Search Results (29)

Plastics are widely used in various industries because of their light weight, low cost, and high durability. The mass production and consumption of plastics have led to a rapid increase in plastic waste problem, necessitating the development of effective recycling technologies. The chemical recycling of plastics has emerged as a promising strategy to address these challenges, enabling the conversion of plastic waste into high-purity monomers or oils, even from contaminated or mixed plastic feedstock. This review focuses on the development of catalysts for the chemical recycling of plastics in South Korea, which has one of the highest per capita plastic consumption rates and both academic and industrial efforts in this field. We examine catalytic depolymerization processes for recovering monomers from polymers, such as polyethylene terephthalate (PET) and polycarbonate (PC), as well as catalytic pyrolysis processes for polyolefins, including polyethylene (PE), polypropylene (PP), and polystyrene (PS). By summarizing recent academic research and industrial initiatives in South Korea, this review highlights the strategic role of the country in advancing chemical recycling. Moreover, this review proposes future research directions including the development of reusable catalysts, energy-efficient recycling process, and strategies for recycling mixed or contaminated plastic waste. Full article

This paper highlights the complexity and urgency of addressing plastic pollution, drawing attention to the environmental challenges posed by improperly discarded plastics. Petroleum-based plastic polymers, with their remarkable range of physical properties, have revolutionized industries worldwide. Their versatility—from flexible to rigid and hydrophilic to hydrophobic—has fueled an ever-growing demand. However, their versatility has also contributed to a massive global waste problem as plastics pervade virtually every ecosystem, from the depths of oceans to the most remote terrestrial landscapes. Plastic pollution manifests not just as visible waste—such as fishing nets, bottles, and garbage bags—but also as microplastics, infiltrating food chains and freshwater sources. This crisis is exacerbated by the unsustainable linear model of plastic production and consumption, which prioritizes convenience over long-term environmental health. The mismanagement of plastic waste not only pollutes ecosystems but also releases greenhouse gases like carbon dioxide during degradation and incineration, thereby complicating efforts to achieve global climate and sustainability goals. Given that mechanical recycling only addresses a fraction of macroplastics, innovative approaches are needed to improve this process. Methods like pyrolysis and hydrogenolysis offer promising solutions by enabling the chemical transformation and depolymerization of plastics into reusable materials or valuable chemical feedstocks. These advanced recycling methods can support a circular economy by reducing waste and creating high-value products. In this article, the focus on pyrolysis and hydrogenolysis underscores the need to move beyond traditional recycling. These methods exemplify the potential for science and technology to mitigate plastic pollution while aligning with sustainability objectives. Recent advances in the pyrolysis and hydrogenolysis of polyolefins focus on their potential for advanced recycling, breaking down plastics at a molecular level to create feedstocks for new products or fuels. Pyrolysis produces pyrolysis oil and syngas, with applications in renewable energy and chemicals. However, some challenges of this process include scalability, feedstock variety, and standardization, as well as environmental concerns about emissions. Companies like Shell and ExxonMobil are investing heavily to overcome these barriers and improve recycling efficiencies. By leveraging these transformative strategies, we can reimagine the lifecycle of plastics and address one of the most pressing environmental challenges of our time. This review updates the knowledge of the fields of pyrolysis and hydrogenolysis of plastics derived from polyolefins based on the most recent works available in the literature, highlighting the techniques used, the types of products obtained, and the highest yields. Full article

This study solved a set of equations to verify the dynamic optimal conditions of nonthermal plasma (NTP)-chemical conversion of solid polyolefin wastes into liquid petroleum hydrocarbons. Furthermore, a novel optimisation model was validated with non-linear experimental conditions to assess the quantitative relationship between the process variables responsible for the degradation rate of wastes. The central composite design (CCD) experimental design was developed based on the Response Surface Model (RSM) technique. These techniques significantly improved the model predictions because of the more-detailed electrochemical description. Experiments were conducted in an in-house-designed and -developed NTP system with advanced data acquisition schemes. Both experimental and the numerical findings exhibited a good agreement, and the results indicated that the electrical factors of NTP could significantly affect the conversion yield (Y_conv%) of solid polyolefin-derived wastes to liquid hydrocarbons. Additionally, the model investigation indicated that factors such as power discharge ($x_1$), voltage intensity ($x_2$), and reaction retention time (RTT) ($x_3$) significantly influenced the conversion yield. After optimisation, a maximum conversion percentage (Y_conv%) of ≈93% was achieved. The findings indicated that this recommended framework could be effectively employed for scaling the plasma synergistic pyrolysis technique for generating the maximal Y_conv% of plastic wastes to yield an oil. Thereafter, the analysis of variance (ANOVA) technique was applied to examine the accuracy of the developed structure in order to upgrade this laboratory-scale processes to an industrial-scale process with >95% effectiveness. The calorific value of the produced oil was seen to be from 43,570.5 J/g to 46,025.5 J/g due to changes of the arrangements of the process factors, which specified that the liquid hydrocarbons showed similar characteristics like commercial diesel in this respect. Full article

