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Keywords = perovskite nanocrystals

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16 pages, 1820 KiB  
Article
Ultrafast Study of Interfacial Charge Transfer Mechanism in Assembled Systems of CsPbBr3 and Titanium Dioxide: Size Effect of CsPbBr3
by Ying Lv, Menghan Duan, Jie An, Yunpeng Wang and Luchao Du
Nanomaterials 2025, 15(14), 1065; https://doi.org/10.3390/nano15141065 - 9 Jul 2025
Viewed by 397
Abstract
Lead halide perovskite quantum dots, also known as perovskite nanocrystals, are considered one of the most promising photovoltaic materials for solar cells due to their outstanding optoelectronic properties and simple preparation techniques. The key factors restricting the photoelectric conversion efficiency of solar cell [...] Read more.
Lead halide perovskite quantum dots, also known as perovskite nanocrystals, are considered one of the most promising photovoltaic materials for solar cells due to their outstanding optoelectronic properties and simple preparation techniques. The key factors restricting the photoelectric conversion efficiency of solar cell systems are the separation and transmission performances of charge carriers. Here, femtosecond time-resolved ultrafast spectroscopy was used to measure the interfacial charge transfer dynamics of different sizes of CsPbBr3 assembled with TiO2. The effect of perovskite size on the charge transfer is discussed. According to our experimental data analysis, the time constants of the interfacial electron transfer and charge recombination of the assembled systems of CsPbBr3 and titanium dioxide become larger when the size of the CsPbBr3 nanocrystals increases. We discuss the physical mechanism by which the size of perovskites affects the rate of charge transfer in detail. We expect that our experimental results provide experimental support for the application of novel quantum dots for solar cell materials. Full article
(This article belongs to the Special Issue Metal Halide Perovskite Nanocrystals and Thin Films)
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16 pages, 2160 KiB  
Article
Enhancing Stability and Emissions in Metal Halide Perovskite Nanocrystals Through Mn2⁺ Doping
by Thi Thu Trinh Phan, Thi Thuy Kieu Nguyen, Trung Kien Mac and Minh Tuan Trinh
Nanomaterials 2025, 15(11), 847; https://doi.org/10.3390/nano15110847 - 1 Jun 2025
Cited by 1 | Viewed by 667
Abstract
Metal halide perovskite (MHP) nanocrystals (NCs) offer great potential for high-efficiency optoelectronic devices; however, they suffer from structural softness and chemical instability. Doping MHP NCs can overcome this issue. In this work, we synthesize Mn-doped methylammonium lead bromide (MAPbBr3) NCs using [...] Read more.
Metal halide perovskite (MHP) nanocrystals (NCs) offer great potential for high-efficiency optoelectronic devices; however, they suffer from structural softness and chemical instability. Doping MHP NCs can overcome this issue. In this work, we synthesize Mn-doped methylammonium lead bromide (MAPbBr3) NCs using the ligand-assisted reprecipitation method and investigate their structural and optical stability. X-ray diffraction confirms Mn2⁺ substitution at Pb2⁺ sites and lattice contraction. Photoluminescence (PL) measurements show a blue shift, significant PL quantum yield enhancement, reaching 72% at 17% Mn2⁺ doping, and a 34% increase compared to undoped samples, attributed to effective defect passivation and reduced non-radiative recombination, supported by time-resolved PL data. Mn2⁺ doping also improves long-term stability under ambient conditions. Low-temperature PL reveals the crystal-phase transitions of perovskite NCs and Mn-doped NCs to be somewhat different than those of pure MAPbBr3. Mn2⁺ incorporation into perovskite promotes self-assembly into superlattices with larger crystal sizes, better structural order, and stronger inter-NC coupling. These results demonstrate that Mn2⁺ doping enhances both optical performance and structural robustness, advancing the potential of MAPbBr3 NCs for stable optoelectronic applications. Full article
(This article belongs to the Special Issue Recent Advances in Halide Perovskite Nanomaterials)
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13 pages, 1143 KiB  
Article
Activation of Perovskite Nanocrystals for Volumetric Displays Using Near-Infrared Photon Upconversion by Triplet Fusion
by Yu Hu, Guiwen Luo, Pengfei Niu, Ling Zhang, Tianjun Yu, Jinping Chen, Yi Li and Yi Zeng
Molecules 2025, 30(11), 2273; https://doi.org/10.3390/molecules30112273 - 22 May 2025
Viewed by 450
Abstract
Coupling organic light-harvesting materials with lead halide perovskite quantum dots (LHP QDs) is an attractive approach that could provide great potential in optoelectronic applications owing to the diversity of organic materials available and the intriguing optical and electronic properties of LHP QDs. Here, [...] Read more.
