Search Results (292)

TiAl alloy offers advantages including low density, high specific strength and stiffness, and excellent high-temperature creep resistance. It is widely used in the aerospace, automotive, and chemical sectors, as well as in other fields. However, at temperatures of 800 °C and above, it forms a porous oxide film predominantly composed of TiO₂, which fails to provide adequate protection. Applying high-temperature protective coatings is therefore essential. Oxides demonstrating protective efficacy at elevated temperatures include Al₂O₃, Cr₂O₃, and SiO₂. The Pilling–Bedworth Ratio (PBR)—defined as the ratio of the volume of the oxide formed to the volume of the metal consumed—serves as a critical criterion for assessing oxide film integrity. A PBR value greater than 1 but less than 2 indicates superior film integrity and enhanced oxidation resistance. Among common oxides, Al₂O₃ exhibits a PBR value within this optimal range (1−2), rendering aluminum-based compound coatings the most extensively utilized. Aluminum coatings can be applied via methods such as pack cementation, thermal spraying, and hot-dip aluminizing. Pack cementation, being the simplest to operate, is widely employed. In this study, a powder mixture with the composition Al:Al₂O₃:NH₄Cl:CeO₂ = 30:66:3:1 was used to aluminize γ-TiAl intermetallic compound specimens via pack cementation at 600 °C for 5 h. Subsequent isothermal oxidation at 900 °C for 20 h yielded an oxidation kinetic curve adhering to the parabolic rate law. This treatment significantly enhanced the high-temperature oxidation resistance of the γ-TiAl intermetallic compound, thereby broadening its potential application scenarios. Full article

Noncommunicable diseases (NCDs) like diabetes and cancer drive demand for therapeutic functional foods. This study developed freeze-dried fermented camel milk (FCM) with Ajwa date pulp (ADP), evaluating its physical and functional properties, probiotic survival, and potential benefits for diabetes and cancer. To achieve this target, six FCM formulations were prepared using ABT-5 starter culture (containing Lactobacillus acidophilus, Bifidobacterium bifidum, and Streptococcus thermophilus) with or without Lacticaseibacillus rhamnosus B-1937 and ADP (12% or 15%). The samples were freeze-dried, and their functional properties, such as water activity, dispersibility, water absorption capacity, water absorption index, water solubility index, insolubility index, and sedimentation, were assessed. Reconstitution properties such as density, flowability, air content, porosity, loose bulk density, packed bulk density, particle density, carrier index, Hausner ratio, porosity, and density were examined. In addition, color and probiotic survivability under simulated gastrointestinal conditions were analyzed. Also, antidiabetic potential was assessed via α-amylase and α-glucosidase inhibition assays, while cytotoxicity was evaluated using the MTT assay on Caco-2 cells. The results show that ADP supplementation significantly improved dispersibility (up to 72.73% in FCM15D+L). These improvements are attributed to changes in particle size distribution and increased carbohydrate and mineral content, which facilitate powder rehydration and reduce clumping. All FCM variants demonstrated low water activity (0.196–0.226), indicating good potential for shelf stability. The reconstitution properties revealed that FCM powders with ADP had higher bulk and packed densities but lower particle density and porosity than controls. Including ADP reduced interstitial air and increased occluded air within the powders, which may minimize oxidation risks and improve packaging efficiency. ADP incorporation resulted in a significant decrease in lightness (L*) and increases in redness (a*) and yellowness (b*), with greater pigment and phenolic content at higher ADP levels. These changes reflect the natural colorants and browning reactions associated with ADP, leading to a more intense and visually distinct product. Probiotic survivability was higher in ADP-fortified samples, with L. acidophilus and B. bifidum showing resilience in intestinal conditions. The FCM15D+L formulation exhibited potent antidiabetic effects, with IC₅₀ values of 111.43 μg mL⁻¹ for α-amylase and 77.21 μg mL⁻¹ for α-glucosidase activities, though lower than control FCM (8.37 and 10.74 μg mL⁻¹, respectively). Cytotoxicity against Caco-2 cells was most potent in non-ADP samples (IC₅₀: 82.22 μg mL⁻¹ for FCM), suggesting ADP and L. rhamnosus may reduce antiproliferative effects due to proteolytic activity. In conclusion, the study demonstrates that ADP-enriched FCM is a promising functional food with enhanced probiotic viability, antidiabetic potential, and desirable physical properties. This work highlights the potential of camel milk and date synergies in combating some NCDs in vitro, suggesting potential for functional food application. Full article