Mixed plastic packaging waste sorting residue (MPO323) was treated by thermal pyrolysis to utilize pyrolysis oil and char. The pyrolysis oil was found to contain aromatic and aliphatic hydrocarbons. The chlorine and bromine contents were as high as 40,000 mg/kg and 200 mg/kg, respectively. Additionally, other elements like sulfur, phosphorous, iron, aluminum, and lead were detected, which can be interpreted as impurities relating to the utilization of oils for chemical recycling. The pyrolysis char showed high contents of potentially active species like silicon, calcium, aluminum, iron, and others. To enhance the content of aromatic hydrocarbons and to reduce the level of contaminants, pyrolysis oil was reformed with the corresponding pyrolysis char to act as an active material in a fixed bed. The temperature of the reactor and the flow rate of the pyrolysis oil feed were varied to gain insights on the cracking and reforming reactions, as well as on performance with regard to decontamination. Full article

The present investigation studies the use of three natural precursors of volcanic origin (pozzolana, ignimbrite and pumice) in the synthesis of low-cost and environmentally friendly zeolites. The developed zeolites were evaluated as sustainable catalysts for the catalytic pyrolysis process in the chemical recycling of polypropylene. A zeolite was synthesized from each precursor. The hydrothermal treatment was performed with NaOH (3M) at 160 °C for 72 h and NH₄Cl (1M) was added to convert it into proton form. The synthesized zeolites were characterized by FTIR, XRD, SEM and BET. The evaluation of the catalytic ability of the obtained zeolites was carried out with polypropylene mixed with a 4, 6 and 8 wt.% catalyst in a ceramic crucible. Pyrolysis was always carried out at 450 °C and for 30 min in a tubular furnace with a continuous flow rate of 250 L·min⁻¹ of gaseous nitrogen. The gases generated were captured in the cooling system. The characterized zeolites show a resemblance to the ZSM-5 commercial zeolite, especially for the ignimbrite and pozzolan zeolites. Likewise, in pyrolysis, liquid products, gases and waxes were obtained. As the amount of catalyst was increased (from 4 to 8%), the yield of the desired liquid–gas products was also increased. The synthesized zeolites showed similar pyrolytic characteristics to ZSM-5, although they did not reach the same pyrolytic efficiency. Zeolites improved the pyrolysis products, especially at 8 wt.%, when compared to thermal pyrolysis. This study highlights the potential of the developed zeolite catalysts to efficiently convert PP into valuable light olefins, advancing sustainable polyolefin recycling technologies. Full article

The recycling of plastic packaging wastes helps to alleviate the problems of white pollution and resource shortage. It is very necessary to develop high-value conversion technologies for plastic packaging wastes. To our knowledge, carbon materials with excellent properties have been widely used in energy storage, adsorption, water treatment, aerospace and functional packaging, and so on. Waste plastic packaging and biomass materials are excellent precursor materials of carbon materials due to their rich sources and high carbon content. Thus, the conversion from waste plastic packaging and biomass materials to carbon materials attracts much attention. However, closely related reviews are lacking up to now. In this work, the pyrolysis routes of the pyrolysis of plastic packaging wastes and biomass materials for conversion to high-value carbons and the influence factors were analyzed. Additionally, the applications of these obtained carbons were summarized. Furthermore, the limitations of the current pyrolysis technology are put forward and the research prospects are forecasted. Therefore, this review can provide a useful reference and guide for the research on the pyrolysis of plastic packaging wastes and biomass materials and the conversion to high-value carbon. Full article