Coupling organic light-harvesting materials with lead halide perovskite quantum dots (LHP QDs) is an attractive approach that could provide great potential in optoelectronic applications owing to the diversity of organic materials available and the intriguing optical and electronic properties of LHP QDs. Here, we demonstrate energy collection by CsPbI3 QDs from a near-infrared (NIR) light-harvesting upconversion system. The upconversion system consists of Pd-tetrakis-5,10,15,20-(p-methoxycarbonylphenyl)-tetraanthraporphyrin (PdTAP) as the sensitizer to harvest NIR photons and rubrene as the annihilator to generate upconverted photons via triplet fusion. Steady-state and time-resolved photoluminescence spectra reveal that CsPbI3 QDs are energized via radiative energy transfer from the singlet excited rubrene with photophysics fidelity of respective components. In addition, a volumetric display demo incorporating CsPbI3 QDs as light emitters employing triplet fusion upconversion was developed, showing bright luminescent images from CsPbI3 QDs. These results present the feasibility of integrating organic light-harvesting systems and perovskite QDs, enabling diverse light harvesting and activation of perovskite materials for optoelectronic applications. Full article
(This article belongs to the Special Issue Photochemistry in Asia)
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15 pages, 3910 KiB  
Article
Incorporating Ag Nanocrystals with LaFeO3 Photocathodes Towards Greatly Enhanced Photoelectrocatalytic Properties
by Sijie Li, Hao Zeng, Jiaqi Fan, Mei Zhu, Caiyi Zhang, Xizhong An, Zhifu Luo, Haitao Fu and Xiaohong Yang
Catalysts 2025, 15(5), 456; https://doi.org/10.3390/catal15050456 - 7 May 2025
Viewed by 546
Abstract
This study focuses on enhancing the photoelectrocatalytic (PEC) performance of LaFeO3 photocathodes by incorporating Ag nanocrystals. LaFeO3, a perovskite-type metal oxide semiconductor, has potential in PEC water splitting but suffers from fast charge carrier recombination. Ag nanoparticles are introduced due [...] Read more.
This study focuses on enhancing the photoelectrocatalytic (PEC) performance of LaFeO3 photocathodes by incorporating Ag nanocrystals. LaFeO3, a perovskite-type metal oxide semiconductor, has potential in PEC water splitting but suffers from fast charge carrier recombination. Ag nanoparticles are introduced due to their surface plasmon resonance (SPR) property and ability to form Schottky junctions with LaFeO3. A series of Ag/LaFeO3 materials are prepared using the molten salt method for LaFeO3 synthesis and the direct reduction method for Ag loading. The results show that Ag nanoparticles are uniformly dispersed on LaFeO3. The 3 mol% Ag/LaFeO3 photocathode demonstrates a remarkable ninefold increase in photocurrent density (15 mA·cm−2 at −0.2 V vs. RHE) compared to pure LaFeO3 (1.7 mA·cm−2). The band gap of LaFeO3 is reduced from 2.07 eV to 1.92 eV with 3 mol% Ag loading, and the charge transfer impedance is reduced by 77%, while the carrier concentration increases by 2.3 times. The novelty of this work lies in the comprehensive investigation of the interaction mechanisms between Ag nanoparticles and LaFeO3, which lead to enhanced light absorption, improved charge separation, and increased electrochemical activity. The optimized Ag loading not only improves the photocatalytic efficiency but also enhances the stability of the photocathode. This work provides valuable insights into the interaction between Ag and LaFeO3, and offers experimental and theoretical support for developing efficient photocatalytic materials for PEC water splitting. Full article
(This article belongs to the Special Issue Advances in Photocatalytic Degradation of Pollutants in Wastewater)
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13 pages, 5562 KiB  
Article
ZrBr4-Mediated Phase Engineering in CsPbBr3 for Enhanced Operational Stability of White-Light-Emitting Diodes
by Muhammad Amin Padhiar, Yongqiang Ji, Jing Wang, Noor Zamin Khan, Mengji Xiong and Shuxin Wang
Nanomaterials 2025, 15(9), 674; https://doi.org/10.3390/nano15090674 - 28 Apr 2025
Viewed by 460
Abstract
The persistent operational instability of all-inorganic cesium lead halide (CsPbX3) perovskite nanocrystals (NCs) has hindered their integration into white-light-emitting diodes (WLEDs). This study introduces a transformative approach by engineering a phase transition from CsPbBr3 NCs to zirconium bromide (ZrBr4 [...] Read more.
