Search Results (25)

This study presents a rapid design-and-validation framework incorporating resistance optimization for 3D-printed bridge pier geometries. A full-factorial experimental campaign comprising 16 reduced-scale solid pier sections is first conducted by systematically varying upstream fairing length and downstream fishtail length while maintaining constant maximum transverse width and cross-sectional area. The specimens are fabricated using fused deposition modeling (FDM) 3D printing with polyethylene terephthalate glycol-modified (PETG) material and tested in controlled towing experiments driven by a field-oriented control (FOC) motor, with motor torque signals recorded as a proxy for hydrodynamic resistance. The raw data are processed through steady-state trimming, null-test bias correction, and one-dimensional Kalman filtering, after which a root-mean-square (RMS) resistance metric is computed for each geometry. A key finding from the two-way analysis of variance (ANOVA) analysis reveals that fairing length exerts the dominant influence on resistance, followed by the fairing-fishtail interaction, whereas fishtail length alone plays a secondary role. The experimental ranking identifies S13, combining a short fairing with a long fishtail, as the optimal geometry, achieving a 33.6% reduction in RMS torque relative to the circular baseline. Bootstrap resampling confirms that the low-resistance cluster is a robust geometry family rather than a statistically fragile optimum. Then, independent COMSOL Multiphysics 6.3 (COMSOL) topology optimization and transient flow-field simulations are employed as morphology-level validation tools, with the optimized outline converging toward a streamlined profile qualitatively consistent with the experimental findings. The drag decomposition further indicates that pressure drag constitutes the dominant component, suggesting that shape-induced pressure redistribution is the primary mechanism underlying resistance reduction. The proposed framework thus provides a physically grounded, low-cost intermediate step between computational shape generation and detailed engineering validation for resistance-optimized bridge-pier sections, and it can be readily extended to a broader range of pier cross-sections or other hydraulic structures. Full article

Liquid organic hydrogen carriers (LOHCs) offer a safe and scalable solution for hydrogen storage and transportation, overcoming many of the limitations of conventional compressed and liquefied hydrogen systems. Among the available LOHCs, the dibenzyltoluene/perhydro-dibenzyltoluene (DBT/18H-DBT) pair is particularly attractive due to its high theoretical hydrogen storage capacity (6.2 wt.%) and favourable handling characteristics. This study investigates the hydrogenation of DBT over a cost-effective 13 wt.% Ni/Al₂O₃ catalyst using a multiphysics modelling approach developed in COMSOL Multiphysics. A zero-dimensional (0D) kinetic model, assessed against available experimental data, was employed to investigate the effects of temperature and hydrogen pressure on conversion, intermediate formation, and selectivity, and was subsequently extended to a two-dimensional (2D) predictive modelling framework to evaluate reactor behaviour under continuous-flow conditions. The simulations identified an optimum operating window of 505–515 K and 2 MPa, achieving complete DBT conversion and 95–97% selectivity towards the fully hydrogenated product, 18H-DBT, while higher pressures provided only marginal additional benefits. The 2D reactor model further predicted a final 18H-DBT selectivity of 96.8%, confirming the suitability of these conditions for continuous hydrogenation. The developed modelling framework provides valuable insight into reactor-scale performance and offers a robust tool for the design and optimisation of efficient, economically viable LOHC hydrogenation systems based on nickel catalysts. Full article

Fused filament fabrication (FFF) is a widely used additive manufacturing method in which the process forces within the hotend play an important role in terms of print quality and speed, particularly in high-throughput applications. This work reports on the influence of filament diameter, melting zone length, and nozzle set temperature on the process forces and the maximum achievable volumetric flow rate. Experimental measurements were carried out using a test rig that integrates a load cell to capture the resulting forces, complemented by non-isothermal numerical simulations. The results show that increasing the melting zone length reduces process forces and increases the attainable volumetric flow rate at high feed rates, as the filament has more time to melt. However, the effect depends strongly on filament diameter. For a diameter of 2.85 mm, extending the melting zone leads to a monotonic increase in the maximum achievable flow rate across the entire investigated range. For a diameter of 1.75 mm, an optimum is observed at an intermediate melting zone length, beyond which additional flow resistance outweighs the benefit of improved melting and thus reduces the attainable flow rate. When normalizing for the maximum transferable extruder force, the smaller filament diameter consistently yields superior throughput performance. The simulations reproduce the experimentally observed trends well and support the interpretation that throughput is limited by the competition between heat-transfer-controlled melting and viscous pressure losses. Full article

