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Keywords = phase shift modulation

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24 pages, 19374 KB  
Article
Tillage Effects on Bacterial Community Structure and Ecology in Seasonally Frozen Black Soils
by Bin Liu, Zhenjiang Si, Yan Huang, Yanling Sun, Bai Wang and An Ren
Agriculture 2025, 15(20), 2132; https://doi.org/10.3390/agriculture15202132 - 14 Oct 2025
Abstract
Against the backdrop of global climate change intensifying seasonal freeze–thaw cycles, deteriorating soil conditions in farmland within seasonal frost zones constrain agricultural sustainability. This study employed an in situ field experiment during seasonal freeze–thaw periods in the black soil zone of Northeast China [...] Read more.
Against the backdrop of global climate change intensifying seasonal freeze–thaw cycles, deteriorating soil conditions in farmland within seasonal frost zones constrain agricultural sustainability. This study employed an in situ field experiment during seasonal freeze–thaw periods in the black soil zone of Northeast China to investigate the joint regulatory effects of seasonal freeze–thaw processes and tillage practices on multidimensional features of soil bacterial communities. Key results demonstrate that soil bacterial communities possess self-reorganization capacity. α-diversity exhibited cyclical fluctuations: an initial decline followed by a rebound, ultimately approaching pre-freeze–thaw levels. Significant compositional shifts occurred throughout this process, with the frozen period (FP) representing the phase of maximal differentiation. Actinomycetota and Acidobacteriota consistently dominated as the predominant phyla, collectively accounting for 33.4–49% of relative abundance. Bacterial co-occurrence networks underwent dynamic topological restructuring in response to freeze–thaw stress. Period-specific response patterns supported sustained soil ecological functionality. Furthermore, NCM and NST analyses revealed that stochastic processes dominated community assembly during freeze–thaw (NCM R2 > 0.75). Tillage practices modulated this stochastic–deterministic balance: no-tillage with straw mulching (NTS) shifted toward determinism (NST = 0.608 ± 0.224) during the thawed period (TP). Across the seasonal freeze–thaw process, soil temperature emerged as the primary driver of temporal community variations, while soil water content governed treatment-specific differences. This work provides a theoretical framework for exploring agricultural soil ecological evolution in seasonal frost zones. Full article
(This article belongs to the Section Agricultural Soils)
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28 pages, 33417 KB  
Article
Self-Synchronized Common-Mode Current Control Strategy for Power Rebalancing in CPS-PWM Modulated Energy-Storage Modular Multilevel Converters
by Biyang Liu, Cheng Jin, Gong Chen, Kangli Liu and Jianfeng Zhao
Electronics 2025, 14(20), 3990; https://doi.org/10.3390/electronics14203990 - 12 Oct 2025
Viewed by 45
Abstract
Capacitor voltage imbalance among submodules in energy storage modular multilevel converters (MMCs) can lead to current distortion, power oscillations, and even system instability. Traditional voltage control strategies, inherited from non-storage MMCs, offer limited regulation capabilities and are insufficient to address the complex balancing [...] Read more.
