Search Results (10)

Exploration practice has proved that preservation conditions are one of the critical factors contributing to shale gas enrichment in the Middle Yangtze area. Well Yidi2 is the discovery well of Cambrian shale gas in this area. The paleo-fluid evolution and its implication for preservation conditions of shale gas remains unclear, posing challenges for shale gas exploration and development. In this study, through systematic analysis of fluid inclusions in fractrue-filling vein of the entire core section of this well, combined with carbon and oxygen isotope tests of veins and host rocks, a paleo-fluid profile was established to explore the formation environment of Cambrian paleo-fluids and their implications for the preservation conditions of the Shuijingtuo Formation (SJT Fm.) shale gas. The results suggest that fractures in the SJT Fm. shale at the base of Cambrian Series 2 mainly formed during the deep burial hydrocarbon generation stage, trapping a large number of liquid hydrocarbon inclusions. Subsequently, numerous high-density methane inclusions and a few of gas-liquid two-phase inclusions were trapped. The SO₄²⁻, Ca²⁺ and Mg²⁺ content of fluid inclusion groups in the veins decreased from the Qinjiamiao Formation (QJM Fm.) at the bottom of Cambrian Series 3 upward and downward respectively, and the rNa⁺/rCl⁻ ratio was the lowest in the SJT Fm. and increased overall upward. The δ¹³C values of calcite veins in Tianheban Formation (THB Fm.)-Shipai Formation (SP Fm.) of the middle Cambrian Series 2 and the Loushanguan Formation (LSG Fm.) of the Cambrian Series 3 were lighter compared to the host rocks. Results indicate the later tectonic activities in this area were relatively weak, and the shale interval remained in a state of high gas saturation for a long time. The QJM Fm. was the main source of high-salinity brine, and the SJT Fm. had strong self-sealing properties and was relatively less affected by external fluids. However, the pressure evolution of high-density methane inclusions in the SJT Fm. indicated that the pressure coefficient of the shale section significantly decreased during the Indosinian uplift and erosion stage. The veins in the THB-SP and LSG Fms. were closely related to the oxidation of hydrocarbon gases by TSR (thermochemical sulfate reduction) and the infiltration of atmospheric water, respectively. Therefore, the paleo-fluid in the fractures of Well Yidi2 have integrally recorded the whole geological process including the evolution from oil to gas, the backflow of high-salinity formation water, the upward escape of shale gas, and the process of shale gas reservoirs evolving from overpressure to normal pressure. Considering that Well Yidi2 area is located in a relatively stable tectonic setting, widely distributed fracture veins probably enhance the self-sealing ability, inhibiting the rapid escape of SJT Fm. shale gas. And the rapid deposition of Cretaceous also delayed the loss of shale gas to some extent. The combination of these two factors creates favorable preservation conditions of shale gas, establishing the SJT Fm. as the primary exploration target in this area. Full article

Usually, deep oil and gas accumulation is often controlled by strike–slip faults. However, in the Tarim Basin, deep Ordovician oil and gas accumulations are also found in areas far from the fault zone. The process of oil and gas accumulation in deep reservoirs far from strike–slip fault zones is still unclear at present. The source and evolution of Ordovician fluids were analyzed using inclusion geochemical methods and the U–Pb dating technique. The analysis of rare earth elements and carbon–oxygen–strontium isotopes in the reservoirs showed that the reservoirs were weakly modified by diagenetic fluid. The fluid was derived from the fluid formation during the same period as the seawater, and no oxidizing fluid invaded the reservoir. The late oil and gas reservoirs had good sealing properties. The U–Pb dating results combined with homogenization temperature data revealed that the first-stage oil was charged during the Late Caledonian Period, and the second-stage natural gas was charged during the Middle Yanshanian Period. The evolution of the paleo-pressure showed that the charging of natural gas in the Middle Yanshanian was the main reason for the formation of reservoir overpressure. The strike–slip fault zone was basically inactive in the Middle Yanshanian. During this period, the charged natural gas mainly migrated to the reservoir along the unconformity surface and the open strike–slip fault zone in the upper part of the Ordovician reservoir. The source of the fluid shows that the reservoir in the late stage had good sealing properties, and there was no intrusion of exogenous fluid. The overpressure in the reservoir is well preserved at present. Full article

