Search Results (315)

Against the backdrop of global agricultural sustainability transition, this study examines the mechanism through which peer effects influence the intention–behaviour paradox in farmers’ adoption of organic fertilisers as a substitute for chemical fertilisers, from the perspective of ecological rationality. Using survey data from 505 rice farmers in Hunan Province, this research integrates peer effects and ecological rationality into a unified analytical framework and employs a Probit model to test the mediating role of ecological rationality in the relationship between peer effects and the intention–behaviour gap in chemical fertiliser reduction for sustainable farmland management. The results show that support from family members and people in one’s immediate social environment can effectively alleviate the intention–behaviour paradox among farmers in the process of substituting chemical fertilisers with organic fertilisers, whereas support from friends is positively correlated with this degree of discrepancy. Ecological rationality serves as a mediating variable that strengthens the positive effect of peer influence on the consistency between farmers’ behavioural intentions and actual practices in sustainable agricultural production. These findings provide a new theoretical perspective for understanding farmers’ pro-environmental behaviour, and offer actionable policy implications for advancing agricultural sustainability by enhancing family and community support and improving farmers’ ecological rationality. Full article

Agricultural intensification with synthetic fertilisers has systematically disrupted soil organic carbon (SOC), influenced rhizosphere networks, and affected human health via the soil–human microbial continuum. Plant Growth-Promoting Microorganisms (PGPMs) can restore biogeochemical cycles; however, field performance varies due to spatial stoichiometric variation. In order to visualise the problem and provide a potential solution, we use global soil carbon-to-nitrogen (C/N) ratio stratification over three depth profiles (0–5, 5–15, and 15–30 cm) to create a potential spatially explicit framework for site-specific PGPM application. In comparison to contemporary models that attribute stable soil organic matter creation mostly to microbial necromass buildup as mineral-associated organic matter (MAOM) via the microbial carbon pump, we assess diazotrophic nitrogen fixation, phosphate solubilisation, and glomalin-mediated aggregation. According to stoichiometric analysis, low C/N ratios (<10:1) increase organic matter mineralisation via priming effects, resulting in clay compaction and sandy soil desiccation, while wide ratios (>30:1) cause microbial nitrogen immobilisation (“nitrogen depression”). To mitigate these limitations, we proposed depth-stratified inoculation, applying chemotactic taxa (Variovorax paradoxus) at 15–30 cm in carbon-depleted subsoils; co-inoculating diazotrophs and arbuscular mycorrhizae (Rhizophagus irregularis) at 5–15 cm for stoichiometric balance and phosphorus acquisition and deploying exopolysaccharide-producing and 1-aminocyclopropane-1-carboxylate (ACC) deaminase-active taxa (Pseudomonas putida, Funneliformis mosseae) at 0–5 cm for erosion. In conclusion, in order to maximise fertiliser use efficiency, improve structural stability, and protect metabolic health within the interdisciplinary One Health framework, we assess the shift toward trait-based, multi-kingdom Synthetic Microbial Communities (SynComs), assembled via genomic metabolic reconstructions and machine learning. We explicitly acknowledge methodological limits in existing field applications, such as substantial spatial variability, equipment constraints, and biotic competition, putting scientific validity ahead of generalised efficacy. Full article

Waste-derived fertilising materials, including sewage sludge, compost, digestate, food-waste-derived products and commercial organic or organo-mineral fertilisers, return nutrients to farmland but can also transfer microplastics to agricultural soil. This critical review examines their occurrence across these streams, analytical constraints, fate after application and the EU regulatory framework. Reported abundances span orders of magnitude and cannot be pooled because extraction, polymer identification and reporting are not harmonised, while particle-counting and mass-based methods measure different quantities. Field evidence indicates topsoil retention and accumulation after repeated application, whereas crop transfer and field-scale ecological effects remain poorly quantified. Regulation (EU) 2019/1009 sets no microplastic-specific product limit. For compost qualifying as CMC 3 and digestate other than fresh crop digestate qualifying as CMC 5, it controls plastic impurities above 2 mm by mass, while smaller particles remain outside that criterion. Waste-derived fertilisers can therefore form a recurrent, incompletely regulated pathway for microplastic transfer to soil. Controlled studies demonstrate hazard potential for selected particles and exposure conditions, but the magnitude and likelihood of effects under field conditions remain uncertain. The immediate priority is harmonised monitoring and reporting of the sub-2 mm fraction, including a stated lower size limit, polymer-confirmed particle counts and minimum QA/QC. Full article