Capacitor voltage imbalance among submodules in energy storage modular multilevel converters (MMCs) can lead to current distortion, power oscillations, and even system instability. Traditional voltage control strategies, inherited from non-storage MMCs, offer limited regulation capabilities and are insufficient to address the complex balancing requirements across phases, arms, and submodules in distributed Energy-Storage MMCs (ES-MMC). This paper proposes a self-synchronized common-mode current strategy to achieve capacitor voltage rebalancing in Carrier Phase-Shifted PWM (CPS-PWM) modulated ES-MMCs. The proposed method establishes both phase-level and arm-level power rebalancing pathways by utilizing the common-mode current in the upper and lower arms. Specifically, the DC component of the common-mode current is employed to regulate common-mode power between the arms, while the fundamental-frequency component, through its interaction with the fundamental modulation voltage, is used to adjust differential-mode power. By coordinating these two power components within each phase, the method enables effective capacitor voltage rebalancing among submodules in the presence of power imbalance caused by a nonuniform distributed energy storage converter. A comprehensive analysis of differential- and common-mode voltage regulation under CPS-PWM is presented. The corresponding control algorithm is developed to inject adaptive common-mode voltage based on capacitor voltage deviations, thereby inducing self-synchronized balancing currents. Simulation and experimental results verify that the proposed strategy significantly improves power distribution uniformity and reduces capacitor voltage deviations under various load and disturbance conditions. Full article
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23 pages, 3898 KB  
Article
Phase-Specific Alterations in Gut Microbiota and Their Associations with Energy Intake and Nutritional Clustering in Competitive Weightlifters
by Chun-Yu Kuo, Yu-Ching Lo, Wei-Ling Chen and Yi-Ju Hsu
Nutrients 2025, 17(20), 3199; https://doi.org/10.3390/nu17203199 - 11 Oct 2025
Viewed by 122
Abstract
Background/Objectives: This study investigated how phase-specific dietary strategies and weight regulation influence gut microbiota composition and diversity in competitive weightlifters. Particular emphasis was placed on integrating energy intake, macronutrient clustering, and weight fluctuations across distinct training phases. Methods: Thirteen competitive weightlifters [...] Read more.
Background/Objectives: This study investigated how phase-specific dietary strategies and weight regulation influence gut microbiota composition and diversity in competitive weightlifters. Particular emphasis was placed on integrating energy intake, macronutrient clustering, and weight fluctuations across distinct training phases. Methods: Thirteen competitive weightlifters were recruited, with 10–12 contributing complete data per phase. Fecal and dietary samples were collected during the preparation, competition, and transition phases. Gut microbiota was profiled via 16S rRNA gene sequencing, and alpha/beta diversity was analyzed using QIIME2. K-means clustering based on caloric/macronutrient intake identified dietary patterns. Taxonomic differences were assessed using DESeq2, and microbial structures were compared across training phases, weight classes, and weight-change categories. Results: Overall phylum- and genus-level profiles and diversity indices remained stable across training phases, indicating community-level resilience. However, specific genera varied with dietary and physiological factors. Enterococcus was higher during the preparation phase, whereas Lactobacillus was enriched during the competition and transition phases as well as in the high-calorie cluster. Lightweight and heavyweight athletes also showed distinct microbial structures, and pre- and post-competition weight changes were associated with shifts in selected taxa. Notably, the low-calorie group exhibited higher Shannon diversity than the high-calorie group (p = 0.0058), with Lactobacillus dominance contributing to reduced evenness in high-energy diets. Conclusions: Despite overall microbial stability, dietary energy availability and body-weight regulation modulated specific taxa relevant to performance and recovery. By integrating dietary clustering, weight-class comparison, and pre- and post-competition weight changes, this study provides novel insight into the microbiota of resistance-trained athletes, a population underrepresented in previous research. Despite the modest sample size and single-season scope, this study offers new evidence linking dietary strategies, weight regulation, and gut microbiota in weightlifters, and highlights the need for validation in broader cohorts. Full article
(This article belongs to the Special Issue Advanced Research on Nutrition and Gut–Brain Axis)
19 pages, 1661 KB  
Article
Joint Wavelet and Sine Transforms for Performance Enhancement of OFDM Communication Systems
by Khaled Ramadan, Ibrahim Aqeel and Emad S. Hassan
Mathematics 2025, 13(20), 3258; https://doi.org/10.3390/math13203258 - 11 Oct 2025
Viewed by 76
Abstract
This paper presents a modified Orthogonal Frequency Division Multiplexing (OFDM) system that combines Discrete Wavelet Transform (DWT) with Discrete Sine Transform (DST) to enhance data rate capacity over traditional Discrete Fourier Transform (DFT)-based OFDM systems. By applying Inverse Discrete Wavelet Transform (IDWT) to [...] Read more.
