Search Results (55)

The long-term reliability of XLPE submarine cable insulation is influenced by progressive thermal degradation during operation and subsequent seawater ingress caused by external damage. Although thermal aging and seawater exposure have been widely investigated individually, the influence of the prior thermal-aging state on the subsequent seawater-induced degradation behavior of XLPE remains insufficiently understood. In this study, XLPE insulation specimens prepared from the same commercial compound used for 500 kV submarine cables were subjected to sequential accelerated aging consisting of controlled thermal pre-aging followed by simulated seawater exposure. Broadband dielectric spectroscopy, AC breakdown testing with two-parameter Weibull analysis, scanning electron microscopy (SEM), and Fourier-transform infrared spectroscopy (FTIR) were employed to investigate the evolution of electrical properties, surface morphology, and molecular structure. The results demonstrate that seawater-induced electrical deterioration strongly depends on the initial thermal-aging state of XLPE. Increasing thermal pre-aging duration resulted in progressively higher relative permittivity and dielectric loss, together with reduced characteristic breakdown strength after subsequent seawater exposure. Under the most severe condition of 1440 h thermal pre-aging followed by 672 h seawater exposure, the power–frequency relative permittivity increased by 32.1%, while the characteristic breakdown strength decreased by more than one-third compared with the initial state. SEM observations revealed that thermally pre-aged specimens developed accelerated surface damage during seawater exposure, including pores, cracks, corrosion pits, and honeycomb-like structures. FTIR analysis further indicated molecular-chain degradation and increased hydroxyl-related species during sequential aging. These results suggest that thermal-aging-induced molecular oxidation, polar-group formation, and microstructural defects enhance water and ion penetration pathways, thereby increasing the susceptibility of XLPE insulation to subsequent seawater-induced degradation. This study provides material-level experimental evidence for understanding sequential aging processes in submarine cable insulation and highlights the importance of considering historical thermal damage in future condition assessment and lifetime evaluation models. Since accelerated laboratory conditions were adopted, the results should be interpreted as comparative degradation characteristics rather than direct predictions of field-service lifetime. Full article

This paper presents a method for estimating moisture content (%MC) in power transformers. It primarily relies on the analysis of the statistical properties of relaxation times characterizing the dielectric frequency response (DFR), which is fitted as a sum of rational functions using the Vector Fitting (VF) tool. The DFR is modeled as a sum of Debye terms (accounting for materials exhibiting different relaxation times due to multiple polarization processes) characterized by poles and residues provided by VF. These parameters are then used to derive statistical factors that correlate with the shape of the dielectric response curve in the context of the Havriliak–Negami (HN) model, which is known for its effectiveness in characterizing materials with multiple relaxation times. By correlating the statistical factors with the HN model parameters, substantial insights into the insulation condition can be achieved. A moisture index (MI) is proposed from these parameters, which, when combined with conductivity, allows for accurate %MC estimation in the solid insulation system (cellulose). The combined MI and conductivity capture combined effects on moisture behavior, addressing both conductivity and polarization losses at different frequencies. The proposed method provides an efficient and straightforward non-invasive approach to insulation assessment without complex optimization algorithms. Experimental work on transformers at varying moisture levels provides validation of the proposed approach and demonstrates strong correlation with industry standards. The results confirm its reliability for moisture evaluation in transformer monitoring. Full article

This paper reviews emerging dielectric fluids for power transformers, including natural and synthetic esters, silicone oils, gas-to-liquid oils, and nanofluids, driven by environmental regulations, fire safety concerns, and the need for extended asset life. The review synthesizes technical data from standards and field experience, including a case study of an Eskom transformer energized in 2016 with natural ester fluid. Analysis confirms these fluids offer significant benefits in fire safety, biodegradability, and dielectric performance, with the case study demonstrating natural esters’ effectiveness in preserving solid insulation. However, trade-offs involving cost, material compatibility, and operational protocols require careful management. Full article

