Search Results (286)

A multi-scale framework is proposed for predicting the equivalent engineering elastic constants of carbon/glass hybrid composite laminates with different fiber volume fractions V_f by integrating multiscale finite element homogenization with analytical micromechanics. Biaxial carbon fiber fabric reinforced vinyl ester composites are used as the target material system, and representative volume element (RVE) models are constructed sequentially at the lamina, laminate, and hybrid-laminate scales. At the lamina scale, the analytical self-consistent field micromechanics (SCFM) approach and the RVE method give highly consistent predictions for the fiber-dominated longitudinal modulus E₁ and in-plane shear modulus G₁₂, with deviations below 2%. However, the SCFM approach overestimates the transverse modulus E₂ and transverse Poisson’s ratio ν₂₃ as the V_f rises. The unidirectional lamina constants predicted by SCFM and RVE are then used as inputs for an analytical solution for predicting elastic constants (ASPE) and a finite-element-analysis-based micromechanics (FEAM) model of laminate and hybrid-laminate. At the laminate scale, the moduli predicted by ASPE(SCFM) and ASPE(RVE) differ by less than 2%, whereas the out-of-plane properties are sensitive to the transverse lamina inputs. Experimental validation shows that the E_x values predicted by ASPE(RVE) and FEAM(RVE) deviate from the measured average by approximately 3.5%, with good agreement also obtained for G_xy and ν_xy. At the hybrid-laminate scale, ASPE(RVE) and FEAM(RVE) exhibit only minor differences in estimating the in-plane moduli, out-of-plane moduli, and Poisson’s ratios. Full article

This study investigates the quasi-static equalbiaxial compression behavior of 3D-printed Miura-ori metamaterials incorporating both out-of-plane and in-plane gradient configurations. The Miura-ori structure, composed of tessellated parallelogram units, exhibits pronounced anisotropic behavior due to its unique folding geometry. To assess this behavior, specimens were fabricated using ABS resin and subjected to equalbiaxial compression in three orthogonal directions: the xy-direction (in-plane compression), the yz-direction (edge-on side loading), and the xz-direction (accordion-like profile loading). In the out-of-plane gradient design, the acute angle ϕ was varied across layers, significantly influencing both yield stress and specific energy absorption (SEA). Compared with the uniform design, gradient configurations exhibited reduced mechanical performance in the xy-direction and yz-direction, and enhanced properties in the xz-direction. In addition, in-plane (x-direction) gradient structures were evaluated under xy-, yz- and xz- direction compression. The results indicate that gradient configuration specimens exhibit significantly lower yield stress and specific energy absorption than uniform structure specimens, with deformation initiating preferentially in regions with smaller acute angles and lower local stiffness. The results highlight the strong influence of geometric gradation and loading direction on the mechanical performance of Miura-ori metamaterials. This work provides new insights into the design and optimization of origami-inspired energy-absorbing structures for use in advanced mechanical, aerospace, and protective engineering applications. Full article

To meet the growing demand for materials combing high thermal conductivity and electrical insulation, we developed epoxy (EP) composites filled with zero-dimensional (0D) silver nanoparticles (AgNPs) and two-dimensional (2D) boron nitride nanosheets (BNNSs). This hybrid filler system synergistically enhances both thermal conductivity and dielectric properties, while retaining excellent electrical insulation. With only 1 wt% AgNPs and 15 wt% BNNSs, the composite achieved a dielectric constant of 4.17 at 100 Hz, outperforming pure EP. At 30 wt% BNNSs and the same AgNP loading, the in-plane and out-of-plane thermal conductivities reached 3.02 and 0.41 W·m⁻¹·K⁻¹, respectively, along with improved thermal stability. Moreover, the composite exhibited an electrical conductivity below 10⁻⁹ S/cm at 1000 Hz, confirming that the minimal metal filler content negligibly affects insulation. Thus, this work offers a feasible strategy for designing next-generation high-performance composites using 0D/2D hybrid fillers, highlighting their promising potential for advanced electronic packaging. Full article

