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28 pages, 4848 KiB  
Article
Mineralogical and Geochemical Features of Soil Developed on Rhyolites in the Dry Tropical Area of Cameroon
by Aubin Nzeugang Nzeukou, Désiré Tsozué, Estelle Lionelle Tamto Mamdem, Merlin Gountié Dedzo and Nathalie Fagel
Standards 2025, 5(3), 20; https://doi.org/10.3390/standards5030020 - 6 Aug 2025
Abstract
Petrological knowledge on weathering processes controlling the mobility of chemical elements is still limited in the dry tropical zone of Cameroon. This study aims to investigate the mobility of major and trace elements during rhyolite weathering and soil formation in Mobono by understanding [...] Read more.
Petrological knowledge on weathering processes controlling the mobility of chemical elements is still limited in the dry tropical zone of Cameroon. This study aims to investigate the mobility of major and trace elements during rhyolite weathering and soil formation in Mobono by understanding the mineralogical and elemental vertical variation. The studied soil was classified as Cambisols containing mainly quartz, K-feldspar, plagioclase, smectite, kaolinite, illite, calcite, lepidocrocite, goethite, sepiolite, and interstratified clay minerals. pH values ranging between 6.11 and 8.77 indicated that hydrolysis, superimposed on oxidation and carbonation, is the main process responsible for the formation of secondary minerals, leading to the formation of iron oxides and calcite. The bedrock was mainly constituted of SiO2, Al2O3, Na2O, Fe2O3, Ba, Zr, Sr, Y, Ga, and Rb. Ce and Eu anomalies, and chondrite-normalized La/Yb ratios were 0.98, 0.67, and 2.86, respectively. SiO2, Al2O3, Fe2O3, Na2O, and K2O were major elements in soil horizons. Trace elements revealed high levels of Ba (385 to 1320 mg kg−1), Zr (158 to 429 mg kg−1), Zn (61 to 151 mg kg−1), Sr (62 to 243 mg kg−1), Y (55 to 81 mg kg−1), Rb (1102 to 58 mg kg−1), and Ga (17.70 to 35 mg kg−1). LREEs were more abundant than HREEs, with LREE/HREE ratio ranging between 2.60 and 6.24. Ce and Eu anomalies ranged from 1.08 to 1.21 and 0.58 to 1.24 respectively. The rhyolite-normalized La/Yb ratios varied between 0.56 and 0.96. Mass balance revealed the depletion of Si, Ca, Na, Mn, Sr, Ta, W, U, La, Ce, Pr, Nd, Sm, Gd and Lu, and the accumulation of Al, Fe, K, Mg, P, Sc, V, Co, Ni, Cu, Zn, Ga, Ge, Rb, Y, Zr, Nb, Cs, Ba, Hf, Pb, Th, Eu, Tb, Dy, Ho, Er, Tm and Yb during weathering along the soil profile. Full article
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41 pages, 7932 KiB  
Article
Element Mobility in a Metasomatic System with IOCG Mineralization Metamorphosed at Granulite Facies: The Bondy Gneiss Complex, Grenville Province, Canada
by Olivier Blein and Louise Corriveau
Minerals 2025, 15(8), 803; https://doi.org/10.3390/min15080803 - 30 Jul 2025
Viewed by 165
Abstract
In the absence of appropriate tools and a knowledge base for exploring high-grade metamorphic terrains, felsic gneiss complexes at granulite facies have long been considered barren and have remained undermapped and understudied. This was the case of the Bondy gneiss complex in the [...] Read more.
