Search Results (31)

Due to its lightweight and superior adsorption properties, carbon foam is frequently employed for the removal of heavy metal pollutants from aqueous solutions. In this study, a novel modified carbon foam (M-CF) was successfully synthesized for the effective removal of Pb²⁺ and Cd²⁺ from water. The synthesis involved partially substituting phenol with the liquefaction product of bamboo powder, followed by modification with a silane coupling agent (KH560) and foaming with n-hexane-loaded activated carbon (H/AC). The prepared carbon foam was comprehensively characterized, and its adsorption performance and mechanism for Pb²⁺ and Cd²⁺ in aqueous solution were investigated. The results showed that M-CF possessed a uniform and well-developed spherical pore structure and demonstrated excellent removal capacity for Cd²⁺ and Pb²⁺. The adsorption process conformed to the Sips isotherm model and the pseudo-second-order kinetic equation, with maximum adsorption capacities of 22.15 mg·g⁻¹ and 61.59 mg·g⁻¹ for Cd²⁺ and Pb²⁺, respectively. Mechanistic analysis revealed that the removal of Cd²⁺ and Pb²⁺ was a result of the synergistic effect of physisorption and chemisorption, accompanied by complexation. Furthermore, precipitates formed during the adsorption process were found to be mainly composed of hydroxides, carbonates, and PbS. This research demonstrates the efficacy of carbon foam prepared from bamboo powder waste as a partial phenol substitute for the efficient removal of Pb²⁺ and Cd²⁺ from water, thus expanding the preparation pathways for novel heavy metal adsorption materials. Full article

Ammonia is increasingly recognised as a promising carbon-free fuel and hydrogen carrier due to its high hydrogen content, ease of liquefaction, and existing global infrastructure. However, its direct utilisation in combustion systems poses significant challenges, including low flame speed, high ignition temperature, and the formation of nitrogen oxides (NO_X). This review explores catalytic ammonia cracking as a viable method to enhance combustion through in situ hydrogen production. It evaluates traditional catalytic burner designs originally developed for hydrocarbon fuels and assesses their adaptability for ammonia-based applications. Special attention is given to ruthenium- and nickel-based catalysts supported on various oxides and nanostructured materials, evaluating their ammonia conversion efficiency, resistance to sintering, and thermal stability. The impact of the main operational parameters, including reaction temperature and gas hourly space velocity (GHSV), is also discussed. Strategies for combining partial ammonia cracking with stable combustion are studied, with practical issues such as catalyst degradation, NO_X regulation, and system scalability. The analysis highlights recent advancements in structural catalyst support, which have potential for industrial-scale application. This review aims to provide future development of low-emission, high-efficiency catalytic burner systems and advance ammonia’s role in next-generation hydrogen energy technologies. Full article

Compared to pure SF₆ gas, the SF₆/CF₄ gas mixture exhibits certain advantages in reducing greenhouse effects, lowering the liquefaction temperature, and decreasing the sensitivity to non-uniform electric fields, demonstrating significant application potential in high-voltage electrical equipment. This study employs a two-dimensional plasma fluid model to investigate the partial discharge phenomena induced by free metallic particles in SF₆/CF₄ gas mixtures, analyzing the spatiotemporal evolution characteristics of key parameters, such as the charged particle density and axial electric field, under different mixing ratios. The simulation results show that there are two kinds of positive stream discharge phenomena, “continuous and decaying”, when the gas mixture ratio is 90%CF₄-10%SF₆ and 40%CF₄-60%SF₆. The proportion of CF₄ in the gas mixture will affect the spatial distribution of charged particles and the production and disappearance of electrons. When the proportion of CF₄ is 90%, the content of positive ions in the discharge channel is the highest, and the electric field formed by the positive space charge of CF₄⁺ in the stream head promotes the continuous propagation of the stream. As the concentration of CF₄ decreases, the main ionization reaction at the stream head shifts from CF₄ to SF₆, and a negative space charge region dominated by SF₆⁻ particles is also formed near the stream head, changing the electric field distribution near the flow head. The adhesion reaction rate is greater than the ionization reaction rate, resulting in the disappearance of electrons greater than the production, and the stream phenomenon tends to decay. These simulation results are helpful to understand the dynamic process of positive stream discharge induced by free metal particles in SF₆/CF₄ gas mixtures, and they provide a theoretical basis for better solutions to equipment damage caused by partial discharge. Full article