Symmetric corrugated hierarchical honeycombs (SCHHs) are critical lightweight load-bearing structures, featuring distinctive topological architectures and excellent mechanical performance. However, they are prone to local buckling under out-of-plane compression and shear loading, which degrades their overall load-bearing capacity. To address this limitation, this work proposes an innovative dual-optimization strategy integrating cylindrical support structure introduction and nano-silica (SiO₂) matrix modification to synergistically enhance the compressive and tribological properties of SCHHs. 3D-printed SCHHs and their reinforced variant (SCHH-AC) with embedded cylindrical supports were fabricated, and the effects of nano-SiO₂ modification (0–9 wt.%) on the compressive performance and tribological behavior of the photopolymer resin matrix were systematically investigated. Experimental results demonstrate that the SCHH-AC-7% SiO₂ configuration achieves optimal compressive performance. A critical SiO₂ concentration threshold was identified: agglomeration at 9 wt.% induces severe mechanical degradation. Tribological tests confirm that SiO₂ incorporation effectively reduces the resin matrix’s friction coefficient and wear rate, with the 7 wt.% concentration yielding the lowest wear rate. Additionally, geometric parametric analysis reveals that increasing the corrugation period number and amplitude further enhances SCHH’s compressive strength and energy absorption. This study establishes a theoretical and experimental foundation for the structural design and material modification of lightweight honeycombs, advancing their practical application in high-performance engineering fields demanding lightweight load-bearing and wear resistance. Full article

The twist angle serves as a geometric tuning parameter in two-dimensional layered materials, enabling modulation of interlayer coupling and band structures without altering the chemical composition. In this work, six commensurate twisted bilayer WSe₂ configurations with rotation angles of 0°, 9.4°, 13.14°, 21.9°, 27.8°, and 60° were systematically investigated using first-principles density functional theory. Structural optimization, together with calculations of electronic structures, density of states, charge redistribution, effective masses, and optical properties, was performed. The results show that AA (0°) and 2H (60°) stackings exhibit the largest and smallest interlayer separations, respectively, whereas intermediate twist angles yield similar average spacings but distinct local stacking registries. All configurations remain indirect-gap semiconductors, with the valence band maximum located at K and the conduction band minimum near the Q point along the K–Γ path. The band gap increases from 1.450 eV at 0° to 1.579 eV at 27.8°, before decreasing to 1.333 eV at 60°, indicating strong twist-angle modulation of interlayer coupling. Density-of-states analysis shows that the valence-band edge mainly originates from Se-p and W-d hybridized states, whereas the conduction-band edge is dominated by W-d states, with intermediate angles exhibiting enhanced band folding and localization features. Charge-density analyses further reveal notable interfacial charge redistribution, which is most pronounced at 9.4°. Optical responses in the in-plane directions are nearly identical and significantly stronger than those along the out-of-plane direction. Optical absorption mainly occurs in the ultraviolet region, with band-edge features appearing in the near-infrared range. Intermediate twist angles exhibit broader dielectric responses in the visible region and extended long-wavelength tails, indicating enhanced interband transition channels. These results demonstrate that twist-angle engineering enables effective tuning of electronic and optical properties in bilayer WSe₂, providing theoretical guidance for the design of tunable optoelectronic devices. Full article

