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Search Results (4,222)

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10 pages, 470 KB  
Article
Between-Session Reliability of Portable Isometric Mid-Thigh Pull and Countermovement Jump Tests in Elite Male Ice Hockey Players from the Swedish Hockey League
by Manne Godhe, Sebastian Bergman and Henrik Petré
Sports 2025, 13(12), 456; https://doi.org/10.3390/sports13120456 - 18 Dec 2025
Abstract
This study investigated the test–retest reliability of strength and power-related measures assessed with a portable IMTP set-up and with CMJ in elite ice hockey players from the Swedish Hockey League. Twenty-two male ice hockey players (age: 26.8 ± 5.1 yr; height: 184.5 ± [...] Read more.
This study investigated the test–retest reliability of strength and power-related measures assessed with a portable IMTP set-up and with CMJ in elite ice hockey players from the Swedish Hockey League. Twenty-two male ice hockey players (age: 26.8 ± 5.1 yr; height: 184.5 ± 3.9 cm; body mass: 88.6 ± 5.7 kg) participated in this study. The participants performed three maximal IMTP and CMJ trials on two separate occasions. Absolute and relative variables from the portable IMTP (force and rate of force development) and CMJ (force, power, velocity, impulse, jump height, time to peak force, time to peak power, concentric duration and eccentric duration) were obtained using force plates. Excellent reliability (ICC > 0.90; CV < 5%) was observed for multiple CMJ parameters, such as peak force (ICC = 0.94; CV = 2.7%), concentric and eccentric impulse (ICC = 0.96; CV = 1.4% resp. ICC = 0.95; CV = 2.9%) and CMJ peak power (ICC = 0.93; CV = 2.3%). IMTP peak force also demonstrated excellent reliability (ICC = 0.95; CV = 2.4%). IMTP rate of force development variables yielded reliability ranging from poor to moderate (CV = 12.9–54.6%). CMJ and portable IMTP provide highly reliable assessments of most strength and power-related variables in elite male ice hockey players. While absolute peak impulse, velocity and force, power and concentric duration displayed the highest reliability and should be prioritized, RFD variables require cautious interpretation due to high variability. Full article
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21 pages, 4516 KB  
Article
The Development and Validation of a CFD Model of a Heave Plate for Industrial Applications Using a Lattice-Boltzmann, LES Method
by Javier Armañanzas-Goñi, Miguel Gil, Antonio Medina-Mánuel, Javier Calderon-Sanchez, Juan Pablo Fuertes, Javier Leon and Leo Gonzalez-Gutierrez
Appl. Sci. 2025, 15(24), 13229; https://doi.org/10.3390/app152413229 - 17 Dec 2025
Abstract
This paper presents the development and validation of a 3D CFD model of a heave plate under forced oscillations using the Lattice-Boltzmann, LES software SIMULIA XFlow 2023, which has never been used for industrial applications in this context. The model must be versatile [...] Read more.
This paper presents the development and validation of a 3D CFD model of a heave plate under forced oscillations using the Lattice-Boltzmann, LES software SIMULIA XFlow 2023, which has never been used for industrial applications in this context. The model must be versatile enough to maintain accuracy in extreme cases of amplitudes and frequencies. The validation is carried out with experimental results from previous research, with some results also compared with the ones obtained using a finite-volume software. A lattice and time step convergence is achieved along with a symmetry study. Once the most efficient model has been selected, it is tested under four extreme cases, analyzing the results yielded for the force, added mass and damping coefficients and also assessing its limitations. The results show a good correlation between the model and the experimentation, especially in cases of higher force values, and also the results from the finite-volume software. Furthermore, a vorticity field study is carried out to better understand the behavior of the heave plate in these extreme cases. Finally, an assessment of the dominance of pressure-induced forces over viscous forces under low KC numbers is carried out using radial and surface integration. Full article
(This article belongs to the Section Marine Science and Engineering)
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16 pages, 3410 KB  
Article
Parametric Detailed Design for Complex Spatially Bending-Torsion Steel Members Based on the Grasshopper Platform
by Huan Wang, Jingtao Wang, Junfeng Zhang and Jianquan Lin
Buildings 2025, 15(24), 4552; https://doi.org/10.3390/buildings15244552 - 17 Dec 2025
Abstract
The proliferation of free-form architecture necessitates efficient detailing methods for complex spatially bending-torsion steel members. Current approaches suffer from low modeling efficiency, inaccurate surface fitting, and limited capabilities for variable-section generation and plate unfolding. This study presents a comprehensive parametric detailing module developed [...] Read more.