Improper disposal of waste plastic has caused serious ecological and environmental pollution problems. Transforming plastics into high value-added chemicals can not only achieve efficient recycling of waste plastics, but is also an effective way to control white pollution. The catalyst selectively breaks the C–C bond of polyolefin plastic under heat treatment and converts it into liquid fuel, thus realizing sustainable recycling of plastics and has a good development prospect. This review provides a detailed overview of the current development of catalytic pyrolysis, catalytic hydrolysis, solvent decomposition, and supercritical hydrothermal liquefaction for cracking plastics to make fuel oil. The reaction mechanism, influencing factors, and promoting effects of catalysts in various degradation technologies are analyzed and summarized, and the latest proposed tandem reaction for degrading plastics is briefly introduced. Finally, some optimization paths of waste plastic pyrolysis to fuel oil technology are proposed: synergies between mixed raw materials, in-depth exploration of catalysts, design and manufacture of reactors that match the pyrolysis technology. All these are important research directions for promoting the industrialization of plastic pyrolysis to fuel oil. Full article

This paper presents the application of two versions of the multilayer fluidized bed made out of two materials with significantly different densities. The first type of fluidized bed was composed of raw cenospheres and quartz sand. The second type of fluidized bed was composed of cenospheres coated with iron oxides and quartz sand. A variable vertical density profiles in the prepared fluidized beds were confirmed, making them suitable for processing polymeric materials, specifically, polyolefins with a density below 1 g/cm³. The polyolefin pyrolysis process was investigated in both versions of the fluidized bed at temperatures of 520, 540, 560, and 590 °C. The products of the pyrolysis were monitored using high-resolution infrared spectroscopy (with a resolution of 1 cm⁻¹). While the process is organized in these fluidized beds, the absence of the accumulation of solid residues is notable. The results show that the pyrolytic gaseous mixture is composed of numerous compounds, namely, unsaturated and saturated aliphatic hydrocarbons and benzene. The possibility of producing a gas rich in ethylene, propylene, and 1-butene during the pyrolysis was demonstrated. Additionally, during the pyrolysis of both polymers, the production of benzene was shown with yields, ranging from 5%_wt. in the fluidized bed made out of raw cenospheres to 11 %_wt. in the fluidized bed made out of cenospheres modified by iron oxides. Due to the complex nature of the resulting pyrolytic gas, it is suggested that we process the created gaseous mixtures entirely in a steam conversion process, making them a potential source of hydrogen. Full article

Wastewater treatment plants (WWTPs) have been identified as significant point sources of microlitter particles (MPs) released into the environment. Simultaneously, they play a crucial role in effectively removing a substantial amount of MPs originated from domestic and industrial activities. This study evaluates the presence and chemical composition of MPs within the range of 5 mm to 25 µm in effluents from three WWTPs in the Canary Islands, each undergoing distinct treatment processes: pretreatment (PRET), activated sludge (AS), and membrane bioreactor (MBR) over an eight-month period. The concentrations of MPs exhibited substantial variations in the three effluent samples: 7461.50 ± 3843.87 MP/L in PRET, 32.71 ± 19.55 MP/L in AS, and 9.53 ± 5.21 MP/L in MBR. The predominant forms of MPs were fragments (58–66%) and fibers (27–33%), with the most prevalent size class being within the range of 150–25 µm. The mass concentrations of plastics, analyzed through pyrolysis gas chromatography–mass spectrometry (Pyr-GC/MS), were determined as 123.33 µg/L for PRET, 17 µg/L for AS, and 10 µg/L for MBR. This study revealed a diverse polymer profile, with polyvinyl chloride (PVC) and polyolefins (PE and PP) predominantly present. This work enhances our understanding of MP dynamics and provides a valuable reference for future assessments, aiding in the selection of effective removal technologies. Full article

