Search Results (32)

The rapid increase in polystyrene (PS) production has led to substantial growth in plastic waste, posing serious environmental and waste management challenges. Current disposal techniques are unsustainable, relying heavily on harsh conditions, high energy input, and generating environmentally harmful byproducts. This review critically discusses alternative green approaches for PS treatment through photocatalytic and non-photocatalytic upcycling methods. Photocatalytic methods utilize light energy (UV, visible, or broad-spectrum irradiation) to initiate radical reactions that cleave the inert carbon backbone of PS. In contrast, non-photocatalytic strategies achieve backbone degradation without direct light activation, often employing catalysts and thermal energy. Both approaches effectively transform PS waste into higher-value compounds, such as benzoic acid and acetophenone, though yields remain moderate for most reported methods. Current limitations, including catalyst performance, low yields, and impurities in real-world PS waste, are highlighted. Future directions toward enhancing the efficiency, selectivity, and scalability of PS upcycling processes are proposed to address the growing plastic waste crisis sustainably. Full article

There has been an unprecedented demand for livestock production due to factors such as the ever-increasing population, limited resources (land, water, feed, etc.), and changing human lifestyles. Moreover, due to the interconnected nature of the world’s biodiversity crisis, pollution, and climate change, environmental sustainability is going to play a pivotal role in addressing these pressing issues. Because of their high nutritional value and environmental benefits compared to conventional livestock feeds, insects as animal feed have demonstrated great potential for long-term sustainability. The current state of the IBF application on ruminants is presented in this review, together with its challenges, future direction, and strength–weakness–opportunity–threat analysis. The results from many studies on ruminants have demonstrated that insect nutrients—primarily amino acids, protein, and fat—are highly digestible, safe, and beneficial to ruminant health and productivity. Additionally, they do not harm the ruminant fermentation and microbiota, even having the benefit of possibly lowering ruminant farms’ well-known methane emissions. Nevertheless, concerns continue to arise because this method is still relatively new and there is a lot of unexplored knowledge; as a result, regulation is not yet well established globally, which is a barrier to its implementation. Full article

Crop failure is defined as crop production that is significantly lower than anticipated, resulting from plants that are harmed, diseased, destroyed, or influenced by climatic circumstances. With the rise in global food security concern, the earliest detection of crop diseases has proven to be pivotal in agriculture industries to address the needs of the global food crisis and on-farm data protection, which can be met with a privacy-preserving deep learning model. However, deep learning seems to be a largely complex black box to interpret, necessitating a prerequisite for the groundwork of the model’s interpretability. Considering this, the aim of this study was to follow up on the establishment of a robust deep learning custom model named CropsDisNet, evaluated on a large-scale dataset named “New Bangladeshi Crop Disease Dataset (corn, potato and wheat)”, which contains a total of 8946 images. The integration of a differential privacy algorithm into our CropsDisNet model could establish the benefits of automated crop disease classification without compromising on-farm data privacy by reducing training data leakage. To classify corn, potato, and wheat leaf diseases, we used three representative CNN models for image classification (VGG16, Inception Resnet V2, Inception V3) along with our custom model, and the classification accuracy for these three different crops varied from 92.09% to 98.29%. In addition, demonstration of the model’s interpretability gave us insight into our model’s decision making and classification results, which can allow farmers to understand and take appropriate precautions in the event of early widespread harvest failure and food crises. Full article

Plastics are indispensable to modern life, but their widespread use has created an environmental crisis due to inefficient waste management. Mixed plastic waste, comprising diverse polymers, presents significant recycling challenges due to the high costs of sorting and processing, leading to ecosystem accumulation and harmful by-product generation. This study addresses this issue by engineering a synthetic bacterial consortium (SBC) designed to degrade mixed plastic monomers. The consortium pairs Escherichia coli Nissle 1917, which uses ethylene glycol (EG), a monomer derived from polyethylene terephthalate (PET), as a carbon source, with Pseudomonas putida KT2440, which metabolizes hexamethylenediamine (HD), a monomer from nylon-6,6, as a nitrogen source. Adaptive evolution of the SBC revealed a novel metabolic interaction where P. putida developed the ability to degrade both EG and HD, while E. coli played a critical role in degrading glycolate, mitigating its by-product toxicity. The evolved cross-feeding pattern enhanced biomass production, metabolic efficiency, and community stability compared to monocultures. The consortium’s performance was validated through flux balance analysis (FBA), high-performance liquid chromatography (HPLC), and growth assays. These findings highlight the potential of cross-feeding SBCs in addressing complex plastic waste, offering a promising avenue for sustainable bioremediation and advancing future polymer degradation strategies. Full article