The proliferation of free-form architecture necessitates efficient detailing methods for complex spatially bending-torsion steel members. Current approaches suffer from low modeling efficiency, inaccurate surface fitting, and limited capabilities for variable-section generation and plate unfolding. This study presents a comprehensive parametric detailing module developed within the Grasshopper (GH) platform to overcome these challenges. The core innovations include (1) a data structure that integrally describes member axes, cross-sections, and unfolding information; (2) an algorithm that automatically generates interpolation points based on curvature variation to ensure axis smoothness; (3) the use of architectural surface normals as member torsion vectors, eliminating manual control point placement; and (4) integrated alignment and unfolding functions for fabrication-ready outputs. In an engineering case study, the module reduced modeling time by approximately 70% compared to conventional methods while achieving a root-mean-square deviation of less than 2 mm between the fitted and target surfaces. The system enables rapid generation of 3D models and 2D fabrication drawings for complex bending-torsion members, significantly enhancing detailing efficiency and precision. Full article
(This article belongs to the Section Building Structures)
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17 pages, 2572 KB  
Article
Analysis of the Concordance Between the Use of Phenotypic Screening Tests with the β-Lactamase Gene Profile in Selected Gram-Negative Bacteria
by Patrycja Głowacka, Izabela Marczuk, Patrycja Wójcicka, Monika Ogórkiewicz, Marta Ciesielska, Dorota Żakowska, Paweł Rutyna, Anna Koszczyńska, Marta Łączyńska, Natalia Podsiadły, Emilia Paziewska and Beata Cieśluk-Olchowska
Antibiotics 2025, 14(12), 1275; https://doi.org/10.3390/antibiotics14121275 - 16 Dec 2025
Abstract
Background: There are many methods of identifying microbial resistance to therapeutic agents; however, they can generally be classified into two main categories: phenotypic and genotypic. The study aims to determine drug sensitivity and to analyze the correlation between the results obtained from [...] Read more.
Background: There are many methods of identifying microbial resistance to therapeutic agents; however, they can generally be classified into two main categories: phenotypic and genotypic. The study aims to determine drug sensitivity and to analyze the correlation between the results obtained from cultures on commercial chromogenic media BrillianceTM CRE (OXOID) and BrillianceTM ESBL (OXOID) and the occurrence of specific resistance genes carbapenemase (IMP, NDM, VIM, KPC, OXA), ESBL β-lactamase (TEM, SHV, CTX-M), and AmpC (CMY, DHA), which will be used in drug sensitivity tests. Methods: The present study used bacteria, including Klebsiella pneumoniae, Acinetobacter baumannii, and Escherichia coli, obtained from patients hospitalized in military hospitals in Poland. All strains were plated on the commercial chromogenic media and subjected to antimicrobial susceptibility testing. Additionally, molecular assays detecting three main classes according to the mechanism of action, enzyme type carbapenemase (IMP, NDM, VIM, KPC, OXA), ESBL β-lactamase (TEM, SHV, CTX-M), and AmpC (CMY, DHA) were performed using the real-time PCR method. Results: The results of the studies indicate the presence of carbapenemases and ESBL genes. Among K. pneumoniae strains, the dominant gene was CTX-M-15 (88.89%), followed by the SHV (84.12%), NDM (46.03%), TEM (41.26%), KPC (34.92%), and OXA-48 (19.04%). In contrast, A. baumanii was dominated by carbapenemases from the OXA family (OXA-51 in 96.00% and OXA-24/40 in 84.00%). E. coli exhibits a high prevalence of CTX-M-15 (53.85%), TEM (46.15%), NDM (38.46%), and CMY-2 (30.77%). It was observed that the CTX-M-15 gene was commonly co-identified with SHV (n = 43). All tested strains grew on chromogenic BrillianceTM CRE medium. In the case of BrillianceTM ESBL medium, the genes determining the resistance mechanism were detected in 41.7% for