In the absence of appropriate tools and a knowledge base for exploring high-grade metamorphic terrains, felsic gneiss complexes at granulite facies have long been considered barren and have remained undermapped and understudied. This was the case of the Bondy gneiss complex in the southwestern Grenville Province of Canada which consists of 1.39–1.35 Ga volcanic and plutonic rocks metamorphosed under granulite facies conditions at 1.19 Ga. Iron oxide–apatite and Cu-Ag-Au mineral occurrences occur among gneisses rich in biotite, cordierite, garnet, K-feldspar, orthopyroxene and/or sillimanite-rich gneisses, plagioclase-cordierite-orthopyroxene white gneisses, magnetite-garnet-rich gneisses, garnetites, hyperaluminous sillimanite-pyrite-quartz gneisses, phlogopite-sillimanite gneisses, and tourmalinites. Petrological and geochemical studies indicate that the precursors of these gneisses are altered volcanic and volcaniclastic rocks with attributes of pre-metamorphic Na, Ca-Fe, K-Fe, K, chloritic, argillic, phyllic, advanced argillic and skarn alteration. The nature of these hydrothermal rocks and the ore deposit model that best represents them are further investigated herein through lithogeochemistry. The lithofacies mineralized in Cu (±Au, Ag, Zn) are distinguished by the presence of garnet, magnetite and zircon, and exhibit pronounced enrichment in Fe, Mg, HREE and Zr relative to the least-altered rocks. In discrimination diagrams, the metamorphosed mineral system is demonstrated to exhibit the diagnostic attributes of, and is interpreted as, a metasomatic iron and alkali-calcic (MIAC) mineral system with iron oxide–apatite (IOA) and iron oxide copper–gold (IOCG) mineralization that evolves toward an epithermal cap. This contribution demonstrates that alteration facies diagnostic of MIAC systems and their IOCG and IOA mineralization remain diagnostic even after high-grade metamorphism. Exploration strategies can thus use the lithogeochemical footprint and the distribution and types of alteration facies observed as pathfinders for the facies-specific deposit types of MIAC systems. Full article
(This article belongs to the Section Mineral Deposits)
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13 pages, 3716 KiB  
Article
Mineralogy and Preparation of High-Purity Quartz: A Case Study from Pegmatite in the Eastern Sector of the North Qinling Orogenic Belt
by Deshui Yu, Yameng Ma, Shoujing Wang, Chi Ma and Fushuai Wei
Minerals 2025, 15(8), 788; https://doi.org/10.3390/min15080788 - 27 Jul 2025
Viewed by 285
Abstract
High-purity quartz (HPQ), an indispensable industrial mineral, serves as a critical raw material for advanced technology sectors. Derived from natural quartz precursors through processing, HPQ preparation efficiency fundamentally depends on raw material selection. Two pegmatite samples (muscovite pegmatite and two-mica pegmatite) sampled from [...] Read more.
High-purity quartz (HPQ), an indispensable industrial mineral, serves as a critical raw material for advanced technology sectors. Derived from natural quartz precursors through processing, HPQ preparation efficiency fundamentally depends on raw material selection. Two pegmatite samples (muscovite pegmatite and two-mica pegmatite) sampled from the eastern sector of the North Qinling Orogenic Belt were investigated through a suite of analytical techniques, as well as processing and purification, to evaluate their potential as raw materials for high-purity quartz. Muscovite pegmatite is predominantly composed of quartz, plagioclase, K-feldspar, muscovite, and garnet, with accessory phases including limonite and kaolinite. However, in addition to quartz, plagioclase, K-feldspar, muscovite, garnet, and limonite, two-mica pegmatite contains minerals such as biotite and calcite. The fluid inclusions in both muscovite and two-mica pegmatite quartz are small, but the former has fewer fluid inclusions. Compared with muscovite pegmatite, surface discontinuity (i.e., cracks, pits, cavities) development is more pronounced in two-mica pegmatite purified quartz, which may be related to its high content of fluid inclusions. Following purification, the total concentration of trace elements decreased significantly. However, the concentrations of Al and Ti appeared to remain the same. Titanium enrichment in purified two-mica pegmatite quartz likely derives from biotite, while Na and Ca concentrations may be related to fluid inclusions or microscopic mineral inclusions. The trace element content (27.69 ppm) in muscovite pegmatite is lower than that (45.28 ppm) of two-mica pegmatite, we thus suggest that muscovite pegmatite quartz is more likely to have the potential to produce high-purity quartz. Full article
(This article belongs to the Special Issue Physicochemical Properties and Purification of Quartz Minerals)
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33 pages, 167102 KiB  
Article
Influence of Mineralogical and Petrographic Properties on the Mechanical Behavior of Granitic and Mafic Rocks
by Muhammad Faisal Waqar, Songfeng Guo, Shengwen Qi, Malik Aoun Murtaza Karim, Khan Zada, Izhar Ahmed and Yanjun Shang
Minerals 2025, 15(7), 747; https://doi.org/10.3390/min15070747 - 17 Jul 2025
Viewed by 368
Abstract
This study investigates the impact of mineralogical and petrographic characteristics on the mechanical behavior of granitic and mafic rocks from the Shuangjiangkou (Sichuan Province) and Damiao complexes (Hebei Province) in China. The research methodology combined petrographic investigation, comprising optical microscopy and Scanning Electron [...] Read more.