This study presents a progressive strength prediction model for cement paste based on the hypothesis that compressive strength is governed by the microstructural compactness of hydration products. A three-stage modeling framework was developed: (1) a semi-empirical model for pure cement paste incorporating water-to-cement ratio and paste density; (2) a density-corrected effective water–cement ratio ${\left(w/c\right)}_{eff}$ that accounts for the physical effects of mineral additives including fly ash, slag, and limestone powder; and (3) a hydration-informed strength model incorporating curing age and temperature through an equivalent hydration degree $\alpha \left(t_e\right)$. Experimental validation using over 60 cement paste mixes demonstrated high predictive accuracy, with coefficients of determination up to 0.97. The proposed model unifies the influence of binder composition, packing density, and curing conditions into a physically interpretable and practically applicable formulation. It enables early-age strength prediction of blended cementitious systems using only routine mix and density parameters, supporting performance-based mix design and optimization. The methodology provides a robust foundation for extending compactness-based modeling to more complex cementitious materials and structural applications. Full article

In this paper, a discrete element method (DEM) coupled with a finite element method (FEM) was used to elucidate the impact of packing structures and size ratios on the cold die compaction behavior of pure copper powders. HCP structure, SC structure, and three random packing structures with different particle size ratios (1:2, 1:3, and 1:4) were generated by the DEM, and then simulated by the FEM to analyze the average relative density, von Mises stress, and force chain structures of the compact. The results show that for HCP and SC structures with a regular stacking structure, the average relative densities of the compact were higher than those of random packing structures, which were 0.9823, 0.9693, 0.9456, 0.9502, and 0.9507, respectively. Compared with their initial packing density, it could be improved by up to 21.13%. For the bigger particle in HCP and SC structures, the stress concentration was located between the adjacent layers, while in the small particles, it was located between contacted particles. During the initial compaction phase, smaller particles tend to occupy the voids between larger particles. As the pressure increases, larger particles deform plastically in a notable way to create a stabilizing force chain. This action reduces the axial stress gradient and improves radial symmetry. The transition from a contact-dominated to a body-stress-dominated state is further demonstrated by stress distribution maps and contact force vector analysis, highlighting the interaction between particle rearrangement and plasticity. Full article

This study systematically investigates how thiol–disulfide interactions influence the structure and mechanical properties of casein gels. Acid gels were prepared from suspensions of micellar casein (MC) powder that were heat-treated at 70 °C. Thiol groups were variably blocked with N-ethylmaleimide (NEM). The gels were characterized using stress–strain measurements, rheological analyses, and confocal microscopy. The stress–strain curves exhibited a biphasic behavior, with an initial linear elastic phase followed by a linear plastic region and a nonlinear failure zone. Compared to control samples, the addition of 100 mM NEM reduced the gel strength by 50%, while G′ and G″ increased by around 100%, unexpectedly. NEM-treated gels consist of uniformly sized building blocks coated with a whey protein layer. Strong physical interactions and dense packing enhance viscoelasticity under short deformations but reduce the compressive strength during prolonged loading. In contrast, control samples without NEM demonstrate weak viscoelasticity and increased compressive strength. The former is attributed to a broader particle size distribution from lower acid stability in the untreated gels, while the particularly high compressive strength of heat-treated gels additionally results from disulfide cross-links. The results show that thiol blocking and heating enable the targeted formation of acid casein gels with high shear stability but a low compressive strength. Full article