Industrial production still relies heavily on thermal processes that predominantly use fossil fuels for energy. This has significant consequences for primary energy use and greenhouse gas emissions. Meanwhile, rapid advances in electrotechnologies—defined as processes that use electrical energy to transform materials through internal heat dissipation (inductive, conductive, or dielectric/microwave) or heat transfer via resistance and infrared systems—are paving the way for a transition to a non-fossil fuel-based energy supply across a wide range of temperatures and power densities. However, replacing fuel with electricity is not simply a case of making a straightforward substitution; the feasibility of this change is determined by process requirements, constraints on installation space and grid connection, the reliability and volatility of the electricity supply, and economics. This paper therefore proposes a simple, decision-oriented methodology to assess the feasibility of defossilisation from energetic and economic perspectives. The methodology centres on a “substitution coefficient” that compares the amount of fossil energy substituted by a given amount of electrical energy and benchmarks this against the primary energy intensity of electricity generation. The methodology is demonstrated using case studies from energy-intensive sectors such as cement production (using resistance and microwave methods), steel strip processing (with inductive boosting combined with resistive holding) and metal melting for cast iron and aluminium. The case studies show under which conditions electrification can be implemented as a drop-in substitute, a hybrid booster or an enabler of new production models. The results indicate where electrotechnologies can deliver primary energy savings and CO₂ reductions today and outline the conditions under which their advantages will increase as power systems become more decarbonised. Full article

Monodisperse mesoporous hollow silica microcapsules present unique opportunities for advanced optical characterization due to their tunable nanostructure, high porosity and easy functionalization. A critical and challenging parameter in the optimization of these applications is the accurate determination of the effective refractive index, which governs light propagation and confinement within the nanostructured matrix of such mesoporous materials. In this study, individual mesoporous hollow silica microcapsules doped with Rhodamine B dye were analysed optically by exploiting whispering gallery mode (WGM) resonances, enabling non-destructive, single-particle refractometry with nanostructural sensitivity. Fourier Transform analysis of the fluorescence emission spectra revealed sharply defined, periodically spaced WGM peaks. For microcapsules with an 88 $\mu$m diameter, the measured intermodal spacing ($\Delta \lambda = 1.296$ nm) yielded an effective refractive index of 1.164. The measured value of the effective refractive index was cross-validated using Lorenz–Lorentz and Bruggeman effective medium models, both predicting porosity values (~63%) that closely match independent Brunauer–Emmett–Teller (BET) nitrogen adsorption measurements. The excellent agreement between optical and adsorption-based porosity demonstrates that WGM spectroscopy combined with Fourier analysis is a powerful, label-free, and non-invasive technique for correlating nanoscale porosity with macroscopic optical properties. This approach is widely applicable to single-particle analyses of nanostructured dielectric materials and opens new possibilities for in situ optical metrology in the development of advanced photonic, catalytic, and biomedical platforms. Full article

In the power industry, various electrically insulating materials are used to ensure proper mechanical, thermal, and dielectric performance over decades of equipment operation. In power transformers, cellulose is the predominant material in manufacturing various insulation components. Most of these products are manufactured by wet-molding technology. However, this process is long, labor-intensive, and highly energy-demanding. Under the frame of an EU-funded grant, a new kind of insulation material and manufacturing process were developed. Fully bio-based material (produced in the form of pellets) can be processed using additive manufacturing, allowing for much shorter manufacturing times for insulation products, with considerably less scrap and energy consumption (due to the elimination of the drying stage). The focus of the project was extrusion additive manufacturing technology, but at a later stage, a biomaterial powder was developed, making it possible to print with other technologies. In the paper, comparative studies on various additive manufacturing techniques of newly developed biopolymers have been presented, including extrusion, High Speed Sintering (HSS), and Selective Laser Sintering (SLS). The applicability of such material in power transformers required extensive testing of various properties. These results are discussed in the paper and include: oil compatibility, volume resistivity measurements, permittivity and dissipation factor measurements, determination of partial discharge inception voltage, partial discharges measurement, and breakdown voltage measurements. Although mechanical properties remain below industrial targets, the pioneering results provide a promising route for unique directions toward more sustainable manufacturing of high-voltage cellulose insulation and ideas for improving the material properties during the printing process. Full article