This study investigates the impact of mineralogical and petrographic characteristics on the mechanical behavior of granitic and mafic rocks from the Shuangjiangkou (Sichuan Province) and Damiao complexes (Hebei Province) in China. The research methodology combined petrographic investigation, comprising optical microscopy and Scanning Electron Microscopy–Energy-Dispersive X-ray Spectroscopy (SEM-EDS) methods, with methodical geotechnical characterization to establish quantitative relationships between mineralogical composition and engineering properties. The petrographic studies revealed three lithologic groups: fine-to-medium-grained Shuangjiangkou granite (45%–60% feldspar, 27%–35% quartz, 10%–15% mica), plagioclase-rich anorthosite (more than 90% of plagioclase), and intermediate mangerite (40%–50% of plagioclase, 25%–35% of perthite). The uniaxial compressive strength tests showed great variations: granite (127.53 ± 15.07 MPa), anorthosite (167.81 ± 23.45 MPa), and mangerite (205.12 ± 23.87 MPa). Physical properties demonstrated inverse correlations between mechanical strength and both water absorption (granite: 0.25%–0.42%; anorthosite: 0.07%–0.44%; mangerite: 0.10%–0.25%) and apparent porosity (granite: 0.75%–0.92%; anorthosite: 0.20%–1.20%; mangerite: 0.29%–0.69%), with positive correlations to specific gravity (granite: 1.88–3.03; anorthosite: 2.67–2.90; mangerite: 2.43–2.99). Critical petrographic features controlling mechanical behavior include the following: (1) mica content in granite creating anisotropic properties, (2) extensive feldspar alteration through sericitization increasing microporosity and reducing intergranular cohesion, (3) plagioclase micro-fracturing and alteration to clinozoisite–sericite assemblages in anorthosite creating weakness networks, and (4) mangerite’s superior composition of >95% hard minerals with minimal sheet mineral content and limited alteration. Failure mode analysis indicated distinct patterns: granite experiencing shear-dominated failure (30–45° diagonal planes), anorthosite demonstrated tensile fracturing with vertical splitting, and mangerite showed catastrophic brittle failure with extensive fracture networks. These findings provide quantitative frameworks that relate petrographic features to engineering behavior, offering valuable insights for rock mass assessment and engineering design in similar crystalline rock terrains. Full article
(This article belongs to the Special Issue Characterization of Geological Material at Nano- and Micro-scales)
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26 pages, 9198 KiB  
Article
The Exotic Igneous Clasts Attributed to the Cuman Cordillera: Insights into the Makeup of a Cadomian/Pan-African Basement Covered by the Moldavides of the Eastern Carpathians, Romania
by Sarolta Lőrincz, Marian Munteanu, Ştefan Marincea, Relu Dumitru Roban, Valentina Maria Cetean, George Dincă and Mihaela Melinte-Dobrinescu
Geosciences 2025, 15(7), 256; https://doi.org/10.3390/geosciences15070256 - 3 Jul 2025
Viewed by 311
Abstract
The Eastern Carpathians are thrust to the east and north over their Eastern European foreland, tectonically covering it over an area several hundred kilometers across. Information about the nature of the underthrust part of the Carpathian foreland can be obtained from the rock [...] Read more.
The Eastern Carpathians are thrust to the east and north over their Eastern European foreland, tectonically covering it over an area several hundred kilometers across. Information about the nature of the underthrust part of the Carpathian foreland can be obtained from the rock fragments preserved in the sedimentary successions of the Carpathian fold and thrust belt, specifically in the Outer Dacides and the Moldavides. Fragments of felsic rocks occurring within the sedimentary units of the Upper Cretaceous successions of the Moldavides have long been attributed to the Cuman Cordillera—an intrabasinal ridge in the Eastern Outer Carpathians. This work is the first complex geochemical and geochronological study on the exotic igneous clasts of the Cuman Cordillera. Igneous clasts from the southern part of the Moldavides (Variegated clay nappe/formation) are investigated here. They include mainly granites and rhyolites. Phaneritic rocks are composed of cumulus plagioclase, albite, amphibole and biotite, and intercumulus quartz and potassium feldspar, with apatite, magnetite, sphene, and zircon as main accessories, while the porphyritic rocks have a mineral assemblage similar to that mentioned above, displayed in a porphyritic texture with a usually crystallized groundmass. SHRIMP U-Pb zircon dating indicated the 583–597 Ma age interval for magma crystallization. Based on calcareous nannofossils, the depositional age of the investigated igneous clasts is Cenomanian to Maastrichtian, implying that the Cuman Cordillera was an emerged piece of land, herein an active source of sediments in the flysch basin for at least 40 Ma, from the Early Cretaceous (Aptian) to the Late Cretaceous (Maastrichtian). The intrusive and subvolcanic rocks show similar trends for trace and major elements, evincing their comagmatic nature. The enrichment in LILE and LREE relative to HFSE and HREE, as well as the element anomalies (e.g., negative Nb, Ta, and Eu and positive Rb, Ba, K, and Pb) suggest a convergent continental plate margin tectonic setting. Mineral chemistry suggests magma crystallization in relatively oxic conditions (magnetite series), during ascent within a depth of 15 km to 5 km. The igneous rocks attributed to the Cuman ridge display compositional and geochronological features similar to Brno and Thaya batholiths in the Brunovistulian terrane, which could be a piece of the Carpathian foreland not covered by the Tertiary thrusts. Our data confirm the non-Carpathian origin of the igneous clasts, revealing a Neoproterozoic history of the Carpathian foreland units, which include a Cadomian/Pan-African continental arc, exposed mainly during the Late Cretaceous as an intrabasinal island of the Alpine Tethys, traditionally known as the Cuman Cordillera. Full article
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29 pages, 12574 KiB  
Article
Weathering Records from an Early Cretaceous Syn-Rift Lake
by Yaohua Li, Qianyou Wang and Richard H. Worden
Hydrology 2025, 12(7), 179; https://doi.org/10.3390/hydrology12070179 - 3 Jul 2025
Viewed by 334
Abstract
The Aptian–Albian interval represents a significant cooling phase within the Cretaceous “hothouse” climate, marked by dynamic climatic fluctuations. High-resolution continental records are essential for reconstructing terrestrial climate and ecosystem evolution during this period. This study examines a lacustrine-dominated succession of the Shahezi Formation [...] Read more.