Biomass carbon foams are extensively utilized across various fields due to their favorable properties and cost-effectiveness. In this study, triethylene glycol (TEG), nylon 66 (PA66), and 3-glycidyl-oxypropyl-trimethoxy-silane (KH560) were incorporated into pine wood liquefaction resin to successfully prepare three novel modified carbon foams (MCFs), and their characteristics were investigated. The results indicate that the compressive strength and specific surface area of the three MCFs were significantly enhanced. Specifically, the compressive strength increased by 37%, 46%, and 89% following modification with TEG, PA66, and KH560, respectively, while the specific surface areas ranged from 383.4 to 499.3 m²/g. Additionally, the cell structures of the three MCFs exhibited greater uniformity, with larger average pore sizes, thinner ligament thicknesses, and increased opening porosities. Notably, the opening porosity of KH560-modified carbon foam (KH560-PLP-PF-CF) reached its maximum value at 87.95%. XPS analysis confirmed the successful introduction of Si-containing molecular bonds, including Si-OH-Si, Si-OH, and Si-CH, into KH560-PLP-PF-CF. Furthermore, FT-IR analysis revealed characteristic Si-O vibration peaks, PA66 amide peaks, and TEG ether bond absorption peaks in the three MCFs. The incorporation of flexible functional groups effectively enhanced their compressive properties. The findings of this study expand the potential for utilizing biomass waste to partially replace phenol in the development of novel carbon foams. Full article

The use of black alder (BA) bark biomass in rigid polyurethane (PUR) foam compositions was the main task of investigation. Extractive compounds isolated from the bark through hot water extraction were used as precursors for bio-polyol synthesis via acid-free liquefaction with the polyether polyol Lupranol 3300 and through oxypropylation with propylene carbonate. The OH functionality and composition of the polyols were analyzed via wet chemistry and FTIR spectroscopy. The solid remaining after the isolation of extractive compounds was also utilized as a natural filler in PUR foams. The effects of replacing commercial polyols with bio-polyols on the foam rising rate and their mechanical properties, morphology, thermal conductivity, and thermal degradation characteristics were examined. The oxypropylated extractive-based PUR compositions demonstrated the most favorable balance between the biomass content and material properties. At an apparent density of 40 kg/m³, the compressive strength of the produced foams was enhanced by 1.4–1.5 times, while the maximum thermal degradation rate in air decreased by 3.8–6.5 times compared to reference materials without adversely affecting the foam morphology. The composition based on liquefied extractives showed lower performance but still improved properties relative to the reference foams. Introducing 3.7–14% of extracted bark into the foam compositions increased the biomass content to 22–24%, although this led to a decrease in the compressive strength and thermal stability. It was shown that partially substituting fossil-derived components with renewable bark biomass in the composition of PUR foams allows for materials with characteristics similar or better to petrochemical-based materials to be obtained. Therefore, the results presented can be considered a contribution to addressing environmental problems and promoting the development of a sustainable economy. Full article

One of the critical challenges facing the mining sector is related to the prevention and mitigation of catastrophic incidents associated with its tailing dams. As mining tailings are very heterogeneous and field characterization is expensive and complex, geotechnical properties of these materials are largely unknown. The seismic cone penetration test (SCPTu) provides a field approach to estimate a large array of geotechnical information, including the liquefaction potential of tailing dams. Yet, the exploration of strain softening behaviors in geomaterials under undrained loading, utilizing the state parameter ($\psi$) inferred from SCPTu tests initially applied to soft soils, has been often used for mining tailings. This study is concerned with the implementation of a tailing classification system which uses the ratio between the small strain shear modulus and the cone tip resistance (${\mathrm{G}}_0/{\mathrm{q}}_{\mathrm{t}}$). A series of laboratory tests was executed, and three different methodologies were adopted to assess the effects of (partial) drainage conditions based on 531.26 m of SCPTu measurements conducted at three different upstream iron ore tailing dams in Brazil. Furthermore, the ${\mathrm{G}}_0/{\mathrm{q}}_{\mathrm{t}}$ ratio is integrated with $\psi$ to assess the liquefaction tendencies of the investigated materials. The findings reveal the heterogeneous nature of the tailings, wherein indications of partial drainage are discernible across numerous records. Liquefaction analyses demonstrate that the tailings exhibit a contractive behavior in over 94% of the SCPTu data, confirming their susceptibility to flow liquefaction. Our findings are relevant for site characterization within iron ore tailing dams and other mining sites with similar geotechnical attributes. Full article

