Search Results (77)

Orogenic gold deposits host a substantial proportion of global gold resources, yet their internal alteration architecture and mineral assemblage variability are commonly reconstructed from random samples, limiting our ability to resolve along-profile zonation and its linkage to gold enrichment. Here we evaluate hyperspectral drill-core spectroscopy, integrated with surface spectroscopy and petrographic validation, as a rapid and spatially continuous approach to delineate alteration zoning in the Liba orogenic gold deposit (West Qinling Orogen, China). We acquired hyperspectral spectra (0.35–2.50 μm) from 255 evenly spaced surface points across two orebodies and from nine representative drill cores scanned at 1 m intervals, and organized the spectral dataset according to Au-grade domains (<0.05 g/t, 0.05–0.5 g/t, and >0.5 g/t). Spectra were quality controlled and interpreted using ENVI-based spectral library matching and The Spectral Geologist (TSG) processing workflows. Petrographic observations from 76 polished thin sections provide independent mineralogical constraints. The hyperspectral results resolve a systematic alteration progression from barren chlorite-dominated assemblages (Au-grade < 0.05 g/t) (locally with minor carbonate) through a weakly mineralized transition (Au-grade 0.05–0.5 g/t) characterized by diminishing chlorite and emergent kaolinite–carbonate with intensified sericitization, to an ore-grade (Au-grade > 0.5 g/t) assemblage dominated by kaolinite–sericite–carbonate–pyrite where biotite persists in distal and proximal zones but was progressively replaced by chlorite during subsequent hydrothermal stages; its modal abundance exhibits a clear inverse correlation with mineralization intensity. These results demonstrate that hyperspectral core scanning, coupled with targeted validation, can rapidly reconstruct a three-dimensional alteration architecture and provide practical mineralogical vectors for exploration targeting and process-oriented studies in orogenic gold systems. Full article

To constrain the Late Paleozoic tectonic evolution of Taiyuan Formation, we conducted detrital zircon U-Pb dating and Hf isotopes analysis. The U-Pb age spectra from ten sandstone samples (taken from both the top and bottom of the formation) display four major age groups of 2.6–2.4 Ga, 2.2–1.8 Ga, 496–421 Ma and 350–270 Ma with highest peaks at ca. 323 Ma and 443 Ma. Moreover, on the basis of the weighted mean age of the five youngest detrital zircons (293.0 ± 4.1 Ma), combined with published results, we propose that the Taiyuan Formation formed during the Early Permian. Comparison of detrital zircon U-Pb age spectra and Hf isotopic compositions with potential source regions indicates that the early Paleozoic zircons were largely derived from the North Qinling orogenic belt, whereas the late Paleozoic zircons originated from the Inner Mongolia uplift. This shift reveals a significant provenance change recorded in the Taiyuan Formation. The uplift of the northern North China Craton (Inner Mongolia uplift) is interpreted as a response to the resubduction of the Paleo-Asian Ocean during the Late Paleozoic. The resulting paleogeographic pattern—higher in the north and lower in the south—redirected sediment supply for the uppermost sandstone and overlying strata of the Taiyuan Formation in the Qinshui Basin from the earlier North Qinling orogenic belt to the Inner Mongolia uplift. Full article

The mechanisms driving the uplift and outward expansion of the Tibetan Plateau remain debated. The Qinghai Lake region at the plateau front, characterized by pronounced basin–range differential uplift, provides a key natural laboratory. Here, we first predict vertical deformation induced by the horizontal GPS velocity field and then construct a three-dimensional (3D) viscoelastic finite-element model to evaluate how lithospheric rheology shapes present-day 3D deformation. Horizontal GPS velocities predict higher uplift in the Songpan–Ganzi Terrane and the Qilian Orogen and lower values in the intervening basins, capturing the first-order basin–range pattern; the predicted uplift in the Qilian Orogen is ~1.0 mm/yr and agrees with observations, indicating that its dominant mechanism is crustal shortening and thickening. However, horizontal constraints alone leave vertical-velocity residuals of ~0.8–1.5 mm/yr in several localized areas, including the West Qinling Orogen, the southern Elashan region, the Qinghai–Nanshan region, and areas south of the Lenglongling Fault. Lateral rheological heterogeneity in the mid–lower crust, acting under mantle-flow drag, can better account for these residuals and more accurately reproduce the present 3D velocity field in the basin–range system. We further propose northeastward mid–lower crustal flow along a weak channel; when the flow is impeded by rigid domains (e.g., the Gonghe Basin and the Qinghai Lake Basin), it promotes material accumulation and localized deformation. These results support a hybrid mechanism that combines crustal shortening and mid–lower crustal flow for the Qinghai Lake basin–range system. Full article

