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Keywords = partial discharge evolution

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13 pages, 2802 KiB  
Article
Redistribution of Residual Stresses in Titanium Alloy Butt-Welded Thick Plates Due to Wire-Cut Electrical Discharge Machining
by Qifeng Wu, Cunrui Bo, Kaixiang Sun and Liangbi Li
Metals 2025, 15(7), 750; https://doi.org/10.3390/met15070750 - 2 Jul 2025
Viewed by 240
Abstract
Welding and cutting behaviour may affect the mechanical properties of titanium alloy welded structures, which may have some impact on the safety assessment of the structure. This study analyses changes in residual stress in Ti80 butt-welded thick plates before and after wire-cut electric [...] Read more.
Welding and cutting behaviour may affect the mechanical properties of titanium alloy welded structures, which may have some impact on the safety assessment of the structure. This study analyses changes in residual stress in Ti80 butt-welded thick plates before and after wire-cut electric discharge machining, using numerical simulations based on thermo-elastoplastic theory and the element birth and death method, validated by X-ray non-destructive testing. The transverse residual tensile stress near the weld exhibits an asymmetric bimodal distribution, while the longitudinal stress is significantly higher than the transverse stress. Wire-cut electric discharge machining had minimal influence on the transverse residual stress distribution but led to partial relief of the longitudinal residual tensile stress. The maximum reductions in transverse and longitudinal welding residual tensile stresses are approximately 60% and 36%, respectively. The findings indicate that wire-cut electric discharge machining can alter surface residual stresses in Ti alloy butt-welded thick plates. This study also establishes a numerical simulation methodology for analysing welding residual stresses and their evolution due to wire-cut electric discharge machining. The results provide a theoretical basis for analysing the structural strength and safety of Ti-alloy-based deep-sea submersibles. Full article
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18 pages, 7946 KiB  
Article
Numerical Simulation of Streaming Discharge Characteristics of Free Metal Particles in SF6/CF4 Gas Mixtures Under Highly Heterogeneous Electric Field
by Bing Qi, Hui Wang, Chang Liu, Fuyou Teng, Daoxin Yu, Yuxuan Liang and Feihu Wang
Sensors 2025, 25(13), 3847; https://doi.org/10.3390/s25133847 - 20 Jun 2025
Viewed by 323
Abstract
Compared to pure SF6 gas, the SF6/CF4 gas mixture exhibits certain advantages in reducing greenhouse effects, lowering the liquefaction temperature, and decreasing the sensitivity to non-uniform electric fields, demonstrating significant application potential in high-voltage electrical equipment. This study employs [...] Read more.
Compared to pure SF6 gas, the SF6/CF4 gas mixture exhibits certain advantages in reducing greenhouse effects, lowering the liquefaction temperature, and decreasing the sensitivity to non-uniform electric fields, demonstrating significant application potential in high-voltage electrical equipment. This study employs a two-dimensional plasma fluid model to investigate the partial discharge phenomena induced by free metallic particles in SF6/CF4 gas mixtures, analyzing the spatiotemporal evolution characteristics of key parameters, such as the charged particle density and axial electric field, under different mixing ratios. The simulation results show that there are two kinds of positive stream discharge phenomena, “continuous and decaying”, when the gas mixture ratio is 90%CF4-10%SF6 and 40%CF4-60%SF6. The proportion of CF4 in the gas mixture will affect the spatial distribution of charged particles and the production and disappearance of electrons. When the proportion of CF4 is 90%, the content of positive ions in the discharge channel is the highest, and the electric field formed by the positive space charge of CF4+ in the stream head promotes the continuous propagation of the stream. As the concentration of CF4 decreases, the main ionization reaction at the stream head shifts from CF4 to SF6, and a negative space charge region dominated by SF6 particles is also formed near the stream head, changing the electric field distribution near the flow head. The adhesion reaction rate is greater than the ionization reaction rate, resulting in the disappearance of electrons greater than the production, and the stream phenomenon tends to decay. These simulation results are helpful to understand the dynamic process of positive stream discharge induced by free metal particles in SF6/CF4 gas mixtures, and they provide a theoretical basis for better solutions to equipment damage caused by partial discharge. Full article
(This article belongs to the Section Electronic Sensors)
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10 pages, 2715 KiB  
Article
Optical Detection and Cluster Analysis of Metal-Particle-Triggered Alternating Current Optical Partial Discharge in SF6
by Hanhua Luo, Yan Liu, Chong Guo and Zuodong Liang
Energies 2025, 18(7), 1649; https://doi.org/10.3390/en18071649 - 26 Mar 2025
Viewed by 295
Abstract
Accurately detecting defect-induced photon emissions enables early defect detection and characterization. To address this, a defect evolution state recognition model based on phase-resolved photon counting and dimensionality reduction calculations is proposed under alternating current (AC) excitation. Initially, photon information from protruding metal defects [...] Read more.