The development of sustainable and climate-resilient food systems increasingly relies on robust analytical methodologies capable of integrating environmental, biochemical, and management-related signals. In this study, a multi-isotope framework based on δ²H, δ¹⁸O, δ¹³C, and δ¹⁵N was applied to assess its capacity to discriminate between contrasting raspberry production systems and to provide chemically grounded indicators of agroecosystem functioning. Raspberry fruits (Rubus idaeus L.; cultivars Opal and Delniwa) were collected during the 2024–2025 growing seasons from two distinct systems in Romania: an organic open-field system and a rainfed agroforestry system. Stable isotope ratio analysis revealed system-dependent isotopic patterns, with the strongest differentiation observed for δ¹⁵N. Nitrogen isotope composition (δ¹⁵N) provided the strongest discrimination, with enriched values in organic fruits (2.73–9.77‰) and depleted values in agroforestry fruits (−3.01 to 0.62‰), reflecting differences in nitrogen sources and cycling pathways. Hydrogen and oxygen isotopes (δ²H: −60.46 to −4.62‰; δ¹⁸O: −6.19 to 10.41‰) were consistent with hydroclimatic variability and evaporative fractionation processes associated with soil–plant–atmosphere interactions. Carbon isotopes (δ¹³C: −28.14 to −22.62‰) provided complementary insights into plant water-use conditions. Multivariate statistical analysis supported the separation between production systems, while short-term fertilisation effects were secondary to system-level controls. The results suggest that raspberry fruits preserve an integrated isotopic fingerprint of production environment and management practices. From an analytical chemistry perspective, this work highlights the relevance of multi-isotope approaches as transferable tools for food authentication, traceability, and sustainability assessment, contributing to the broader application of stable isotope techniques across complex biological systems. Full article

Soil mesofauna play important roles in soil food webs, organic matter decomposition, and nutrient cycling. We quantified mesofauna responses to tillage, liming, fertilisation, and Geo2 biostimulant application at two Croatian experimental sites differing in soil type and land-use history: a long-term arable Stagnosol in Čačinci and a recently converted Gleysol in Križevci. Mesofauna were sampled in spring and autumn 2023 and analysed using generalised linear mixed-effects models (GLMMs). Seasonal dynamics exerted the strongest influence on mesofauna communities, with Collembola and Acari abundances approximately sixfold and sevenfold higher, respectively, in spring than in autumn. A significant Season × Location interaction for total Acari and Oribatida indicated a stronger spring increase at Križevci. Liming increased Mesostigmata (+94%) and total Acari (+33%), while recommended fertilisation increased Entomobryomorpha (+78%) and total Collembola (+46%). In contrast, tillage treatments did not significantly affect the abundance of Acari, Collembola, or their major subgroups. The Collembola:Acari ratio remained relatively stable (0.56–0.93), suggesting parallel responses of dominant taxa. Overall, site-specific conditions and seasonal variation exerted stronger effects on soil mesofauna communities than the tested management practices, emphasising the importance of local environmental factors and land-use history in shaping mesofauna community dynamics in agricultural soils. Full article

Decades of cultivation and the often exclusive use of mineral fertilisers as a substitute for organic inputs have reduced the soil organic carbon (SOC) content of agricultural soils, meaning they now represent a potential sink for carbon sequestration to mitigate climate change and improve soil function. As well as being a legacy of management, SOC will also be dependent on local scale climate, topography, and soil properties; accounting for this local context is important when benchmarking fields and quantifying the potential for additional carbon sequestration. We developed a landscape-scale methodology, using a handheld infrared device, for baselining SOC stocks in the top 30 cm across a 45,000 ha farm cluster in the UK. The cluster is exploring opportunities for landscape-scale environmental improvement with a focus on natural flood protection and water pollution reduction through conversion of arable land to permanent grassland. We used the baseline data to estimate additional benefits of arable reversion for soil carbon sequestration. Because all the farms in the cluster share the same pedoclimatic conditions, variance in SOC at the field scale could be confidently attributed to differences in soil type and land use. Average SOC stocks in arable and permanent pasture fields were 103.9 and 140.3 Mg C ha⁻¹, respectively. Variance in %SOC was modelled using soil series, sample depth, land use, and clay content, and fields were benchmarked based on deviation from the expected value. The fields with the largest SOC stocks were identified and used as references to predict future potential sequestration. The conversion of arable land to permanent pasture resulted in a predicted average uplift in SOC of 55.0 Mg C ha⁻¹. Our landscape-scale methodology provides robust evidence on current and future carbon stocks for public subsidy schemes and natural capital markets that account for local constraints and opportunities. Full article