Earthquake-induced soil liquefaction is a catastrophic phenomenon that can damage existing building foundations and other structures, resulting in significant economic losses. Traditional mitigation techniques against liquefaction present critical aspects, such as high construction costs, impact on surrounding infrastructure and effects on the surrounding environment. Therefore, research is ongoing in order to develop new approaches and technologies suitable to mitigate liquefaction risk. Among the innovative countermeasures against liquefaction, Induced Partial Saturation (IPS) is considered one of the most promising technologies. It consists of introducing gas/air bubbles into the pore water of sandy soils in order to increase the compressibility of the fluid phase and then enhance liquefaction resistance. IPS is economical, eco-friendly and suitable for urbanised areas, where the need to reduce the risk of liquefaction must be addressed, taking into account the integrity of existing buildings. However, IPS is still far from being a routine technology since more aspects should be better understood. The main aim of this review is to raise some important questions and encourage further research and discussions on this topic. The review first analyses and discusses the effects of air/gas bubbles on the cyclic behaviour of sandy soils, focusing on the soil volume element scale and then extending the considerations to the real scale. The use of useful design charts is also described. Moreover, a section will be devoted to the effect of IPS under shallow foundations. The readers will fully understand the research trend of IPS liquefaction mitigation and will be encouraged to further explore new practical aspects to overcome the application difficulties and contribute to spreading the use of this technology. Full article

Induced partial saturation (IPS) is a new foundation treatment method for mitigating soil liquefaction using biogas. A series of laboratory tests were performed to demonstrate the influencing factors of IPS using Pseudomonas stutzeri biogas. On the basis of the optimal biogas production conditions, the intervention effect of Pseudomonas stutzeri biogas on the foundation deformation under buildings was investigated based on shaking table tests. The test results showed that the best carbon source in the denitrification process of Pseudomonas stutzeri biogas is sodium citrate. The most effective initial value of optical density-based concentration was 0.1. The carbon–nitrogen ratio (C/N) of the bacterium suspension was used as the index to control the saturation. The degree of saturation reduction showed a good linear correlation with the C/N. The optimum temperature of this method was between 20 °C and 30 °C. The most suitable pH value was between 7 and 9. The environmental factors had minimal influence on the degree of saturation reduction but had a significant effect on the average rate of gas generation and the period of initial stagnation. After Pseudomonas stutzeri biogas desaturation, the settlement of the building was greatly reduced. The settlement of saturation of 92.5% sand foundation reached 17.1 mm, and the 85% saturation was only 10.6 mm. These results provide a good foundation for the feasibility of utilizing Pseudomonas stutzeri biogas mitigation of the liquefaction hazard of sand. Full article

The state parameter allows the evaluation of the in situ state of soils, which can be particularly useful in tailings impoundments where flow liquefaction is the most common failure model. Positive state parameter values characterize a contractive response during shearing and, for non-plastic soils, can indicate flow liquefaction susceptibility. This paper presents a methodology to classify and estimate the state parameter (Ψ) for non-plastic silty soils based on seismic cone penetration measurements. The method expands on a previous methodology developed for sands that use the ratio of the small strain shear modulus and the cone tip resistance G₀/q_t for classification and Ψ assessment. For non-plastic silty soils, drainage conditions during cone penetration must be accounted for and are used to allow soil classification and correct the cone tip resistance. An empirical formulation is proposed to correct q_t for partial drainage measurements and predict Ψ for non-plastic silty soils. Mining tailings results of in situ and laboratory tests were used to validate the proposed methodology producing promising responses. The Ψ value estimated through the proposed methodology are in the range of those obtained from laboratory tests, indicating an adequate prediction of behavior for non-plastic silty soils. Full article

