation area of SSG from 30 May 2022 to 18 May 2023 were analyzed, and the average melting depth of SSG was simulated. The results indicate the following: (1) The average annual temperature of AQK and the terminus of SSG is −3.7 °C and −7.7 °C, respectively, and the vertical lapse rate of temperature in the summer half of the year is greater than that in the winter half of the year. Precipitation timing has a great influence on daily temperature differences. (2) Precipitation in both places is concentrated in summer; the glaciers in this area are of the summer recharge type, and precipitation has a significant reducing effect on the solar incident radiation and increases the relative humidity in this region. (3) AQK and SSG both have local circulation development, in the area of AQK all year round due to the lake effect, while the terminus of SSG only has the development of valley winds in the summer, being controlled in the winter by the westerly wind belt. (4) The average mass balance value of the ablation area of SSG was −1786 mm as measured by the range poles method. The average annual ablation depth of SSG simulated by using the empirical formula was 587–597 mm, which is not large compared with other glacier areas in the Tibetan Plateau, and it has the characteristics of typical continental-type glaciers. Full article

Quantifying the effects of alpine GMB (Glacier Mass Balance) on river runoff is an important content of climate change. Uncertainty exists in GMB monitoring when applying remote-sensing technology. There are several reasons for these uncertainties, such as terrain deviation co-registration among different topographic data, the mismatch between GSE (Glacier Surface Elevation) from satellite monitoring and the GMB that comprises the physical glacier properties, the driving factors of GMB, and the response patterns of the runoff within the basin. This paper proposed a method based on the ridge line co-registration of DEMs (Digital Elevation Models), and the Tailan River basin, which is a typical glacier melt runoff recharge basin located in the southern Tianshan Mountains, was selected. Abnormal values in GSE changes were removed using ice thickness data, and the GSE results were optimized based on the regularity of the GSE change with altitude to estimate the GMB. The driving factors of the GMB and the response characteristics of the runoff in the basin were also explored. The results showed that the accuracy of the optimized GSE results across different periods has improved by more than 25%. The mean annual thinning value of GSE in the basin from 2000 to 2022 was −0.25 ± 0.02 m·a⁻¹, corresponding to a GMB value of −0.30 ± 0.02 m w.e.a⁻¹, indicating a consistent GMB loss state. Combined with climate data, the glaciers in the basin were impacted by rising temperatures, and the smallest increase in annual precipitation in the basin was insufficient to compensate for the GMB loss. Moreover, in the past 22 years, glacier meltwater accounts for 46.15% of the total runoff in the Tailan River basin. Full article