Accurately detecting defect-induced photon emissions enables early defect detection and characterization. To address this, a defect evolution state recognition model based on phase-resolved photon counting and dimensionality reduction calculations is proposed under alternating current (AC) excitation. Initially, photon information from protruding metal defects simulated using needle–plane electrodes during partial discharge (PD) evolution is analyzed in SF6. Subsequently, phase-resolved photon counting (PRPC) techniques and statistical analysis are employed to extract feature parameters for quantitative characterization of defect-induced photon responses. Finally, a t-distributed stochastic neighbor embedding (t-SNE) dimensionality reduction analysis is utilized to establish criteria for categorizing defect evolution states. The findings reveal that metal-particle-triggered optical PRPC maintains the obvious polarity effect, and the entire evolution of the discharge can be divided into three processes. These research findings are expected to advance the accurate assessment of operational risks in gas-insulated systems. Full article
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40 pages, 6247 KiB  
Review
Electrical Diagnosis Techniques for Power Transformers: A Comprehensive Review of Methods, Instrumentation, and Research Challenges
by Peter Mwinisin, Alessandro Mingotti, Lorenzo Peretto, Roberto Tinarelli and Mattewos Tefferi
Sensors 2025, 25(7), 1968; https://doi.org/10.3390/s25071968 - 21 Mar 2025
Viewed by 1398
Abstract
This paper serves as a comprehensive “starter pack” for electrical diagnostic methods for power transformers. It offers a thorough review of electrical diagnostic techniques, detailing the required instrumentation and highlighting key research directions. The methods discussed include frequency response analysis, partial discharge testing, [...] Read more.
This paper serves as a comprehensive “starter pack” for electrical diagnostic methods for power transformers. It offers a thorough review of electrical diagnostic techniques, detailing the required instrumentation and highlighting key research directions. The methods discussed include frequency response analysis, partial discharge testing, dielectric dissipation factor (tan delta), direct current (DC) insulation resistance, polarization index, transformer turns ratio test, recovery voltage measurement, polarization–depolarization currents, frequency domain spectroscopy, breakdown voltage testing, and power factor and capacitance testing. Additionally, the paper brings attention to less-explored electrical diagnostic techniques from the past decade. For each method, the underlying principles, applications, necessary instrumentation, advantages, and limitations are carefully examined, alongside emerging trends in the field. A notable shift observed over the past decade is the growing emphasis on hybrid diagnostic approaches and artificial intelligence (AI)-driven data analytics for fault detection. This study serves as a structured reference for researchers—particularly those in the early stages of their careers—as well as industry professionals seeking to explore electrical diagnostic techniques for power transformer condition assessment. It also outlines promising research avenues, contributing to the ongoing evolution of transformer diagnostics. Full article
(This article belongs to the Special Issue Smart Sensors, Smart Grid and Energy Management)
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23 pages, 2411 KiB  
Review
Review of Explosion Mechanism and Explosion-Proof Measures for High-Voltage Cable Intermediate Joints
by Wei Qiu, Chen Li, Nianqiao Chen, Yuhua Huang, Zhibin Jiang, Jiangjing Cui, Peifeng Wang and Gang Liu
Energies 2025, 18(6), 1552; https://doi.org/10.3390/en18061552 - 20 Mar 2025
Viewed by 774
Abstract
The intermediate joint of high-voltage cables, as a critical component in the power transmission system, plays a direct role in the stable operation of the entire electrical system. In recent years, frequent explosions of intermediate joints in high-voltage cables have led to significant [...] Read more.