Plastic waste (PW) presents a significant environmental challenge due to its persistent accumulation and harmful effects on ecosystems. According to the United Nations Environment Program (UNEP), global plastic production in 2024 is estimated to reach approximately 500 million tons. Without effective intervention, most of this plastic is expected to become waste, potentially resulting in billions of tons of accumulated PW by 2060. This study explores innovative approaches to convert PW into high-value carbon nanomaterials (CNMs) such as graphene, carbon nanotubes (CNTs), and other advanced carbon structures. Various methods including pyrolysis, arc discharge, catalytic degradation, and laser ablation have been investigated in transforming PW into CNMs. However, four primary methodologies are discussed herein: thermal decomposition, chemical vapor deposition (CVD), flash joule heating (FJH), and stepwise conversion. The scalability of the pathways discussed for industrial applications varies significantly. Thermal decomposition, particularly pyrolysis, is highly scalable due to its straightforward setup and cost-effective operation, making it suitable for large-scale waste processing plants. It also produces fuel byproducts that can be used as an alternative energy source, promoting the concept of energy recovery and circular economy. CVD, while producing high-quality carbon materials, is less scalable due to the high cost and required complex equipment, catalyst, high temperature, and pressure, which limits its use to specialized applications. FJH offers rapid synthesis of high-quality graphene using an economically viable technique that can also generate valuable products such as green hydrogen, carbon oligomers, and light hydrocarbons. However, it still requires optimization for industrial throughput. Stepwise conversion, involving multiple stages, can be challenging to scale due to higher operational complexity and cost, but it offers precise control over material properties for niche applications. This research demonstrates the growing potential of upcycling PW into valuable materials that align with global sustainability goals including industry, innovation, and infrastructure (Goal 9), sustainable cities and communities (Goal 11), and responsible consumption and production (Goal 12). The findings underscore the need for enhanced recycling infrastructure and policy frameworks to support the shift toward a circular economy and mitigate the global plastic crisis. Full article

Acting in accordance with the requirements of the 2015 Paris Agreement, Poland, as well as other European Union countries, have committed to achieving climate neutrality by 2050. One of the solutions to reduce emissions of harmful substances into the environment is the implementation of large-scale hydrogen technologies. This article presents the cost of producing green hydrogen produced using an alkaline electrolyzer, with electricity supplied from a photovoltaic farm. The analysis was performed using the Monte Carlo method, and for baseline assumptions including an electricity price of 0.053 EUR/kWh, the cost of producing green hydrogen was 5.321 EUR/kgH₂. In addition, this article presents a sensitivity analysis showing the impact of the electricity price before and after the energy crisis and other variables on the cost of green hydrogen production. The large change occurring in electricity prices (from 0.035 EUR/kWh to 0.24 EUR/kWh) significantly affected the levelized cost of green hydrogen (LCOH), which could change by up to 14 EUR/kgH₂ in recent years. The results of the analysis showed that the parameters that successively have the greatest impact on the cost of green hydrogen production are the operating time of the plant and the unit capital expenditure. The development of green hydrogen production facilities, along with the scaling of technology in the future, can reduce the cost of its production. Full article

Environmental regulation (ER) and internet development (ID) are important options for addressing the environmental health crisis, but the actual impact of both on public health outcomes (PHOs) is still unclear. This study aims to explain how and to what extent China’s ER and ID jointly affect PHO. This is especially important for enhancing the degree of coordination between ecosystems and socioeconomic systems and realizing a harmonious symbiotic relationship between human beings and nature. Unlike previous studies, this paper innovatively incorporates ER and ID into the Grossman health production function, establishing a research framework that includes these factors and their impact on PHO. We employed the provincial panel data from China to methodically analyze the importance of ER and ID in responding to environmental health crises and improving public health, so as to close the gaps in the literature. On the basis of the validation of pollution in China endangering PHO and having heterogeneous manifestations, this paper employed a moderating effect model to confirm that ER and ID can mitigate the harm pollution has on PHO. Furthermore, the two have both demonstrated considerable PHO improvement impacts, with the regional heterogeneity of ER’s PHO improvement effect being more pronounced. The usage of the spatial effects model proves that ER and ID have significant spatial performance. Furthermore, as the internet develops, the PHO-improving effects of both comprehensive ER and diverse environmental regulatory tools are becoming more pronounced. According to the study’s findings, the government should consider ER and ID as major policy alternatives for improving national health. We developed a policy framework that incorporates multiple measures to boost public health protection in the two, and which aids in the exploration and improvement of feasible solutions to improve public health levels. Full article