Recent exploration has demonstrated significant prospecting potential at the Huayagou Au deposit in Longnan mineral Field, Gansu Province, West Qinling Orogen, Central China. However, the nature and evolution of the auriferous fluids responsible for gold enrichment remain poorly constrained, hindering effective exploration targeting of high-grade ores. In this study, apatite and tourmaline closely associated with gold mineralization are investigated as mineralogical recorders of fluid composition and evolution. Integrated petrographic observations, TIMA phase mapping, cathodoluminescence imaging, electron probe microanalysis, and in situ trace element analyses were used to distinguish magmatic, metamorphic, and syn-ore hydrothermal generations of apatite and tourmaline, together with in situ Nd isotopic analyses of apatite and B isotopic analyses of tourmaline. Syn-ore hydrothermal apatite is characterized by homogeneous blue cathodoluminescence, fluorapatite compositions, strong LREE depletion, and εNd(t) values overlapping those of Triassic magmatic apatite, whereas Early-Devonian magmatic and metamorphic apatites display more distinct signatures. Tourmaline records a systematic evolution from early dravite to late schorl, accompanied by trace element enrichment and a shift toward heavier δ¹¹B values. These mineralogical and isotopic features, together with published sulfur isotope constraints, indicate that gold mineralization at Huayagou was dominantly controlled by structurally focused metamorphic fluids, with localized Triassic magmatic–hydrothermal overprinting enhancing gold enrichment in high-grade ores. The Huayagou Au deposit is, therefore, best interpreted as an atypical orogenic gold system, highlighting enhanced exploration potential in structurally favorable zones at depth, particularly in the western part of the district where Triassic magmatism is inferred. Full article

The Yawan gold deposit, located in the Western Qinling Orogen, contains gold mineralisation that is predominantly controlled by approximately east-west-trending fault systems. This study integrates field geology, petrography, cathodoluminescence imaging, electron probe microanalysis of gold-bearing minerals (pyrite and arsenopyrite), and in situ laser ablation U-Pb dating of calcite to constrain the timing of mineralisation and to elucidate the mechanisms of gold enrichment. This study reveals that the deposit is significantly structurally controlled and comprises two discrete mineralisation stages: a quartz-pyrite (Py1)-arsenopyrite (Apy1)-chalcopyrite assemblage (Stage 1), and a quartz-calcite-pyrite (Py2)-arsenopyrite (Apy2)-stibnite-sphalerite-galena assemblage (Stage 2). Py1 displays distinct zonation, with rim As contents notably higher than core values, while Co and Ni contents gradually decrease from core to rim. Py2 is characterised by high As (0.00%–4.72%), low Fe/S ratios, and a porous texture, containing gold and arsenopyrite inclusions. Invisible gold occurs in lattice-bound form in both Py1 and Py2. The As-Fe-S ternary diagram of pyrite indicates that Au⁺ likely entered the crystal lattice as a solid solution. Arsenopyrite geothermometry yields a mineralisation temperature of 389 ± 44 °C, and sulfur fugacity (ƒS₂) decreased markedly from Stage 1 to Stage 2. Combined with the S and Fe characteristics of pyrite, these features support a medium-temperature metamorphic hydrothermal environment. U-Pb dating of calcite from Stage 2 yields an age of 215.6 ± 7.1 Ma. In summary, the Yawan gold deposit belongs to the orogenic gold system, with its gold precipitation and enrichment controlled by sulfidation triggered by Late Triassic tectono-fluid activity. Full article