The intermediate joint of high-voltage cables, as a critical component in the power transmission system, plays a direct role in the stable operation of the entire electrical system. In recent years, frequent explosions of intermediate joints in high-voltage cables have led to significant economic losses and safety risks. Therefore, studying the explosion mechanisms and explosion prevention measures of high-voltage cable intermediate joints is particularly important. This article provides a systematic review of the explosion mechanisms and explosion prevention measures for high-voltage cable intermediate joints. It begins by introducing the composition of cable systems and the structural features of the 220 kV prefabricated cable joint. Next, the article elaborates on the spatiotemporal evolution process of cable joint explosions. Typically, a cable joint explosion undergoes several stages: partial discharge, arc breakdown, and insulation material decomposition, which ultimately leads to explosion and ignition. Subsequently, the article reviews each of these dynamic stages in detail. Finally, the article discusses the existing explosion prevention measures and their shortcomings, and proposes future directions for the development of explosion prevention measures. This article can provide a theoretical foundation and technical reference for the research on the explosion mechanisms of high-voltage cable joints, as well as for the development of explosion prevention measures. Full article
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36 pages, 2018 KiB  
Review
Advancing Power Transformer Cooling: The Role of Fluids and Nanofluids—A Comprehensive Review
by Sandra Sorte, Alexandre Salgado, André Ferreira Monteiro, Diogo Ventura, Nelson Martins and Mónica S. A. Oliveira
Materials 2025, 18(5), 923; https://doi.org/10.3390/ma18050923 - 20 Feb 2025
Cited by 4 | Viewed by 1213
Abstract
The ongoing pursuit of enhanced efficiency and sustainability in power transformer cooling systems has spurred extensive research into the properties and performance of insulating fluids. This review explores the evolution of transformer cooling technologies, focusing on traditional mineral oils and the emerging roles [...] Read more.
The ongoing pursuit of enhanced efficiency and sustainability in power transformer cooling systems has spurred extensive research into the properties and performance of insulating fluids. This review explores the evolution of transformer cooling technologies, focusing on traditional mineral oils and the emerging roles of alternative fluids, such as natural and synthetic esters, and nanofluids. Mineral oils, though widely used, degrade over time, leading to a reduction in breakdown voltage (BDV) from 46 kV to 30 kV, exhibiting low fire resistance. Natural and synthetic esters provide improved biodegradability, fire safety but have higher viscosities—potentially limiting convective cooling. Nanofluids, have demonstrated BDV enhancements of up to 47.8%, reaching 88.7 kV in optimised formulations, alongside increases in partial discharge inception voltage (PDIV) of 20–23%. Additionally, thermal conductivity improvements of 5–20% contribute to enhanced heat dissipation. Moreover, it addresses challenges such as nanoparticle agglomeration, sedimentation, ageing, and compatibility with transformer materials. The analysis provides critical insights into the trade-offs between technical performance and economic feasibility. Concluding with an outlook on future research directions, the review identifies key parameters across various categories, establishing a roadmap for nanofluid integration with existing transformer systems. Full article
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25 pages, 6816 KiB  
Article
Online High Frequency Impedance Identification Method of Inverter-Fed Electrical Machines for Stator Health Monitoring
by Jérémy Creux, Najla Haje Obeid, Thierry Boileau and Farid Meibody-Tabar
Appl. Sci. 2024, 14(23), 10911; https://doi.org/10.3390/app142310911 - 25 Nov 2024
Cited by 2 | Viewed by 1113
Abstract
In electric powertrain traction applications, the adopted trend to improve the performance and efficiency of electromechanical power conversion systems is to increase supply voltages and inverter switching frequencies. As a result, electrical machine conductors are subjected to ever-increasing electrical stresses, leading to premature [...] Read more.