A. baumannii, 53.8% for E. coli, and 100% for K. pneumoniae. Chromogenic media perfectly differentiate strains to species. A moderate positive correlation of the occurrence of the antibiotic resistance genes was observed for OXA-51 and OXA-24/40 genes, which were resistant to meropenem (rho = 0.45, p < 0.001). K-means cluster analysis performed on integrated genotype–phenotype data allowed for the identification of three distinct clusters characterized by distinct resistance gene profiles. These results demonstrate that selective agar media enable faster identification compared to other conventional techniques; however, the obtained results should be confirmed by other validated phenotypic methods, and, if possible, by a molecular assay. Full article
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20 pages, 6671 KB  
Article
A Nanosecond-Scale, High-Spatiotemporal-Resolution, Near-UV–Visible Imaging System for Advanced Optical Diagnostics with Application to Rotating Detonation Engines
by Junhui Ma, Wen Dai, Dongqi Chen, Jingling Hu, Dong Yang, Lingxue Wang, Dezhi Zheng, Yingchen Shi, Haocheng Wen and Bing Wang
Photonics 2025, 12(12), 1233; https://doi.org/10.3390/photonics12121233 - 16 Dec 2025
Abstract
The combustion diagnostics of rotating detonation engines (RDE) based on excited-state hydroxyl radical (OH*) chemiluminescence imaging is an important method used to characterize combustion flow fields. Overcoming the limitations of imaging devices to achieve nanosecond-scale temporal resolution is crucial for observing the propagation [...] Read more.
The combustion diagnostics of rotating detonation engines (RDE) based on excited-state hydroxyl radical (OH*) chemiluminescence imaging is an important method used to characterize combustion flow fields. Overcoming the limitations of imaging devices to achieve nanosecond-scale temporal resolution is crucial for observing the propagation of high-frequency detonation waves. In this work, a nanosecond-scale imaging system with an ultra-high spatiotemporal resolution was designed and constructed. The system employs four near ultraviolet (NUV)-visible ICMOS, equipped with a high-gain, dual-microchannel plate (MCP) architecture fabricated using a new atomic layer deposition (ALD) process. The system has a maximum electronic gain of 107, a minimum integration time of 3 ns, a minimum interval time 4 ns, and an imaging resolution of 1608 × 1104 pixels. Using this system, high-spatiotemporal-resolution visualization experiments were conducted on RDE, fueled by H2–oxygen-enriched air and NH3–H2–oxygen-enriched air. The results enable the observation of the detonation wave structure, the cellular structure, and the propagation velocity. In combination with optical flow analysis, the images reveal vortex structures embedded within the cellular structure. For NH3-H2 mixed fuel, the results indicate that detonation wave propagation is more unstable than in H2 combustion, with a larger bright gray area covering both the detonation wave and the product region. The experimental results demonstrate that high spatiotemporal OH* imaging enables non-contact, full-field measurements, providing valuable data for elucidating RDE combustion mechanisms, guiding model design, and supporting NH3 combustion applications. Full article
(This article belongs to the Special Issue Optical Measurement Systems, 2nd Edition)
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20 pages, 3813 KB  
Article
Numerical Modeling of Asymmetric-Temperature Cycling for Lithium-Ion Batteries Under Fast-Charging Conditions
by Han Ling, Tao Huang, Wen-Zhen Fang and Wen-Quan Tao
Energies 2025, 18(24), 6570; https://doi.org/10.3390/en18246570 - 16 Dec 2025
Abstract
High temperatures during charge–discharge cycles pose a significant threat to the safety and capacity of lithium-ion batteries by accelerating solid–electrolyte interphase (SEI) growth. Conversely, elevating the temperature during charging enhances Li-ion transport and suppresses lithium plating, suggesting an asymmetric temperature modulation (ATM) strategy [...] Read more.