Power transformer insulation systems, composed of liquid and solid insulators, are continuously exposed to thermal and electrical stresses that degrade their performance over time and may lead to premature failure. Since these stresses are unavoidable during operation, selecting effective insulating materials is critical for long-term reliability. In this study, Kraft insulation paper was used as the solid insulator and impregnated with three different liquids: mineral oil and two natural esters (NE1204 and NE1215), to evaluate their stability under simultaneous thermal and electrical stress. The degradation behavior of the oil-impregnated papers was assessed using frequency-domain dielectric spectroscopy (FDS) and Fourier-transform infrared spectroscopy (FTIR), enabling early fault detection. Comparative analyses were conducted to evaluate the withstand capability of each liquid type during operation. Results revealed strong correlations between FTIR indicators (e.g., oxidation and hydroxyl group loss) and dielectric parameters (permittivity and loss factor), confirming the effectiveness of this combined diagnostic approach. Post-aging breakdown analysis showed that natural esters, particularly NE1215, offered superior preservation of insulation integrity compared to mineral oil. Differences between the two esters also highlight the role of chemical composition in insulation performance. This study reinforces the potential of natural esters as viable, eco-friendly alternatives in thermally and electrically stressed applications. Full article

The ongoing electrification process also requires improvements in the efficiency of power transmission devices, such as transformers, the main part of which is the magnetic core. Despite great progress in the development of core material, losses and audible noise during their operation is still a critical issue to be solved. Currently, a magnetic material used to produce the transformer core is amorphous steel, which is gaining popularity. Compared to traditionally used grain-oriented silicon electrical steel, a significantly larger number of very thin amorphous ribbons is needed to produce the core, which is due to the fact that they are about an order of magnitude thinner, making mechanical stability a challenge. The presented article describes the preparation of a hybrid binder for amorphous steel based on the two types of silanes, tetraethyl orthosilicate and 1,2-bis(triethoxysilyl)ethane, for which their anticorrosive character and good dielectric properties were confirmed. Using the obtained binders, model toroidal cores were produced and their magnetic and acoustic properties were tested. The obtained results indicate that the applied silane-based hybrid binders improved important functional properties by reducing the magnetic no-load losses and audible noise. Full article

The reliability of the electrical grid is vital to economic prosperity and quality of life. Power transformers, key components of transmission and distribution systems, represent major capital investments. Traditionally, these machines have relied on petroleum-based mineral oil as an insulating liquid. However, with a global shift toward sustainability, renewable insulating materials like natural esters are gaining attention due to their environmental and fire safety benefits. These biodegradable liquids are poised to replace hydrocarbon-based oils in transformers, aligning with Sustainable Development Goals 7 and 13 by promoting clean energy and climate action. Despite their advantages, natural esters face challenges in high-voltage applications, particularly due to oxidation stability issues linked to their fatty acid composition. Various antioxidants have been explored to address this, with synthetic antioxidants proving more effective than natural ones, especially under high-temperature conditions. Their superior thermal stability ensures that natural esters retain their cooling and dielectric properties, essential for transformer performance. Furthermore, integrating machine learning and artificial intelligence in antioxidant development and monitoring presents a transformative opportunity. This review provides insights into the role of antioxidants in natural ester-filled power equipment, supporting their broader adoption and contributing to a more sustainable energy future. Full article

Contact electrification (CE) spans from atomic to macroscopic scales, facilitating charge transfer between materials upon contact. This interfacial charge exchange, occurring in solid–solid (S–S) or solid–liquid (S–L) systems, initiates radical generation and chemical reactions, collectively termed contact-electro-chemistry (CE-Chemistry). As an emerging platform for green chemistry, CE-Chemistry facilitates redox, luminescent, synthetic, and catalytic reactions without the need for external power sources as in traditional electrochemistry with noble metal catalysts, significantly reducing energy consumption and environmental impact. Despite its broad applicability, the mechanistic understanding of CE-Chemistry remains incomplete. In S–S systems, CE-Chemistry is primarily driven by surface charges, whether electrons, ions, or radicals, on charged solid interfaces. However, a comprehensive theoretical framework is yet to be established. While S–S CE offers a promising platform for exploring the interplay between chemical reactions and triboelectric charge via surface charge modulation, it faces significant challenges in achieving scalability and optimizing chemical efficiency. In contrast, S–L CE-Chemistry focuses on interfacial electron transfer as a critical step in radical generation and subsequent reactions. This approach is notably versatile, enabling bulk-phase reactions in solutions and offering the flexibility to choose various solvents and/or dielectrics to optimize reaction pathways, such as the degradation of organic pollutants and polymerization, etc. The formation of an interfacial electrical double layer (EDL), driven by surface ion adsorption following electron transfer, plays a pivotal role in CE-Chemical processes within aqueous S–L systems. However, the EDL can exert a screening effect on further electron transfer, thereby inhibiting reaction progress. A comprehensive understanding and optimization of charge transfer mechanisms are pivotal for elucidating reaction pathways and enabling precise control over CE-Chemical processes. As the foundation of CE-Chemistry, charge transfer underpins the development of energy-efficient and environmentally sustainable methodologies, holding transformative potential for advancing green innovation. This review consolidates recent advancements, systematically classifying progress based on interfacial configurations in S–S and S–L systems and the underlying charge transfer dynamics. To unlock the full potential of CE-Chemistry, future research should prioritize the strategic tuning of material electronegativity, the engineering of sophisticated surface architectures, and the enhancement of charge transport mechanisms, paving the way for sustainable chemical innovations. Full article