The Aptian–Albian interval represents a significant cooling phase within the Cretaceous “hothouse” climate, marked by dynamic climatic fluctuations. High-resolution continental records are essential for reconstructing terrestrial climate and ecosystem evolution during this period. This study examines a lacustrine-dominated succession of the Shahezi Formation (Lishu Rift Depression, Songliao Basin, NE Asia) to access paleo-weathering intensity and paleoclimate variability between the Middle Aptian and Early Albian (c. 118.2–112.3 Ma). Multiple geochemical proxies, including the Chemical Index of Alteration (CIA), were applied within a sequence stratigraphic framework covering four stages of lake evolution. Our results indicate that a hot and humid subtropical climate predominated in the Lishu paleo-lake, punctuated by transient cooling and drying events. Periods of lake expansion corresponded to episodes of intense chemical weathering, while two distinct intervals of aridity and cooling coincided with phases of a reduced lake level and fan delta progradation. To address the impact of potassium enrichment on CIA values, we introduced a rectangular coordinate system on A(Al2O3)-CN(CaO* + Na2O)-K(K2O) ternary diagrams, enabling more accurate weathering trends and CIA corrections (CIAcorr). Uncertainties in CIA correction were evaluated by integrating geochemical and petrographic evidence from deposits affected by hydrothermal fluids and external potassium addition. Importantly, our results show that metasomatic potassium addition cannot be reliably inferred solely from deviations in A-CN-K diagrams or the presence of authigenic illite and altered plagioclase. Calculations of “excess K2O” and CIAcorr values should only be made when supported by robust geochemical and petrographic evidence for external potassium enrichment. This work advances lacustrine paleoclimate reconstruction methodology and highlights the need for careful interpretation of weathering proxies in complex sedimentary systems. Full article
(This article belongs to the Special Issue Lakes as Sensitive Indicators of Hydrology, Environment, and Climate)
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25 pages, 3819 KiB  
Article
Evolution of Mafic Tungnárhraun Lavas: Transcrustal Magma Storage and Ascent Beneath the Bárðarbunga Volcanic System
by Tanya Furman, Denali Kincaid and Collin Oborn Brady
Minerals 2025, 15(7), 687; https://doi.org/10.3390/min15070687 - 27 Jun 2025
Viewed by 482
Abstract
The Tungnárhraun basalts in southern Iceland record a transcrustal magma system formed during Holocene deglaciation. These large-volume (>1 km3) Early through Mid-Holocene lavas contain ubiquitous plagioclase feldspar macrocrysts that are too primitive to have grown from the host lavas. Thermobarometry based [...] Read more.