High temperatures during charge–discharge cycles pose a significant threat to the safety and capacity of lithium-ion batteries by accelerating solid–electrolyte interphase (SEI) growth. Conversely, elevating the temperature during charging enhances Li-ion transport and suppresses lithium plating, suggesting an asymmetric temperature modulation (ATM) strategy in which cells are charged at elevated temperatures and discharged at room temperature to mitigate degradation under extreme fast-charging conditions. In this study, a one-dimensional electrochemical model incorporating key side reactions—SEI formation, lithium plating, and lithium stripping—is developed to analyse the ageing behaviour of plug-in hybrid electric vehicle (PHEV) cells under ATM operation. Within the present modelling framework and for the investigated temperature and current ranges, lithium plating is found to exert only a modest influence on the SEI growth rate, and the capacity degradation associated with SEI formation at a given temperature follows a unique time dependence that shows only a weak sensitivity to the charging rate. A phenomenological hill-shaped dependence of plating reversibility on the state of charge (SOC) is implemented based on experimental observations. The simulation results show good agreement with experimental data for PHEV cells operated under ATM, reproducing a capacity retention of about 80% after 1000 cycles at a charging temperature of 49 °C. Full article
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17 pages, 9490 KB  
Article
Drop Dispersion Through Arrayed Pores in the Combined Trapezoid Spray Tray (CTST)
by Honghai Wang, Kunlong Yi, Quancheng Li, Weiyi Su, Yuqi Hu, Chunli Li and Xiong Yu
Processes 2025, 13(12), 4050; https://doi.org/10.3390/pr13124050 - 15 Dec 2025
Viewed by 111
Abstract
Understanding drop dispersion behavior is significant to the optimization of liquid dispersion devices. In this work, the drop dispersion behavior in the combined trapezoid spray tray was directly observed and analyzed with a high-speed camera. It was found that the fracture of the [...] Read more.
Understanding drop dispersion behavior is significant to the optimization of liquid dispersion devices. In this work, the drop dispersion behavior in the combined trapezoid spray tray was directly observed and analyzed with a high-speed camera. It was found that the fracture of the liquid neck is the main mode for the liquid column to generate drops. The dispersion behavior of the drops was simulated by CFD, and it was found that the liquid neck is caused by the surrounding vortex field and the uneven pressure distribution inside the liquid column. At the same time, the dispersion time of the drops was counted, and it was found that the drop dispersion time ranges from 5 to 60 ms, depending on the drop diameter and the gas kinetic energy factor in plate hole F0. Full article
(This article belongs to the Section Chemical Processes and Systems)
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9 pages, 653 KB  
Article
An Achiasmatic Mechanism That Ensures the Regular Segregation of Sex Chromosomes in Male Meiosis in the Black Spongilla-fly Sisyra nigra (Retzius 1738), Sisyridae, Differs from the Mechanism Commonly Observed Within Neuroptera
by Seppo Nokkala and Christina Nokkala
Insects 2025, 16(12), 1273; https://doi.org/10.3390/insects16121273 - 15 Dec 2025
Viewed by 126
Abstract
The family Sisyridae, the Spongilla-flies, is notable for its phylogenetic position as a basal group within Neuroptera. Using the improved Schiff-Giemsa method, we analyzed the behavior of the sex chromosomes X and Y during male meiosis in Sisyra nigra (Retzius 1738). The diploid [...] Read more.
The family Sisyridae, the Spongilla-flies, is notable for its phylogenetic position as a basal group within Neuroptera. Using the improved Schiff-Giemsa method, we analyzed the behavior of the sex chromosomes X and Y during male meiosis in Sisyra nigra (Retzius 1738). The diploid chromosome number in males was 2n = 12 + XY. In pachytene, X and Y chromosomes appeared positively heteropycnotic and loosely paired. In early diakinetic nuclei, autosomal bivalents typically exhibited one distally located chiasma, although bivalents with two chiasmata were occasionally observed. The X and Y univalents were isopycnotic with the autosomes, with the X considerably larger than the Y. During the first meiotic division, metaphase plates were radial, with autosomal bivalents forming a ring and X and Y univalents positioned centrally, well separated from each other. In metaphase cells, X and Y were located at the equator, strongly indicating their amphitelic orientation. However, they later formed a pseudobivalent from which X and Y segregated simultaneously with autosomal half bivalents at anaphase I. This achiasmatic segregation mechanism, touch-and-go pairing, has now been observed for the first time in a species carrying chromosomes with a localized centromere. At the second metaphase, two cell types were observed: one with the X chromosome and the other with the Y chromosome. The behavior of the sex chromosomes in S. nigra is notably different from that in other Neuroptera, where sex chromosomes exhibit syntelic orientation and distance pairing at metaphase I. The unusual mechanism of sex chromosome segregation in the family Sisyridae aligns well with molecular phylogenetic findings concerning the family’s basal position within the order Neuroptera. Full article
(This article belongs to the Section Insect Behavior and Pathology)
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13 pages, 2152 KB  
Article
Physical Fitness Performance and Psychomotor Abilities in Trained Young Female Handball Players
by Maciej Śliż, Francisco Martins, Cíntia França, Élvio Rúbio Gouveia and Krzysztof Przednowek
Appl. Sci. 2025, 15(24), 13150; https://doi.org/10.3390/app152413150 - 15 Dec 2025
Viewed by 145
Abstract
Physical fitness and psychomotor performance can play a crucial role in decision-making ability, reaction time, and movement time among female handball players at different age levels. Our study aimed to compare the physical fitness performance and psychomotor abilities among trained young female handball [...] Read more.