The rheological behavior of cementitious paste plays a pivotal role in determining the workability, pumpability, and uniformity of fresh concrete. Classical rheological models often struggle to capture the complex flocculation and hydration effects inherent in cement-based systems, and they typically depend on parameters that are difficult to measure directly, limiting their practical utility. This study presents a novel composition-based constitutive model that introduces a virtual maximum packing fraction (${\varphi }_{max}$) to account for interparticle flocculation and entrapped water effects. By establishing quantitative relationships between powder characteristics—such as particle size and specific surface area—and rheological parameters, the model enables physically interpretable and measurable predictions of yield stress and plastic viscosity. Our validation against 65 paste formulations with varying water-to-binder ratios, mineral admixture types and dosages, and superplasticizer contents demonstrates strong predictive accuracy (R² > 0.98 for plain pastes and >0.85 for blended systems). The influence of superplasticizers is effectively captured through modifications to ${\varphi }_{max}$, allowing the model to remain both robust and parameter efficient. This framework supports forward prediction of paste rheology from raw material properties, offering a valuable tool for intelligent mix design in high-performance concrete applications such as self-consolidating and 3D-printed concrete. Full article

This study systematically investigates the utilization of marble industry waste—waste marble powder (WMP) as partial cement replacement and waste marble aggregates (WMA) as partial fine aggregate replacement—in self-compacting concrete (SCC). A detailed experimental program evaluated the effects of various replacement levels (5%, 10%, and 20% for WMP; 20%, 30%, and 40% for WMA) on compressive strength and durability, particularly resistance to aggressive sulfuric acid environments. Results indicated that a 5% WMP replacement increased compressive strength by 4.9%, attributed primarily to the filler effect, whereas higher levels (10–20%) led to strength reductions due to limited pozzolanic activity and cement dilution. In contrast, WMA replacement consistently enhanced strength (maximum increase of 11.5% at 30% substitution) due to improved particle packing and aggregate-paste interface densification. Durability tests revealed significantly reduced compressive strength losses and mass loss in marble-containing mixtures compared to control samples, with optimal acid resistance observed at 20% WMP and 40% WMA replacements. A comprehensive life cycle assessment demonstrated notable reductions in environmental impacts, including up to 20% decreases in Global Warming Potential (GWP) at 20% WMP replacement. A desirability-based eco-cost-mechanical optimization—simultaneously integrating mechanical strength, environmental indicators, and production cost—identified the 10% WMP substitution mix as the most sustainable option, achieving optimal balance among key performance criteria. These findings underscore the significant potential for marble waste reuse in SCC, promoting environmental sustainability, resource efficiency, and improved concrete durability in chemically aggressive environments. Full article

In this study, the effects of stearic acid coating concentration (0.85%, 1%, and 1.15% wt.) and storage duration (up to 30 days) on the flow properties of surface-modified micronized calcite powder were investigated to evaluate their implications for critical industrial processes including transportation, feeding, dispersion, and production capacity. The results demonstrated that both stearic acid concentration and storage duration significantly influenced the rheological properties of the coated calcite powders, suggesting that the calcite surfaces had dynamic characteristics. The Conditioned Bulk Density (CBD) values increased significantly from day 1 to day 30, indicating efficient packing of the powders. Although stearic acid-coated calcite powders initially demonstrated enhanced flowability (SE: 5.1→3.7 mJ/g; BFE: 77→59.3 mJ) within the first 8 days, a subsequent increase (SE: 4.6 mJ/g; BFE: 74.3 mJ) by day 30 indicated a time-dependent surface reorganization of the coated particles. The reduction in the Flow Rate Index (FRI) values after a 30-day period indicated a decrease in cohesiveness. The stability index (SI) values initially indicated instability but improved after 30 days. These findings highlight the importance of considering the coating amount and time-dependent behavior when designing experiments, formulating products, and establishing quality control procedures involving calcite fillers. Full article