There exists an east–west trending albitite (breccia) zone, approximately 400 km in length, closely related to gold mineralization, in Devonian strata in the South Qinling tectonic belt. The genesis and formation age of these albitite (breccia) are of great significance for understanding gold enrichment mechanisms and guiding future exploration. Past studies have mainly focused on the Fengxian–Taibai area in the western segment of the albitite (breccia) zone, whereas the eastern segment remains significantly understudied. In this study, a systematic field investigation, as well as petrology, geochemistry, and accessory-mineral geochronology studies were conducted on albitites and albitite breccias in the Shangnan area, the eastern segment of the albitite (breccia) zone. The results show that the albitites are interlayered with or occur as lenses within Devonian clastic rocks. The albitite breccias are mostly enclosed in albitite and Devonian strata, and the clasts within are subangular, uniform in type, and exhibit minimal displacement. Both albitites and albitite breccias exhibit similar trace-element characteristics and detrital zircon age spectra to those of Devonian clastic rocks. Abundant hydrothermal monazites with U–Pb ages ranging from 260 to 252 Ma are present in both albitites and albitite breccias but absent in Devonian clastic rocks. Collectively, these results indicate that the albitites in the Shangnan area are of hydrothermal metasomatic origin, while the albitite breccias record hydraulic fracturing and cementation, and both are products of the same fluid activity event in the Late Permian. We propose that albitite (breccia) zones in the South Qinling tectonic belt were formed under distinct tectonic settings during different evolution stages of the Late Paleozoic Mianlüe Ocean. Specifically, the albitites (breccias) in the Shangnan area are products of thorough metasomatism, local fracturing, and cementation of Devonian clastic rocks by mixed fluids, which ascended along the Fengzhen–Shanyang Fault coeval with the emplacement of magmatic rocks related to subduction of the Mianlüe Ocean. In contrast, the albitite breccias in the Fengxian–Taibai area are the result of fluid activity during the transition from regional compression to extension after the closure of the Mianlüe Ocean. Full article

The western Ordos Basin (OB) is situated at the junction of multiple tectonic units with distinct properties. The prolonged and complex tectonic interactions from adjacent tectonic units have resulted in diverse structural phenomena and intricate evolutionary history in this region. The late Paleozoic represents a critical period for the transition of the tectonic regime in this area. However, due to the effects of intense later-stage modification, the late Paleozoic provenance system and paleogeomorphology of this region remain poorly constrained. Against this background, systematic fieldwork and detrital zircon geochronological analyses of the Youjingshan and Quwushan Permian sections were conducted to determine sediment provenance, and spatial variations in detrital zircon geochronological characteristics across different parts of the OB are further discussed. The results indicate that the detrital zircon age spectra of the Permian Dahuangou and Yaogou formations in the Youjingshan and Quwushan sections are dominated by late Paleozoic (250–360 Ma), early Paleozoic (360–500 Ma), and Paleoproterozoic (1600–2500 Ma) age populations. However, significant differences in age composition are also observed among different samples. This study proposes that the detritus of the Dahuangou Formation in the Youjingshan area was mainly derived from the Alxa Block (AB), while that from the Yaogou Formation was sourced from the Yinshan-Daqingshan-Wulashan Orogenic Belt (YDWOB). In contrast, the West Qinling Orogenic Belt (WQOB) and North Qilian Orogenic Belt (NQOB) were identified as the source areas for the Dahuangou and Yaogou Formations in the Quwushan area. Based on a comprehensive comparison of detrital zircon geochronological data of the Permian strata in the OB, three major provenance systems can be identified: the southwestern source area (WQOB and NQOB); the northwestern source area (YDWOB and AB); and the interior source area (YDWOB). During the Permian, the tectonic-sedimentary evolution of the OB was primarily controlled by the combined effects of the Paleo-Asian Ocean (PAO) to the north and the Paleo-Tethys Ocean (PTO) to the south. Differences in the timing and intensity of subduction/collision between the PAO and the PTO resulted in a general paleogeographic pattern of “higher in the north and lower in the south” in the OB. Full article