In electric powertrain traction applications, the adopted trend to improve the performance and efficiency of electromechanical power conversion systems is to increase supply voltages and inverter switching frequencies. As a result, electrical machine conductors are subjected to ever-increasing electrical stresses, leading to premature insulation degradation and eventual short-circuits. Winding condition monitoring is crucial to prevent such critical failures. Based on the scientific literature, several methods can be used for early identification of aging. A first solution is to monitor partial discharges. This method requires the use of a specific measurement device and an undisturbed test environment. A second solution is to monitor the inter-turn winding capacitance, which is directly related to the condition of the insulation and can cause a change in the stator impedance behavior. Several approaches can be used to estimate or characterize this impedance behavior. They must be performed on a machine at standstill, which limits their application. In this paper, a new characterization method is proposed to monitor the high-frequency stator impedance evolution of voltage source inverter-fed machines. This method can be applied at any time without removing the machine from its operating environment. The range and accuracy of the proposed frequency characterization depend in particular on the supply voltage level and the bandwidth of the measurement probes. The effects of parameters such as temperature, switching frequency, and DC voltage amplitude on the impedance characteristic were also studied and will be presented. Tests carried out on an automotive traction machine have shown that the first two series and parallel resonances of the high-frequency impedance can be accurately identified using the proposed technique. Therefore, by monitoring these resonances, it is possible to predict the aging rate of the conductor. Full article
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13 pages, 3384 KiB  
Article
Partial Discharge Inception Voltage Monitoring of Enameled Wires under Thermal Stress over Time
by Ishtiaq Khan, Francesco Guastavino, Laura Della Giovanna and Eugenia Torello
Energies 2024, 17(18), 4578; https://doi.org/10.3390/en17184578 - 12 Sep 2024
Viewed by 1317
Abstract
Electrical insulation is a critical component in electrical machines. The performance of the insulation system can be adversely affected by operating conditions that induce aging. Assessing the impact of environmental stresses is essential for predicting the failure of electrical insulation. Predicting maintenance to [...] Read more.
Electrical insulation is a critical component in electrical machines. The performance of the insulation system can be adversely affected by operating conditions that induce aging. Assessing the impact of environmental stresses is essential for predicting the failure of electrical insulation. Predicting maintenance to prevent service interruptions caused by insulation breakdown is a key objective. For type I insulating systems used in low-voltage and low-power rotating electrical machines, it has been demonstrated that partial discharges (PDs) are a contributing factor to electrical insulation breakdown. In fact, these insulating systems are not able to withstand the action of PD activity. The inception and evolution of PD activity is an indication of the poor conditions of the electrical insulating system, and this activity can be produced by the electronic power supply. The progressive reduction in partial discharge inception voltage (PDIV) is attributed to the deterioration of insulation properties induced by operational stresses. This study aims to evaluate and compare the effects of thermal stress on various types of enameled wires by collecting the PDIV values over time. In this paper, the authors analyze some particular effects of thermal stress as an aging factor. During the tests, an electrical stress was applied, which acted as a conditioning stress rather than one capable of producing degradation phenomena, as it was not high enough to initiate PD activity. In this research study, twisted pairs prepared from copper wires were evaluated. These wires were coated with various types of enamel and belonged to the thermal class of 200 °C. The samples were subjected to thermal aging tests at different temperatures. An electrical conditioning stress was also applied during all the tests and pertained to the same voltage, amplitude and frequency. The PDIV value pertaining to each sample was regularly measured to monitor its evolution over time. Full article
(This article belongs to the Special Issue Advances in High-Voltage Insulation)
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14 pages, 4537 KiB  
Article
Numerical Simulation of the Negative Streamer Propagation Initiated by a Free Metallic Particle in N2/O2 Mixtures under Non-Uniform Field
by Bing Qi and Daoxin Yu
Processes 2024, 12(8), 1554; https://doi.org/10.3390/pr12081554 - 25 Jul 2024
Cited by 41 | Viewed by 1545
Abstract
Under atmospheric pressure, partial discharge initiated by free metallic particles has consistently been a significant factor leading to failures in high-voltage electrical equipment. Simulating the propagation of negative streamer discharge in N2/O2 mixtures contributes to a better understanding of the [...] Read more.