Polypropylene (PP) membranes have found diverse applications, such as in wastewater treatment, lithium-ion batteries, and pharmaceuticals, due to their low cost, excellent mechanical properties, thermal stability, and chemical resistance. However, the intrinsic hydrophobicity of PP materials leads to membrane fouling and filtration flux reduction, which greatly hinders the applications of PP membranes. Dielectric barrier discharge (DBD) is an effective technique for surface modification of materials because it generates a large area of low-temperature plasma at atmospheric pressure. In this study, O₂ was added to nanosecond pulsed Ar DBD to increase its reactivity. Electrical and optical diagnostic techniques were used to study the discharge characteristics of the DBD at varying O₂ contents. The uniformity of the discharge was quantitatively analyzed using the observed discharge images. Water contact angle measurements were used to assess the surface hydrophilicity of polypropylene. The surface morphology and chemical composition of the PP materials before and after treatment were analyzed using field emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), Fourier-transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). The results show that the moderate addition of O₂ enhances surface hydrophilicity and the uniformity of the modification. By increasing the O₂ addition from 0% to 0.1%, the average power increased from 4.19 W to 5.79 W, and the energy efficiency increased from 17.78% to 21.51%. The water contact angle of the DBD-treated PP showed a tendency to decrease and then increase with increasing O₂ content, with the optimum O₂ addition determined to be 0.1%. Under this condition, the water contact angle of the PP surface decreased by 31.88°, which is 52.31% lower than the untreated surface. O₂ increases the number of oxygen-containing polar groups (-OH, C=O, and O-C=O) on the surface of the material, and deepens and densifies the grooves on the surface of the PP material, resulting in an increase in the hydrophilicity of the PP surface. Full article

When the power converter connects to the high-frequency transformer breaks through the bottleneck and reaches a frequency of 100 kHz or even higher, the high-frequency transformer’s inter-turn insulation faces more serious high-frequency discharge and high-temperature problems. In order to improve the service performance of oil-immersed high-frequency transformer insulation paper, composite K-BNNS particles are prepared by ultrasonic stripping, heat treatment, and thermomagnetic stirring. Then, K-BNNS particles are mixed with PMIA (polymeric m-phenylenediamine solution) slurry to produce composite aramid paper. And the effects of K-BNNS particles with different contents on the thermal conductivity, dielectric properties, partial discharge properties, and mechanical properties of aramid paper are explored. It can be found that, when the addition of composite particles (K-BNNS) is 10%, the comprehensive performance of composite aramid paper is the best. Compared with Nomex paper, the in-plane and through-plane thermal conductivity of composite insulating paper F-10 increased by 668.33% and 760.66%, respectively. Moreover, the high-frequency breakdown voltage increased by 48.73% and the tensile strength increased by 2.49%. The main reason is that the composite particles form a complete thermal conductive network in the aramid paper matrix and a large number of hydrogen bonds with the matrix, which enhances the internal interface bonding force of the material and changes the charge transport mechanism. Full article