The persistent operational instability of all-inorganic cesium lead halide (CsPbX3) perovskite nanocrystals (NCs) has hindered their integration into white-light-emitting diodes (WLEDs). This study introduces a transformative approach by engineering a phase transition from CsPbBr3 NCs to zirconium bromide (ZrBr4)-stabilized hexagonal nanocomposites (HNs) through a modified hot-injection synthesis. Structural analyses revealed that the ZrBr4-mediated phase transformation induced a structurally ordered lattice with minimized defects, significantly enhancing charge carrier confinement and radiative recombination efficiency. The resulting HNs achieved an exceptional photoluminescence quantum yield (PLQY) of 92%, prolonged emission lifetimes, and suppressed nonradiative decay, attributed to effective surface passivation. The WLEDs with HNs enabled a breakthrough luminous efficiency of 158 lm/W and a record color rendering index (CRI) of 98, outperforming conventional CsPbX3-based devices. The WLEDs exhibited robust thermal stability, retaining over 80% of initial emission intensity at 100 °C, and demonstrated exceptional operational stability with negligible PL degradation during 50 h of continuous operation at 100 mA. Commission Internationale de l’Éclairage (CIE) coordinates of (0.35, 0.32) validated pure white-light emission with high chromatic fidelity. This work establishes ZrBr4-mediated HNs as a paradigm-shifting material platform, addressing critical stability and efficiency challenges in perovskite optoelectronics and paving the way for next-generation, high-performance lighting solutions. Full article
(This article belongs to the Special Issue Recent Advances in Halide Perovskite Nanomaterials)
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25 pages, 5995 KiB  
Review
Novel Lead Halide Perovskite and Copper Iodide Materials for Fluorescence Sensing of Oxygen
by Jingwen Jin, Yaning Huang, Chen Zhang, Li Zhang, Shaoxing Jiang and Xi Chen
Biosensors 2025, 15(3), 132; https://doi.org/10.3390/bios15030132 - 21 Feb 2025
Cited by 1 | Viewed by 1335
Abstract
The most commonly used optical oxygen sensing materials are phosphorescent molecules and functionalized nanocrystals. Many exploration studies on oxygen sensing have been carried out using the fluorescence or phosphorescence of semiconductor nanomaterials. Lead halide perovskite nanocrystals, a new type of ionic semiconductor, have [...] Read more.
The most commonly used optical oxygen sensing materials are phosphorescent molecules and functionalized nanocrystals. Many exploration studies on oxygen sensing have been carried out using the fluorescence or phosphorescence of semiconductor nanomaterials. Lead halide perovskite nanocrystals, a new type of ionic semiconductor, have excellent optical properties, making them suitable for use in optoelectronic devices. They also show promising applications in analytical sensing and biological imaging, especially manganese-doped perovskite nanocrystals for optical oxygen sensing. As a class of materials with diverse sources, copper iodide cluster semiconductors have rich structural and excellent luminescent properties, and have attracted attention in recent years. These materials have adjustable optical properties and sensitive stimulus response properties, showing great potential for optical sensing applications. This review paper provides a brief introduction to traditional oxygen sensing using organic molecules and introduces research on oxygen sensing using novel luminescent semiconductor materials, perovskite metal halides and copper iodide hybrid materials in recent years. It focuses on the mechanism and application of these materials for oxygen sensing and evaluates the future development direction of these materials for oxygen sensing. Full article
(This article belongs to the Special Issue State-of-the-Art Biosensors in China (2nd Edition))
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24 pages, 8526 KiB  
Review
Research Progress of Halide Perovskite Nanocrystals in Biomedical Applications: A Review
by Guiyun Wang, Yanxia Qi, Zhiyan Zhou, Zhuang Liu and Ruowei Wang
Inorganics 2025, 13(2), 55; https://doi.org/10.3390/inorganics13020055 - 13 Feb 2025
Cited by 1 | Viewed by 1326
Abstract
Halide perovskite nanocrystals have rapidly emerged as a prominent research topic in materials science over the past decade owing to their exceptional optoelectronic properties and tunability. Their distinctive characteristics, including high light absorption coefficients, high quantum yields, narrow-band emissions, low defect densities, and [...] Read more.