The multilayers of Ta/Pd/[CoFeB (0.3 nm)/Pd]×5/Pd films were fabricated by ultra-high-vacuum (UHV) magnetron sputtering and subsequently annealed at temperatures (T_A) ranging from 100 °C to 400 °C. The magnetic measurements were performed with the applied field oriented parallel and perpendicular to the film plane to evaluate the out-of-plane magnetic anisotropy (PMA). A maximum effective PMA energy density (K_eff) of ≈7.82 × 10⁵ erg/cc and a small out-of-plane saturation magnetisation (M_s⊥) were achieved at the optimal T_A. The evolution of PMA is associated with interfacial atomic migration and oxidation processes, as confirmed by X-ray photoelectron spectroscopy (XPS). Annealing at 300 °C initiates the formation of TaB and TaOB interfacial phases, whereas annealing at 400 °C promotes the enhanced growth of Ta₂O₅ and TaB, along with additional TaOB formation owing to increased oxygen migration. These thermally stable Ta–boride phases lead to pronounced modifications in the magnetic properties. Consequently, oxygen migration and interfacial reactions at elevated temperatures primarily alter the chemical states of the B 1s, Pd 3d, and Ta 4f orbitals, thereby influencing the PMA. The field-dependent electrical resistance (MR) study demonstrates that annealing at 100–400 °C optimises the anisotropic effect in the [CoFeB/Pd]×5-based multilayers. However, higher temperatures can trigger atomic intermixing, which degrades PMA strength and the resistance response. Moreover, the samples were further characterised by their structural, anomalous Hall effect (AHE) and magnetoresonance (MRO) properties. Overall, controlled T_A-driven oxygen diffusion and interfacial oxidation enable effective tuning of the PMA, MR, and MRO properties of ultrathin [CoFeB/Pd]×5 multilayers, highlighting their strong potential for spin–orbit torque (SOT), Dzyaloshinskii–Moriya interaction (DMI), and magnetic skyrmion-based spintronic devices. Full article

In this study, an active vibration control (AVC) strategy is effectively used on a system made of a honeycomb polymer–paper core and carbon fiber-reinforced polymer (CFRP) plates. A cost-effective and practical solution based on an AVC system has been developed and tested using a microcontroller unit (MCU) from Texas Instruments. The control system is studied by applying out-of-plane disturbances to the composite panel via an electrodynamic shaker, by exciting the identified mode shapes obtained through experimental modal analysis, i.e., impact tests. The actuator chosen for the AVC system is a Macro Fiber Composite (MFC) patch. Multiple analog signal processing circuits were developed to scale and shift the signal at the input and output of the MCU. The proposed control algorithm is based on a positive position feedback (PPF) technique. Modal analysis was performed to identify the natural frequencies and mode shapes of the structure, which are essential for the design and tuning of the modal-based PPF controller. This analysis also enabled optimal sensor and actuator placement, ensuring effective targeting and control of the dominant vibration modes. Then, a series of tests were performed using pure sine excitations at frequencies of interest, close to the 2nd and 8th mode at 25.13 Hz and 129 Hz, respectively. The results of the experiments revealed a velocity attenuation of 55.8% to 76.9% and a Power Spectral Density (PSD) attenuation of 5.8 dB to 12.8 dB, depending on the mode under study. Owing to the size and mass properties of the Macro Fiber Composite (MFC) patches, the control system is very much suitable for automobile and aerospace applications. Full article

In this work, measurements of thermal diffusivity, heat capacity and thermal expansion of 40HM (42CrMo4, 1.7225, AISI 4140) steel manufactured conventionally and via Laser Powder Bed Fusion (L-PBF) were carried out in the temperature range from room temperature (RT) to 1000 °C. Thermophysical properties were tested using specialized test stands from NETZSCH. Thermal diffusivity was studied using both the LFA 427 laser flash apparatus and the LFA 467 xenon flash apparatus. Specific heat capacity was investigated using DSC 404 F1 Pegasus differential scanning calorimeter, and thermal expansion was investigated using the DIL 402 C. Inconel 600 and A310 steel were selected as the reference materials during the thermal diffusivity test using LFA467 in the RT÷500 °C range. The conventionally manufactured 40HM steel, in the form of hot-rolled bar stock, was subjected to standard heat treatment for this steel grade—quenching followed by high-temperature tempering. The additively manufactured 40HM steel was subjected to stress-relief annealing. The results revealed no significant differences between the thermophysical properties of the L-PBF-produced samples in the out-of-plane and in-plane build orientations. Furthermore, no substantial differences were observed between the thermophysical properties of the conventionally produced material and the material manufactured using the L-PBF technique. Full article