To eliminate the problem of the aging of cellulose insulation in the manufacturing stage, a new drying method is being developed based on the use of methanol vapors. Previous studies have shown that the complete removal of methanol from the cellulose insulation after the drying process is very difficult. Therefore, it is necessary to check how the remaining methanol after drying affects the properties of both the cellulose materials and mineral oil. To conduct such studies, it is necessary to know the methanol content in oil that can be expected depending on its initial content in the cellulose materials and the temperature of the insulation system. Therefore, the main goal of this work is to develop methanol equilibrium curves for oil–paper insulation. To achieve the assumed goal, three-stage studies were conducted. A gas chromatograph equipped with a flame ionization detector was used in all stages of these studies. The gas partition coefficient between oil and air was determined for a temperature of 70 °C. The key experimental finding was the development of methanol equilibrium curves for oil–paper insulation. Thanks to this achievement, it is possible to estimate the methanol content in cellulose materials and mineral oil depending on the insulation temperature. Such data are necessary, among others, to plan appropriate studies aimed at assessing the impact of methanol content on the dielectric and physicochemical properties of these materials, important from the point of view of the operation of power transformers. Full article

In general, a high voltage (HV) substation can be made up of multiple insulation subsystems: an air insulation subsystem (AIS), gas insulation subsystem (GIS), liquid insulation subsystem (power transformers), and solid insulation subsystem (power cables), all of them with their grounding structures interconnected and linked to the substation earth. Partial discharge (PD) pulses, which are generated in a HV apparatus belonging to a subsystem, travel through the grounding structures of the others. PD analyzers using high-frequency current transformer (HFCT) sensors, which are installed at the connections between the grounding structures, are sensitive to these traveling pulses. In a substation made up of an AIS, several non-critical PD sources can be detected, such as possible corona, air surface, or floating discharges. To perform the correct diagnosis, non-critical PD sources must be separated from critical PD sources related to insulation defects, such as a cavity in a solid dielectric material, mobile particles in SF6, or surface discharges in oil. Powerful diagnostic tools using PD clustering and phase-resolved PD (PRPD) pattern recognition have been developed to check the insulation condition of HV substations. However, a common issue is how to determine the subsystem in which a critical PD source is located when there are several PD sources, and a critical one is near the boundary between two HV subsystems, e.g., a cavity defect located between a cable end and a GIS. The traveling direction of the detected PD is valuable information to determine the subsystem in which the insulation defect is located. However, incorrect diagnostics are usually due to the constraints of PD measuring systems and inadequate PD diagnostic procedures. This paper presents a diagnostic procedure using an appropriate PD analyzer with multiple HFCT sensors to carry out efficient insulation condition diagnoses. This PD procedure has been developed on the basis of laboratory tests, transient signal modeling, and validation tests. The validation tests were carried out in a special test bench developed for the characterization of PD analyzers. To demonstrate the effectiveness of the procedure, a real case is also presented, where satisfactory results are shown. Full article

Group-III nitrides have transformed solid-state lighting and are strategically positioned to revolutionize high-power and high-frequency electronics. To drive this development forward, a deep understanding of fundamental material properties, such as charge carrier behavior, is essential and can also unveil new and unforeseen applications. This underscores the necessity for novel characterization tools to study group-III nitride materials and devices. The optical Hall effect (OHE) emerges as a contactless method for exploring the transport and electronic properties of semiconductor materials, simultaneously offering insights into their dielectric function. This non-destructive technique employs spectroscopic ellipsometry at long wavelengths in the presence of a magnetic field and provides quantitative information on the charge carrier density, sign, mobility, and effective mass of individual layers in multilayer structures and bulk materials. In this paper, we explore the use of terahertz (THz) OHE to study the charge carrier properties in group-III nitride heterostructures and bulk material. Examples include graded AlGaN channel high-electron-mobility transistor (HEMT) structures for high-linearity devices, highlighting the different grading profiles and their impact on the two-dimensional electron gas (2DEG) properties. Next, we demonstrate the sensitivity of the THz OHE to distinguish the 2DEG anisotropic mobility parameters in N-polar GaN/AlGaN HEMTs and show that this anisotropy is induced by the step-like surface morphology. Finally, we present the temperature-dependent results on the charge carrier properties of 2DEG and bulk electrons in GaN with a focus on the effective mass parameter and review the effective mass parameters reported in the literature. These studies showcase the capabilities of the THz OHE for advancing the understanding and development of group-III materials and devices. Full article