The West Qinling Orogenic Belt (WQOB) contains a sedimentary succession that is approximately 15 km thick, spanning from the Carboniferous to the Jurassic period. This succession offers critical insights into the tectonic evolution of the Paleo-Tethys Ocean. While previous models have suggested various depositional environments, the late Paleozoic to Mesozoic tectonic evolution of the WQOB is still not fully understood. In this study, we incorporate new detrital zircon U-Pb age data and whole-rock geochemical analyses from six stratigraphic units, dating back to the Carboniferous to Triassic periods in the Xiahe–Hezuo region, alongside existing datasets. The detrital zircon age spectra from the WQOB reveal three distinct groups: Devonian–Carboniferous strata exhibit dominant Neoproterozoic (~800–900 Ma) zircon populations, whereas Permian–Triassic rock samples show prominent Paleoproterozoic (1840–1880 Ma) and Archean (2450–2500 Ma) peaks. A minor Neoproterozoic component in Permian spectra disappears by the Triassic, while Jurassic–Cretaceous assemblages lack Precambrian grains. These trends reflect evolving source terranes linked to Paleo-Tethyan subduction dynamics. Furthermore, the geochemical signatures of the Devonian–Triassic clastic rocks align with the composition of upper continental crust, indicating a tectonic relationship with continental island arcs and active continental margins. By synthesizing these findings with established detrital zircon ages, magmatic records, and geophysical data, we propose that the WQOB underwent pre-Triassic tectonic evolution that was marked by pre-Triassic subduction and localized extension during the process of continental underthrusting. Full article

The provenance of the Middle-Upper Permian in the Lintan and Jiangligou areas, remnants of rift basin sedimentation within the West Qinling, remains controversial, hindering understanding of the basin-range coupling evolution of the Qinling Orogenic Belt and its periphery. Heavy minerals, major and trace elements, rare earth elements, detrital zircon U-Pb dating, and in situ Lu-Hf isotopes were analyzed to determine the provenance of the Middle-Upper Permian sandstones. Results were integrated with previous studies to investigate basin-range coupling processes. The results reveal the following: (1) The Upper Member of the Shilidun Formation in the Lintan area was deposited during the Late Permian. Heavy minerals are dominated by moderately to highly stable species. Source rocks were derived from intermediate-acidic magmatic rocks and low- to medium-grade metamorphic terrains. The provenance was primarily situated in a continental island arc tectonic setting. Diverse source rock types were identified, including materials from felsic igneous, quartzose recycled, and mafic igneous provenances. Detrital zircon U–Pb age spectra display two major peak ages at 285 Ma and 442 Ma, along with five subordinate peaks at 818 Ma, 970 Ma, 1734 Ma, 1956 Ma, and 2500 Ma. The ε_Hf(t) values range from –44.95 to 42.67, and T_DM2 ages vary from 367 Ma to 4106 Ma. It is concluded that the sedimentary materials were mainly derived from the North Qinling Orogenic Belt, with minor contributions from the basement of the North China Craton. (2) In the Jiangligou area, the Shiguan Formation is characterized by highly and stable heavy minerals. The provenance is dominated by intermediate-acidic magmatic rocks, within an oceanic island arc tectonic setting. Detrital zircon U–Pb age spectrum displays a prominent peak at 442 Ma. The ε_Hf(t) values range from –0.5 to 10.55, with T_DM2 ages ranging from 744 Ma to 897 Ma. These results indicate that the sedimentary materials were derived from the North Qilian Orogenic Belt. (3) The Permian in the Western Qinling exhibit multi-provenance supply, dominated by the North Qinling Orogenic Belt and the North China Craton basement, with local contributions from the North Qilian Orogenic Belt. Significant regional variations in provenance contributions were identified. This study further constrains the closure of the Shangdan Ocean to pre-Late Permian. It reveals that the Western Qinling was situated in a back-arc rift basin setting during the Late Paleozoic. Key sedimentary evidence is provided for understanding the tectonic evolution of the Paleo-Tethys Ocean and the collision between the North China and Yangtze cratons. Full article

The evolution of ore-forming fluids in gold precipitation is a key aspect in understanding the genesis of orogenic gold deposits. Traditional fluid inclusion analyses are often limited in revealing the fluid property changes during mineralization, leading to significant debates on the mineralization temperature and fluid sources. In this study, we selected the Liba gold deposit in the West Qinling orogen and employed scanning electron microscope–cathodoluminescence (SEM-CL) and laser ablation–inductively coupled plasma mass spectrometry (LA-ICPMS) to analyze the microstructure and trace element characteristics of quartz veins, revealing the multi-stage evolution of ore-forming fluids and the mineralization mechanisms. SEM-CL imaging identified five distinct quartz stages. The pre-mineralization (Qz0) and early-stage mineralization (Qz1) fluids were predominantly magmatic–metamorphic in origin, as indicated by relatively high δ¹⁸O and δD values. During the primary metallogenic (Qz2a, Qz2b) and late-stage mineralization (Qz3), temperatures progressively decreased, and the gradual mixing of meteoric water and formation water was observed, which promoted gold precipitation. And the content of trace elements in post-mineralization quartz (Qz4) is significantly lower and similar to that in the Qz0 stage. Through the analysis of quartz trace elements (e.g., Al/Ti, Ge/Al ratios) and isotope data (δ18O = 8.25‰ to 12.67‰, δD = −119.1‰ to −79.8‰), the results indicate that the Liba gold deposit is a medium- to low-temperature orogenic gold deposit. Furthermore, the gold enrichment process was primarily driven by a hydrothermal system, with variations in the fluid composition during mineralization contributing to the concentration of gold. Full article