Phosphorus (P) is an important and irreplaceable macronutrient. It is central to energy and information storage and exchange in living cells. P is an element with a “broken geochemical cycle” since it lacks abundant volatile compounds capable of closing the P cycle. P fertilizers are critical for global food security, but the reserves of minable P are scarce and non-evenly distributed between countries of the world. Accordingly, the risks of global crisis due to limited access to P reserves are expected to be graver than those entailed by competition for fossil hydrocarbons. Paradoxically, despite the scarcity and value of P reserves, its usage is extremely inefficient: the current waste rate reaches 80% giving rise to a plethora of unwanted consequences such as eutrophication leading to harmful algal blooms. Microalgal biotechnology is a promising solution to tackle this challenge. The proposed review briefly presents the relevant aspects of microalgal P metabolism such as cell P reserve composition and turnover, and the regulation of P uptake kinetics for maximization of P uptake efficiency with a focus on novel knowledge. The multifaceted role of polyPhosphates, the largest cell depot for P, is discussed with emphasis on the P toxicity mediated by short-chain polyPhosphates. Opportunities and hurdles of P bioremoval via P uptake from waste streams with microalgal cultures, either suspended or immobilized, are discussed. Possible avenues of P-rich microalgal biomass such as biofertilizer production or extraction of valuable polyPhosphates and other bioproducts are considered. The review concludes with a comprehensive assessment of the current potential of microalgal biotechnology for ensuring the sustainable usage of phosphorus. Full article

Unprecedented plastic production has resulted in over six billion tons of harmful waste. Certain insect taxa emerge as potential agents of plastic biodegradation. Through a comprehensive manual and bibliometric literature analysis, this review analyses and consolidates the growing literature related to insect-mediated plastic breakdown. Over 23 insect species, representing Coleoptera, Lepidoptera, and 4 other orders, have been identified for their capacity to consume plastic polymers. Natural and synthetic polymers exhibit high-level similarities in molecular structure and properties. Thus, in conjunction with comparative genomics studies, we link plastic-degrading enzymatic capabilities observed in certain insects to the exaptation of endogenous enzymes originally evolved for digesting lignin, cellulose, beeswax, keratin and chitin from their native dietary substrates. Further clarification is necessary to distinguish mineralisation from physicochemical fragmentation and to differentiate microbiome-mediated degradation from direct enzymatic reactions by insects. A bibliometric analysis of the exponentially growing body of literature showed that leading research is emerging from China and the USA. Analogies between natural and synthetic polymer’s degradation pathways will inform engineering robust enzymes for practical plastic bioremediation applications. By aggregating, analysing, and interpreting published insights, this review consolidates our mechanistic understanding of insects as a potential natural solution to the escalating plastic waste crisis. Full article