In recent years, hydrothermal liquefaction (HTL) has gained attention as a means of enhancing and increasing the production of biofuels from biomass. Co-HTL involves the simultaneous processing of two or more feedstocks, with the potential for interactions that can affect the overall yield and quality of the resulting biofuels. This study investigates the bio-crude yield, chemical composition, and energy content of bio-crudes obtained through formic acid-assisted hydrothermal liquefaction of combined digested sewage sludge (DSS) and lignocellulose (LC). The bio-crude yields are in the range of 26.8–58.9 wt%, with a higher heating value (HHV) of approximately 32 MJ/kg. The best experiment shows that mixtures with more DSS and high levels of process condition variables (350 °C, formic acid present, and 50 wt% EtOH) give high bio-crude yields with a maximum value of 58.9 wt%. For comparison, pure DSS and LC run at these process conditions resulted in a bio-crude yield of 52.5 wt% and 48.3 wt%, respectively. Partial least squares (PLS) regression reveals a synergistic effect from mixing the feedstocks, as the quadratic term of the regression equation for mixture ratio shows a negative coefficient. GC–MS data show that combining feedstocks results in the formation of new compounds, mostly phenols, that are not present in the bio-crudes from the separate feedstocks. Thus, combining feedstocks will not only increase the resource availability for hydrothermal liquefaction and streamline the process but will also increase the overall production of bio-crude with its synergistic effect. Full article

Understanding the stability of the seabed foundation holds paramount significance in guaranteeing the safety and structural soundness of the breakwater alongside additional offshore structures. This study aimed to investigate the stability of a sandy seabed foundation around a semi-circular breakwater under wave loading in nearshore areas. A coupled numerical model of waves, a semi-circular breakwater, and the seabed was developed based on the OpenFOAM platform. The VARANS equations were used to govern the wave behavior. Meanwhile, the Biot’s partially dynamic model was employed to numerically simulate the seabed response considering both consolidation under self-weight and dynamic response under wave loading. The effects of various wave parameters, seabed properties, and the radius of the structure on the dynamic response of the seabed and the depth of liquefaction were investigated. The numerical results indicate that an increase in wave height, period, and permeability coefficient intensifies the dynamic response of the seabed soil. Furthermore, an increase in water depth weakened the soil’s dynamic response. There was a negative correlation between the radius of the semi-circular breakwater and the dynamic response. The influence of Poisson’s ratio on the dynamic response of the seabed was relatively small. Furthermore, a stronger dynamic pore pressure response was observed at the connection between the semi-circular breakwater and the rubble foundation. Full article

Asphalt is an essential material in the construction of asphalt pavements. Due to its high demand and dependence on petroleum, it is crucial to use greener materials that can fully or partially replace petroleum-based binders. The characteristics of asphalt cause the bio-binder obtained through a hydrothermal liquefaction process from swine manure to have great potential to be used as a modifier due to its similarities with asphalt, contributing to the construction of more sustainable roads. Thus, this paper characterizes an asphalt binder modified with a new bio-binder obtained from swine manure at different rates (0%, 10%, and 20%). Several characterization tests were performed, including penetration, ring and ball, Fraass, viscosity, Cleveland open cup, and the UCL method. Furthermore, the possible leaching of the bio-binder was studied, showing no environmental problems. Results from the rheological tests showed that as the content of bio-binder increases, the softening temperature, Fraass breaking point, and viscosity of the bio-modified asphalt binder decrease, indicating the lower consistency of the bio-modified binder and its greater thermal susceptibility. Full article