Halide perovskite nanocrystals have rapidly emerged as a prominent research topic in materials science over the past decade owing to their exceptional optoelectronic properties and tunability. Their distinctive characteristics, including high light absorption coefficients, high quantum yields, narrow-band emissions, low defect densities, and adjustable chemical compositions and sizes, position them as highly promising candidates for applications in optoelectronic devices, energy conversion units, and other related systems. However, due to the toxicity and instability of halide perovskite nanocrystals, their widespread application in the biomedical field has been limited in the past. In recent years, numerous innovative coating strategies have been reported to effectively enhance the stability of halide perovskite nanocrystals while confining their toxic metal ions within the coating layers, thereby significantly improving their biocompatibility. This review provides a comprehensive summary of the recent progress of halide perovskite nanocrystals in the field of biomedicine. It covers coating strategies to enhance stability and biocompatibility, as well as the applications of coated halide perovskite nanocrystals in biomedicine, with a particular focus on their unique advantages in bioimaging and chemical sensing. Finally, we address unresolved issues and challenges, such as the metabolic pathways and final products of halide perovskite nanocrystals in vivo. We hope to inspire researchers in the field and provide direction for future studies. Full article
(This article belongs to the Special Issue Advanced Inorganic Semiconductor Materials, 2nd Edition)
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16 pages, 5371 KiB  
Article
Perovskite Nanocrystal-Coated Inorganic Scintillator-Based Fiber-Optic Gamma-ray Sensor with Higher Light Yields
by Seokhyeon Jegal, Siwon Song, Jae Hyung Park, Jinhong Kim, Seunghyeon Kim, Sangjun Lee, Cheol Ho Pyeon, Sin Kim and Bongsoo Lee
Photonics 2024, 11(10), 936; https://doi.org/10.3390/photonics11100936 - 4 Oct 2024
Viewed by 1498
Abstract
Radiation possesses inherent physical characteristics, such as penetrability and radionuclide energy, which enable its widespread applicability in fields such as medicine, industry, environment, security, and research. Advancements in scintillator-based radiation detection technology have led to revolutionary changes by ensuring the safe use and [...] Read more.
Radiation possesses inherent physical characteristics, such as penetrability and radionuclide energy, which enable its widespread applicability in fields such as medicine, industry, environment, security, and research. Advancements in scintillator-based radiation detection technology have led to revolutionary changes by ensuring the safe use and precise measurement of radiation. Nevertheless, certain fields require higher scintillation yields to obtain more refined and detailed results. Therefore, in this study, we explored inorganic scintillators coated with perovskite nanomaterials to detect gamma rays with high light yields. By mixing perovskite with a polymer, we improved the intrinsic characteristics of quantum dots, which otherwise failed to maintain their performance over time. On this basis, we investigated the interactions among inorganic scintillators and a mixed material (CsPbBr3 + PMMA) and confirmed an increase in the scintillation yield and measurement trends. Furthermore, optimized scintillation yield measurement experiments facilitated gamma spectroscopy, demonstrating the validity of our approach through the analysis of the peak channel increases in the energy spectra of various gamma sources in relation to the increased scintillation yield. Full article
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13 pages, 4891 KiB  
Article
Förster Resonance Energy Transfer and Enhanced Emission in Cs4PbBr6 Nanocrystals Encapsulated in Silicon Nano-Sheets for Perovskite Light Emitting Diode Applications
by Araceli Herrera Mondragon, Roberto Gonzalez Rodriguez, Noah Hurley, Sinto Varghese, Yan Jiang, Brian Squires, Maoding Cheng, Brooke Davis, Qinglong Jiang, Mansour Mortazavi, Anupama B. Kaul, Jeffery L. Coffer, Jingbiao Cui and Yuankun Lin
Nanomaterials 2024, 14(19), 1596; https://doi.org/10.3390/nano14191596 - 3 Oct 2024
Cited by 1 | Viewed by 1907
Abstract
Encapsulating Cs4PbBr6 quantum dots in silicon nano-sheets not only stabilizes the halide perovskite, but also takes advantage of the nano-sheet for a compatible integration with the traditional silicon semiconductor. Here, we report the preparation of un-passivated Cs4PbBr6 [...] Read more.