Physical fitness and psychomotor performance can play a crucial role in decision-making ability, reaction time, and movement time among female handball players at different age levels. Our study aimed to compare the physical fitness performance and psychomotor abilities among trained young female handball players from different age groups (U14 vs. U16). The study group included 61 female handball players (U14 = 26; 13.2±0.8) and U16 = 35; 15.1±0.8). The Mann–Whitney U test was conducted to compare the performance of physical fitness and psychomotor abilities between groups (U14 and U16). Afterward, the Pearson product-moment correlation was used to explore the relationship between physical fitness and psychomotor abilities performance among all participants. Results showed that zig-zag with the ball (s) had a significant correlation with movement time (ms) in the Spatial Attention Test (SPANT) (r = 0.30). The plate tapping test (s) emerged as a strong indicator of psychomotor speed (ms), showing significant correlations with a range of variables, including Simple Reaction Time Test (SIRT) movement time (r = 0.48), Choice Reaction Time Test (CHORT) movement time (r = 0.57), Hand–Eye Coordination Test (HECOR) reaction time (r = –0.48), HECOR movement time (r = 0.69), SPANT reaction time (r = 0.63), and SPANT movement time (r = 0.52). These findings have implications for the development of trained young female handball players. Training programs may benefit from age-specific emphasis, focusing more on fundamental coordination and reaction-based exercises in younger athletes and progressively incorporating cognitively demanding drills for older adolescents. Full article
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27 pages, 4420 KB  
Article
Real-Time Quarry Truck Monitoring with Deep Learning and License Plate Recognition: Weighbridge Reconciliation for Production Control
by Ibrahima Dia, Bocar Sy, Ousmane Diagne, Sidy Mané and Lamine Diouf
Mining 2025, 5(4), 84; https://doi.org/10.3390/mining5040084 - 14 Dec 2025
Viewed by 114
Abstract
This paper presents a real-time quarry truck monitoring system that combines deep learning and license plate recognition (LPR) for operational monitoring and weighbridge reconciliation. Rather than estimating load volumes directly from imagery, the system ensures auditable matching between detected trucks and official weight [...] Read more.
This paper presents a real-time quarry truck monitoring system that combines deep learning and license plate recognition (LPR) for operational monitoring and weighbridge reconciliation. Rather than estimating load volumes directly from imagery, the system ensures auditable matching between detected trucks and official weight records. Deployed at quarry checkpoints, fixed cameras stream to an edge stack that performs truck detection, line-crossing counts, and per-frame plate Optical Character Recognition (OCR); a temporal voting and format-constrained post-processing step consolidates plate strings for registry matching. The system exposes a dashboard with auditable session bundles (model/version hashes, Region of Interest (ROI)/line geometry, thresholds, logs) to ensure replay and traceability between offline evaluation and live operations. We evaluate detection (precision, recall, mAP@0.5, and mAP@0.5:0.95), tracking (ID metrics), and (LPR) usability, and we quantify operational validity by reconciling estimated shift-level tonnage T against weighbridge tonnage T* using Mean Absolute Error (MAE), Mean Absolute Percentage Error (MAPE), R2, and Bland–Altman analysis. Results show stable convergence of the detection models, reliable plate usability under varied optics (day, dusk, night, and dust), low-latency processing suitable for commodity hardware, and close agreement with weighbridge references at the shift level. The study demonstrates that vision-based counting coupled with plate linkage can provide regulator-ready KPIs and auditable evidence for production control in quarry operations. Full article
(This article belongs to the Special Issue Mine Management Optimization in the Era of AI and Advanced Analytics)
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21 pages, 4679 KB  
Article
Parametric Analysis of CFRP Flexural Strengthening of Steel I-Beams Under Monotonic Loading
by Pragyan Shrestha, Alaa Elsisi and Said Abdel-Monsef
J. Compos. Sci. 2025, 9(12), 696; https://doi.org/10.3390/jcs9120696 - 13 Dec 2025
Viewed by 172
Abstract
Externally bonded carbon-fiber-reinforced polymer (CFRP) can increase the flexural capacity of steel beams, but the benefit is often limited by the performance of the adhesive interface. This study develops and validates a three-dimensional finite-element model (FEM) with an explicit cohesive-zone representation of the [...] Read more.