Soil liquefaction often occurs as a secondary hazard during earthquakes and can lead to significant structural and infrastructure damage. Liquefaction is most often documented through field reconnaissance and recorded as point locations. Complete liquefaction inventories across the impacted area are rare but valuable for developing empirical liquefaction prediction models. Remote sensing analysis can be used to rapidly produce the full spatial extent of liquefaction ejecta after an event to inform and supplement field investigations. Visually labeling liquefaction ejecta from remotely sensed imagery is time-consuming and prone to human error and inconsistency. This study uses a partially labeled liquefaction inventory created from visual annotations by experts and proposes a pixel-based approach to detecting unlabeled liquefaction using advanced machine learning and image processing techniques, and to generating an augmented inventory of liquefaction ejecta with high spatial completeness. The proposed methodology is applied to aerial imagery taken from the 2011 Christchurch earthquake and considers the available partial liquefaction labels as high-certainty liquefaction features. This study consists of two specific comparative analyses. (1) To tackle the limited availability of labeled data and their spatial incompleteness, a semi-supervised self-training classification via Linear Discriminant Analysis is presented, and the performance of the semi-supervised learning approach is compared with supervised learning classification. (2) A post-event aerial image with RGB (red-green-blue) channels is used to extract color transformation bands, statistical indices, texture components, and dimensionality reduction outputs, and performances of the classification model with different combinations of selected features from these four groups are compared. Building footprints are also used as the only non-imagery geospatial information to improve classification accuracy by masking out building roofs from the classification process. To prepare the multi-class labeled data, regions of interest (ROIs) were drawn to collect samples of seven land cover and land use classes. The labeled samples of liquefaction were also clustered into two groups (dark and light) using the Fuzzy C-Means clustering algorithm to split the liquefaction pixels into two classes. A comparison of the generated maps with fully and manually labeled liquefaction data showed that the proposed semi-supervised method performs best when selected high-ranked features of the two groups of statistical indices (gradient weight and sum of the band squares) and dimensionality reduction outputs (first and second principal components) are used. It also outperforms supervised learning and can better augment the liquefaction labels across the image in terms of spatial completeness. Full article

The evaluation of wave-induced residual pore pressure in a porous seabed and associated seabed liquefaction is essential for designing marine infrastructure foundations. The strength and stiffness of the seabed could be weakened due to the build-up of pore pressures under cyclic wave action, further leading to residual liquefaction. Existing models for residual liquefaction are limited to the quasi-static uncoupled approaches, which do not account for the effect of oscillatory pore pressure on the accumulative pore pressure acceleration of solid particles, despite the mutual influence of these two mechanisms. To overcome these limitations, this paper proposes a new model for residual soil response with $u-p$ approximation (partial dynamic model) that couples oscillatory and residual mechanisms. The proposed model is validated through wave flume tests and centrifuge tests. Based on the coupling model, a new criterion of liquefaction integrating both oscillatory and residual mechanisms is also proposed. Numerical examples demonstrate that the coupling effect significantly affects the wave-induced seabed liquefaction potential. Furthermore, a new parameter ($\mathsf{\Omega }$) representing the ratio of oscillatory and residual pore pressure is introduced to clarify which mechanism dominates the pore pressure development. Full article

Decarbonization of the aviation sector relies on deployment of sustainable aviation fuels (SAF) at commercial scale. Hydrothermal liquefaction (HTL) has been recognized as a promising technology to help supply the increasing projected SAF demand. High availability of agro-industrial residues, combined with a well-established biorefinery system, makes the sugarcane industry in Brazil a good option for HTL technology deployment. Moreover, challenges regarding the economic feasibility of SAF from HTL could be partially addressed by the RenovaBio policy, a market-driven incentive mechanism of carbon credits implemented in Brazil. This study investigated both the techno-economic and life cycle assessment of SAF production from sugarcane lignocellulosic residues, considering HTL integrated to a first-generation ethanol distillery and a HTL stand-alone facility. The evaluated scenarios showed great climate mitigation potential, reaching a reduction of up to 73–82% when compared to fossil jet fuel. The minimum fuel selling price of SAF at 15.4 USD/GJ indicated potential of economic competitiveness with fossil jet fuel in the best integrated scenario. The economic benefits obtained from carbon credits are not enough to enable feasibility of HTL in the stand-alone scenarios, even with carbon prices projected at 125 USD/tonne CO₂-eq avoided. Full article