State of the Art of Catalytical Technology in Korea, 2nd Edition

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalytic Materials".

Deadline for manuscript submissions: closed (20 January 2025) | Viewed by 5152

Special Issue Editors


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Guest Editor
Graduate School of Energy Science and Technology, Chungnam National University, Daejeon, Republic of Korea
Interests: heterogeneous catalysts; catalyst designs; in-situ characterization
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Guest Editor Assistant
Graduate School of Energy Science and Technology, Chungnam National University, Daejeon, Republic of Korea
Interests: catalyst reaction; environmental catalyst; hydrogen production
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Following the first successful Special Issue on this topic (available here), we are happy to announce a second edition titled “State-of-the-Art of Catalytical Technology in Korea, 2nd Edition”.

Following the devastation cause by the Korean War in 1950, Korea's per capita income at that time was only USD 50, and it was one of the poorest countries receiving food aid from the United Nations. However, through remarkable economic development, today, in 2024, the Republic of Korea has achieved unprecedented economic growth and grown into a country that attracts attention from all countries around the world. Many experts say that the chemical industry has been at the center of economic development in Korea, and catalytical technology is a cornerstone for that success. Diverse types of catalysis, including homogenous and heterogeneous catalysis, biocatalysis, and electrocatalysis, have undergone extremely rapid development for a variety of chemical reactions used in the chemical, fuel, pharmaceutical, and agricultural industries affording a wide range of products in our daily life. In this Special Issue, we are going to focus on the state of the art of catalytic technology in the Republic of Korea and the direction in which we believe we should be heading. All experimental and theoretical results on catalysis from academia and industry are encouraged to be submitted in the form of regular research articles, short communications, or reviews.

If you would like to submit papers to this Special Issue or have any questions, please contact the in-house editor, Ms. Rita Lin (rita.lin@mdpi.com).

Prof. Dr. Kyubock Lee
Guest Editor

Dr. Min-Jae Kim
Guest Editor Assistant

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Catalysts is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2200 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • Korean economy
  • chemical industry
  • catalyst technology
  • homogeneous catalysis
  • heterogeneous catalysis
  • biocatalysis

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Related Special Issue

Published Papers (3 papers)