Recirculating organic byproducts like food waste, wastewater and manure efficiently and at scale in a circular bioeconomy will be critical to ensuring future food security, energy security, climate resilience, water security and environmental health. Ultimately, we will not be able to live within the safe operating space of our planetary boundaries if we do not stop our wasteful and inefficient habits. Our food, waste, energy and water sectors are starting to transform towards circularity, driven by a diverse range of drivers, from net zero emissions targets, to food waste policies, and to rising fertiliser prices and geopolitical risks. However, these sectors are often not transforming in a coordinated manner, risking unintended consequences like competition between end-uses, technology lock-in, the prevention of scalability, or failure to achieve key sustainability targets, causing rebound effects. For example, society’s organic waste is being earmarked for the production of bioenergy, sustainable aviation fuels, biomaterials, and biofertilisers; however, it is not clear if there will be a sufficient supply of organic waste to meet these diverse demands. Phosphorus flow analyses indicate that we will need to secure almost all of the nutrients in organic waste as fertiliser raw material to produce food. There are some existing pockets of innovation within sectors related to food waste, water and wastewater, fertilisers and agriculture, and bioenergy. However, many initiatives are being driven by short-term challenges, are not operating at scale, or are not sufficiently integrated across sectors. In this paper, we provide examples of innovations and challenges from around the world, including Italy, Australia, Sri Lanka, the UK, Japan, and Malawi. This paper identifies a pathway to navigate tensions to achieve co-existing sustainability goals, including key enablers and barriers, ranging from overcoming regulatory fragmentation to a lack of capital investments. Creating a truly viable circular economy for organic byproducts requires the integration of policies, markets, technologies and people. This means engaging diverse stakeholders, from local councils and private waste contractors, farmers, and fertiliser companies to energy retailers and wastewater utilities, NGOs, informal collectors, and environmental regulators and policy-makers. Full article

The widespread use of pesticides in agriculture has increased their levels in water bodies, threatening aquatic ecosystems. Among these, glyphosate and chlorpyrifos are widely used in Mexico and can cause toxic effects even at low doses. In aquatic organisms, early exposure to these pollutants can disrupt vital processes, such as sex determination, through oxidative stress. This study assessed the effects of exposure to environmental concentrations of glyphosate (100 μg/L), chlorpyrifos (1.5 μg/L), and their combination on zebrafish (Danio rerio) from early stages to 90 days post fertilisation (dpf). Survival was measured using Kaplan–Meier curves; lipid peroxidation was assessed by malondialdehyde (MDA); sex-related gene expression was measured by qPCR of selected genes at 30 dpf; and gonadal development was assessed by histology at 65 dpf. The results showed increased MDA levels in exposed fish. Glyphosate caused early toxicity and a higher proportion of undifferentiated fish, implying delayed sex determination. Chlorpyrifos induced oxidative stress and affected amh gene expression linked to masculinisation. Combined exposure reduced survival and altered gene expression and gonadal development. Exposure shifted the sex ratio toward males, suggesting that pesticide-induced oxidative stress may alter the expression of sex determination genes during early development. Full article

This study evaluated the multi-scale spatial heterogeneity of soil fertility in walnut orchards in the middle and lower reaches of the Yarlung Zangbo River valley. The investigation focused on Jiacha, Lang, and Milin counties, covering four river terrace levels and three soil depths within the 0–60 cm layer, and further examined the effects of such heterogeneity on walnut fruit quality. Using integrated multivariate statistical approaches and fuzzy comprehensive evaluation, 321 paired soil and fruit samples collected in September and October of 2023 were analyzed. Overall soil fertility was moderate (0.4 ≤ IFI < 0.6) with a mean integrated fertility index (IFI) of 0.527, but showed pronounced spatial variation. PCA-based composite scores indicated the highest fertility in Milin County, followed by Lang County, with Jiacha County ranking lowest. Soil fertility across 11 towns was classified into five grades. Cluster analysis based on ten standardized soil fertility indicators revealed clear regional aggregation patterns, where close towns exhibited similar fertility conditions. Third-level river terraces exhibited significantly higher fertility than other terrace levels. Available phosphorus was widely deficient, while exchangeable magnesium and available zinc were also low, representing key limiting nutrients with strong regional variability. Spatial differences in soil enzyme activities reflected variation in microbially mediated nutrient cycling, with phosphatase activity negatively correlated with available phosphorus, suggesting potential microbial responses to phosphorus-stressed environments. Soil fertility significantly influenced walnut fruit quality, with alkaline hydrolyzable nitrogen, phosphorus, potassium, and exchangeable calcium and magnesium identified as key drivers. These findings provide a theoretical basis for suggesting a zoned precision fertilization strategy, where prioritizing P, Zn, and Mg inputs in deficient areas could be considered alongside organic fertilisation. Such site-specific management strategies are suggested to support the sustainable development of the walnut industry along the Yarlung Zangbo River valley. Full article