The Tungnárhraun basalts in southern Iceland record a transcrustal magma system formed during Holocene deglaciation. These large-volume (>1 km3) Early through Mid-Holocene lavas contain ubiquitous plagioclase feldspar macrocrysts that are too primitive to have grown from the host lavas. Thermobarometry based on plagioclase melt and clinopyroxene melt equilibrium reveals a transcrustal structure with at least three distinct storage regions. A lower-crustal mush zone at ~14–30 km is fed by primitive, low 87Sr/86Sr magmas with diverse Ti/K and Al/Ti signatures. Plagioclase feldspar growth is controlled by an experimentally determined pseudoazeotrope where crystals develop inversely correlated An and Mg contents. The rapid ascent of magmas to mid-crustal levels (~8–9 km) allows the feldspar system to revert to conventional thermodynamic phase constraints. Continued plagioclase growth releases heat, causing olivine and pyroxene to be resorbed and giving the magmas their characteristic high CaO/Al2O3 values (~0.8–1.0) and Sc contents (~52 ppm in matrix material). Mid-Holocene MgO-rich lavas with abundant plagioclase feldspar macrocrysts erupted directly from this depth, but both older and younger magmas ascended to a shallow-crustal storage chamber (~5 km) where they crystallized olivine, clinopyroxene, and plagioclase feldspar and evolved to lower MgO contents. The Sr isotope differences between the plagioclase macrocrysts and their carrier melts suggest that the fractionation involves the minor assimilation of country rock. This model does not require the physical disruption of an established and long-lived gabbroic cumulate mush. The transcrustal structures documented here existed in south Iceland at least throughout the Holocene and likely influenced much of Icelandic magmatism. Full article
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18 pages, 6291 KiB  
Article
Petrological Exploration of Magma Storage and Evolution Conditions at the Eastern Virunga Volcanic Province (Rwanda, East African Rift System)
by Fabio Colle, Teresa Trua, Serena Giacomelli, Massimo D’Orazio and Roberto Valentino
Minerals 2025, 15(7), 666; https://doi.org/10.3390/min15070666 - 20 Jun 2025
Cited by 1 | Viewed by 303
Abstract
The Virunga Volcanic Province (VVP), located in the western branch of the East African Rift System, hosts a variety of alkaline lavas erupted from closely spaced volcanic centers. However, the magmatic system of this region, particularly in its eastern sector, remains insufficiently constrained. [...] Read more.
The Virunga Volcanic Province (VVP), located in the western branch of the East African Rift System, hosts a variety of alkaline lavas erupted from closely spaced volcanic centers. However, the magmatic system of this region, particularly in its eastern sector, remains insufficiently constrained. In this study, we present a petrological and geochemical investigation of basaltic to trachytic lavas from the eastern VVP. Thermobarometric analysis of mineral phases indicates that basalts originated from magma storage zones between 4 and 30 km deep, with crystallization temperatures of ~1200 °C and melt H2O contents lower than 1 wt%. In contrast, more evolved magmas crystallized at similar depths, but at lower temperatures (~1050 °C) and higher H2O contents, ranging from 2 to 4 wt%. Thermodynamic modelling suggests that extensive (up to 70%) fractional crystallization of an assemblage dominated by olivine, clinopyroxene, and plagioclase can produce the more evolved trachytic derivatives from basaltic parental melts. When integrated with previous studies from other VVP volcanoes, our findings deepen the understanding of the architecture of the magmatic system beneath the region, suggesting it resembles a well-developed multi-level plumbing system. Full article
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6 pages, 1798 KiB  
Proceeding Paper
Mineralogical Mapping of Pyroxene and Anorthosite in Dryden Crater Using M3 Hyperspectral Data
by Iskren Ivanov and Lachezar Filchev
Eng. Proc. 2025, 94(1), 3; https://doi.org/10.3390/engproc2025094003 - 19 Jun 2025
Viewed by 304
Abstract
This study investigates the mineral composition of the lunar Dryden Crater using Moon Mineralogy Mapper (M3) data. A RGB false-color composite reveals distinct pyroxene, anorthosite, and possibly spinel distribution patterns. Orthopyroxenes, excavated from deep crustal layers, dominate steep slopes, while plagioclase-rich [...] Read more.
This study investigates the mineral composition of the lunar Dryden Crater using Moon Mineralogy Mapper (M3) data. A RGB false-color composite reveals distinct pyroxene, anorthosite, and possibly spinel distribution patterns. Orthopyroxenes, excavated from deep crustal layers, dominate steep slopes, while plagioclase-rich materials align with magma ocean models of lunar crustal formation. Minor clinopyroxenes indicate impact melt origins. While space weathering and shock metamorphism pose analytical challenges, integrating spectral data with geological context elucidates the crater’s complex history. The resulting mineral distribution map supports targeted exploration during upcoming lunar missions, resource prospecting and resource utilization initiatives within this geologically complex region. Full article
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24 pages, 40890 KiB  
Article
Contrasts in Two-Stage Superimposed Magmatism of the Shizhuzi Magmatic Complex-Mo-Cu-Au System, Liaodong Peninsula, North China Craton
by Jinjian Wu, Jinzhong Yang, Jinhui Yang and Qingdong Zeng
Minerals 2025, 15(6), 631; https://doi.org/10.3390/min15060631 - 10 Jun 2025
Viewed by 417
Abstract
The North China Craton (NCC) experienced extensive destruction and modification of its subcontinental lithospheric mantle during the Mesozoic, a period marked by intensive tectonism, magmatism, and mineralization. Among the key manifestations of this event are the Shizhuzi magmatic complex (SMC) and related Mo-Cu-Au [...] Read more.