This paper presents a modified Orthogonal Frequency Division Multiplexing (OFDM) system that combines Discrete Wavelet Transform (DWT) with Discrete Sine Transform (DST) to enhance data rate capacity over traditional Discrete Fourier Transform (DFT)-based OFDM systems. By applying Inverse Discrete Wavelet Transform (IDWT) to the modulated Binary Phase Shift Keying (BPSK) bits, the constellation diagram reveals that half of the time-domain samples after single-level Haar IDWT are zeros, while the other half are real. The proposed system utilizes these 0.5N zero values, modulating them with the DST (IDST) and assigning them as the imaginary part of the signal. Performance comparisons demonstrate that the Bit-Error-Rate (BER) of this hybrid DWT-DST configuration lies between that of BPSK and Quadrature Phase Shift Keying (QPSK) in a DWT-based system, while also achieving data rate improvement of 0.5N. Additionally, simulation results indicate that the proposed approach demonstrates stable performance even in the presence of estimation errors, with less than 3.4% BER degradation for moderate errors, and consistently better robustness than QPSK-based systems while offering improved data rate efficiency over BPSK. This novel configuration highlights the potential for more efficient and reliable data transmission in OFDM systems, making it a promising alternative to conventional DWT or DFT-based methods. Full article
(This article belongs to the Special Issue Computational Intelligence in Communication Networks)
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27 pages, 21804 KB  
Article
Analysis and Compensation of Dead-Time Effect in Dual Active Bridge with Asymmetric Duty Cycle
by Pengfei Liu, Shuairan Yu, Ruiyang Zhang, Yanming Cheng and Shaojie Yu
Symmetry 2025, 17(10), 1701; https://doi.org/10.3390/sym17101701 - 10 Oct 2025
Viewed by 88
Abstract
The dead-time effect seriously affects the soft-switching performance and operating efficiency of the dual-active-bridge converter, and also causes problems such as reduced duty cycle, distortion of voltage and current waveforms, and narrowed transmission power range. The proposal of the five-degree-of-freedom modulation strategy transforms [...] Read more.
The dead-time effect seriously affects the soft-switching performance and operating efficiency of the dual-active-bridge converter, and also causes problems such as reduced duty cycle, distortion of voltage and current waveforms, and narrowed transmission power range. The proposal of the five-degree-of-freedom modulation strategy transforms the working voltage waveforms of the primary and secondary sides as well as the inductor current waveform of the DAB converter from symmetric to asymmetric, while the dead-time issue still persists. Based on the five-degree-of-freedom modulation strategy, this paper analyzes the electrical characteristics of the converter before and after the introduction of dead time, designs switch drive pulses to avoid the dead time, and proposes a dead-time compensation modulation strategy based on five-degree-of-freedom phase shift. The results show that the proposed dead-time compensation control strategy can avoid problems such as voltage and current waveform distortion and reduction in the soft-switching power range caused by dead time, realizing dead-time compensation in the full power range. Experimental measurements show that, for different voltage transmission ratios, the maximum efficiency improvement is approximately 3.8–4% and the current stress is reduced by 2.11% to 3.13% under low-power operating conditions. The maximum efficiency improvement is approximately about 1.4–2.8% and the current stress is reduced by 1.84% to 2.53% under high-power operating conditions. Full article
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16 pages, 6701 KB  
Article
Novel Fabry-Pérot Filter Structures for High-Performance Multispectral Imaging with a Broadband from the Visible to the Near-Infrared
by Bo Gao, Tianxin Wang, Lu Chen, Shuai Wang, Chenxi Li, Fajun Xiao, Yanyan Liu and Weixing Yu
Sensors 2025, 25(19), 6123; https://doi.org/10.3390/s25196123 - 3 Oct 2025
Viewed by 339
Abstract
The integration of a pixelated Fabry–Pérot filter array onto the image sensor enables on-chip snapshot multispectral imaging, significantly reducing the size and weight of conventional spectral imaging equipment. However, a traditional Fabry–Pérot cavity, based on metallic or dielectric layers, exhibits a narrow bandwidth, [...] Read more.