Insect frass fertilisers (IFFs) are increasingly promoted as sustainable soil amendments within circular agricultural systems. However, the compatibility of IFFs with nitrogen-fixing legumes is poorly understood. This study evaluated the effects of a fertiliser produced from Hermetia illucens frass (HexaFrass™; HF) on germination, seedling emergence, shoot growth, and root nodulation in six forage legume species (Trifolium repens L., T. pratense L., T. incarnatum L., T. hybridum L., Melilotus albus Medik., and Medicago lupulina L.). Aqueous HF extracts (1% w/v) had no significant effect on seed germination, whereas higher concentrations (10% w/v) reduced germination in both T. pratense and T. incarnatum. In glasshouse trials, incorporation of HF (3 g per pot) did not affect seedling emergence but significantly increased shoot biomass across all plant species tested, with growth responses comparable to, or exceeding, those obtained with an equivalent mass of organic chicken manure. Across species, the shoot dry weight of the HF-treated plants was over nine times that obtained in the unfertilised control plants. Plant responses to HF application rate were non-linear, with maximum shoot biomass achieved at intermediate doses (~4–5 g per pot). Root nodulation exhibited a similar dose-dependent pattern: low HF application rates slightly enhanced nodulation, whereas higher rates suppressed nodule numbers. These findings indicate that IFFs can promote early growth of forage legumes, but reinforce that for each plant system (plant species, growing conditions, growing medium etc) there is a need to optimise fertiliser application rates to balance nutrient supply while avoiding the inhibitory effects observed at high rates. Further work is needed to establish the compatibility of IFFs with forage legumes in long-term trials performed under field conditions. Full article

Nitrogen and sulphur are among the most important plant nutrients (along with C, H, and O) and the main elements comprising the organic substance of plants. In this study, it is assumed that light soils (Cambisols) do not naturally meet the nitrogen and sulphur needs of spring wheat and, consequently, impact the phosphorus and silicon content in the plant biomass. Therefore, to determine the effect of N and S on the content and uptake of these elements at specific growth stages (BBCH 30–31: in leaves, BBCH 55–59: in whole plants, BBCH 89–90: in grain and straw), a three-year field experiment was conducted using different doses of nitrogen (0, 40, 80, and 120 kg ha⁻¹) and sulphur (0, 50 kg ha⁻¹). The results show that fertilisation with N and S had a significant effect on increasing the content and uptake of P and Si by phytomass in the phenostages studied. In general, as the N fertilisation dose increased, the yields of phytomass and grain increased. A beneficial effect of S on increases in green weight, straw, and spring wheat grain was found. A significant effect of N and S fertilisation on the growth of the Si:P ratio in individual parts of plants in the studied stages was also observed. A significant positive correlation between P and Si content was proven, indicating that the two elements do not act antagonistically towards each other. In contrast, a negative correlation was observed between the P content in plants and their Si uptake. Si is taken up more strongly by plants under conditions of N and S fertilisation, as evidenced by the increase in the Si:P ratio and the fact that plants accumulated on average 3.5 times more Si than P. The highest Si content was found in the green parts of plants in the BBCH 30–31 and BBCH 55–59 stages, while in BBCH 89–92, straw had nearly half that amount and grain contained a thousand times less silicon. Full article

Economic comparison of different production models, focusing on production costs and economic viability–profitability are essential to guide decision-making and enhance the competitiveness and resilience of the agri-food chain. This is the overall objective of the paper: to establish the production and cost structure and to economically evaluate two greenhouse pepper production models. Data on the production process of the production models (organic and conventional greenhouse pepper) and their cost and income structures were collected through 15 on-site surveys conducted with growers and horticultural sector technicians. The initial investment is very high (140,030 €·ha⁻¹) and requires a significant financial effort for implementation, being the same for both conventional and organic cultivation, this means that fixed costs are high in percentage terms, especially when compared to other intensive outdoor horticultural crops. The key cost differences between the two systems are found in fertilisers, plant protection treatments, and biotechnological control and cost structure indicates a higher unit cost for organically produced peppers, 0.60 €·kg⁻¹ for conventional and 0.75 €·kg⁻¹ for organic production. Greenhouse pepper cultivation in southeastern Spain is an economically viable and profitable activity under both conventional and organic management. Profitability indicators consistently show that the conventional system is more profitable at the same farm scale or size. Full article

