The recent years have brought significant challenges and changes in the energy sector in Poland and worldwide. Growing concerns related to adverse climate change, depletion of traditional fossil fuel sources, as well as increasingly stringent environmental regulations have contributed to taking steps towards green energy transformation.
Green transformation is the process of changing current energy production and consumption systems to be more environmentally friendly and sustainable. One of the main goals is to utilize renewable energy sources (RESs) and reduce carbon dioxide emissions into the atmosphere. A highly promising solution, feasible on a large scale, is the production of green hydrogen from RESs. Unlike the conventional method of hydrogen production from natural gas, green hydrogen is considered environmentally friendly because it does not emit greenhouse gases during production and usage [
1]. This hydrogen can be used in various forms of transportation, such as powering heavy-duty vehicles, ships, and aircraft, in the energy sector as an energy carrier, and also for energy storage purposes. Additionally, it finds applications in the chemical industry as a raw material for producing various chemicals, including ammonia or methanol [
1,
2].
There are many methods of hydrogen production, but to a greater or lesser extent, harmful substances are emitted into the atmosphere during their use, which negatively impacts the environment. The most desirable is green hydrogen, characterized by the cleanliness of its production.
Figure 1 illustrates the schematic of green hydrogen production using an electrolyzer. Water enters the water treatment station, where it is appropriately purified and deionized and then directed to the electrolyzer. There, under the influence of supplied electrical energy from renewable sources such as wind farms or solar panels, water is split into hydrogen and oxygen. The resulting products are then either stored/transported in tanks or immediately used in further processes [
4,
5].
Several types of electrolyzers with different characteristics available on the market can be distinguished:
Choosing the right type of electrolyzer and optimizing its parameters can have a major impact on the cost of green hydrogen production. The prices of alkaline electrolyzers and PEMs are projected to decrease in the coming years due to the synergy of research and development initiatives and the learning of this technology over time [
9]. In Publication [
9], the authors analyzed the economic and competitive dynamics of alkaline electrolyzers and PEMs in relation to the developing hydrogen economy. The authors examined the cost reduction potential of alkaline and PEM electrolyzers by 2050, which was 77% and 79%, respectively. Additionally, the study concluded that proton exchange membrane electrolyzers will dominate alkaline electrolyzers. Despite the positive outlook for falling prices of electrolyzers, research should still be conducted on increasing their efficiency, which, together with the price of RES electricity, is most likely to contribute to the falling price of hydrogen production in electrolysis. In addition, material science research is important as it can help replace expensive materials with cheaper ones and improve the strength of the installation [
10,
11].
Another important aspect is the scale of electrolyzers under construction, which is highly related to capital expenditures. Electrolyzers with a capacity of 200 kW can have up to 2.3 times higher costs than electrolyzers with a capacity of 1 MW [
10]. Mass production will result in lower costs, which will have a positive impact on LCOH. The authors of Publication [
10] estimate that by 2030, capital expenditures of electrolyzers operating on a large industrial scale could drop to 240 EUR/kW and, by 2050, to 80 EUR/kW.
Green Hydrogen in the Market
In recent years, green hydrogen has played a crucial role in decarbonizing the energy sector and reducing environmental impact. Based on renewable energy sources, it enables the creation of a sustainable economy, contributing to the reduction in greenhouse gas emissions.
According to the report from the International Energy Agency (IEA) [
12], global hydrogen production from all sources reached 95 Mt in 2022, with electrolysis-based hydrogen production being relatively low, below 100 kt. Such low production is attributed to its high manufacturing costs. Currently, the cost of producing green hydrogen is about 4.5 EUR/kgH
2, while the cost of producing hydrogen using fossil fuels with CCS is twice as cheap [
11].
The cost of producing green hydrogen is mainly dependent on the price of purchasing electricity from renewable energy sources. Over the past decade, there has been a noticeable dynamic development in renewable energy sources, and this trend continuing in the coming years could lead to a significant reduction in the production cost of green hydrogen.
Table 2 shows the average production cost of green hydrogen for two sources of supplied energy: wind farms and photovoltaic systems based on [
13].
The production cost of green hydrogen for electricity supplied from a wind farm in 2020 was 2.35 EUR/kgH
2 cheaper compared to when the energy was supplied from photovoltaic panels. In the forecasts for 2030 and 2050, this difference decreases to only about 0.4 EUR/kgH
2 [
13].
Many publications present the present and projected costs of green hydrogen production for different countries of the world. Due to the geographical location of each country, the conditions for the production of renewable energy, and thus hydrogen using this energy, are different. In Article [
14], the authors presented, among other things, a techno-economic analysis of green hydrogen production in Australia. They estimated that currently, LCOH ranges from 7.32 EUR/kgH
2 to 9.12 EUR/kgH
2 using wind and solar. The authors estimate that in the next few years, there will be a sharp decline in the capital expenditures of electrolyzers, the price of electricity from solar farms, and, consequently, the cost of producing green hydrogen, which is expected to be 6.27 EUR/kgH
2 and 3.23 EUR/kgH
2 by 2030 and 2040, respectively. In the case of reducing electricity prices from wind farms, LCOH is likely to be 5.04 EUR/kgH
2 and 2.76 EUR/kgH
2 by 2030 and 2040, respectively.