In a constantly changing environment brought about by the climate crisis and escalated anthropogenic perturbations driven by the growing population, harmful algal bloom dynamics and their impacts are expected to shift, necessitating adaptive management strategies and comprehensive research efforts. Similar to primary productivity, HABs have been thought to be driven primarily by major nutrients such as N, P, and Si. However, recent investigations on the role and importance of micronutrients as limiting factors in aquatic environments have been highlighted. This paper provides a review of metal and phytoplankton interactions, with a specific emphasis on pertinent information on the influence of trace nutrients on growth, toxin production, and other underlying mechanisms related to the dynamics of HABs. Low to near-depleted levels of essential nutrients, including Fe, Cu, Zn, Se, Mn, Co, and Mo, negatively impact cell growth and proliferation of various marine and freshwater HAB species. However, evidence shows that at elevated levels, these trace elements, along with other non-essential ones, could still cause toxic effects to certain HAB species manifested by decreased photosynthetic activities, oxidative stress, ultrastructure damage, and cyst formation. Interestingly, while elevated levels of these metals mostly result in increased toxin production, Co (i.e., yessotoxins, gymnodimine, and palytoxins) and Mn (i.e., isodomoic acid, okadaic and diol esters) enrichments revealed otherwise. In addition to toxin production, releasing dissolved organic matter (DOM), including dissolved organic carbon (DOC) and humic substances, was observed as an adaptation strategy, since these organic compounds have been proven to chelate metals in the water column, thereby reducing metal-induced toxicity. Whilst current research centers on free metal toxicity of specific essential elements such as Cu and Zn, a comprehensive account of how trace metals contribute to the growth, toxin production, and other metabolic processes under conditions reflective of in situ scenarios of HAB-prone areas would yield new perspectives on the roles of trace metals in HABs. With the growing demands of the global population for food security and sustainability, substantial pressure is exerted on the agriculture and aquaculture sector, highlighting the need for effective communication of information regarding the interactions of macro- and micronutrients with HABs to improve existing policies and practices. Full article

The United States (US) opioid epidemic is a persistent and pervasive public health emergency that claims the lives of over 80,000 Americans per year as of 2021. There have been sustained efforts to reverse this crisis over the past decade, including a number of measures designed to decrease the use of prescription opioids for the treatment of pain. This study analyzed the changes in federal production quotas for prescription opioids and the distribution of prescription opioids for pain and identified state-level differences between 2010 and 2019. Data (in grams) on opioid production quotas and distribution (from manufacturer to hospitals, retail pharmacies, practitioners, and teaching institutions) of 10 prescription opioids (codeine, fentanyl, hydrocodone, hydromorphone, meperidine, methadone, morphine, oxycodone, oxymorphone, and tapentadol) for 2010 to 2019 were obtained from the US Drug Enforcement Administration. Amounts of each opioid were converted from grams to morphine milligram equivalent (MME), and the per capita distribution by state was calculated using population estimates. Total opioid production quotas increased substantially from 2010 to 2013 before decreasing by 41.5% from 2013 (87.6 MME metric tons) to 2019 (51.3). The peak year for distribution of all 10 prescription opioids was between 2010 and 2013, except for codeine (2015). The largest quantities of opioid distribution were observed in Tennessee (520.70 MME per person) and Delaware (251.45) in 2011 and 2019. There was a 52.0% overall decrease in opioid distribution per capita from 2010 to 2019, with the largest decrease in Florida (−61.6%) and the smallest in Texas (−18.6%). Southern states had the highest per capita distribution for eight of the ten opioids in 2019. The highest to lowest state ratio of total opioid distribution, corrected for population, decreased from 5.25 in 2011 to 2.78 in 2019. The mean 95th/5th ratio was relatively consistent in 2011 (4.78 ± 0.70) relative to 2019 (5.64 ± 0.98). This study found a sustained decline in the distribution of ten prescription opioids during the last five years. Distribution was non-homogeneous at the state level. Analysis of state-level differences revealed a fivefold difference in the 95th:5th percentile ratio between states, which has remained unchanged over the past decade. Production quotas did not correspond with the distribution, particularly in the 2010–2016 period. Future research, focused on identifying factors contributing to the observed regional variability in opioid distribution, could prove valuable to understanding and potentially remediating the pronounced disparities in prescription opioid-related harms in the US. Full article

Electronic vapor products (EVPs) are non-conventional tobacco products that use a battery to heat liquid, generating an aerosol to be inhaled by the user. Despite being initially proposed as a harm reduction tool for adults looking to quit conventional tobacco cigarettes, EVP usage has grown significantly in the adolescent population over the past decade. Data from the 2021 Youth Risk Behavior Survey (YRBS) show that currently, in the United States, 36% of adolescents have ever used an EVP, 18% currently use an EVP, and 5% use EVPs daily. Initial studies have raised concerns about the health effects on multiple organ systems (e.g., respiratory, cardiovascular, and neurodevelopmental), and little information is known about the long-term effects, as well as the impacts specific to the still-developing adolescent body. EVP usage in the adolescent population is a public health crisis. The purpose of this narrative review is to address what is known thus far and to advise areas of focus for future research and advocacy. Full article