The Western Qinling Orogenic Belt, China’s second-largest Au-metallogenic province, hosts numerous polymetallic deposits, with gold resources particularly concentrated in the northwestern Xiahe–Hezuo area. The Changshitougounao gold deposit, located south of the Xiahe Fault, comprises disseminated ores controlled by near E–W-trending faults and is primarily hosted in quartz diorite and the Lower Triassic Longwuhe Formation. Zircon LA–ICP–MS U–Pb dating of fresh quartz diorite yields an age of 241.8 ± 2.6 Ma. Two generations of monazite were identified: type I magmatic monazite and type II hydrothermal monazite. Type I monazite is intergrown with feldspar, quartz, and biotite, and in situ LA–ICP–MS U–Pb analysis gives an age of 239.2 ± 2.2 Ma. Type II monazite occurs as irregular granular aggregates associated with Au-bearing sulfides and hydrothermal sericite, with an in situ U–Pb age of 230 ± 3.5 Ma. Apatite, also coeval with Au-bearing sulfides and type II monazite, yields an LA–ICP–MS U–Pb age of 230.9 ± 2.5 Ma and 230.7 ± 3.0 Ma. Zircon and type I monazite thus constrain the emplacement of the ore-bearing quartz diorite to ca. 240 Ma, whereas hydrothermal type II monazite and apatite constrain the timing of mineralization to ca. 230 Ma. The ~10 Ma interval between magmatism and mineralization indicates that goldmineralization in the Changshitougounao deposit is decoupled from Early Triassic magmatic activity. Integrating previous studies of the West Qinling geodynamic evolution, we infer that the Changshitougounao deposit formed during collisional orogenesis, in response to the closure of the Paleo-Tethys Ocean. Consequently, the Changshitougounao gold deposit is best classified as an orogenic gold system. Pyrite–arsenopyrite and sericite alteration serve as effective exploration vectors, and the contact zone between quartz diorite veins and slate represents a favorable structural setting for ore prospecting. Full article

Precise Re-Os isotopic ages of the Jinduicheng and Donggou Mo deposits in the East Qinling orogenic belt can shed light on the controversies about multiple-stage pulses of mineralization and further elucidate the genesis and metallogenic process of the deposits. In this study, we propose two major events of Mo mineralization in this orogenic belt occurring during the Late Mesozoic: the early stage of 156–130 Ma and late stage of 122–114 Ma. Results of molybdenite Re-Os isotopic analysis reveal that the Jinduicheng deposit formed at 139.2 ± 2.9 Ma, while the Donggou deposit exhibited two-stage mineralization at 115.4 ± 1.6 Ma and 111.9 ± 1.3 Ma. These isotopic ages align with the spatiotemporal evolution of coeval ore-barren granites exposed in eastern Qinling, pointing to a close genetic relationship between the magmatism and mineralization that was controlled by the same tectonic activity, likely in a post-collisional setting. This highlights the multiple-stage Mo mineralization and provides evidence for further understanding the geodynamics and metallogenic process in the eastern Qinling orogenic belt. Full article