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Research

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12 pages, 3261 KiB  
Article
High-Efficiency Biodiesel Production Using ZnO-Modified Starfish-Based Catalysts
by Jeyoung Ha, Sungho Lee and Oi Lun Li
Catalysts 2025, 15(4), 372; https://doi.org/10.3390/catal15040372 - 11 Apr 2025
Viewed by 469
Abstract
This study introduces a novel approach to biodiesel production by repurposing starfish, an abundant marine waste, as a sustainable catalyst material. Starfish, primarily composed of Ca-Mg carbonate, were calcined to produce calcium oxide (CaO) and magnesium oxide (MgO), which were subsequently doped with [...] Read more.
This study introduces a novel approach to biodiesel production by repurposing starfish, an abundant marine waste, as a sustainable catalyst material. Starfish, primarily composed of Ca-Mg carbonate, were calcined to produce calcium oxide (CaO) and magnesium oxide (MgO), which were subsequently doped with varying zinc loadings through hydrothermal treatment. This innovative use of marine waste not only addresses environmental concerns but also provides a cost-effective catalyst source. Among the tested compositions, the catalyst doped with 10 wt% Zn achieved the highest biodiesel yield of 96.6%, outperforming both lower and higher Zn loadings. Zinc incorporation significantly improved the catalyst’s surface area, pore volume, and active site density, as confirmed by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and Brunauer–Emmett–Teller (BET) surface analysis. These enhancements facilitated a biodiesel yield of 96.6% within 10 h, a substantial increase compared to the undoped catalyst (86.5%) under identical conditions. Reusability tests further confirmed the catalyst’s high activity over three consecutive cycles, with yields of 96.6%, 94.2%, and 86.5%, respectively, while SEM-EDS analysis demonstrated effective Zn retention after repeated use. This study demonstrates a pioneering strategy for transforming marine waste into a high-performance catalyst, paving the way for sustainable biodiesel production. Full article
(This article belongs to the Special Issue State of the Art of Catalytical Technology in Korea, 2nd Edition)
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13 pages, 5189 KiB  
Article
Enhanced Methane Dry Reforming with Ni/SiO2 Catalysts Featuring Hierarchical External Nanostructures
by Yong Jun Kim, Min-Jae Kim, Dong Hyun Kim, Anush Mnoyan and Kyubock Lee
Catalysts 2024, 14(4), 265; https://doi.org/10.3390/catal14040265 - 16 Apr 2024
Cited by 5 | Viewed by 2732
Abstract
Global energy demand escalates the interest in effective and durable catalytic systems for the dry reforming of methane (DRM), a process that converts CO2/CH4 into H2/CO syngas. Porous silica-supported nickel (Ni) catalysts are recognized as a promising candidate [...] Read more.
Global energy demand escalates the interest in effective and durable catalytic systems for the dry reforming of methane (DRM), a process that converts CO2/CH4 into H2/CO syngas. Porous silica-supported nickel (Ni) catalysts are recognized as a promising candidate due to robust DRM activity associated with the confinement of Ni particles in the mesopores that reduces the catalyst deactivation by carbon byproduct deposits and sintering of active Ni sites. However, the small-sized pore configurations in the mesoporous catalysts hinders the fast mass transfer of reactants and products. A unique combination of the hierarchical nanostructure with macro–mesoporous features of the support is adopted to enhance the catalytic performance via the dual effect of the efficient mass transfer and minimized sintering issue. This study delves into the influence of SiO2 geometry and pore structure on the catalytic performance of Ni-based catalysts. Three types of porous silica supports were synthesized through various methods: (a) hydrothermal-assisted sol–gel for dendritic mesoporous silica (DMS), (b) spray-pyrolysis-assisted sol–gel for spray evaporation-induced self-assembly (EISA) silica, and (c) oven-assisted sol–gel for oven EISA silica. Among the prepared catalysts the hierarchical external nanostructured Ni/DMS showed the superior CH4 and CO2 conversion rates (76.6% and 82.1%), even at high space velocities (GHSV = 360 L∙g−1·h−1). The distinctive macro–mesoporous geometry effectively prevents the sintering of Ni particles and promotes the smooth diffusion of the reactants and products, thus improving catalytic stability over extended reaction periods (24 h). This research highlights the significant impact of macro–mesoporosity revealed in DMS support catalysts on the physicochemical properties of Ni/DMS and their crucial role in enhancing DRM reaction efficiency. Full article
(This article belongs to the Special Issue State of the Art of Catalytical Technology in Korea, 2nd Edition)
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Review

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23 pages, 4612 KiB  
Review
Advancements in Chemical Recycling Catalysts for Plastic Waste in South Korea
by Taemin Jang, Ik Shin, Jungwook Choi, Sohyeon Lee, Hyein Hwang, Minchang Kim and Byung Hyo Kim
Catalysts 2025, 15(5), 414; https://doi.org/10.3390/catal15050414 - 23 Apr 2025
Viewed by 1347
Abstract
Plastics are widely used in various industries because of their light weight, low cost, and high durability. The mass production and consumption of plastics have led to a rapid increase in plastic waste problem, necessitating the development of effective recycling technologies. The chemical [...] Read more.
Plastics are widely used in various industries because of their light weight, low cost, and high durability. The mass production and consumption of plastics have led to a rapid increase in plastic waste problem, necessitating the development of effective recycling technologies. The chemical recycling of plastics has emerged as a promising strategy to address these challenges, enabling the conversion of plastic waste into high-purity monomers or oils, even from contaminated or mixed plastic feedstock. This review focuses on the development of catalysts for the chemical recycling of plastics in South Korea, which has one of the highest per capita plastic consumption rates and both academic and industrial efforts in this field. We examine catalytic depolymerization processes for recovering monomers from polymers, such as polyethylene terephthalate (PET) and polycarbonate (PC), as well as catalytic pyrolysis processes for polyolefins, including polyethylene (PE), polypropylene (PP), and polystyrene (PS). By summarizing recent academic research and industrial initiatives in South Korea, this review highlights the strategic role of the country in advancing chemical recycling. Moreover, this review proposes future research directions including the development of reusable catalysts, energy-efficient recycling process, and strategies for recycling mixed or contaminated plastic waste. Full article
(This article belongs to the Special Issue State of the Art of Catalytical Technology in Korea, 2nd Edition)
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