Encapsulating Cs4PbBr6 quantum dots in silicon nano-sheets not only stabilizes the halide perovskite, but also takes advantage of the nano-sheet for a compatible integration with the traditional silicon semiconductor. Here, we report the preparation of un-passivated Cs4PbBr6 ellipsoidal nanocrystals and pseudo-spherical quantum dots in silicon nano-sheets and their enhanced photoluminescence (PL). For a sample with low concentrations of quantum dots in silicon nano-sheets, the emission from Cs4PbBr6 pseudo-spherical quantum dots is quenched and is dominated with Pb2+ ion/silicene emission, which is very stable during the whole measurement period. For a high concentration of Cs4PbBr6 ellipsoidal nanocrystals in silicon nano-sheets, we have observed Förster resonance energy transfer with up to 87% efficiency through the oscillation of two PL peaks when UV excitation switches between on and off, using recorded video and PL lifetime measurements. In an area of a non-uniform sample containing both ellipsoidal nanocrystals and pseudo-spherical quantum dots, where Pb2+ ion/silicene emissions, broadband emissions from quantum dots, and bandgap edge emissions (515 nm) appear, the 515 nm peak intensity increases five times over 30 min of UV excitation, probably due to a photon recycling effect. This irradiated sample has been stable for one year of ambient storage. Cs4PbBr6 quantum dots encapsulated in silicon nano-sheets can lead to applications of halide perovskite light emitting diodes (PeLEDs) and integration with traditional semiconductor materials. Full article
(This article belongs to the Special Issue Nanostructured Materials for Electric Applications)
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25 pages, 5505 KiB  
Review
A Review on Pulsed Laser Preparation of Quantum Dots in Colloids for the Optimization of Perovskite Solar Cells: Advantages, Challenges, and Prospects
by Liang Sun, Yang Li, Jiujiang Yan, Wei Xu, Liangfen Xiao, Zhong Zheng, Ke Liu, Zhijie Huang and Shuhan Li
Nanomaterials 2024, 14(19), 1550; https://doi.org/10.3390/nano14191550 - 25 Sep 2024
Viewed by 2043
Abstract
In recent years, academic research on perovskite solar cells (PSCs) has attracted remarkable attention, and one of the most crucial issues is promoting the power conversion efficiency (PCE) and operational stability of PSCs. Generally, modification of the electron or hole transport layers between [...] Read more.
In recent years, academic research on perovskite solar cells (PSCs) has attracted remarkable attention, and one of the most crucial issues is promoting the power conversion efficiency (PCE) and operational stability of PSCs. Generally, modification of the electron or hole transport layers between the perovskite layers and electrodes via surface engineering is considered an effective strategy because the inherent structural defects between charge carrier transport layers and perovskite layers can be reshaped and modified by adopting the functional nanomaterials, and thus the charge recombination rate can be naturally decreased. At present, large amounts of available nanomaterials for surface modification of the perovskite films are extensively investigated, mainly including nanocrystals, nanorods, nanoarrays, and even colloidal quantum dots (QDs). In particular, as unique size-dependent nanomaterials, the diverse quantum properties of colloidal QDs are different from other nanomaterials, such as their quantum confinement effects, quantum-tunable effects, and quantum surface effects, which display great potential in promoting the PCE and operational stability of PSCs as the charge carriers in perovskite layers can be effectively tuned by these quantum effects. However, preparing QDs with a neat and desirable size remains a technical difficulty, even though the present chemical engineering is highly advanced. Fortunately, the rapid advances in laser technology have provided new insight into the precise preparation of QDs. In this review, we introduce a new approach for preparing the QDs, namely pulsed laser irradiation in colloids (PLIC), and briefly highlight the innovative works on PLIC-prepared QDs for the optimization of PSCs. This review not only highlights the advantages of PLIC for QD preparation but also critically points out the challenges and prospects of QD-based PSCs. Full article
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10 pages, 2956 KiB  
Article
Preparation and Properties Study of CsPbX3@PMMA Luminescent Resin
by Xinqiang Ma, Shengying Fan, Wenwen Yang, Jiajie Wei, Xiaolei Wang, Jincheng Ni, Wei Cheng and Qinhe Zhang
Micromachines 2024, 15(9), 1150; https://doi.org/10.3390/mi15091150 - 13 Sep 2024
Viewed by 1295
Abstract
Perovskite as an emerging semiconductor luminescent material has attracted widespread attention due to its simple preparation, high luminescence quantum yield, high color purity, tunable spectrum, and ability to cover the entire visible light band. However, due to the influence of water or other [...] Read more.