Externally bonded carbon-fiber-reinforced polymer (CFRP) can increase the flexural capacity of steel beams, but the benefit is often limited by the performance of the adhesive interface. This study develops and validates a three-dimensional finite-element model (FEM) with an explicit cohesive-zone representation of the adhesive layer. It reproduced benchmark four-point bending tests in terms of peak load, corresponding mid-span deflection, and the transition from end/intermediate debonding to laminate rupture. A one-factor-at-a-time parametric analysis is carried out to examine the influence of (i) member geometry (beam depth; flange and web thickness), (ii) CFRP configuration (bonded length; laminate thickness), and (iii) bond quality (cohesive normal strength). Within the ranges studied, cohesive strength and bonded length are the primary variables controlling both capacity and failure mode: strengths below about 25 MPa and short plates lead to debonding-governed response. Increasing strength to around 27 MPa and bonded length to 650–700 mm delays debonding, promotes CFRP rupture, and produces the largest incremental gains in peak load, while further increases in length give smaller additional gains. Increasing laminate thickness and steel depth or flange/web thickness always raises peak load, but under baseline bond conditions failure remains debonding and the added material is only partially mobilized. When cohesive strength is increased above the threshold, additional CFRP thickness becomes more effective. A linear regression model is fitted to the FEM dataset to express peak load as a function of bonded length, cohesive strength, laminate thickness, and steel dimensions, and is complemented by a failure-mode map and a cost–capacity chart based on material quantities. Together, these results provide quantitative trends and simple relations that can support preliminary design of CFRP-strengthened steel beams for similar configurations. Full article
(This article belongs to the Special Issue Carbon Fiber Composites, 4th Edition)
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29 pages, 4201 KB  
Article
The Effect of Boron Oxide on the Biocompatibility, Cellular Response, and Antimicrobial Properties of Phosphosilicate Bioactive Glasses for Metallic Implants’ Coatings
by Joy-anne N. Oliver, Qichan Hu, Jincheng Du and Melanie Ecker
Appl. Sci. 2025, 15(24), 13120; https://doi.org/10.3390/app152413120 - 12 Dec 2025
Viewed by 96
Abstract
Bioactive glasses remain promising candidates for enhancing osseointegration on metallic implants. However, achieving a composition that combines controlled dissolution, cytocompatibility, and antimicrobial functionality remains an ongoing challenge. Building upon the prior structural and thermal characterization of boron-substituted 6P55 phosphosilicate glasses, this study investigates [...] Read more.