Under atmospheric pressure, partial discharge initiated by free metallic particles has consistently been a significant factor leading to failures in high-voltage electrical equipment. Simulating the propagation of negative streamer discharge in N2/O2 mixtures contributes to a better understanding of the occurrence and evolution of partial discharge, optimizing the insulation performance of electrical equipment. In this study, a two-dimensional plasma fluid dynamics model coupled with the current module was employed to simulate the evolution process of negative streamer discharge caused by one free metallic particle under a suspended potential at 220 kV applied voltage conditions. Simulation results indicated that the discharge process could be divided into two distinct stages: In the first stage, the electron ionization region detached from the electrode surface and propagated independently. During this stage, the corona discharge on the negative electrode surface provided seed electrons crucial for the subsequent development of negative corona discharge. The applied electric field played a dominant role in the propagation of the electron region, especially in the electron avalanche region. In the second stage, space charge gradually took over, causing distortion in the spatial field, particularly generating a substantial electric field gradient near the negative electrode surface, forming an ionization pattern dominated by ionization near the negative electrode surface. These simulation results contribute to a comprehensive understanding of the complex dynamic process of negative streamer discharge initiated by free metallic particles, providing essential insights for optimizing the design of electrical equipment and insulation systems. Full article
(This article belongs to the Section Particle Processes)
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14 pages, 2969 KiB  
Article
A Comparative Study of Time-Evolution Characteristics of Single and Double Cavity Partial Discharges
by Isaac Kwabena Kyere, Cuthbert Nyamupangedengu and Andrew Graham Swanson
Energies 2024, 17(8), 1905; https://doi.org/10.3390/en17081905 - 17 Apr 2024
Cited by 3 | Viewed by 1711
Abstract
Partial discharge (PD) in cavities can lead to a breakdown in solid insulation and, therefore, indicate the onset of aging in electrical equipment. It is necessary to investigate the activity of single- and double-cavity PD under aging conditions, which is the focus of [...] Read more.
Partial discharge (PD) in cavities can lead to a breakdown in solid insulation and, therefore, indicate the onset of aging in electrical equipment. It is necessary to investigate the activity of single- and double-cavity PD under aging conditions, which is the focus of this study. The results obtained can be useful in monitoring the condition of insulation systems. The factors (pressure, effective work function, and charge decay time constant) that influence PD behaviour under different test conditions were permutated in a PD model. The simulation results agree with measurements obtained for the same applied voltage. The model can generate PD pulse distribution shapes similar to the measured PD of single and double cavities. Both turtle-like and rabbit-ear-like phase-resolved PD (PRPD) patterns were observed during the aging process of the samples in both double and single cavities. This study concludes that the identification of the PD pattern achieved in this work for closely coupled cavities is a step towards characterizing multiple defects phenomena through PD evolution patterns. Full article
(This article belongs to the Special Issue Partial Discharge Monitoring and Analysis)
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10 pages, 274 KiB  
Article
Factors Associated with the Evolution of Superficial Vein Thrombosis and Its Impact on the Quality of Life: Results from a Prospective, Unicentric Study
by Blanca Ros Gómez, Javier Gómez-López, Manuel Quintana-Díaz, Sheila Victoria Calvo Sevilla, Pablo Rodríguez-Fuertes, Fabian Tejeda-Jurado, Paula Berrocal-Espinosa, Juan Francisco Martínez-Ballester, Sonia Rodríguez-Roca, María Angélica Rivera Núñez, Ana M. Martínez Virto, Alberto Martín-Vega, Carmen Fernández-Capitán, Giorgina Salgueiro-Origlia, Raquel Marín-Baselga, Alicia Lorenzo Hernández, Teresa Sancho Bueso, Ramón Puchades Rincón de Arellano, Belén Gutiérrez-Sancerni, Alejandro Díez-Vidal, Sergio Carrasco-Molina and Yale Tung-Chenadd Show full author list remove Hide full author list
J. Vasc. Dis. 2024, 3(1), 1-10; https://doi.org/10.3390/jvd3010001 - 2 Jan 2024
Viewed by 2216
Abstract
Background: Superficial venous thrombosis (SVT) is a common clinical condition caused by inflammation and the presence of a thrombus inside a superficial vein. It has traditionally been considered a benign and banal disorder, although it can progress or can be associated with thromboembolic [...] Read more.