Perovskite as an emerging semiconductor luminescent material has attracted widespread attention due to its simple preparation, high luminescence quantum yield, high color purity, tunable spectrum, and ability to cover the entire visible light band. However, due to the influence of water or other highly polar solvents, oxygen, temperature, and radiation, perovskite nanocrystals will aggregate or collapse in the lattice, eventually leading to luminescence quenching. This study starts from the postprocessing of perovskite, uses methyl methacrylate as the monomer and TPO as the photoinitiator, and encapsulates the perovskite powder prepared by the hot injection method through ultraviolet light initiation. A method is proposed to improve the luminescence and crystal structure stability of perovskite. By eliminating the influence of environmental factors on perovskite nanocrystals through the dense structure formed by organic polymers, the resistance of perovskite to strong polar solvents such as water will be greatly improved, and it has great potential in the protection of perovskite. Finally, by changing the proportion of halogen elements in the perovskite resin to change the color of the luminescent resin, a fluorescent coating emitting light in all visible light bands is prepared. Fluorescent coatings are widely used in life and industry fields such as plastics, sol, and paper. Full article
(This article belongs to the Special Issue Optical and Laser Material Processing)
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11 pages, 1890 KiB  
Article
Nanofiber Space-Confined Fabrication of High-Performance Perovskite Films for Flexible Conversion of Fluorescence Quantum Yields in LED Applications
by Ningbo Yi, Xue Guan, Xiaoting Chen, Luojia Xie, Nan Zhang, Jinfeng Liao, Long Su, Yancheng Wu, Feng Gan, Guoqiang Chang, Liyong Tian and Yangfan Zhang
Polymers 2024, 16(18), 2563; https://doi.org/10.3390/polym16182563 - 11 Sep 2024
Cited by 1 | Viewed by 1326
Abstract
Perovskite is an advanced optoelectronic semiconductor material that has garnered significant attention in recent years. However, its drawback lies in its environmental instability, limiting its practical applications. To tackle this issue, this research delved into the idea of creating a space-confined structure and [...] Read more.
Perovskite is an advanced optoelectronic semiconductor material that has garnered significant attention in recent years. However, its drawback lies in its environmental instability, limiting its practical applications. To tackle this issue, this research delved into the idea of creating a space-confined structure and used electrospinning to produce a film of perovskite nanocomposite fibers. By effectively encapsulating perovskite nanocrystals into a polymer matrix, the perovskite could be shielded from water and oxygen in the environment, thereby reducing the likelihood of perovskite decomposition and enhancing the stability of its structure and properties. This study examined the influence of material composition and the spinning process on the nanofiber structure to create good spatial confinement. This strategy resulted in a high photoluminescence quantum yield of over 80% and a long-term environmental stability of as long as 1000 h over 90% of the original PLQY. By harnessing the flexibility of the composite fibers, this study demonstrated the potential applications and performance of this nanocomposite film in flexible quantum fluorescence conversion for LED applications. Full article
(This article belongs to the Section Polymer Applications)
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21 pages, 3867 KiB  
Review
A Review of Deep-Red (650–700 nm)-Emitting Semiconductor Nanocrystals
by Geyu Jin, Fangze Liu, Jing Wei and Hongbo Li
Crystals 2024, 14(9), 788; https://doi.org/10.3390/cryst14090788 - 5 Sep 2024
Cited by 1 | Viewed by 1597
Abstract
Deep-red light has significant application value in various fields, including biomedicine, plant cultivation, and displays. The development of high-efficiency deep-red luminescent materials is therefore of great importance. Semiconductor nanocrystals have been extensively studied as novel luminescent materials due to their wavelength tunability, narrow [...] Read more.