To clarify the oil–gas multiphase flow behavior of natural gas/CO₂ composite flooding in the dual-medium system of the BZ26-6 fractured reservoir, systematic oil–gas relative permeability experiments were conducted under reservoir temperature and pressure conditions. Using the steady-state method, the effects of core type, gas composition, and reservoir pressure on relative permeability behavior were investigated. The results show that the relative permeability curves are characterized by relatively high oil-phase permeability and low gas-phase permeability. Increasing the CO₂ fraction generally enhances oil mobilization and displacement efficiency, whereas the two-phase co-flow zone may reach an optimum at an intermediate CO₂ fraction, depending on the core structure. Specifically, with increasing CO₂ fraction, displacement efficiency increased from 37.05% to 43.70% in fractured metamorphic cores and from 60.74% to 64.63% in fractured carbonate cores. In contrast, decreasing reservoir pressure may induce stress-sensitive fracture compression, narrow the co-flow zone, and reduce flow capacity. Oil–gas two-phase flow behavior is strongly controlled by reservoir structure, with fractured carbonate cores exhibiting higher displacement efficiency and a wider co-flow region than fractured metamorphic cores. Within the scope of this study, a CO₂ fraction of 40% appears to be a comparatively favorable composite-gas composition when both displacement performance and gas-source economics are considered. Full article

The non-thermal plasma-driven cascade process for CO₂-to-methanol conversion shows significant potential in the field of green methanol synthesis. This process innovatively couples a plasma activation module with a catalytic synthesis module via a multi-stage pressurization device, establishing an efficient two-step pathway that converts CO₂ into methanol via a CO intermediate. Such an arrangement establishes an energy conversion system characterized by both low carbon emissions and high efficiency. This work involved an initial technical evaluation employing a custom-built, lab-scale apparatus. The optimum parameters determined through this assessment were a plasma input voltage of 40 V combined with a subsequent reaction temperature of 240 °C. Operation at these specified parameters yielded a CO₂ conversion of 48%, with the methanol selectivity and production rate reaching 40% and 502 g_MeOH${·\mathrm{kg}}_{\mathrm{cat}}^{-1}$·h⁻¹, respectively. Furthermore, industrial-scale process design and scale-up were performed, accompanied by process simulation using Aspen Plus and a subsequent techno-economic evaluation. The results indicate that, compared to the conventional direct CO₂ hydrogenation process, the proposed cascade route can reduce the capital investment by approximately 17%. Full article

Global carbon dioxide emissions are rising and the use of fossil fuels in several sectors are the leading causes. As global population and economies continue to grow significantly, the most practical method of lowering such emissions is to capture CO₂. Although other technologies are more developed, adsorption is very promising and has attracted much attention. To ensure this technology’s success, it is essential to have suitable CO₂ adsorbent materials. In this work, several new hydrotalcites (HTs) with different initial concentrations of ion precursors were prepared for the first time by the co-precipitation method—it was possible to verify that the ion concentrations influence the characteristics of the materials. The prepared HTs were characterized by thermogravimetric analysis (TG), X-Ray diffraction (XRD), surface area measurements and temperature-programmed desorption of CO₂ (TPD-CO₂) to relate their CO₂ capture capacity to their physicochemical properties; the CO₂ adsorption equilibrium isotherms were determined at 35 and 300 °C for the prepared samples, as well as for some commercial materials: magnesium oxide, calcium oxide, aluminium oxide and Zeolite 13X. After determining which materials present the best CO₂ adsorption capacity, these were submitted to adsorption-desorption cycles to study their stability. The main objective of the work was to prepare and study different CO₂ adsorbents for processes that are carried out at low and intermediate temperatures. From the experimental results, it was possible to conclude that the Zeolite 13X showed the best capacity at 35 °C, 3.38 mmol·g⁻¹ (@$p_{{\mathrm{C}\mathrm{O}}_2}$ = 1 bar), and a prepared calcined HT (c-HT2) was the best at 300 °C, 0.97 mmol·g⁻¹ (@$p_{{\mathrm{C}\mathrm{O}}_2}$ = 1 bar). Moreover, it seems there is an optimum initial concentration of the ions’ solutions for the tested HTs, which depends on the final application—c-HT1 showed a better capacity at 35 °C and c-HT2 at 300 °C. From the adsorption-desorption cycles—performed at 35 and 300 °C with the best materials using a magnetic suspension microbalance at 1 bar of CO₂ partial pressure —, a working cyclic capacity of 2.69 mmol∙g⁻¹ was achieved by the Zeolite at 35 °C; in turn, c-HT2 showed a working cyclic capacity of 0.79 mmol∙g⁻¹ at 300 °C. Full article