Background: Superficial venous thrombosis (SVT) is a common clinical condition caused by inflammation and the presence of a thrombus inside a superficial vein. It has traditionally been considered a benign and banal disorder, although it can progress or can be associated with thromboembolic disease of deep territories in up to 20%, asymptomatic or symptomatic pulmonary embolism (PE), especially if it affects the main trunk of the internal saphenous vein. The impact of deep vein thrombosis on the quality of life and its sequelae have long been described in the literature; however, they have not been studied in superficial vein thrombosis. Objectives: We aimed to evaluate the risk factors, management, and complications of SVT and its impact on the quality of life of our patients. Methods: Observational, prospective, single-center study to evaluate the management of SVT. The ultrasound (US) was performed initially on symptomatic patients, during treatment with low-molecular-weight heparin (LMWH), at a follow-up, and at the end of 45 days of treatment. A quality-of-life questionnaire was administered to determine the risk factors, management, and complications of SVT at the moment of diagnosis and at the end of treatment. We included patients referred from the emergency department to a monographic consultation for thromboembolic disease, over 18 years of age with a diagnosis of acute SVT symptomatic, without contraindication to initiate anticoagulation. Results: In total, 63 patients were evaluated between October 2020 and April 2022. The mean age was 65.8 years (SD 13.5), of which 35 were women (55.6%), 39 presented cardiovascular risk factors (61.9%), 25 had a history of previous personal venous thromboembolism (VTE) (39.7%), and 10 had obesity (15.9%), 47 had chronic venous insufficiency or varicose veins (74.9%). During follow-up with ultrasound, 39.7% had partial revascularization, and at discharge, 63.5% had permeabilized the thrombosis against 19% who had residual thrombosis or progression of thrombosis. There was a positive correlation between mobility parameters and improvement in the performance of daily activities (rho = 0.35; p = 0.012) and with improvement in pain/discomfort (rho = 0.37; p = 0.007). An improvement in pain parameters was statistically significantly related to a global assessment health perception (rho = 0.48; p < 0.001). Anxiety and depression parameters were related to a global assessment health perception (rho = 0.462; p = 0.001) and to an overall improvement at 12 months (rho = 0.45; p = 0.001). CONCLUSIONS: Superficial venous thrombosis (SVT) is a highly prevalent disease, which is traditionally considered banal and has good evolution, with heterogeneous management in clinical practice and limited information on patient selection for therapies, current treatment routes, and drug use, as well as outcomes. In recent years, the importance of this entity has become evident due to its frequency in clinical practice, its risk of complications, and the impact it has on the quality of life. This study’s results emphasize the importance of the diagnosis, treatment, and follow-up of superficial venous thrombosis. Full article
(This article belongs to the Section Peripheral Vascular Diseases)
20 pages, 10112 KiB  
Article
The Stability of Dams with Different Stoping Elevations in the Tongling Valley-Type Tailings Impoundment: A Case Study in Yunnan China
by Yiwen Pan, Jianping Chen, Xiaohuan Zuo, Cheng Zhang and Shuangshuang Wu
Minerals 2023, 13(11), 1365; https://doi.org/10.3390/min13111365 - 26 Oct 2023
Cited by 3 | Viewed by 2110
Abstract
Significant interest has been focused on recovery rates, recovery options, and recovery utilization when tailings impoundments are re-mined. However, the stability of the tailings dams during the recovery process is also a severe issue. Based on engineering geological surveys and laboratory tests, the [...] Read more.