This paper presents a comprehensive methodology for developing a numerical model of a masonry wall using the Non-Smooth Contact Dynamics (NSCD) method implemented in the open-source software LMGC90 version 2025. The modeling procedure relies on Python scripting and includes defining material properties, importing geometry from CAD tools, configuring the model, and specifying contact interactions between discrete elements. Each brick is modeled as an individual rigid element, allowing realistic simulation of frictional and cohesive behavior at joints. It outlines key theoretical aspects of the NSCD framework, including the formulation of global and local variables, interaction laws, and numerical integration. Numerical examples demonstrate the discrete element approach’s ability to capture complex in-plane and out-of-plane structural phenomena induced by seismic loading and differential foundation settlement. The results highlight the advantages of discrete modeling in representing discontinuities and failure processes that are difficult to simulate with a conventional continuum-based approach. Full article

The study focuses on the results of the analysis of data recorded during Ambient Vibration Tests (AVT) conducted on a portion of the Medieval Walls of Verona (Northern Italy). Seismometric stations were installed both at the top and at the base of the walls, recording the free vibrations of the structure. Spectral analyses provide information about the principal modal frequencies, which are compared with the results obtained through Operational Modal Analysis (OMA) techniques. Numerical models were developed to describe the elastic behavior of the walls and to support the interpretation of the experimentally identified modes. Seismic noise measurements were also performed on the ground to characterize the spectral response of the soil and to estimate the soil–structure interaction. The combined use of AVT data, OMA procedures, and numerical modeling allowed for a robust identification of the fundamental dynamic properties of the walls, highlighting the predominance of out-of-plane modes and the limited dynamic coupling with the underlying soil. The study demonstrates the effectiveness of this non-invasive approach for improving the knowledge of structural assessment, reducing uncertainties in mechanical parameter calibration, and supporting informed conservation, maintenance, and risk-mitigation strategies for historic defensive masonry structures. Full article

This paper investigates the properties of zirconium oxide thin films deposited on Ti6Al4V and Si substrates via oblique angle deposition, using varying out-of-plane θ (15 to 85°) and in-plane Φ (0 and 180°) substrate orientations. ZrO₂ films have garnered significant interest due to their antibacterial properties and mechanical performance. The aim is to engineer surfaces capable of inhibiting bacterial growth while maintaining excellent mechanical integrity. The methodology combines experimental deposition by DC magnetron sputtering with multi-scale simulations using SRIM and SIMTRA. Structural analyses were conducted via X-ray diffraction, while microstructure and surface morphology were examined using scanning electron microscopy and atomic force microscopy. Nanoindentation tests were performed to assess hardness and elastic modulus. Results revealed that increasing the incidence angle α from 7 to 74° significantly affected surface morphology, microstructure, film thickness, and columnar tilt. The hardness and Young’s modulus of the films exceeded those of Ti6Al4V, for incidence angle α between 7 and 50°, but decreased with the increasing incidence angle α. Furthermore, the films exhibited strong antibacterial activity against Gram-positive pathogens (Staphylococcus aureus), particularly at the highest incidence angle α, with inhibition rates exceeding 90%. Full article

This research focused on the synthesis of triangular silver nanoplates (TSNPs) with sharp corners using a photomediated seed growth method. The TSNPs produced had an average edge length of 27.2 ± 9.2 nm and a (110) crystalline plane structure. In terms of optical properties, the TSNPs displayed three key absorbance peaks at approximately 400 nm, 500 nm, and 660 nm, which correspond to out-of-plane dipolar resonance, in-plane quadrupolar resonance, and in-plane dipolar resonance, respectively. The prepared TSNP colloidal solutions served as surface-enhanced Raman spectroscopy (SERS)-active materials for detecting paraquat residue in aqueous samples. We optimized the mixing time of the liquid SERS with the sample, maintaining a 1:1 volume ratio. The findings showed a remarkable enhancement of the Raman signal with 10 min mixing time using laser excitation at a wavelength of 785 nm. This study achieved the development of novel SERS-active substrates capable of detecting pesticides with excellent accuracy, sensitivity, and reproducibility for both qualitative and quantitative analysis in tap water, river water, drinking water, and cannabis water. Additionally, it paved the way for using the SERS technique as a promising approach in the areas of food safety and environmental monitoring, especially in the organic farming field. Full article