Food waste poses significant environmental, economic and public health challenges. The black soldier fly (Hermetia illucens) larvae (BSFL) represent a promising solution for organic waste valorisation, converting substrates into protein-rich biomass for animal feed and organic fertiliser. However, the use of food waste as an insect substrate remains prohibited in the European Union due to regulatory and safety concerns. This study evaluated the suitability of heterogeneous food waste for BSFL rearing under industrial conditions by comparing larval performance on a standard Gainesville diet (control) and a blend derived from local restaurant waste (test). The 14-day bioconversion assay assessed bioconversion rate (BCR), feed conversion ratio (FCR), survival rate, average growth rate, and nutritional composition. Compared with the control, the test group showed significantly improved (p < 0.001) BCR (18.34% vs. 11.02%), FCR (5.48 vs. 9.09 kg/kg), survival (69.29% vs. 51.30%), and growth (8.38 vs. 6.59 mg/day). Larvae reared on food waste also exhibited significantly higher protein (19.70% vs. 16.80%), fat (13.70% vs. 7.20%), ash (6.97% vs. 3.51%), carbohydrates (7.00% vs. 3.60%), and fibre (5.20% vs. 2.90%). Overall, heterogeneous food waste is a suitable substrate for BSFL, supporting agrifood sustainability; however, future research should focus on standardisation of these substrates. Full article

Biochar mineral complex (BMC) can improve nutrient use efficiency (NUE) and reduce nutrient leaching, but the optimal application form and rate of application in soilless cropping systems remain unclear. This study evaluated co-applying BMC, either in solid form and placed to form a horizontal laminar layer approximately halfway up the potting media column, or as a liquid BMC suspension combined with reduced fertiliser rates in a protected ginger cropping system using pine bark potting media. Six treatments were examined: full-rate (15 t ha⁻¹) and half-rate (7.5 t ha⁻¹) organic fertiliser blend, BMC at high-rate (1 t ha⁻¹) and low-rate (0.5 t ha⁻¹) co-applied with half-rate fertiliser, BMC at high-rate without fertiliser, and BMC suspension at high-rate co-applied with half-rate fertiliser. Aboveground biomass, rhizome yield, nitrogen (N) and phosphorus (P) leaching, NUE, and net income were assessed. Fertiliser costs were reduced by 28% to 30% by applying half-rate fertiliser with or without BMC, respectively, and without decreasing rhizome yield, aboveground biomass, and NUE, compared to applying full-rate fertiliser. Co-applying solid BMC as a layer and at a low rate with half-rate fertiliser reduced N and P leaching without affecting yield or profitability. The BMC suspension showed no significant difference from full-rate fertiliser in yield and leaching outcomes while offering advantages for mechanised application in labour-intensive cropping systems. Overall, co-applying BMC either as a solid layer or as a liquid suspension with reduced fertiliser rates offers an economically and environmentally sustainable alternative to conventional fertiliser use in soilless cropping systems. Full article

Soil health is a major environmental concern. Biochars are a promising solution to address both soil contamination and amendment. They represent a sustainable valorisation alternative for solid wastes produced in huge amounts, namely agroforestry residues and sludge from wastewater treatment plants. Biochar’s superior properties, enhanced pore structure and high specific surface area can contribute to restoring soil quality, by adsorbing several pollutants (e.g., pharmaceutical compounds, pesticides, and metals) from water and soil, enhancing water retention capacity, improving soil aggregation, regulating pH, and reducing the need for synthetic fertilisers. Multiple studies have reported removal efficiencies exceeding 70% for metals and 60% for organic compounds in soils, as well as over 40% for both organic compounds and metals in waters. These efficiencies depend on factors such as feedstock, pyrolysis conditions, modification strategies, and target contaminants. Recent advancements in the field have introduced both chemical and physical modifications that can enhance adsorption selectivity. This review provides a comprehensive analysis of the fundamentals of biochar production, modification strategies, and their environmental applications in soil remediation and water treatment. By comparing unmodified and modified biochars, this review highlights the crucial factors that influence the performance of this highly versatile and cost-effective solution. Full article