The objective of this study was to obtain and evaluate a coffee aroma extract/oil with sensorial attributes close to the original brew of Greek coffee for use in an instant Greek coffee powder. The oil was obtained directly from commercial Greek coffee by solid-liquid extraction using hexane as a solvent and treated with a series of hexane-ethanol mixtures (0:10, 1:4, 1:9) to remove the intense roasted flavor of the crude coffee oil obtained by hexane; the de-oiled coffee was used for the recovery of water-soluble compounds, and the produced water extract was freeze-dried. The aromatic volatiles of the coffee oil samples were analyzed by using a purge-and-trap device coupled to GC-MS, as well as sensory analysis. The instant Greek coffee powder was produced by mixing the freeze-dried base (74.4%) with the extract derived after treatment of the crude oil with hexane-ethanol mixture 1:4 (18.2%) and foaming agent (7.4%). Two different materials were studied as bases: instant coffee (F3_Gr-D) and ground Greek coffee (reference sample, C_Gr). The shelf-life stability of the produced powders was examined at three storage temperatures (25, 45, 60 °C). Instrumental analysis (purge-and-trap GC-MS) of aroma and sensory analysis (aroma, taste, staling, total sensory quality on a 1–9 hedonic scale) was conducted. Aroma loss (furfuryl alcohol, furfural, dimethyl pyrazines, ethyl methyl pyrazines) and scores for sensory attributes during storage were modeled using 1st and 0-order reaction kinetics, respectively. The storage temperature effect was expressed by the Arrhenius model (activation energy E_a). According to the results, the developed instant coffee powder presented satisfactorily the aroma characteristics of regular Greek coffee. The shelf life for the instant Greek coffee powder was estimated as 80 days (air packed) (based on 20% retention of furfuryl alcohol that was the most abundant aromatic volatile of Greek coffee aroma, ground as well as extract oil). Full article

Nuclear fuel pellets are subject to stress for long periods during the in-pile operation, and this study on high-temperature creep performance is of great significance for predicting the in-pile behaviors and safety evaluation of fuel elements. In the present study, a mixture of ZrC (50 wt%), SiC (46 wt%), and Si (4 wt%) powder was ball-milled for 24 h and then evaporated to obtain ZrC–SiC composite material. ZrC–SiC composite was adopted as the matrix, with ZrO₂ surrogate kernel TRSIO particles and dispersion coated particle fuel pellets prepared with different TRISO packing fractions using the Spark Plasma Sintering (SPS) process. This study on compressive creep performances was conducted under a temperature range of 1373–2073 K and a stress range of 5–250 MPa, elucidating the creep behavior and mechanism of dispersed coated particles fuel pellets, and obtaining the variation laws of key parameters such as creep stress exponents and activation energy with TRISO packing fraction. The results showed that creep stress exponents of the surrogate fuel pellets are between 0.89 and 2.12. The activation energies for high temperature–low stress creep (1873–2073 K, 5–50 MPa) are 457.81–623.77 kJ/mol, and 135.14–161.59 kJ/mol for low temperature high stress creep (1373–1773 K, 50–250 MPa). Based on the experimental results, a high-temperature creep model was established, providing a valuable reference for the research and application of a ceramic matrix dispersed with coated particle fuels. Full article

Powder bed fusion using a laser beam (PBF-LB) offers a suitable alternative to manufacturing Ti65 with intricate geometries and internal structures in hypersonic aerospace applications. However, issues such as undesirable surface roughness, defect formation, and microstructural inhomogeneity remain critical barriers to its wide application. In this study, a coupled discrete element method–computational fluid dynamics (DEM-CFD) model was utilized to investigate the spreading behavior of Ti65 powder in a multi-layer PBF-LB process. The macro- and microscopic characteristics of the powder beds were systematically analyzed across different layers and regions under various spreading velocities. The results show that the packing density and uniformity of the powder beds in multi-layer PBF-LB of Ti65 powder improves as the number of solidified layers increases. Poor bed quality is observed in the first two layers due to a strong boundary effect, while a stable and denser powder bed emerges from the fourth layer. The presence of a previously solidified region strongly influences its neighboring unsolidified areas, enhancing density in the upstream region and causing looser packing downstream. Additionally, due to the existence of a solidified region, the height of the powder bed progressively decreases along the spreading direction. Full article