High-purity quartz (HPQ), an indispensable industrial mineral, serves as a critical raw material for advanced technology sectors. Derived from natural quartz precursors through processing, HPQ preparation efficiency fundamentally depends on raw material selection. Two pegmatite samples (muscovite pegmatite and two-mica pegmatite) sampled from the eastern sector of the North Qinling Orogenic Belt were investigated through a suite of analytical techniques, as well as processing and purification, to evaluate their potential as raw materials for high-purity quartz. Muscovite pegmatite is predominantly composed of quartz, plagioclase, K-feldspar, muscovite, and garnet, with accessory phases including limonite and kaolinite. However, in addition to quartz, plagioclase, K-feldspar, muscovite, garnet, and limonite, two-mica pegmatite contains minerals such as biotite and calcite. The fluid inclusions in both muscovite and two-mica pegmatite quartz are small, but the former has fewer fluid inclusions. Compared with muscovite pegmatite, surface discontinuity (i.e., cracks, pits, cavities) development is more pronounced in two-mica pegmatite purified quartz, which may be related to its high content of fluid inclusions. Following purification, the total concentration of trace elements decreased significantly. However, the concentrations of Al and Ti appeared to remain the same. Titanium enrichment in purified two-mica pegmatite quartz likely derives from biotite, while Na and Ca concentrations may be related to fluid inclusions or microscopic mineral inclusions. The trace element content (27.69 ppm) in muscovite pegmatite is lower than that (45.28 ppm) of two-mica pegmatite, we thus suggest that muscovite pegmatite quartz is more likely to have the potential to produce high-purity quartz. Full article

This study investigates the provenance of the Permian Shihezi Formation (Fm) siliciclastic sediments in the Luonan area, southern margin of the North China Block, which constrain the sediment sources and tectonic evolution of the basin. Our research investigates the heavy mineral characteristics, geochemical features, detrital zircon U-Pb geochronology, and Lu-Hf isotope tracing the provenance characteristics of the Shihezi Fm in this region. Zircon yielded three distinct U-Pb age groups as follows: 320–300 Ma, 1950–1850 Ma, and 2550–2450 Ma. The ε_Hf(t) values of zircons ranged from −41 to 50, and the two–stage Hf model’s ages (T_DM2) values are concentrated between 3940 Ma and 409 Ma, suggesting that magmatic sources likely derive from Early Archaean–Devonian crustal materials. The heavy mineral assemblages are primarily composed of zircon, leucoxene, and magnetite. Further geochemical analyses of the rocks indicate a diverse provenance area and a complex tectonic evolution. Taken together, these results suggest that the provenance of the Shihezi Fm is from the North China Block, with secondary contributions from the Qinling Orogenic Belt and the North Qilian Orogenic Belt. The provenance of Luonan shares similarities with the southern Ordos Basin. Investigating the provenance of the Luonan area along the southern margin of the North China Craton provides critical supplementary constraints for shedding light on the Late Paleozoic tectonothermal events in the Qinling Orogenic Belt. Full article

Understanding ecological niche evolution patterns is crucial for elucidating biogeographic history and guiding biodiversity conservation. Taxus is a Tertiary relict gymnosperm with 11 lineages mainly distributed across East Asia, spanning from tropical to subarctic regions. However, the spatiotemporal dynamics of its ecological niche evolution and the roles of ecological and geographical factors in lineage diversification, remain unclear. Using occurrence records, environmental data, and reconstructed phylogenies, we employed ensemble ecological niche models (eENMs), environmental principle components analysis (PCA-env), and phyloclimatic modeling to analyze niche similarity and evolution among 11 Taxus lineages. Based on reconstructed Bayesian trees and geographical distribution characteristics, we classified the eleven lineages into four clades: Northern (T. cuspidata), Central (T. chinensis, T. qinlingensis, and the Emei type), Western (T. wallichiana, T. florinii, and T. contorta), and Southern (T. calcicola, T. phytonii, T. mairei, and the Huangshan type). Orogenic activities and climate changes in the Tibetan Plateau since the Late Miocene likely facilitated the local adaptation of ancestral populations in Central China, the Hengduan Mountains, and the Yunnan–Guizhou Plateau, driving their expansion and diversification towards the west and south. Key environmental variables, including extreme temperature, temperature and precipitation variability, light, and altitude, were identified as major drivers of current niche divergence. Both niche conservatism and divergence were observed, with early conservatism followed by recent divergence. The Southern clade exhibits high heat and moisture tolerance, suggesting an adaptive shift, while the Central and Western clades retain ancestral drought and cold tolerance, displaying significant phylogenetic niche conservatism (PNC). We recommend prioritizing the conservation of T. qinlingensis, which exhibits the highest PNC level, particularly in the Qinling, Daba, and Taihang Mountains, which are highly degraded and vulnerable to future climate fluctuations. Full article