The North China Craton (NCC) experienced extensive destruction and modification of its subcontinental lithospheric mantle during the Mesozoic, a period marked by intensive tectonism, magmatism, and mineralization. Among the key manifestations of this event are the Shizhuzi magmatic complex (SMC) and related Mo-Cu-Au deposits in the Liaodong Peninsula. This study presents new zircon U-Pb ages and Hf isotope data, along with whole-rock major and trace element geochemical data. Meanwhile, by incorporating published datasets, the magmatism and mineralization of the SMC are discussed. Two-stage magmatic activity is identified in the SMC as follows: (1) Stage I (130–126 Ma) associated with mineralization, and (2) Stage II (121–117 Ma), both corresponding to the peak destruction of the NCC. The mineralized granitoids exhibit I-type affinities and formed in an extension setting. Quartz diorites within this suite were derived from the partial melting of an enriched mantle source, and the high-temperature thermal underplating associated with this process subsequently triggered partial melting of the basaltic lower crust, leading to the generation of granodiorites and monzonitic granites. These rocks experienced limited fractional crystallization (dominated by plagioclase + biotite) and are linked to Mo-Cu-Au mineralization. In contrast, the non-mineralized granitoids are high-K calc-alkaline, peraluminous A-type granites, which developed in an extremely extensional tectonic setting. They were derived from partial melting of ancient lower crust and display characteristics of highly fractionated granites, having undergone extensive crystallization differentiation involving plagioclase + K-feldspar during magmatic evolution. The mineralized and non-mineralized granitoids exhibit distinct differences in lithology, major/trace element characteristics, Hf isotopes, and degree of fractional crystallization. Our proposed two-stage magmatic model—coupled with a mineralization phase—provides significant insights into both magmatic processes and metallogenesis in the Liaodong Peninsula. It further offers key perspectives into the Early Cretaceous decratonization of the NCC in terms of its tectonic–magmatic–mineralization evolution. Full article
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30 pages, 7259 KiB  
Article
Hornblende and Plagioclase Micro-Texture and Compositions: Evidence for Magma Mixing in High-Mg Adakitic Pluton, North China Craton
by Xiaowei Guo and Nengsong Chen
Minerals 2025, 15(6), 604; https://doi.org/10.3390/min15060604 - 4 Jun 2025
Viewed by 425
Abstract
In this study, we performed microtextural, major/minor element, and Sr-isotope analyses on hornblende and plagioclase (as phenocrysts, groundmass, or inclusions) from the Early Cretaceous Jiagou pluton (eastern North China Craton), to elucidate the magma source, possible magma mixing process, and the transition from [...] Read more.
In this study, we performed microtextural, major/minor element, and Sr-isotope analyses on hornblende and plagioclase (as phenocrysts, groundmass, or inclusions) from the Early Cretaceous Jiagou pluton (eastern North China Craton), to elucidate the magma source, possible magma mixing process, and the transition from low-Mg to high-Mg adakitic magmas. Petrographic study and electron microprobe (EMP) analyses reveal well-defined compositional zoning in hornblende and plagioclase phenocrysts. Outward from the core (first zone), the second and third zones show pronounced oscillatory zoning and significant variations in Mg# and An%, while the fourth zone is relatively homogeneous. A corroded albitic plagioclase core with sieve texture is enclosed in the first zone and locally intergrows with worm-like quartz streaks and fine hornblende inclusions, featuring Mg# = 81 (core) and 62 (rim). The new plagioclase infill has An% = 14–41. The corroded plagioclase has an initial 87Sr/86Sr = 0.7074, while that of zoned phenocrystic plagioclase ranges from 0.7068 to 0.7079, suggesting EMI and EMII mantle input. Inclusion hornblende is low in Ti and Cr, while phenocrystic hornblende shows higher Cr in the first zone and lower Cr in the outer zones. The newly discovered mafic microgranular enclaves (MMEs) and regional geochemical data suggest three major magma mixing events. The felsic parental magma was likely originated from a mixed EMI–EMII mantle source before mixing with a mafic magma derived from the partial melting of, successively, a low-Cr and a high-Cr peridotite. Our findings support a petrogenetic model of lower crustal delamination and highlight the critical role of repeated mafic injections in generating high-Mg adakitic magmas. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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21 pages, 6026 KiB  
Article
Tectonic Setting of the Neoproterozoic Gabbroic Intrusions in the Luanchuan Area, Southern Margin of the North China Craton: Constraints from Ilmenite and Biotite Mineralogy
by Jianhan Huang, Zhenzhen Huang, Danli Chen, Kekun Li, Xiaoxiao Huang, Minghao Ren and Yazhou Fan
Minerals 2025, 15(6), 602; https://doi.org/10.3390/min15060602 - 3 Jun 2025
Viewed by 345
Abstract
The Luanchuan Neoproterozoic gabbroic intrusions are located at the southern margin of the North China Craton (NCC), intruding into the marble and schist from the Nannihu and Meiyaogou Formations of the Neoproterozoic Luanchuan Group. The gabbroic rocks consist of plagioclase (30%–50%) and amphibole [...] Read more.