A method for characterizing carbon nanotubes (CNTs) in powder form with different packing densities in the microwave regions is proposed. The CNTs were sandwiched between two dielectric walls in (Polyvinyl Chloride) PVC and put in a waveguide shim. We measured the transmission/reflection S-parameters of the waveguide using a Vector Network Analysis (VNA), and the impacts of the PVCs on the measured S-parameters were de-embedded by microwave network analysis. Then, the well-known Nicolson–Ross–Weir (NRW) method was processed to determine the complex permittivity and permeability of the CNTs. Furthermore, we pressed the PVC to increase the packing densities of the CNTs. The results of the characterization can be employed to design microwave devices using the CNTs. Full article

In this paper, the analysis method which coupled discrete element method (DEM) and finite element method (FEM) is used to simulate the double compaction of random packing of Cu and Al composite powders with multiple particle sizes. Cu and Al composite powders with varying particle size ratios from 1:2 to 1:5 were generated by DEM and then imported to MSC. Marc software (MSC.MARC2015 version) to construct FEM analysis. The effects of metal ratios, compaction pressure and size ratios on the relative density and von Mises stress of the compact were studied. The results show that the average relative density of the compact increases with the Al content, and the stress decreases. The stress in the Cu particle is particularly higher than that in the Al particle, mainly because the contact normal force of the Cu particle is nearly parallel at each contact surface. Therefore, the phenomenon of stress concentration is easier to occur within copper particles. When Al content is 30wt.%, the particle size difference enhances densification efficiency by up to 12.3%, as evidenced by an initial relative density increase from 0.7915 to 0.8047, primarily due to smaller Cu particles effectively filling interparticle voids. When the compaction pressure is fixed, the average relative density of the compact with the particle size ratio 1:5 is higher than the others, and the contact forces inside the particles significantly decrease. Full article

Characterizing powder feedstock is crucial for ensuring the quality and reliability of parts produced through metal additive manufacturing (AM). The morphology of particles impacts the flowability, packing density, and spreadability of powders, affecting productivity and part quality. A new methodology has been developed to classify particle morphological features in AM powder feedstocks, such as spherical or elongated shapes, and the presence of satellites and facets. This approach uses multiple descriptors for quantitative evaluation. The results from shape descriptors can vary based on image resolution, gray/color thresholding, and software algorithms. There are various commercial systems available for characterizing particle shape, some of which use images taken of static particles, while others use images of particles in motion. This diversity can lead to differences in powder characterization across laboratories with different equipment and methods. This paper compares results from a particle classification approach using two software programs that work with metallographic images with those from an automated static particle analyzer. While traditional methods offer higher resolution and precision, this study shows that automated systems can achieve similar particle shape classification using different shape descriptors and thresholds. Full article

This research focuses on the merocyanine form of a new synthesized spiroindolinonaphthoxazine compound. The merocyanine molecule (abbreviated as MC) has multiple fragments with different degrees of mobility. The conformational changes and the flexibility of MC in presence and in absence of the solvent molecules were studied by Molecular Dynamics simulations, providing insights into how they orient and interact with each other and with solvent molecules. The molecular packing of MC in presence and in absence of solvents with different polarities was thoroughly investigated in order to determine how the physicochemical interactions with the solvent influence the structure and stability of the MC molecule. Furthermore, the powders of MC obtained from its solutions in water, methanol, ethanol, and acetonitrile were experimentally characterized using differential scanning calorimetry, thermogravimetry, Fourier transform infrared spectroscopy, and scanning electron microscopy. Both calculations and experimental results reveal the effect of the solvent polarity on the dissolved MC molecule. Full article