Bioactive glasses remain promising candidates for enhancing osseointegration on metallic implants. However, achieving a composition that combines controlled dissolution, cytocompatibility, and antimicrobial functionality remains an ongoing challenge. Building upon the prior structural and thermal characterization of boron-substituted 6P55 phosphosilicate glasses, this study investigates the biological consequences of incorporating 0, 5, 10, and 15 mol% B2O3 to determine their suitability as coatings for Ti6Al4V. Glass extracts were evaluated using L-929 fibroblast cultures (MTT assay and ImageJ-based cell counting), antimicrobial assays against Escherichia coli and Staphylococcus aureus using a semi-quantitative dilution-plating method, and SBF immersion studies to assess pH evolution, surface mineralization, and Ca/P ratio development. FTIR and SEM analyses revealed composition-dependent formation of phosphate-, carbonate-, and silicate-rich surface layers, with 5B exhibiting the most consistent early-stage hydroxyapatite-like signatures, supported by Ca/P ratios approaching the stoichiometric value. The pH measurements showed rapid alkalization for 5B and moderate buffering behavior at higher boron contents, consistent with boron-dependent modifications to network connectivity. Cytocompatibility studies demonstrated a dose- and time-dependent reduction in cell number at elevated B2O3 levels, whereas the 0B and 5B extracts maintained higher viability and preserved cell morphology. Antibacterial assays revealed strain-dependent and sub-lethal inhibitory effects, with E. coli exhibiting stronger sensitivity than S. aureus, likely due to differences in cell wall architecture and susceptibility to ionic osmotic microenvironment changes. When considered alongside previously published computational and physicochemical results, the biological data indicate that moderate boron incorporation (5 mol%) provides the most favorable balance between dissolution kinetics, apatite formation, cytocompatibility, and antimicrobial modulation. These findings identify the 5B composition as a strong candidate for further optimization toward bioactive glass coatings on Ti6Al4V implants. Full article
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12 pages, 1200 KB  
Article
Viscosity-Dependent Shrinkage Behavior of Flowable Resin Composites
by Nadja Jeconias, Peter Fischer and Tobias T. Tauböck
Polymers 2025, 17(24), 3292; https://doi.org/10.3390/polym17243292 - 11 Dec 2025
Viewed by 244
Abstract
Flowable resin composites are extensively used in restorative dentistry, where linear polymerization shrinkage and the resulting shrinkage stress are critical for clinical success. This study investigated the relationship between viscosity, linear polymerization shrinkage, and shrinkage stress in flowable resin composite materials. Two low-flow [...] Read more.
Flowable resin composites are extensively used in restorative dentistry, where linear polymerization shrinkage and the resulting shrinkage stress are critical for clinical success. This study investigated the relationship between viscosity, linear polymerization shrinkage, and shrinkage stress in flowable resin composite materials. Two low-flow resin composites (Beautifil Flow Plus F00, Estelite Universal Flow SuperLow), two medium-flow resin composites (Tetric EvoFlow, Estelite Universal Flow Medium), and two high-flow resin composites (Beautifil Flow F10, Estelite Universal Flow High) were examined. Viscosity (n = 3) of the unset materials was determined using a cone–plate rheometer. The composites were photoactivated for 20 s at 1226 mW/cm2, and linear polymerization shrinkage (n = 8) and shrinkage stress (n = 8) of 1.5 mm-thick specimens were recorded in real time for 5 min using a custom-made linometer and stress analyzer, respectively. Data were analyzed with Kruskal–Wallis rank tests followed by Conover post hoc tests, and Spearman correlation analyses were conducted to assess relationships between parameters (α = 0.05). A significant negative correlation was observed between viscosity and shrinkage stress (r = −0.943, p = 0.017). Beautifil Flow F10 exhibited the significantly lowest viscosity (14.60 ± 0.17 Pa·s) and the highest shrinkage stress (0.83 ± 0.14 MPa) among the materials, whereas low-flow composite Estelite Universal Flow SuperLow showed the lowest shrinkage stress (0.65 ± 0.10 MPa). Linear shrinkage ranged from 1.89 ± 0.13% to 3.18 ± 0.21%, but was not correlated with viscosity or stress (p > 0.05). In conclusion, viscosity critically influences polymerization-induced shrinkage stress development in flowable resin composites. Higher-viscosity flowable composites might be beneficial regarding stress build-up during polymerization compared with high-flow composites. Full article
(This article belongs to the Special Issue Advanced Polymeric Materials for Dental Applications III)
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24 pages, 4686 KB  
Article
Parameter Calibration and Experimentation of the Discrete Element Model for Mixed Seeds of Vetch (Vicia villosa) and Oat (Avena sativa) in a Pneumatic Seed Drilling System
by Yu Fu, Dewei Wang, Xufeng Wang, Long Wang, Jianliang Hu, Xingguang Chi and Mao Ji
Appl. Sci. 2025, 15(24), 13048; https://doi.org/10.3390/app152413048 - 11 Dec 2025
Viewed by 93
Abstract
This paper focuses on mixed seeds of Vicia villosa and Avena sativa, with their discrete element model and contact parameters being systematically calibrated and validated to provide reliable theoretical support for the structural design and parameter optimization of the air-assisted seed delivery [...] Read more.