The Luanchuan Neoproterozoic gabbroic intrusions are located at the southern margin of the North China Craton (NCC), intruding into the marble and schist from the Nannihu and Meiyaogou Formations of the Neoproterozoic Luanchuan Group. The gabbroic rocks consist of plagioclase (30%–50%) and amphibole (40%–60%), with minor ilmenite (2%–5%), biotite (1%–3%), and titanite (~1%). Based on the occurrence and mineral chemistry, two types of biotites were identified. The first type of biotite (Bt I) is brown, with a fine- to micro-grained anhedral texture, occurring around the magmatic ilmenite and coexisting with titanite. Bt I is characterized by high TiO2 and FeO contents, with TiO2 > 2 wt% (2.03 wt%–3.15 wt%) and FeO ranging from 19.94 wt% to 22.08 wt%. The other type of biotite (Bt II) is light grayish-brown to dark reddish-brown, with a medium- to coarse-grained euhedral texture, coexisting with grayish-green amphibole. Bt II exhibits lower TiO2 (1.40 wt%–1.90 wt%) and FeO contents (18.03 wt%–21.42 wt%). The K2O (7.56 wt%–9.32 wt%) and SiO2 (34.49 wt%–37.04 wt%) contents of Bt I are slightly lower than those of Bt II (8.28 wt%–9.73 wt% and 35.18 wt%–37.52 wt%, respectively). Despite the low Ti content in biotites, the mineral occurrence indicates that both types of biotite yield a magmatic origin, resulting from the reactions between early crystallized minerals and residual magma. Bt I originated from the reaction between ilmenite and residual magma, while Bt II resulted from the production of the reaction between clinopyroxne and residual magma. Ilmenite exhibits low MgO and Fe2O3 contents but high FeO and MnO contents, suggesting genetic similarities to the Skaergaard and Panzhihua intrusions. Both types of biotites record consistent temperatures (T = 766 to 818 °C), pressures (P = 5.30–8.80 kbar), and oxygen fugacities (log fO2 = −12.35 to −14.06), aligning with those of the Fanshan complex and the Falcon Island intrusion. The mineralogy of ilmenite and biotite indicates that the Luanchuan gabbroic intrusions formed in a continental rift setting, which is considered to be associated with the breakup of the Rodinia supercontinent. Full article
(This article belongs to the Section Mineral Deposits)
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20 pages, 14949 KiB  
Article
The Impact of Redox Atmosphere on the High-Temperature Melting Behavior of Basalt Materials
by Kaiwen Shi, Guanli Xu, Di Wu, Zhen Li, Hao Wang, Huaiming Liu, Jie Li and Jiangfan Liang
Minerals 2025, 15(6), 596; https://doi.org/10.3390/min15060596 - 2 Jun 2025
Viewed by 377
Abstract
This study systematically reveals the fundamental mechanisms controlling redox-induced phase transformations occurring in basalt melting processes via integrated high-temperature redox experiments combined with thermodynamic simulations. Our findings demonstrate that oxidizing conditions drive clinopyroxene dissolution and concurrent crystallization of refractory phases—hematite [(Fe,Ti,Al)2O [...] Read more.
This study systematically reveals the fundamental mechanisms controlling redox-induced phase transformations occurring in basalt melting processes via integrated high-temperature redox experiments combined with thermodynamic simulations. Our findings demonstrate that oxidizing conditions drive clinopyroxene dissolution and concurrent crystallization of refractory phases—hematite [(Fe,Ti,Al)2O3] and magnesioferrite [(Mg,Fe)(Fe,Al)2O4]—where distinct crystallization pathways govern magnesioferrite morphology evolution. Conversely, reducing environments suppress oxide mineral formation while promoting phase transformation from high-melting-point plagioclase to low-melting-point clinopyroxene solid solutions, thus lowering the system’s liquidus temperature to achieve full melting. This provides a theoretical basis for optimizing energy consumption in basalt fiber production and offers new insights into the effects of material melting temperature. Full article
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29 pages, 4366 KiB  
Review
A Comparative Review of Mechanical and Petrographic Properties and Their Role in Estimating the Brittleness Index of Norite: Implications for Geomechanical Applications
by Selaki Grace Molomo, Vhutali Carol Madanda and Fhatuwani Sengani
Appl. Sci. 2025, 15(11), 6200; https://doi.org/10.3390/app15116200 - 30 May 2025
Viewed by 524
Abstract
Norite is a coarse-grained mafic igneous rock dominated by essential calcic plagioclase and orthopyroxene. Norite is known for its toughness, and it has a high compressive strength which makes it important in engineering. This paper examines the mechanical and petrographic properties of norite, [...] Read more.