The hydrogen sorption of materials based on 80 wt.% MgH₂ with the addition of 15 wt.% Ni or V and 5 wt.% activated carbons synthesized from polyolefin wax, a waste product from polyethylene production (POW), walnut shells (CAN), and peach stones (CPS) prepared by milling under an inert Ar atmosphere for a period of 1 h, is investigated. All precursors are submitted to pyrolysis followed by steam activation in order to obtain the activated carbons. The hydrogen sorption evaluations are carried out for absorption at 473 and 573 K with pressure of 1 MPa and for desorption at 623 and 573 K with pressure of 0.15 MPa. The composition of the samples after milling and hydrogenation is monitored by X-ray diffraction analyses. The 80 wt.% MgH₂–15 wt. %Ni–5 wt.% POW or CAN after absorption–desorption cycling and in a hydrogenated state at 573 K and 1 MPa are analyzed by TEM. Full article

Quinoline (QN) is highly toxic and carcinogenic and has been detected in soil, groundwater, and biological tissues. Advanced oxidation processes (AOPs) have shown promise to address its degradation in wastewater treatment, with catalytic wet peroxide oxidation (CWPO) being highlighted due to its cost-effectiveness and mild operation. However, developing active and inexpensive catalysts is crucial for CWPO’s effectiveness. Another pressing issue is the accumulation of mixed, dirty plastic solid waste (PSW), particularly polyolefins used in packaging. Although recycling rates have increased, much plastic packaging remains in landfills. However, polyolefins can be converted into carbon-based nanostructured materials (CNMs), such as carbon nanotubes (CNTs), through chemical vapor deposition (CVD) using PSW as a carbon precursor. While many studies focus on CNT preparation, their application is often overlooked. In this context, this work proposes the preparation of CNMs, particularly CNTs, through CVD using a single-stage pyrolysis reactor. Polyolefins (LDPE, HDPE, and PP), both individually and in a mixture simulating PSW, were used as carbon sources. Given a sufficiently high temperature, the desired CNT architecture was successfully synthesized regardless of the starting polymer. These CNMs were then tested as catalysts for CWPO in simulated wastewater containing QN. The results showed a rapid degradation of QN (30–120 min) and high removals of total organic carbon (TOC) and aromatic compounds (75% and >90%, respectively), demonstrating the applicability of PSW-derived CNTs in the CWPO process for QN abatement. Full article

Plastics are engineering marvels that have found widespread use in all aspects of modern life. However, poor waste management practices and inefficient recycling technologies, along with their extremely high durability, have caused one of the major environmental problems facing humankind: waste plastic pollution. The upcycling of waste plastics to chemical feedstock to produce virgin plastics has emerged as a viable option to mitigate the adverse effects of plastic pollution and close the gap in the circular economy of plastics. Pyrolysis is considered a chemical recycling technology to upcycle waste plastics. Yet, whether pyrolysis as a stand-alone technology can achieve true circularity or not requires further investigation. In this study, we analyzed and critically evaluated whether oil obtained from the non-catalytic pyrolysis of virgin polypropylene (PP) can be used as a feedstock for naphtha crackers to produce olefins, and subsequently polyolefins, without undermining the circular economy and resource efficiency. Two different pyrolysis oils were obtained from a pyrolysis plant and compared with light and heavy naphtha by a combination of physical and chromatographic methods, in accordance with established standards. The results demonstrate that pyrolysis oil consists of mostly cyclic olefins with a bromine number of 85 to 304, whereas light naphtha consists of mostly paraffinic hydrocarbons with a very low olefinic content and a bromine number around 1. Owing to the compositional differences, pyrolysis oil studied herein is completely different than naphtha in terms of hydrocarbon composition and cannot be used as a feedstock for commercial naphtha crackers to produce olefins. The findings are of particular importance to evaluating different chemical recycling opportunities with respect to true circularity and may serve as a benchmark to determine whether liquids obtained from different polyolefin recycling technologies are compatible with existing industrial steam crackers’ feedstock. Full article