Plastic waste is an environmental crisis that is becoming increasingly well-documented. The rapid expansion of plastic manufacturing and consumption has led to a harmful cycle of pollution and greenhouse gas emissions due to petroleum-based production and plastic waste disposal. Plastic production and disposal depend on the consumption behavior of people. This study aimed to examine the plastic consumption behavior in Thailand and its impact on climate change at the end-of-life stage. The general information, plastic consumption, and plastic waste management were collected via questionnaires for each product lifetime, including single-use, medium-use, and long-use plastics. Based on 567 questionnaires, the results showed that people consumed single-use plastic, e.g., plastic bag, food container, cutlery, straws, and bottles, at a rate of about nine pieces/household/day or three pieces/cap/day. The medium-use and long-use plastic were 10 pieces/household/month and 50 pieces/household/year, respectively. It should be remarked that population density, education, and number of household members affected plastic consumption behavior, especially for single-use plastic. Regarding the disposal of end-of-life plastics, Thai people, on average, contribute 0.15 kg CO₂eq/household/day to climate change. Many households have mismanaged waste by open dumping and open burning. Therefore, practicing proper waste management will help Thailand on the path to carbon neutrality in the future. Full article

The climate crisis, growing pollution of the environment with waste, and ubiquitous microplastics have encouraged the search for new methods and new opportunities to use natural materials in the least harmful processes. Replacing synthetic materials with raw materials is not only a matter of “fashion”, but also a necessity. Therefore, this study aimed to produce fibers from an aqueous solution containing the highest possible concentration of soy protein isolate (SPI) through solution-blowing. As the aqueous solution of SPI has no fiber-forming potential, polyethylene oxide (PEO) was used as the carrier/matrix. The rheology of the aqueous PEO solution and PEO/SPI blends (flow curves, loss modulus, and storage modulus) was then analyzed. The proportions of the PEO/SPI mixtures and the process parameters were determined on this basis. As a result of the conducted research, nanofibers were produced from water solutions of PEO/SPI with a soy protein content of up to 7.88%, with a PEO share of 1.25%. The average diameter of the obtained fibers was 225–495 nm, depending on the process parameters and SPI content—as the SPI content in the PEO/SPI mixture increased, the average fiber diameter decreased. The production of nanofibers with a high soy protein content increases their application possibilities. Firstly, due to a much larger surface area, and secondly, due to the presence of numerous functional groups in the protein structure, which can be a place of attachment for additional compounds that give the obtained nanofibers the desired properties. Full article

(1) Background: Synthetic cannabinoids (SCs) are emerging drugs of abuse sold as ‘K2’, ‘K9’ or ‘Spice’. Evidence shows that using SCs products leads to greater health risks than cannabis. They have been associated with greater toxicity and higher addiction potential unrelated to the primary psychoactive component of marijuana, Δ9-tetrahydrocannabinol (Δ9-THC). Moreover, early cases of intoxication and death related to SCs highlight the inherent danger that may accompany the use of these substances. However, there is limited knowledge of the toxicology of Spice ingredients. This systematic review intends to analyze the toxicity of SCs compounds in Spice/K2 drugs. (2) Methods: Studies analyzing synthetic cannabinoid toxicity and dependence were included in the present review. We searched the PubMed database of the US National Library of Medicine, Google Scholar, CompTox Chemicals, and Web of Science up to May 2022. (3) Results: Sixty-four articles reporting the effects of synthetic cannabinoids in humans were included in our review. Ten original papers and fifty-four case studies were also included. Fourteen studies reported death associated with synthetic cannabinoid use, with AB-CHMINACA and MDMB-CHMICA being the main reported SCs. Tachycardia and seizures were the most common toxicity symptoms. The prevalence of neuropsychiatric symptoms was higher in third-generation SCs. (4) Conclusion: SCs may exhibit higher toxicity than THC and longer-lasting effects. Their use may be harmful, especially in people with epilepsy and schizophrenia, because of the increased risk of the precipitation of psychiatric and neurologic disorders. Compared to other drugs, SCs have a higher potential to trigger a convulsive crisis, a decline in consciousness, and hemodynamic changes. Therefore, it is crucial to clarify their potential harms and increase the availability of toxicology data in both clinical and research settings. Full article