The integration of a pixelated Fabry–Pérot filter array onto the image sensor enables on-chip snapshot multispectral imaging, significantly reducing the size and weight of conventional spectral imaging equipment. However, a traditional Fabry–Pérot cavity, based on metallic or dielectric layers, exhibits a narrow bandwidth, which restricts their utility in broader applications. In this work, we propose novel Fabry–Pérot filter structures that employ dielectric thin films for phase modulation, enabling single-peak filtering across a broad operational wavelength range from 400 nm to 1100 nm. The proposed structures are easy to fabricate and compatible with complementary metal-oxide-semiconductor (CMOS) image sensors. Moreover, the structures show low sensitivity to oblique incident angles of up to 30° with minimal wavelength shifts. This advanced Fabry–Pérot filter design provides a promising pathway for expanding the operational wavelength of snapshot spectral imaging systems, thereby potentially extending their application across numerous related fields. Full article
(This article belongs to the Section Sensing and Imaging)
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10 pages, 1603 KB  
Article
Beam Tracking X-Ray Phase-Contrast Imaging Using a Conventional X-Ray Source
by Jiaqi Li, Jianheng Huang, Xin Liu, Yaohu Lei, Botao Mai and Chenggong Zhang
Sensors 2025, 25(19), 6089; https://doi.org/10.3390/s25196089 - 2 Oct 2025
Viewed by 298
Abstract
To address the issue of insufficient contrast in conventional X-ray absorption imaging for biological soft tissues and weakly absorbing materials, this paper proposes a beam tracking X-ray phase-contrast imaging system using a conventional X-ray source. A periodic pinhole array mask is placed between [...] Read more.
To address the issue of insufficient contrast in conventional X-ray absorption imaging for biological soft tissues and weakly absorbing materials, this paper proposes a beam tracking X-ray phase-contrast imaging system using a conventional X-ray source. A periodic pinhole array mask is placed between the X-ray source and the sample to spatially modulate the X-ray beam, dividing it into multiple independent sub-beams. Each sub-beam is deflected due to the modulation effect of the sample, resulting in slight positional shifts in the intensity patterns formed on the detector. The experiments employ an X-ray source with a 400 μm focal spot and use a two-dimensional step-scanning approach to acquire image sequences of various samples. The experimental results show that this method can extract the edge profile and structural changes in the samples to some extent, and it demonstrates good contrast and detail recovery under weak absorption conditions. These results suggest that this method has certain application potential in material inspection, non-destructive testing, and related fields. Full article
(This article belongs to the Special Issue Recent Innovations in X-Ray Sensing and Imaging)
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18 pages, 716 KB  
Article
Metacognitive Modulation of Cognitive-Emotional Dynamics Under Social-Evaluative Stress: An Integrated Behavioural–EEG Study
by Katia Rovelli, Angelica Daffinà and Michela Balconi
Appl. Sci. 2025, 15(19), 10678; https://doi.org/10.3390/app151910678 - 2 Oct 2025
Viewed by 318
Abstract
Background/Objectives: Decision-making under socially evaluative stress engages a dynamic interplay between cognitive control, emotional appraisal, and motivational systems. Contemporary models of multi-level co-regulation posit that these systems operate in reciprocal modulation, redistributing processing resources to prioritise either rapid socio-emotional alignment or deliberate evaluation [...] Read more.