This paper focuses on mixed seeds of Vicia villosa and Avena sativa, with their discrete element model and contact parameters being systematically calibrated and validated to provide reliable theoretical support for the structural design and parameter optimization of the air-assisted seed delivery system. The physical properties of both seed types, including triaxial dimensions, density, moisture content, Poisson’s ratio, and shear modulus, were first measured. The Hertz–Mindlin (no slip) contact model and the multi-sphere aggregation method were employed to construct the discrete element models of Vicia villosa and Avena sativa, with preliminary calibration of the intrinsic model parameters. Poisson’s ratio, elastic modulus, collision restitution coefficient, static friction coefficient, and rolling friction coefficient between the seeds and PLA plastic plate were determined through uniaxial compression, free fall, inclined sliding, and inclined rolling tests. Each test was repeated five times, and the calibration criterion for contact parameters was based on minimizing the relative error between simulation and experimental results. Based on this, experiments on the packing angle of mixed seeds, steepest slope, and a three-factor quadratic rotational orthogonal combination were conducted. The inter-seed collision restitution coefficient, static friction coefficient, and rolling friction coefficient were set as the experimental factors. A total of 23 treatments were designed with repetitions at the center point, and a regression model was established for the relative error of the packing angle with respect to each factor. Based on the measured packing angle of 28.01° for the mixed seeds, the optimal contact parameter combination for the mixed seed pile was determined to be: inter-seed collision restitution coefficient of 0.312, static friction coefficient of 0.328, and rolling friction coefficient of 0.032. The relative error between the simulated packing angle and the measured value was 1.32%. The calibrated inter-seed contact parameters were further coupled into the EDEM–Fluent gas–solid two-phase flow model. Simulations and bench verification tests were carried out under nine treatment combinations, corresponding to three fan speeds (20, 25, and 30 m·s−1) and three total transport efficiencies (12.5, 17.5, and 22.5 g·s−1), with the consistency coefficient of seed distribution in each row being the main evaluation variable. The results showed that the deviation in the consistency coefficient of seed distribution between the simulation and experimental measurements ranged from 1.24% to 3.94%. This indicates that the calibrated discrete element model for mixed seeds and the EDEM–Fluent coupled simulation can effectively reproduce the air-assisted seed delivery process under the conditions of Vicia villosa and Avena sativa mixed sowing, providing reliable parameters and methodological support for the structural design of seeders and DEM-CFD coupled simulations in legume–grass mixed sowing systems. Full article
(This article belongs to the Section Agricultural Science and Technology)
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Article
Effect of Graphene on Interfacial Microstructure and Thermal Conductivity in Copper/Aluminum Composite Plate
by Yifan Liu, Zhaoyang Yang, Yusha Shen, Rui Wang and Lianbo Wang
Coatings 2025, 15(12), 1468; https://doi.org/10.3390/coatings15121468 - 11 Dec 2025
Viewed by 257
Abstract
This study prepared Copper(Cu)/Aluminum(Al) composite materials using hot-rolling technology. The influence of annealing treatment on the interfacial microstructure was systematically investigated, thereby elucidating the correlation between microstructural characteristics and thermal conductivity. The results demonstrated that annealing treatment induced the formation of a continuous [...] Read more.
This study prepared Copper(Cu)/Aluminum(Al) composite materials using hot-rolling technology. The influence of annealing treatment on the interfacial microstructure was systematically investigated, thereby elucidating the correlation between microstructural characteristics and thermal conductivity. The results demonstrated that annealing treatment induced the formation of a continuous intermetallic compound layer at the Cu/Al interface, with its thickness increasing proportionally to elevated temperature and prolonged duration. After spraying graphene onto the aluminum surface via ultrasonic spraying technology, followed by rolling and an annealing treatment, the intermetallic compounds at the Cu/Al interface exhibited a discontinuous distribution pattern. When annealed at 300 °C, the thermal conductivity of the Cu/Al composite plate increased progressively with prolonged duration. For instance, in the absence of graphene, the value increased from 39.288 to 61.827; when graphene was applied via ultrasonic spraying with a spraying distance of 1 mm, the value increased from 49.884 to 73.203, whereas at 400 °C annealing, it exhibited a notable decline as annealing time extended. Graphene at the interface inhibits the diffusion of Cu/Al atoms, reduces the formation of intermetallic compounds, establishes efficient thermal conduction paths, and ultimately enhances the thermal conductivity of the composite material. Full article
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