Significant interest has been focused on recovery rates, recovery options, and recovery utilization when tailings impoundments are re-mined. However, the stability of the tailings dams during the recovery process is also a severe issue. Based on engineering geological surveys and laboratory tests, the evolution of the Tongling tailings impoundment’s instability characteristics under different recovery heights and diverse working conditions was analyzed by numerical simulation. Firstly, with the help of 2D software, the position of the tailings dam infiltration line and the alteration of the dam safety factor during the stoping process were calculated. Secondly, 3Dmine (2017) software was used to create the 3D surface structure of the tailings impoundment, and then a 3D numerical analysis model was established by means of Midas GTS NX software. The numerical simulation of seepage and stress analyses were conducted based on the model. Consequently, the evolution of the stability characteristics of tailings dam under different operating conditions was calculated. The research demonstrates that the dry beach length of the tailings pond gradually reduces with a decrease in the extraction height, resulting in a lower infiltration line. Under flood conditions, the saturation line has partial overflow due to the poor seepage discharge capacity of the dam. The total displacement of the dam body is inversely proportional to the retrieval height. The more extreme the analyzed working conditions, the more the safety factor will be reduced. Additionally, the plastic variation area of the dam body will be more comprehensive, which will increase the risk of a dam collapse. Full article
(This article belongs to the Topic Green Mining)
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18 pages, 4182 KiB  
Article
Unraveling the Phase Transition Behavior of MgMn2O4 Electrodes for Their Use in Rechargeable Magnesium Batteries
by Carmen Miralles, Teresa Lana-Villarreal and Roberto Gómez
Materials 2023, 16(15), 5402; https://doi.org/10.3390/ma16155402 - 1 Aug 2023
Cited by 4 | Viewed by 2047
Abstract
Rechargeable magnesium batteries are an attractive alternative to lithium batteries because of their higher safety and lower cost, being spinel-type materials promising candidates for their positive electrode. Herein, MgMn2O4 with a tetragonal structure is synthesized via a simple, low-cost Pechini [...] Read more.
Rechargeable magnesium batteries are an attractive alternative to lithium batteries because of their higher safety and lower cost, being spinel-type materials promising candidates for their positive electrode. Herein, MgMn2O4 with a tetragonal structure is synthesized via a simple, low-cost Pechini methodology and tested in aqueous media. Electrochemical measurements combined with in-situ Raman spectroscopy and other ex-situ physicochemical characterization techniques show that, in aqueous media, the charge/discharge process occurs through the co-intercalation of Mg2+ and water molecules. A progressive structure evolution from a well-defined spinel to a birnessite-type arrangement occurs during the first cycles, provoking capacity activation. The concomitant towering morphological change induces poor cycling performance, probably due to partial delamination and loss of electrical contact between the active film and the substrate. Interestingly, both MgMn2O4 capacity retention and cyclability can be increased by doping with nickel. This work provides insights into the positive electrode processes in aqueous media, which is vital for understanding the charge storage mechanism and the correlated performance of spinel-type host materials. Full article
(This article belongs to the Special Issue Advanced Electrode Materials for Batteries)
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21 pages, 1760 KiB  
Review
Treatment of High-Polyphenol-Content Waters Using Biotechnological Approaches: The Latest Update
by Barbara Muñoz-Palazon, Susanna Gorrasi, Aurora Rosa-Masegosa, Marcella Pasqualetti, Martina Braconcini and Massimiliano Fenice
Molecules 2023, 28(1), 314; https://doi.org/10.3390/molecules28010314 - 30 Dec 2022
Cited by 8 | Viewed by 3680
Abstract
Polyphenols and their intermediate metabolites are natural compounds that are spread worldwide. Polyphenols are antioxidant agents beneficial for human health, but exposure to some of these compounds can be harmful to humans and the environment. A number of industries produce and discharge polyphenols [...] Read more.