Background/Objectives: Decision-making under socially evaluative stress engages a dynamic interplay between cognitive control, emotional appraisal, and motivational systems. Contemporary models of multi-level co-regulation posit that these systems operate in reciprocal modulation, redistributing processing resources to prioritise either rapid socio-emotional alignment or deliberate evaluation depending on situational demands. Methods: Adopting a neurofunctional approach, a novel dual-task protocol combining the MetaCognition–Stress Convergence Paradigm (MSCP) and the Social Stress Test Neuro-Evaluation (SST-NeuroEval), a simulated social–evaluative speech task calibrated across progressive emotional intensities, was implemented. Twenty professionals from an HR consultancy firm participated in the study, with concurrent recording of frontal-temporoparietal electroencephalography (EEG) and bespoke psychometric indices: the MetaStress-Insight Index and the TimeSense Scale. Results: Findings revealed that decision contexts with higher socio-emotional salience elicited faster, emotionally guided choices (mean RT difference emotional vs. cognitive: −220 ms, p = 0.026), accompanied by oscillatory signatures (frontal delta: F(1,19) = 13.30, p = 0.002; gamma: F(3,57) = 14.93, p ≤ 0.001) consistent with intensified socio-emotional integration and contextual reconstruction. Under evaluative stress, oscillatory activity shifted across phases, reflecting the transition from anticipatory regulation to reactive engagement, in line with models of phase-dependent stress adaptation. Across paradigms, convergences emerged between decision orientation, subjective stress, and oscillatory patterns, supporting the view that cognitive–emotional regulation operates as a coordinated, multi-level system. Conclusions: These results underscore the importance of integrating behavioural, experiential, and neural indices to characterise how individuals adaptively regulate decision-making under socially evaluative stress and highlight the potential of dual-paradigm designs for advancing theory and application in cognitive–affective neuroscience. Full article
(This article belongs to the Special Issue Brain Functional Connectivity: Prediction, Dynamics, and Modeling)
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15 pages, 4024 KB  
Article
Comparative Analysis of Efficiency and Harmonic Generation in Multiport Converters: Study of Two Operating Conditions
by Francisco J. Arizaga, Juan M. Ramírez, Janeth A. Alcalá, Julio C. Rosas-Caro and Armando G. Rojas-Hernández
World Electr. Veh. J. 2025, 16(10), 566; https://doi.org/10.3390/wevj16100566 - 2 Oct 2025
Viewed by 237
Abstract
This study presents a comparative analysis of efficiency and harmonic generation in Triple Active Bridge (TAB) converters under two operating configurations: Case I, with one input source and two loads, and Case II, with two input sources and one load. Two modulation strategies, [...] Read more.
This study presents a comparative analysis of efficiency and harmonic generation in Triple Active Bridge (TAB) converters under two operating configurations: Case I, with one input source and two loads, and Case II, with two input sources and one load. Two modulation strategies, Single-Phase Shift (SPS) and Dual-Phase Shift (DPS), are evaluated through frequency-domain modeling and simulations performed in MATLAB/Simulink. The analysis is complemented by experimental validation on a laboratory prototype. The results show that DPS reduces harmonic amplitudes, decreases conduction losses, and improves output waveform quality, leading to higher efficiency compared to SPS. Harmonic current spectra and total harmonic distortion (THD) are analyzed to quantify the impact of each modulation method. The findings highlight that DPS is more suitable for applications requiring stable power transfer and improved efficiency, such as renewable energy systems, electric vehicles, and multi-source DC microgrids. Full article
(This article belongs to the Section Power Electronics Components)
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20 pages, 7171 KB  
Article
Research on a Phase-Shift-Based Discontinuous PWM Method for 24V Onboard Thermally Limited Micro Voltage Source Inverters
by Shuo Wang and Chenyang Xia
Micromachines 2025, 16(10), 1128; https://doi.org/10.3390/mi16101128 - 30 Sep 2025
Viewed by 277
Abstract
This research explores a phase-shift-based discontinuous PWM method used for 24 V battery-powered onboard micro inverters, which are critical for thermally limited applications like micromachines, where efficient heat dissipation and compact size are paramount. Discontinuous pulse width modulation (DPWM) reduces switching losses by [...] Read more.