Travertines formed of crystalline crust have been widely reported, but there has not been focus on their geochemical characteristics. We therefore carefully conducted a series of geochemical investigations and U-Th dating on a travertine mound mainly composed of crystalline crust from Sobcha (southwest China) to determine their geochemical features and geological implications. The Sobcha travertines dominantly consist of granular crystals and fan crystals and show δ¹³C from 3.4‰ to 4.9‰ V-PDB, δ¹⁸O from −26.7‰ to −23.7‰ V-PDB, and ⁸⁷Sr/⁸⁶Sr from 0.712458 to 0.712951. When normalized to PASS, the Sobcha travertines exhibit MREE enrichment relative to HREE and LREE, HREE enrichment relative to LREE, and positive Eu anomalies. The δ¹³C signatures and mother CO₂ evaluation of the Sobcha travertines show that the Sobcha travertines were thermogene travertines largely receiving mother CO₂ from (upper) mantle (i.e., magmatic CO₂) or a mixture of soil-derived CO₂ and CO₂ related to carbonate decarbonation. The ⁸⁷Sr/⁸⁶Sr of the Sobcha travertines is out of the ⁸⁷Sr/⁸⁶Sr ranges of local deposits exposed at Sobcha and surrounding areas but is well matched with the mean ⁸⁷Sr/⁸⁶Sr of Nadi Kangri volcanic rocks which cropped out to the northeast of the studied travertines (over 20 km away). This might indicate the important role of the Nadi Kangri volcanic rocks in suppling Sr to the studied travertines, but more studies are required. The LREE depletion compared to MREE and HREE in the Sobcha travertines was interpreted to be caused by the difference in geochemical mobility between LREEs and HREEs during water–rock interaction at depth, while the MREE enrichment compared to HREE was considered to be most likely inherited from reservoir/aquifer rocks. The positive Eu anomalies of the Sobcha travertines may result from very high reservoir temperatures and/or preferential dissolution of Eu-rich minerals/rocks (especially plagioclase). The Sobcha travertine mounds displays no or very slight vertical variations in δ¹³C, ⁸⁷Sr/⁸⁶Sr, and REE patterns, indicating the compositional stability of mother CO₂ and paleo-fluids. However, a significant vertical increase in δ¹⁸O was observed and was explained as the result of gradual water temperature decrease related to climate cooling, self-closure of the vents, or mound vertical growth. The findings in this study might help us better understand the deposition of crystalline crust in Ca²⁺-deficient hot spring systems. Full article

Natural fractures caused by tectonic stress in shale can not only improve the seepage capacity of shale, but also become the migration and loss channel of free gas. Calcite, quartz and other minerals in shale fracture veins record the fluid evolution information of the shale. Through the analysis of different types of fracture cements in the shale of the Silurian–Ordovician Wufeng–Longmaxi Formations in the southern Sichuan Basin, the effect of different fractures on shale gas construction or destruction was clarified. Geochemical investigations included the diagenetic mineral sequences in the hole–cavity veins, paleo-pressure recovery by Raman quantitative analysis, and the environments of diagenetic fluids traced by rare earth elements (REE) signatures. The density, composition, pressure, and temperature properties of CH₄-bearing fluid inclusions were determined by Raman quantitative measurement and thermodynamic simulations to establish the trapping condition of the geo-fluids, and so constrain the periods of gas accumulation. The diagenetic sequences in the fracture veins can be summarized as follows: Cal-I→Qz-II→Cal-III. The Cal-I in the bedding fracture veins crystallized in the late Jurassic (~180 Ma), and originated from hydrothermal origin and diagenetic fluid; the Qz-II veins crystallized in the middle Jurassic (~190 Ma); the Cal-III veins in the high-angle fractures precipitated during the early Eocene (~12 Ma), and derived from atmospheric freshwater leaching. Pore fluid pressure gradually increased. The pressure coefficient of the shale gas reservoir gradually increased to strong overpressure from 160 Ma to 86 Ma. Between 75 Ma and the present day, the pore fluid pressure and the pressure coefficient in the shale reservoirs, having been affected by tectonic activities and strata uplift-erosion, have significantly reduced. Bedding slippage fractures play a constructive role in the enrichment of shale gas, and fracture slip can significantly improve fracture permeability. High-angle shear fractures usually cut through different strata in areas with strong tectonic activity, and destroy the sealing of the shale. The entrapment of primary methane gas inclusions recorded the process of excess reservoir pressure reduction, and indicated the partial loss of shale free gas. Full article