Deep-red light has significant application value in various fields, including biomedicine, plant cultivation, and displays. The development of high-efficiency deep-red luminescent materials is therefore of great importance. Semiconductor nanocrystals have been extensively studied as novel luminescent materials due to their wavelength tunability, narrow emission linewidth, and high luminescence efficiency. However, the advancement of deep-red nanocrystals has lagged behind that of red, green, and blue nanocrystals, primarily due to material selection limitations. This review summarizes the recent progress in the synthesis of deep-red nanocrystals based on their material composition, including II-VI, III-V, I-III-VI, and perovskite nanocrystals. Full article
(This article belongs to the Special Issue Advances of Perovskite Solar Cells—2nd Edition)
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11 pages, 3841 KiB  
Article
In Situ Growth Method for Large-Area Flexible Perovskite Nanocrystal Films
by Xingting Zhou, Bin Xu, Xue Zhao, Hongyu Lv, Dongyang Qiao, Xing Peng, Feng Shi, Menglu Chen and Qun Hao
Materials 2024, 17(14), 3550; https://doi.org/10.3390/ma17143550 - 18 Jul 2024
Viewed by 1138
Abstract
Metal halide perovskites have shown unique advantages compared with traditional optoelectronic materials. Currently, perovskite films are commonly produced by either multi-step spin coating or vapor deposition techniques. However, both methods face challenges regarding large-scale production. Herein, we propose a straightforward in situ growth [...] Read more.
Metal halide perovskites have shown unique advantages compared with traditional optoelectronic materials. Currently, perovskite films are commonly produced by either multi-step spin coating or vapor deposition techniques. However, both methods face challenges regarding large-scale production. Herein, we propose a straightforward in situ growth method for the fabrication of CsPbBr3 nanocrystal films. The films cover an area over 5.5 cm × 5.5 cm, with precise thickness control of a few microns and decent uniformity. Moreover, we demonstrate that the incorporation of magnesium ions into the perovskite enhances crystallization and effectively passivates surface defects, thereby further enhancing luminous efficiency. By integrating this approach with a silicon photodiode detector, we observe an increase in responsivity from 1.68 × 10−2 A/W to 3.72 × 10−2 A/W at a 365 nm ultraviolet wavelength. Full article
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23 pages, 22654 KiB  
Review
Ligand Engineering of Inorganic Lead Halide Perovskite Quantum Dots toward High and Stable Photoluminescence
by Changbo Deng, Qiuping Huang, Zhengping Fu and Yalin Lu
Nanomaterials 2024, 14(14), 1201; https://doi.org/10.3390/nano14141201 - 15 Jul 2024
Cited by 5 | Viewed by 3810
Abstract
The ligand engineering of inorganic lead halide perovskite quantum dots (PQDs) is an indispensable strategy to boost their photoluminescence stability, which is pivotal for optoelectronics applications. CsPbX3 (X = Cl, Br, I) PQDs exhibit exceptional optical properties, including high color purity and [...] Read more.
The ligand engineering of inorganic lead halide perovskite quantum dots (PQDs) is an indispensable strategy to boost their photoluminescence stability, which is pivotal for optoelectronics applications. CsPbX3 (X = Cl, Br, I) PQDs exhibit exceptional optical properties, including high color purity and tunable bandgaps. Despite their promising characteristics, environmental sensitivity poses a challenge to their stability. This article reviews the solution-based synthesis methods with ligand engineering. It introduces the impact of factors like humidity, temperature, and light exposure on PQD’s instability, as well as in situ and post-synthesis ligand engineering strategies. The use of various ligands, including X- and L-type ligands, is reviewed for their effectiveness in enhancing stability and luminescence performance. Finally, the significant potential of ligand engineering for the broader application of PQDs in optoelectronic devices is also discussed. Full article
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