This research explores a phase-shift-based discontinuous PWM method used for 24 V battery-powered onboard micro inverters, which are critical for thermally limited applications like micromachines, where efficient heat dissipation and compact size are paramount. Discontinuous pulse width modulation (DPWM) reduces switching losses by clamping the phase voltage to the DC bus in order to improve inverter efficiency. Due to the change in power factor at different operating points from motors or the inductor load, the use of only one DPWM method cannot achieve the optimal efficiency of a three-phase voltage source inverter (3ph-VSI). This paper proposes a generalized DPWM method with a continuously adjustable phase shift angle, which extends the six traditional DPWM methods to any type. According to different power factors, the proposed DPWM method is divided into five power factor angle intervals, namely [−90°, −60°], [−60°, −30°], [−30°, 30°], [30°, 60°], and [60°, 90°], and automatically adjusts the phase shift angle to the optimal-efficiency DPWM mode. The power factor is calculated by means of the Synchronous Reference Frame Phase-Locked Loop (SRF-PLL) method. The switching losses and harmonic characteristics of the proposed DPWM are analyzed, and finally, a 24 V onboard 3ph-VSI experimental platform is built. The experimental results show that the efficiency of DPWM methods can be improved by 3–6% and the switching loss can be reduced by 40–50% under different power factors. At the same time, the dynamic performance of the proposed algorithm with a transition state is verified. This method is particularly suitable for miniaturized inverters where efficiency and thermal management are critical. Full article
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20 pages, 4879 KB  
Article
Sub-Module Capacitor Voltage Ripple Suppression in MMDTC-Based PET Using Three-Port Active Bridge
by Xiangzheng Cui, Decun Niu, Qizhong Yan, Dong Wang, Zhenwei Li and Lei Zhang
Energies 2025, 18(19), 5178; https://doi.org/10.3390/en18195178 - 29 Sep 2025
Viewed by 232
Abstract
For power electronic transformer (PET) based Modular Multilevel DC-Link Based T-type Converters (MMDTC) with Double Active Bridges (DABs) (namely DABs-based MMDTC-PET), the sub-module capacitor voltages exhibit relatively large ripples. To reduce the voltage ripple of sub-module capacitors, this paper proposes a novel MMDTC-PET [...] Read more.
For power electronic transformer (PET) based Modular Multilevel DC-Link Based T-type Converters (MMDTC) with Double Active Bridges (DABs) (namely DABs-based MMDTC-PET), the sub-module capacitor voltages exhibit relatively large ripples. To reduce the voltage ripple of sub-module capacitors, this paper proposes a novel MMDTC-PET structure that utilizes the Three-Port Active Bridges (TABs) to replace the DABs as the isolation stage (TABs-based MMDTC-PET). When the two full bridges of the TAB on the primary side adopt identical phase-shift modulation, the two sub-module capacitors within the upper and lower arms form a parallel connection. This configuration endows the sub-module capacitors with switched-capacitor characteristics, suppressing voltage ripple in the sub-module capacitors and enabling power ripple flow to the secondary side. Meanwhile, by leveraging the characteristic that the AC power components of the upper and lower arm sub-modules have equal amplitudes but opposite phases, these AC power components are mutually canceled on the secondary side of the TAB. Simulation and experimental results verify the effectiveness of the proposed scheme. Full article
(This article belongs to the Section F3: Power Electronics)
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19 pages, 1183 KB  
Article
Changes in Autonomic Balance, Cardiac Parasympathetic Modulation, and Cardiac Baroreflex Gain in Older Adults Under Different Orthostatic Stress Conditions
by Dihogo Gama de Matos, Jefferson Lima de Santana, Felipe J. Aidar, Stephen M. Cornish, Gordon G. Giesbrecht, Albena Nunes-Silva, Roman Romero-Ortuno, Todd A. Duhamel and Rodrigo Villar
Healthcare 2025, 13(19), 2404; https://doi.org/10.3390/healthcare13192404 - 24 Sep 2025
Viewed by 399
Abstract
Background: As we age, our autonomic function declines, resulting in altered autonomic balance during postural transitions. These changes can affect the dynamic interplay between sympathetic and parasympathetic modulation, compromising short-term compensatory responses to active standing. Objectives: This study aimed to compare [...] Read more.