This study assesses potential geological connections between the unconventional petroleum plays in the Beetaloo Sub-basin, regional aquifers in overlying basins, and the near surface water assets in the Beetaloo Sub-basin Northern Territory, Australia. To do so, we built an innovative multi-disciplinary toolbox including multi-physics and multi-depth imaging of the geological formations, as well as the study of potentially active tectonic surface features, which we combined with measurement of the helium content in water sampled in the aquifer systems and a comparative analysis of the surface drainage network and fault lineaments orientation. Structures, as well as potential natural active and paleo-fluid or gas leakage pathways, were imaged with a reprocessing and interpretation of existing and newly acquired Beetaloo seismic reflection 2D profiles and magnetic datasets to determine potential connections and paleo-leakages. North to north-northwest trending strike slip faults, which have been reactivated in recent geological history, are controlling the deposition at the edges of the Beetaloo Sub-basin. There are two spring complexes associated with this system, the Hot Spring Valley at the northern edge of the eastern Beetaloo Sub-basin and the Mataranka Springs 10 km north of the western sub-basin. Significant rectangular stream diversions in the Hot Spring Valley also indicates current or recently active tectonics. This suggests that those deep-rooted fault systems are likely to locally connect the shallow unconfined aquifer with a deeper gas or fluid source component, possibly without connection with the Beetaloo unconventional prospective plays. However, the origin and flux of this deeper source is unknown and needs to be further investigated to assess if deep circulation is happening through the identified stratigraphic connections. Few north-west trending post-Cambrian fault segments have been interpreted in prospective zones for dry gas plays of the Velkerri Formation. The segments located in the northern part of the eastern Beetaloo Sub-basin do not show any evidence of modern leakages. The segments located around Elliot, in the south of the eastern Beetaloo Sub-basin, as well as low-quality seismic imaging of potential faults in the central part of the western sub-basin, could have been recently reactivated. They could act as open pathways of fluid and gas leakage, sourced from the unconventional plays, deeper formations of the Beetaloo Sub-basin or even much deeper origin, excluding the mantle on the basis of low ³He/⁴He ratios. In those areas, the data are sparse and of poor quality; further field work is necessary to assess whether such pathways are currently active. Full article

Utilizing sophisticated tools in carbonate rocks is crucial to interpretating the origin and evolution of diagenetic fluids from the Upper Jurassic carbonate rocks along the Zagros thrust-fold Belt. The origin and evolution of the paleofluids utilizing in-situ strontium isotope ratios by high resolution laser ablation ICP-MS, integrated with stable isotopes, petrography and fieldwork are constrained. Due to the lack of information on the origin of the chemistry of the fluids, the cements that filled the Jurassic carbonate rocks were analysed from the fractures and pores. This allowed us to trace the origin of fluids along a diagenetic sequence, which is defined at the beginning from the sediment deposition (pristine facies). Based on petrography and geochemistry (oxygen-, carbon- and strontium-isotope compositions) two major diagenetic stages involving the fluids were identified. The initial stage, characterized by negative δ¹³C_VPDB values (reaching −10.67‰), involved evaporated seawater deposited with the sediments, mixed with the input of freshwater. The second stage involved a mixture of meteoric water and hot fluids that precipitated as late diagenetic cements. The late diagenetic cements have higher depleted O–C isotope compositions compared to seawater. The diagenetic cements display a positive covariance and were associated with extra- δ¹³C_VPDB and δ¹⁸O_VPDB values (−12.87‰ to −0.82‰ for δ¹⁸O_VPDB and −11.66‰ to −1.40‰ for δ¹³C_VPDB respectively). The distinction between seawater and the secondary fluids is also evident in the ⁸⁷Sr/⁸⁶Sr of the host limestone versus cements. The limestones have ⁸⁷Sr/⁸⁶Sr up to 0.72859, indicative of riverine input, while the cements have ⁸⁷Sr/⁸⁶Sr of (0.70772), indicative of hot fluid circulation interacting with meteoric water during late diagenesis. Full article

Unravelling the burial-deformation history of sedimentary rocks is prerequisite information to understand the regional tectonic, sedimentary, thermal, and fluid-flow evolution of foreland basins. We use a combination of microstructural analysis, stylolites paleopiezometry, and paleofluid geochemistry to reconstruct the burial-deformation history of the Meso-Cenozoic carbonate sequence of the Cingoli Anticline (Northern Apennines, central Italy). Four major sets of mesostructures were linked to the regional deformation sequence: (i) pre-folding foreland flexure/forebulge; (ii) fold-scale layer-parallel shortening under a N045 σ₁; (iii) syn-folding curvature of which the variable trend between the north and the south of the anticline is consistent with the arcuate shape of the anticline; (iv) the late stage of fold tightening. The maximum depth experienced by the strata prior to contraction, up to 1850 m, was quantified by sedimentary stylolite paleopiezometry and projected on the reconstructed burial curve to assess the timing of the contraction. As isotope geochemistry points towards fluid precipitation at thermal equilibrium, the carbonate clumped isotope thermometry (Δ₄₇) considered for each fracture set yields the absolute timing of the development and exhumation of the Cingoli Anticline: layer-parallel shortening occurred from ~6.3 to 5.8 Ma, followed by fold growth that lasted from ~5.8 to 3.9 Ma. Full article