Apple skin color is essential for market value. Therefore, this study evaluated the efficiency of pneumatic defoliation (PD) on the enhancement of red skin color and anthocyanin pigments in ‘Picnic’ apples. Three weeks before harvesting, apple trees were treated with PD with low- (0.7 bar) and high- (0.9 bar) air pressure at a tractor driving speed of 2 km/h. Undefoliated trees served as controls. Higher leaf defoliation and leaf damage rates were observed in the high-PD treatment than those in the low-PD treatment. Photosynthetically active radiation inside the canopies was the highest in trees subjected to high-pressure PD than in those that underwent low-pressure PD and the controls. At harvest, the fruit color (a*) value, red-colored area, and anthocyanin content in the fruit skin were the highest in the high-PD treatment, intermediate in the low-PD treatment, and the lowest in the control treatments. Additionally, a higher expression of anthocyanin biosynthetic genes was observed in both defoliation treatments, especially under high PD. However, except for higher flesh firmness under low PD, the L* and b* values and fruit quality indices (fruit weight, starch pattern index, titratable acidity, soluble solids content, and sunburn occurrence) were not significantly affected by either PD treatment. In conclusion, PD can be used to enhance skin coloration and anthocyanin pigments in apples; further PD with high air pressure achieved optimum red skin coloration in ‘Picnic’ apples. Full article

A passive micromixer based on the modified Tesla mixing unit was designed by embedding tip clearance above the wedge-shape divider, and its mixing performance was simulated over a wider range of the Reynolds numbers from 0.1 to 80. The mixing performance was evaluated in terms of the degree of mixing (DOM) at the outlet and the required pressure load between inlet and outlet. The height of tip clearance was varied from 40 μm to 80 μm, corresponding to 25% to 33% of the micromixer depth. The numerical results show that the mixing enhancement by the tip clearance is noticeable over a wide range of the Reynolds numbers Re < 50. The height of tip clearance is optimized in terms of the DOM, and the optimum value is roughly h = 60 μm. It corresponds to 33% of the present micromixer depth. The mixing enhancement in the molecular diffusion regime of mixing, Re ≤ 1, is obtained by drag and connection of the interface in the two sub-streams of each Tesla mixing unit. It appears as a wider interface in the tip clearance zone. In the intermediate range of the Reynolds number, 1 < Re ≤ 50, the mixing enhancement is attributed to the interaction of the flow through the tip clearance and the secondary flow in the vortex zone of each Tesla mixing unit. When the Reynolds number is larger than about 50, vortices are formed at various locations and drive the mixing in the modified Tesla micromixer. For the Reynolds number of Re = 80, a pair of vortices is formed around the inlet and outlet of each Tesla mixing unit, and it plays a role as a governing mechanism in the convection-dominant regime of mixing. This vortex pattern is little affected as long as the tip clearance remains smaller than about h = 70 μm. The DOM at the outlet is little enhanced by the presence of tip clearance for the Reynolds numbers Re ≥ 50. The tip clearance contributes to reducing the required pressure load for the same value of the DOM. Full article