Background: As we age, our autonomic function declines, resulting in altered autonomic balance during postural transitions. These changes can affect the dynamic interplay between sympathetic and parasympathetic modulation, compromising short-term compensatory responses to active standing. Objectives: This study aimed to compare heart rate variability (HRV) at baseline, cardiac parasympathetic modulation (CPM), and cardiac baroreflex gain (CRG) between younger adults (YA) and older adults (OA) following active standing orthostatic stress. A secondary objective was to analyze the incidence of orthostatic intolerance (OI) symptoms. Methods: Participants (n = 76) completed sit-to-stand and lie-to-stand maneuvers with continuous beat-to-beat blood pressure and heart rate (HR, electrocardiogram). HRV at baseline was analyzed in both time and frequency domains. CPM was measured by the HR 30:15 ratio on standing. CBG was determined as the ratio of HR and SBP changes (ΔHR/ΔSBP) at specific phase time points (30 s, 60 s, 180 s, and 420 s). Results: At baseline, OA showed reduced Standard Deviation of RR intervals (SDRR), Root Mean Square of Successive Differences (RMSSD), low-frequency (LF), and high-frequency (HF) power, and elevated LF/HF ratio (all p < 0.05), indicating a shift toward sympathetic dominance. During active standing orthostatic stress, OA demonstrated a lower HR30:15 ratio and CBG in later phases (phases 2–4) (all p < 0.05). Also, OA reported more symptoms (14%) of OI than YA (0%) (p = 0.041). Conclusions: These findings indicate that older adults have impaired autonomic function characterized by reduced HRV, CPM and CBG responses. These impairments lead to diminished autonomic regulation under active-standing orthostatic stress and a higher incidence of OI symptoms. Full article
(This article belongs to the Special Issue Chronic Disease Management for Older Adults)
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11 pages, 578 KB  
Article
Biophysical Characterization of Membrane Interactions of 3-Hydroxy-4-Pyridinone Vanadium Complexes: Insights for Antidiabetic Applications
by Luísa M. P. F. Amaral, Tânia Moniz and Maria Rangel
Inorganics 2025, 13(10), 311; https://doi.org/10.3390/inorganics13100311 - 24 Sep 2025
Viewed by 277
Abstract
The development of metallopharmaceuticals for diabetes treatment has garnered increasing attention due to its insulin-mimetic properties, particularly in vanadium complexes. In this study, we report the biophysical evaluation of a series of 3-hydroxy-4-pyridinone (3,4-HPO) vanadium complexes, designed to improve lipophilicity and biological cytocompatibility. [...] Read more.
The development of metallopharmaceuticals for diabetes treatment has garnered increasing attention due to its insulin-mimetic properties, particularly in vanadium complexes. In this study, we report the biophysical evaluation of a series of 3-hydroxy-4-pyridinone (3,4-HPO) vanadium complexes, designed to improve lipophilicity and biological cytocompatibility. Dynamic light scattering (DLS) was used to get insight on the size of the liposomes and Differential Scanning Calorimetry (DSC) was employed to investigate the interaction of these complexes with model biological membranes made from dimyristoylphosphatidylcholine (DMPC) unilamellar liposomes. The thermotropic phase behavior of the lipid bilayers was analyzed in the presence of vanadium complexes. The results reveal that the alkyl chain length of the 3,4-HPO ligands modulates membrane interaction of the respective vanadium compounds, with specific complexes inducing significant shifts in the lipid phase transition temperature (Tm), suggesting alterations in membrane fluidity and packing. These findings provide valuable insight into the membrane affinity of vanadium-based drug candidates and support their potential as next-generation antidiabetic agents. Full article
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11 pages, 552 KB  
Article
Continuous-Variable Quantum Key Distribution Based on N-APSK Modulation over Seawater Channel
by Lei Mao, Zhangtao Liang, Zhiyue Zuo, Hang Zhang and Yijun Wang
Entropy 2025, 27(9), 990; https://doi.org/10.3390/e27090990 - 22 Sep 2025
Viewed by 297
Abstract
A continuous-variable quantum key distribution (CVQKD) can be realized over the seawater channel, but the transmission of quantum signals in seawater media exhibits significant attenuation effects. Therefore, we propose an N-symbol amplitude and phase shift keying (N-APSK) modulation scheme to [...] Read more.