Renewable source-derived carbon is found to be a green alternative catalyst to zeolite for the pyrolysis of plastics. However, only polyethylene (PE) catalytic pyrolysis over biomass-derived carbon has been extensively studied. In this work, carbon was produced from industrial organic solid waste using different activation agents, and their catalytic performance on the thermal degradation of typical polymers, namely PE, polypropylene (PP), polystyrene (PS), and polyethylene terephthalate (PET) were investigated. The degradation mechanisms and the roles of different active sites of the carbons are discussed. Steam failed to activate the carbon, which has a low specific surface area (6.7 m²/g). Chemical activation using H₃PO₄ and ZnCl₂ produces carbons with higher specific surface area and more porosity. The pyrolysis characteristics of LDPE, PP, PS, and PET catalyzed by the carbons were studied using TGA and a fixed-bed reactor. The thermogravimetric results indicate that all three carbons reduce the pyrolysis temperature. The analysis of the products shows that the P- and Zn-involved acid sites on the AC-HP and AC-ZN change the reaction pathway of plastics and promote: (1) C-C cracking and aromatization of polyolefins; (2) the protonation of phenyl carbon of PS to yield higher benzene, toluene, and ethylbenzene; and (3) the decarboxylation of the terephthalic acid intermediate of PET, resulting in higher CO₂ and benzene. In addition, the high-value chemicals, long-chain alkylbenzenes, were found in the liquids of AC-ZN and AC-HP. The long-chain alkylbenzenes are probably formed by acid-catalyzed alkylation of aromatic hydrocarbons. This study provides basic data for the development of a cheap catalyst for plastic pyrolysis. Full article

Fast pyrolysis of five post-consumer plastic waste materials was studied using pyrolysis coupled with gas chromatography/mass spectrometry (Py-GC/MS) technique. Prescription medicine bottles, landfill liners, and one type of industrial plastic waste represented polyolefin-based polymers, whereas packaging material represented polystyrene, and other industrial plastic waste represented polyurethane. The noncatalytic and catalytic degradation mechanisms of all five post-consumer plastic wastes were elucidated. The noncatalytic pyrolysis experiments were conducted at a temperature of 600 °C for a residence time of 5 min. For catalytic pyrolysis, a spent FCC catalyst was utilized for polystyrene, a sulfated zirconia-based catalyst was utilized for polyurethane, and a Y-zeolite catalyst was used for polyolefinic plastic waste. The results suggested that the thermal reaction has higher monomeric and oligomeric selectivity than the catalytic reaction. Results from the catalytic runs showed that the addition of catalysts greatly influences product compositions and has a significant effect on the selectivity of a specific compound. One of the plastic wastes, landfill liner, was selected for a batch scale pyrolysis at 420–440 °C using Y-zeolite as a catalyst to demonstrate the product properties and potential use of the liquid product formed. The complete product distribution of plastic crude oil was performed followed by distillation to produce aviation range fuel. The fuel properties of aviation range fuel were examined, and results suggested that the fuel fraction can be easily blended with commercially available fuels for direct applications. Full article

Among the different thermo-chemical recycling routes for plastic waste valorization, gasification is one of the most promising, converting plastic waste into syngas (H₂+CO) and energy in the presence of an oxygen-rich gas. Plastic waste gasification is associated with many different complexities due to the multi-scale nature of the process, the feedstock complexity (mixed polyolefins with different contaminations), intricate reaction mechanisms, plastic properties (melting behavior and molecular weight distribution), and complex transport phenomena in a multi-phase flow system. Hence, creating a reliable model calls for an extensive understanding of the phenomena at all scales, and more advanced modeling approaches than those applied today are required. Indeed, modeling of plastic waste gasification (PWG) is still in its infancy today. Our review paper shows that the thermophysical properties are rarely properly defined. Challenges in this regard together with possible methodologies to decently define these properties have been elaborated. The complexities regarding the kinetic modeling of gasification are numerous, compared to, e.g., plastic waste pyrolysis, or coal and biomass gasification, which are elaborated in this work along with the possible solutions to overcome them. Moreover, transport limitations and phase transformations, which affect the apparent kinetics of the process, are not usually considered, while it is demonstrated in this review that they are crucial in the robust prediction of the outcome. Hence, possible approaches in implementing available models to consider these limitations are suggested. Finally, the reactor-scale phenomena of PWG, which are more intricate than the similar processes—due to the presence of molten plastic—are usually simplified to the gas-solid systems, which can result in unreliable modeling frameworks. In this regard, an opportunity lies in the increased computational power that helps improve the model’s precision and allows us to include those complexities within the multi-scale PWG modeling. Using the more accurate modeling methodologies in combination with multi-scale modeling approaches will, in a decade, allow us to perform a rigorous optimization of the PWG process, improve existing and develop new gasifiers, and avoid fouling issues caused by tar. Full article