Polyphenols and their intermediate metabolites are natural compounds that are spread worldwide. Polyphenols are antioxidant agents beneficial for human health, but exposure to some of these compounds can be harmful to humans and the environment. A number of industries produce and discharge polyphenols in water effluents. These emissions pose serious environmental issues, causing the pollution of surface or groundwater (which are used to provide drinking water) or harming wildlife in the receiving ecosystems. The treatment of high-polyphenol-content waters is mandatory for many industries. Nowadays, biotechnological approaches are gaining relevance for their low footprint, high efficiency, low cost, and versatility in pollutant removal. Biotreatments exploit the diversity of microbial metabolisms in relation to the different characteristics of the polluted water, modifying the design and the operational conditions of the technologies. Microbial metabolic features have been used for full or partial polyphenol degradation since several decades ago. Nowadays, the comprehensive use of biotreatments combined with physical-chemical treatments has enhanced the removal rates to provide safe and high-quality effluents. In this review, the evolution of the biotechnological processes for treating high-polyphenol-content water is described. A particular emphasis is given to providing a general concept, indicating which bioprocess might be adopted considering the water composition and the economic/environmental requirements. The use of effective technologies for environmental phenol removal could help in reducing/avoiding the detrimental effects of these chemicals. In addition, some of them could be employed for the recovery of beneficial ones. Full article
(This article belongs to the Special Issue Natural Polyphenols in Human Health)
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17 pages, 4754 KiB  
Article
Solid Electrolyte Interphase Layer Formation on the Si-Based Electrodes with and without Binder Studied by XPS and ToF-SIMS Analysis
by Zhan-Yu Wu, Li Deng, Jun-Tao Li, Sandrine Zanna, Antoine Seyeux, Ling Huang, Shi-Gang Sun, Philippe Marcus and Jolanta Światowska
Batteries 2022, 8(12), 271; https://doi.org/10.3390/batteries8120271 - 5 Dec 2022
Cited by 18 | Viewed by 6867
Abstract
The formation and evolution of the solid electrolyte interphase (SEI) layer as a function of electrolyte and electrolyte additives has been extensively studied on simple and model pure Si thin film or Si nanowire electrodes inversely to complex composite Si-based electrodes with binders [...] Read more.
The formation and evolution of the solid electrolyte interphase (SEI) layer as a function of electrolyte and electrolyte additives has been extensively studied on simple and model pure Si thin film or Si nanowire electrodes inversely to complex composite Si-based electrodes with binders and/or conductive carbon. It has been recently demonstrated that a binder-free Si@C-network electrode had superior electrochemical properties to the Si electrode with a xanthan gum binder (Si-XG-AB), which can be principally related to a reductive decomposition of electrolytes and formation of an SEI layer. Thus, here, the Si@C-network and Si-XG-AB electrodes have been used to elucidate the mechanism of SEI formation and evolution on Si-based electrodes with and without binder induced by lithiation and delithiation applying surface analytical techniques. The X-ray photoelectron spectroscopy and time-of-flight ion mass spectrometry results demonstrate that the SEI layer formed on the surface of the Si-XG-AB electrode during the discharge partially decomposes during the subsequent charging process, which results in a less stable SEI layer. Contrarily, on the surface of the Si@C-network electrode, the SEI shows less significant decomposition during the cycle, demonstrating its stability. For the Si@C-network electrode, initially, the inorganic and organic species are formed on the surface of the carbon shell and the silicon surface, respectively. These two parts of species in the SEI layer gradually grow and then fuse when the electrode is fully discharged. The behavior of the SEI layer on both electrodes corroborates with the electrochemical results. Full article
(This article belongs to the Special Issue High Energy Lithium-Ion Batteries)
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