Article [
15] presents the competitiveness of green hydrogen production using Power To X technology in Germany and Saudi Arabia for 2030 and beyond. The authors analyzed 16 different scenarios in which the average cost of hydrogen production was 2.23–2.93 EUR/kgH
2 in Saudi Arabia and 2.9–3.5 EUR/kgH
2 in Germany. The analysis showed that despite the additional transportation costs (at an assumed price of 0.95 EUR/kgH
2 it is more cost-effective to supply green hydrogen from Saudi Arabia to Germany than to produce it there. These countries, due to their diverse geographic locations, differ in terms of the predominant type of RES power generation facilities. The publication notes that Germany mainly uses wind farms to produce electricity, while Saudi Arabia uses solar f0arms. The different capital expenditures of these two installations also had an impact on the final cost of green hydrogen production. It was estimated that the investment requirements for green hydrogen production in Saudi Arabia are 25% less than in Germany.
The scalability of green hydrogen production mainly depends on the availability of cheap electricity from renewable energy sources. The decline in the price of energy from these sources over the next few years will have a huge impact on increasing the competitiveness of hydrogen produced with electrolyzers compared to other methods, which are less environmentally friendly. The current forecasts for the price of electricity from RES create promising prospects for the profitability of green hydrogen production. Since 2015, a gradual downward trend has been observed in the cost of hydrogen produced by electrolysis due to the reduced costs of RES electricity and a decrease in the cost of capital expenditures for the electrolyzer [
16]. In the context of green hydrogen production, energy storage facilities should not be forgotten either. They are essential for optimizing and stabilizing the process of green hydrogen production, which relies on sources with variable and time-unstable energy generation, such as wind power and solar power [
9,
17,
18].
The utilization of green hydrogen in transportation has contributed to the dynamic expansion of hydrogen refueling stations in Europe and worldwide. In Poland, as of December 2023, there are currently three green hydrogen stations located in Rybnik, Warszawa, and Solec Kujawski, respectively. While the first two are available to all users, the latter was established for internal use by the Solbet company. The Solbet station produces hydrogen through electrolysis based on wind turbines located on the company’s premises, situated less than 100 m away from the refueling point [
19,
20,
21]. The station in Rybnik was established as a result of signing a contract for the delivery of 20 hydrogen buses by NESO (Zero Emission, Cleansing), which started operating in the city in October 2023. The selling price of green hydrogen at the stations in Rybnik and Warsaw is currently 69 PLN/kg (15.62 EUR/kg) [
19,
22,
23]. The average selling prices of green hydrogen in the European Union are lower than in Poland and range from 3.7 to 11 EUR/kg hydrogen [
24]. In Germany, at H
2 Mobility stations, starting from October 1st, the price of green hydrogen depends on the level of refueling pressure. For refueling hydrogen under 700 bar pressure, the price is 11 EUR/kg; meanwhile, for refueling at a lower pressure of 350 bar, the price is 9.5 EUR/kg [
25,
26]. The selling prices of green hydrogen in Poland, unlike other European countries, may vary significantly due to Poland’s heavy reliance on fossil fuels. Poland had a tougher start in the green energy transformation compared to other European countries; however, in recent years, significant progress has been made in reducing the environmental impact of various sectors and increasing the share of renewable energy sources in the overall energy mix [
27].
The aspect of green hydrogen production and utilization is addressed in many publications. The authors of Article [
28] presented a study of detailed cost and potential curves for green hydrogen for selected 28 countries until 2050. The analyses carried out show a very high hydrogen potential for African and Middle Eastern countries due to geographic locations characterized by high insolation. The results obtained were compared by the authors with the results of the IRENA study and were shown to be higher, influenced by the difference in CAPEX assumptions, WACC, and electrolyzer efficiency. For example, for Australia, the paper’s authors estimated that by 2050, green hydrogen will cost 2.6 EUR/kg, while IRENA estimates this cost at 0.8 EUR/kg.
Green hydrogen can have a wide range of end uses. In Article [
29], the authors presented an analysis of systems for substitute natural gas (SNG) and methanol production. An essential component of both these systems is a hydrogen generator, which is powered by surplus electricity from renewable energy sources. In addition, it is worth mentioning that the carbon dioxide used in the process is extracted using carbon capture and storage (CCS) technology from the flue gas of a conventional coal-fired power plant. The article examines the effect of changing parameters on changing the efficiency of SNG and methanol production and the possibility of increasing it using organic Rankine cycle (ORC) modules in both cases. It was shown that the use of ORC modules increases the efficiency of hydrogen and CO
2 conversion.
The economic aspects of producing renewable methanol from green hydrogen and carbon dioxide captured using CCS technology are presented by the authors in Article [
30]. The publication compared the prices of the various methanol production processes. It was estimated that the cost of producing methanol from renewable energy sources is the most expensive of all the production technologies analyzed, at 600–1450 EUR/t. The cost of producing methanol from fossil fuels is only 200–250 EUR/t. The high price and its fluctuations when producing methanol with an electrolyzer are influenced by the price of electricity from RES, which affects the price of hydrogen. The publication presents and compares the prices of electricity produced through various renewable energy sources.
Publication [
31] analyzed the cost of producing methanol from green hydrogen. The authors showed that the production of methanol from green hydrogen is more expensive than conventional production and calculated that the cost of producing renewable methanol is 1280 USD/t (1195 EUR/t). In addition, they estimated that the price of renewable methanol production is the most influenced by the price of hydrogen and the least influenced by capital expenditures. Despite the higher price, the method has many environmental benefits and will help reduce carbon dioxide emissions.