This work presents the effect of Co loading on the performance of CNR115 carbon-supported catalysts in the continuous-flow chemoselective hydrogenation of 2-methyl-2-pentenal for the obtention of 2-methylpentanal, an intermediate in the synthesis of the sedative drug meprobamate. The Co loading catalysts (2, 6, 10, and 14 wt.%) were characterized by Brunauer–Emmett–Teller (BET) surface area analysis, transmission electron microscopy (TEM), H₂ temperature-programmed reduction (H₂-TPR), temperature-programmed desorption of hydrogen (H₂-TPD) analysis, X-ray diffraction (XRD), and X-ray photoelectron spectroscopy for selected samples, and have been studied as hydrogenation catalysts at different pressure and temperature ranges. The results reveal that a certain amount of Co is necessary to achieve significant conversion values. However, excessive loading affects the morphological parameters, such as the surface area available for hydrogen adsorption and the particle size, preventing an increase in conversion, despite the increased presence of Co. Moreover, the larger particle size, caused by increasing the loading, alters the chemoselectivity, favouring the formation of 2-methyl-2-pentenol and, thus, decreasing the selectivity towards the desired product. The 6 wt.% Co-loaded material demonstrates the best catalytic performance, which is related to the formation of NPs with optimum size. Almost 100% selectivity towards 2-methylpentanal was obtained for the catalysts with lower Co loading (2 and 6 wt.%). Full article

This paper presents an investigation on the optimum design for a plate-fin heat exchanger (PFHE) of a gas and supercritical carbon dioxide combined cycle which uses thermal oil as intermediate heat-transfer fluid. This may promote the heat transfer from low heat-flux exhaust to a high heat-flux supercritical carbon dioxide stream. The number of fin layers, plate width and geometrical parameters of fins on both sides of PFHE are selected as variables to be optimized by a non-dominated sorting genetic algorithm-II (NSGA-II), which is a multi-objective genetic algorithm. For the confliction of heat transfer area and pressure drop on the exhaust side, which are the objective indexes, the result of NSGA-II is a Pareto frontier. The technique for order of preference by similarity to ideal solution (TOPSIS) approach is applied to choose the optimum solution from the Pareto frontier. Finally, further simulation is performed to analyze the effect of each parameter to objective indexes and confirm the rationality of optimization results. Full article

Aristotelia chilensis is a plant rich in phenolics and other bioactive compounds. Their leaves are discarded as waste in the maqui berry industry. A new application of these wastes is intended by the recovery of bioactive compounds using pressurized hot water extraction with conventional or microwave heating. Both technologies have been selected for their green character regarding the type of solvent and the high efficiency in shorter operation times. Extractions were performed in the temperature range 140–200 °C with a solid/liquid ratio of 1:15 (w:w). The extracts’ total phenolic content, antioxidant capacity, and saccharides content obtained with both heating methods were measured. Additionally, the thermo-rheological properties of the gelling matrix enriched with these extracts were analyzed. Optimum conditions for lyophilized extracts were found with conventional heating, at 140 °C and 20 min extraction; 250.0 mg GAE/g dry extract and 1321.5 mg Trolox/g dry extract. Close to optimum performance was achieved with microwave heating in a fraction of the time (5 min) at 160 °C (extraction), yielding extracts with 231.9 mg GAE/g dry extract of total phenolics and antiradical capacity equivalent to 1176.3 mg Trolox/g dry extract. Slightly higher antioxidant values were identified for spray-dried extracts (between 5% for phenolic content and 2.5% for antioxidant capacity). The extracts obtained with both heating methods at 200 °C contained more than 20% oligosaccharides, primarily glucose. All the formulated gelling matrices enriched with the obtained extracts displayed intermediate gel strength properties. The tested technologies efficiently recovered highly active antioxidant extracts, rich in polyphenolics, and valuable for formulating gelling matrices with potential applicability in foods and other products. Full article