Comparison between fossil and analogue active geothermal systems permit to obtain key-parameters to define a conceptual model of the area under exploration. The approach is based on structural, kinematic, and fluid inclusions analyses. The fossil system is investigated to describe the distribution of the hydrothermal mineralization as witness of the fluid flow through geological structures and bodies, at depth. Structural and kinematic data (to define the preferential direction of fluid flow) are collected in structural stations and by scan lines and scan boxes on key outcrops. Distribution, length, width of fractures, and hydrothermal veins bring to evaluate permeability in the fossil system and, by analogy, in the deep roots of the active system. Fluid inclusions analysis shed light on density, viscosity, and temperature of the paleo-fluids. Data integration provides the hydraulic conductivity. In active geothermal systems, fieldwork is addressed to paleo-stress analysis with data from recent faults (<2 Ma), to compare with local focal mechanisms. By this, indications on the present fluid pathways are given. The main advantage resides in obtaining parameters normally got after drilling, thus contributing to strengthen the strategy of exploration, de-risking unsuccessful boreholes. Full article

The strontium isotope signature (⁸⁷Sr/⁸⁶Sr) of calcite precipitated in rock fractures and faults is a frequently used tool to trace paleofluid flow. However, bedrock fracture networks, such as in Precambrian cratons, have often undergone multiple fracture reactivations resulting in complex sequences of fracture mineral infillings. This includes numerous discrete calcite crystal overgrowths. Conventional ⁸⁷Sr/⁸⁶Sr analysis of dissolved bulk samples of such crystals is not feasible as they will result in mixed signatures of several growth zonations. In addition, the zonations are too fine-grained for sub-sampling using micro-drilling. Here, we apply high spatial resolution ⁸⁷Sr/⁸⁶Sr spot analysis (80 µm) in transects through zoned calcite crystals in deep Paleoproterozoic granitoid fractures using laser ablation multi-collector inductively coupled plasma mass spectrometry (LA-MC-ICP-MS) to trace discrete signs of paleofluid flow events. We compare the outermost calcite growth zone with ⁸⁷Sr/⁸⁶Sr values of the present-day groundwater sampled in the same boreholes to distinguish potential modern precipitates. We then connect our results to previously reported radiometric dating and C and O isotope signatures to understand the temporal history and physicochemical evolution of fluid flow within the fractures. Comparisons of modern calcite precipitated in a borehole over a period of 17 years with modern waters prove the concept of using ⁸⁷Sr/⁸⁶Sr as a marker for fluid origin in this environment and for how ⁸⁷Sr/⁸⁶Sr changed during marine water infiltration. Intermittent calcite precipitation over very long time spans is indicated in calcite of the currently open fractures, showing an evolution of ⁸⁷Sr/⁸⁶Sr from ~0.705–0.707—a population dated to ~1.43 billion years—to crystal overgrowth values at ~0.715–0.717 that overlap with the present-day groundwater values. This shows that high spatial resolution Sr isotope analysis of fine-scaled growth zonation within single calcite crystals is applicable for tracing episodic fluid flow in fracture networks. Full article

The deep biosphere hosted in fractured rocks within the upper continental crust is one of the least understood and studied ecological realms on Earth. Scarce knowledge of ancient life and paleo-fluid flow within this realm is owing to the lack of deep drilling into the crust. Here we apply microscale high spatial-resolution analytical techniques to fine-grained secondary minerals in a deep borehole (COSC-1) drilled into the Silurian-Devonian Scandinavian Caledonide mountain range in central Sweden. The aim is to detect and date signs of ancient microbial activity and low-temperature fluid circulation in micro-karsts (foliation-parallel dissolution cavities in the rock) and fractures at depth in the nappe system. Vein carbonates sampled at 684 to 2210 m show a decreased C isotope variability at depths below 1050 m; likely due to decreased influence of organic-C at great depth. Micro-karsts at 122–178 m depth feature at least two generations of secondary calcite and pyrite growth in the voids as shown by secondary ion mass spectrometry analytical transects within individual grains. The younger of these two precipitation phases shows ³⁴S-depleted δ³⁴S_pyrite values (−19.8 ± 1.6‰ vs. Vienna-Canyon Diablo Troilite (V-CDT)) suggesting microbial sulfate reduction in situ. The calcite of this late phase can be distinguished from the older calcite by higher δ¹⁸O_calcite values that correspond to precipitation from ambient meteoric water. The late stage calcite gave two separate laser ablation inductively coupled mass spectrometry-derived U-Pb ages (9.6 ± 1.3 Ma and 2.5 ± 0.2 Ma), marking a minimum age for widespread micro-karst formation within the nappe. Several stages of fluid flow and mineral precipitation followed karst formation; with related bacterial activity as late as the Neogene-Quaternary; in structures presently water conducting. The results show that our combined high spatial-resolution stable isotope and geochronology approach is suitable for characterizing paleo-fluid flow in micro-karst; in this case, of the crystalline crust comprising orogenic nappe units. Full article