Walls in masonry structures exhibit sensitive behavior under out-of-plane displacements. Although numerous studies address in-plane behavior, research focusing on out-of-plane response remains limited. The performance of masonry walls is influenced by several factors, including material characteristics, construction defects, mortar quality, support conditions, wall slenderness, and the properties of openings. Because of those parameters, detailed experimental and numerical studies are required to understand the behavior. Double- or multi-wythe masonry is commonly used, and header (or through) bricks are often placed to ensure interlocking between the wythes. The number and arrangement of the header bricks directly influence the wall behavior. Particularly after recent earthquakes, significant damage has been observed in multi-wythe walls, and the role of header bricks in wall performance is not yet fully understood. This study investigates the out-of-plane behavior of double-wythe, two-sided brick walls, in which header bricks are used only in the out-of-plane direction. Numerical analyses were performed on eight different wall models. In these models, header bricks with varying quantities and arrangements were placed perpendicular to the wythes. Lateral load analyses were conducted using the finite element method and micro-modeling technique implemented in ABAQUS software (Version 2022). Two models were validated using the referenced experimental results. The findings indicate that all walls that incorporate header brick exhibit higher lateral capacities. When compared to the reference wall model, the load-to-weight ratio increased with the increase in the number of header bricks. The lateral capacity ratio increased by factors of 1.29, 1.50, 1.68, and 1.81 in walls containing one, two, three, and four vertical rows of header bricks, respectively. When the header bricks were distributed uniformly throughout the wall, the capacity increased by a factor of 1.61. These results demonstrate that the header brick pattern also affects the wall capacity. Additionally, the presence of header bricks directly influences the failure mechanism of the wall. Full article

In this study, we investigate the mechanical energy absorption performance of reusable 3D-printed honeycomb structures fabricated using fused deposition modeling with three thermoplastic polyurethane variants: TPU 70A, TPU 85A, and TPU 95A. Prior to manufacturing, the mechanical properties of the TPU filaments were analyzed as a function of printing temperature to optimize tensile strength and layer adhesion. Four honeycomb configurations, including hexagonal and circular cell geometries, both with and without a 30° twist, were subjected to out-of-plane compression testing to evaluate energy absorption efficiency, specific energy absorption, and crushing load efficiency. The highest energy absorption efficiency, 47%, was achieved by the hexagonal honeycomb structure fabricated from TPU 95A, surpassing the expected values for expanded polystyrene and approaching the performance reported for high-cost advanced lattice structures. Additionally, twisted honeycomb configurations exhibited improved crushing load efficiency values (up to 73.5%), indicating better stress distribution and enhanced reusability. Despite variations in absorbed energy, TPU 95A demonstrated the best balance of elasticity, structural integrity, and reusability across multiple compression cycles. These findings suggest that TPU-based honeycomb structures could provide a viable, cost-effective alternative for energy-absorbing applications in impact protection systems, automotive safety, and sports equipment. Full article

Owing to their dimensions and high aspect ratio, magnetic nanowires possess distinctive physical and chemical properties and are of great importance in building nanoelectronics devices. Nanowires are traditionally produced by electrochemical deposition methods using alumina or polycarbonate membranes, and their parameters (porosity, size, and arrangement of pores) strongly influence the magnetic properties of nanowires. However, very often, the effect that cannot be neglected during synthesis is overdeposition. The influence of overdeposition on the magnetic properties of nanowires is often overlooked, but it can strongly alter the magnetic behavior of the system. In this study, we use micromagnetic simulations to investigate how different levels of overdeposition affect the hysteretic behavior of nanowires and their magnetization switching mechanism. It was shown that the formation of hemispherical caps on the ends of the nanowires may alter the out-of-plane magnetic anisotropy of the nanowires and strongly influence the squareness of the hysteresis loop. The demagnetizing field distribution for nanowires with overdeposition was also investigated, showing a strong influence of its spatial distribution change on the reversal mechanism and interaction between nanowires. The obtained results were compared to existing experimental observations, showing good agreement with the magnetic behavior of the system. Performed research can be of great interest to experimental groups, as it highlights the importance of controlling overdeposition during nanowire synthesis and its potential influence on magnetic performance. Full article