This paper describes the technological process of manufacturing bimetallic billets, which are capable of operating at high pressures, high temperatures, and in corrosive environments, from VT-14 titanium alloy and 12KH18N10T stainless steel. To obtain a joint with a strength of at least 350 MPa, the diffusion welding method was used, which makes it possible to obtain equal-strength joints using dissimilar materials. The connection of VT-14 titanium alloy with 12KH18N10T stainless steel after obtaining bimetallic billets with the desired properties was investigated. We studied the welded VT-14 and 12KH18N10T joint obtained by diffusion welding through intermediate spacers of niobium Nb (NbStrip-1) and copper Cu (M1). On the basis of our investigations, the optimum welding modes are as follows: welding temperature: 1137 K; welding pressure: 18 MPa; welding time: 1200 s. Mechanical tests, tightness tests, and metallographic, factographic, and micro-X-ray structural studies were carried out, the results of which indicate the effectiveness of the proposed approach. Full article

The optimization of the steam parameters of the heat recovery steam generators (HRSG) of Combined Cycle Gas Turbines (CCGT) has become one of the important means to reduce the power generation cost of combined cycle units. Based on the structural theory of thermoeconomics, a thermoeconomic optimization model for a triple pressure reheat HRSG is established. Taking the minimization of the power generation cost of the combined cycle system as the optimization objective, an optimization algorithm based on three factors and six levels of orthogonal experimental samples to determine the optimal solution for the high, intermediate and low pressure steam pressures under different gas turbine (GT) operation strategies. The variation law and influencing factors of the system power generation cost with the steam pressure level under all operation strategies are analyzed. The research results show that the system power generation cost decreases as the GT load rate increases, T₄ plays a dominant role in the selection of the optimal pressure level for high pressure (HP) steam and, in order to obtain the optimum power generation cost, the IGV T3-650-F mode should be adopted to keep the T₄ at a high level under different GT load rates. Full article

Hydrothermal liquefaction is one of the common thermochemical conversion methods adapted to convert high-water content biomass feedstocks to biofuels and many other valuable industrial chemicals. The hydrothermal process is broadly classified into carbonization, liquefaction, and gasification with hydrothermal liquefaction conducted in the intermediate temperature range of 250–374 °C and pressure of 4–25 MPa. Due to the ease of adaptability, there has been considerable research into the process on using various types of biomass feedstocks. Over the years, various solvents and co-solvents have been used as mediums of conversion, to promote easy decomposition of the lignocellulosic components in biomass. The product separation process, to obtain the final products, typically involves multiple extraction and evaporation steps, which greatly depend on the type of extractive solvents and process parameters. In general, the main aim of the hydrothermal process is to produce a primary product, such as bio-oil, biochar, gases, or industrial chemicals, such as adhesives, benzene, toluene, and xylene. All of the secondary products become part of the side streams. The optimum process parameters are obtained to improve the yield and quality of the primary products. A great deal of the process depends on understanding the underlined reaction chemistry during the process. Therefore, this article reviews the major works conducted in the field of hydrothermal liquefaction in order to understand the mechanism of lignocellulosic conversion, describing the concept of a batch and a continuous process with the most recent state-of-art technologies in the field. Further, the article provides detailed insight into the effects of various process parameters, co-solvents, and extraction solvents, and their effects on the products’ yield and quality. It also provides information about possible applications of products obtained through liquefaction. Lastly, it addresses gaps in research and provides suggestions for future studies. Full article

Sweet sorghum (Sorghum bicolor L. Moench) is highly susceptible to weed competition during the early growth stages; hence, intercropping is considered to overcome the weed competition challenge. This study was conducted to determine the performance of sweet sorghum in legume intercropping systems under different weed management pressures. Three cropping systems (sole crop, inter-row, and intra-row intercropping) and three weed management levels (no weeding after crop emergency, ceasing weeding 50 days after crop emergency, and weeding throughout) were tested. Intercropping pattern had a significant (p < 0.05) impact on the plant and the number of leaves per plant, while other treatments remained insignificant during the 2017/18 growing season. During the 2018/19 growing season, the intercropping pattern had a significant (p < 0.05) effect on dry and fresh biomass and plant height at 60 days after emergence. An increase in weeding frequencies reduced Brix (^◦Bx). Uncontrolled weed plots had the lowest sweet sorghum dry biomass accumulation, whereas the biomass increased as weeding frequencies increased but remained insignificant as weeding frequencies further increased from 50% to 100% in both seasons. Consequently, SS/DB intra-row intercropping and intermediate weeding are sufficient for optimum SS biomass production and sugar levels. Full article