A continuous-variable quantum key distribution (CVQKD) can be realized over the seawater channel, but the transmission of quantum signals in seawater media exhibits significant attenuation effects. Therefore, we propose an N-symbol amplitude and phase shift keying (N-APSK) modulation scheme to enhance the transmission performance of the CVQKD over the seawater channel. Specifically, an optimal N-APSK modulation scheme is designed based on the principle of maximizing the minimum Euclidean distance (MED). The simulation results show that the CVQKD protocol based on N-APSK modulation achieves a longer transmission distance over the seawater channel compared to the Gaussian modulation protocol. Additionally, increasing the value of N simultaneously expands the number of rings in the constellation diagram, further enhancing the communication distance. This study transfers modulation methods from the field of classical communications to the field of quantum communications, achieving a substantial improvement in communication distance and thereby promoting the integration of quantum communications and classical communications. Full article
(This article belongs to the Special Issue Recent Advances in Continuous-Variable Quantum Key Distribution)
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18 pages, 2746 KB  
Article
First-Principles Investigation of Structural, Electronic, and Optical Transitions in FexZr1−xO2 Solid Solutions
by Djelloul Nouar, Ahmed Hamdi, Ali Benghia and Mohammed ElSaid Sarhani
Appl. Sci. 2025, 15(18), 10224; https://doi.org/10.3390/app151810224 - 19 Sep 2025
Viewed by 431
Abstract
First-principles density-functional theory (PBE, Quantum ESPRESSO) was employed to quantify how Fe substitution modulates the structural, elastic, electronic, and optical behaviour of cubic fluorite FexZr1−xO2 (x = 0.00–1.00). The fluorite FeO2 end member was treated as a [...] Read more.
First-principles density-functional theory (PBE, Quantum ESPRESSO) was employed to quantify how Fe substitution modulates the structural, elastic, electronic, and optical behaviour of cubic fluorite FexZr1−xO2 (x = 0.00–1.00). The fluorite FeO2 end member was treated as a hypothetical ambient-pressure limit to trace trends across the solid solution (experimental FeO2 being stabilized in the high-pressure pyrite phase). Mechanical stability was verified via the cubic Born criteria, and composition-dependent stiffness and anisotropy were assessed through Voigt–Reuss–Hill moduli, Pugh ratio, and elastic indices. A strong band-gap narrowing was found—from 3.41 eV (x = 0) to ≈0.02 eV (x = 0.50)—which was accompanied by a visible–NIR red-shift, large absorption (α ≈ 105 cm−1 at higher x), and enhanced refractive index and permittivity; metallic-like response was indicated at high Fe content. Spin-polarized calculations converged to zero total and absolute magnetization, indicating a non-magnetic ground state at 0 K within PBE. The effect of oxygen vacancies (V0)—expected under Fe3+ charge compensation—was explicitly considered: V0 is anticipated to influence lattice metrics, elastic moduli (B, G, G/B), and sub-gap optical activity, potentially modifying stability and optical figures of merit. Stoichiometric (formal Fe4+) predictions were distinguished from V0-rich scenarios. Absolute band gaps may be underestimated at the PBE level. Full article
(This article belongs to the Section Materials Science and Engineering)
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