Norite is a coarse-grained mafic igneous rock dominated by essential calcic plagioclase and orthopyroxene. Norite is known for its toughness, and it has a high compressive strength which makes it important in engineering. This paper examines the mechanical and petrographic properties of norite, including their relevance to geomechanical applications. Despite improvements in brittleness estimation, standardizing brittleness indices remains a challenge due to geological variability, incompatible petrographic techniques, and difficulties in relating mineral composition to mechanical behavior. Current brittleness models mainly rely on mechanical properties, often ignoring key petrographic factors like grain size, mineral composition, alteration, and porosity. This limits their accuracy, especially for complex rocks like norite. Few studies integrate both petrographic and mechanical data, creating a gap in fully understanding the geomechanical behavior of norite. This review was carried out by examining the origin, formation, and petrographic properties of norite, and a comparative analysis of its strength, flexibility, mineral structure, and fracture mechanics was conducted, highlighting their importance in the engineering and mining industries. The results of this study highlight how factors like strength, brittleness, and durability influence norite’s suitability for geomechanical applications in mining, tunneling, and construction. Furthermore, the results outline that the mineral composition of norite affects its strength, with quartz enhancing strength and altered minerals like feldspar, mica, and biotite weakening the rock and making it more prone to fracturing. These results are important for tunneling projects as they help predict how rocks will behave, ensuring tunnel stability and better design in underground support systems. Full article
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44 pages, 10740 KiB  
Article
Fluid Evolution in the Bundelkhand Granite, North Central India: Implications for Hydrothermal Activities in the Bundelkhand Craton
by Duttanjali Rout, Jayanta K. Pati, Terrence P. Mernagh and Mruganka K. Panigrahi
Minerals 2025, 15(6), 579; https://doi.org/10.3390/min15060579 - 29 May 2025
Viewed by 433
Abstract
The Bundelkhand granite (BG) constitutes the bulk of the granitoid complex in the Bundelkhand Craton and preserves imprints of its evolution from the magmatic to a protracted hydrothermal stage as deduced from the petrography. In order to reconstruct such a path of evolution [...] Read more.
The Bundelkhand granite (BG) constitutes the bulk of the granitoid complex in the Bundelkhand Craton and preserves imprints of its evolution from the magmatic to a protracted hydrothermal stage as deduced from the petrography. In order to reconstruct such a path of evolution in this study, thermobarometric calculations were attempted on the mineral chemistry of the major (hornblende, plagioclase, biotite) and minor (epidote, apatite) magmatic phases. They yielded magmatic temperatures and pressures (in excess of 700 °C and ~5 kbar), although not consistently, and indicate mid-crustal conditions at the onset of crystallization. Temperatures in the hydrothermal regime within the BG are better constrained by the chemistry of the chlorite and epidote minerals (340 to 160 °C) that conform with the ranges of homogenization temperatures of aqueous–biphase inclusions in matrix quartz in the BG and subordinate quartz veins. These reconstructions indicate that fluid within the BG evolved down to lower temperatures and towards the deposition of quartz and, more importantly, bears a striking similarity to the temperature–salinity characteristics of fluid in the giant quartz reef system. Scanty mixed aqueous–carbonic inclusions in the BG are indicative of the CO2-poor nature of the BG magma and the exsolution of CO2 at lower pressure (~2.6 kbar). The dominant mechanism of fluid evolution in the BG appears to be the incursion of meteoric fluid, which caused fluid dilution. Laser Raman microspectrometry reveals many types of solid phases in aqueous–carbonic inclusions in the BG domain. The occurrence of unusual, effervescent-type inclusions, though infrequent, bears a striking similarity to that reported in the giant quartz reef domain. Thus, the highlight of the present work is the convincing fluid inclusion evidence that genetically links the BG with the giant quartz reef system, although many cited discrepancies arise from the radiometric dates. We visualize the episodic release of silica-transporting fluid to the major fracture system (now occupied by the giant reef) from the BG, thus making the fluid in the two domains virtually indistinguishable. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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