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Search Results (1,633)

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Keywords = nonlinear analysis relationship

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17 pages, 1488 KiB  
Article
Experimental Investigation of Impact Mechanisms of Seeding Quality for Ridge-Clearing No-Till Seeder Under Strip Tillage
by Yuanyuan Gao, Yongyue Hu, Shuo Yang, Xueguan Zhao, Shengwei Lu, Hanjie Dou, Qingzhen Zhu, Peiying Li and Yongyun Zhu
Agronomy 2025, 15(8), 1875; https://doi.org/10.3390/agronomy15081875 (registering DOI) - 1 Aug 2025
Abstract
Under conservation tillage in the Huang-Huai-Hai wheat–maize rotation area, the ridge-clearing no-till seeder for strip tillage mitigates the adverse impacts of surface residues on seeding quality by clearing stubble specifically within the seed rows, demonstrating significant potential for application and promotion. However, the [...] Read more.
Under conservation tillage in the Huang-Huai-Hai wheat–maize rotation area, the ridge-clearing no-till seeder for strip tillage mitigates the adverse impacts of surface residues on seeding quality by clearing stubble specifically within the seed rows, demonstrating significant potential for application and promotion. However, the inadequate understanding of the seeder’s operational performance and governing mechanisms under varying field conditions hinders its high-quality and efficient implementation. To address this issue, this study selected the stubble height, forward speed, and stubble knife rotational speed (PTO speed) as experimental factors. Employing a three-factor quasi-level orthogonal experimental design, coupled with response surface regression analysis, this research systematically elucidated the interaction mechanisms among these factors concerning the seeding depth consistency and seed spacing uniformity of the seeder. An optimized parameter-matching model was subsequently derived through equation system solving. Field trials demonstrated that a lower forward speed improved the seed spacing uniformity and seeding depth consistency, whereas high speeds increased the missing rates and spacing deviations. An appropriate stubble height enhanced the seed spacing accuracy, but an excessive height compromised depth precision. Higher PTO speeds reduced multiple indices but impaired depth accuracy. Response surface analysis based on the regression models demonstrated that the peak value of the seed spacing qualification index occurred within the forward speed range of 8–9 km/h and the stubble height range of 280–330 mm, with the stubble height being the dominant factor. Similarly, the peak value of the seeding depth qualification index occurred within the stubble height range of 300–350 mm and the forward speed range of 7.5–9 km/h, with the forward speed as the primary factor. Validation confirmed that combining stubble heights of 300−330 mm, forward speeds of 8−9 km/h, and PTO speeds of 540 r/min optimized both metrics. This research reveals nonlinear coupling relationships between operational parameters and seeding quality metrics, establishes a stubble–speed dynamic matching model, and provides a theoretical foundation for the intelligent control of seeders in conservation tillage systems. Full article
(This article belongs to the Collection AI, Sensors and Robotics for Smart Agriculture)
23 pages, 10868 KiB  
Article
Quantitative Analysis and Nonlinear Response of Vegetation Dynamic to Driving Factors in Arid and Semi-Arid Regions of China
by Shihao Liu, Dazhi Yang, Xuyang Zhang and Fangtian Liu
Land 2025, 14(8), 1575; https://doi.org/10.3390/land14081575 (registering DOI) - 1 Aug 2025
Abstract
Vegetation dynamics are complexly influenced by multiple factors such as climate, human activities, and topography. In recent years, the frequency, intensity, and diversity of human activities have increased, placing substantial pressure on the growth of vegetation. Arid and semi-arid regions are particularly sensitive [...] Read more.
Vegetation dynamics are complexly influenced by multiple factors such as climate, human activities, and topography. In recent years, the frequency, intensity, and diversity of human activities have increased, placing substantial pressure on the growth of vegetation. Arid and semi-arid regions are particularly sensitive to climate change, and climate change and large-scale ecological restoration have led to significant changes in the dynamic of dryland vegetation. However, few studies have explored the nonlinear relationships between these factors and vegetation dynamic. In this study, we integrated trend analysis (using the Mann–Kendall test and Theil–Sen estimation) and machine learning algorithms (XGBoost-SHAP model) based on long time-series remote sensing data from 2001 to 2020 to quantify the nonlinear response patterns and threshold effects of bioclimatic variables, topographic features, soil attributes, and anthropogenic factors on vegetation dynamic. The results revealed the following key findings: (1) The kNDVI in the study area showed an overall significant increasing trend (p < 0.01) during the observation period, of which 26.7% of the area showed a significant increase. (2) The water content index (Bio 23, 19.6%), the change in land use (15.2%), multi-year average precipitation (pre, 15.0%), population density (13.2%), and rainfall seasonality (Bio 15, 10.9%) were the key factors driving the dynamic change of vegetation, with the combined contribution of natural factors amounting to 64.3%. (3) Among the topographic factors, altitude had a more significant effect on vegetation dynamics, with higher altitude regions less likely to experience vegetation greening. Both natural and anthropogenic factors exhibited nonlinear responses and interactive effects, contributing to the observed dynamic trends. This study provides valuable insights into the driving mechanisms behind the condition of vegetation in arid and semi-arid regions of China and, by extension, in other arid regions globally. Full article
(This article belongs to the Section Land Use, Impact Assessment and Sustainability)
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11 pages, 1758 KiB  
Article
Nonlinear Absorption Properties of Phthalocyanine-like Squaraine Dyes
by Fan Zhang, Wuyang Shi, Xixiao Li, Yigang Wang, Leilei Si, Wentao Gao, Meng Qi, Minjie Zhou, Jiajun Ma, Ao Li, Zhiqiang Li, Hongming Wang and Bing Jin
Photonics 2025, 12(8), 779; https://doi.org/10.3390/photonics12080779 (registering DOI) - 1 Aug 2025
Abstract
This study synthesizes and comparatively investigates two squaric acid-based phthalocyanine-like dyes, SNF and its long-chain alkylated derivative LNF, to systematically elucidate the influence of peripheral hydrophobic groups on their third-order nonlinear optical (NLO) properties. The NLO characteristics were comprehensively characterized using femtosecond Z-scan [...] Read more.
This study synthesizes and comparatively investigates two squaric acid-based phthalocyanine-like dyes, SNF and its long-chain alkylated derivative LNF, to systematically elucidate the influence of peripheral hydrophobic groups on their third-order nonlinear optical (NLO) properties. The NLO characteristics were comprehensively characterized using femtosecond Z-scan and I-scan techniques at both 800 nm and 900 nm. Both dyes exhibited strong saturable absorption (SA), confirming their potential as saturable absorbers. Critically, the comparative analysis revealed that SNF exhibits a significantly greater nonlinear absorption coefficient (β) compared to LNF under identical conditions. For instance, at 800 nm, the β of SNF was approximately 3–5 times larger than that of LNF. This result conclusively demonstrates that the introduction of long hydrophobic alkyl chains attenuates the NLO response. Furthermore, I-scan measurements revealed excellent SA performance, with high modulation depths (e.g., LNF: 43.0% at 900 nm) and low saturation intensities. This work not only clarifies the structure–property relationship in these D-A-D dyes but also presents a clear strategy for modulating the NLO properties of organic chromophores for applications in near-infrared pulsed lasers. Full article
(This article belongs to the Section Optoelectronics and Optical Materials)
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26 pages, 1669 KiB  
Article
Predefined-Time Adaptive Neural Control with Event-Triggering for Robust Trajectory Tracking of Underactuated Marine Vessels
by Hui An, Zhanyang Yu, Jianhua Zhang, Xinxin Wang and Cheng Siong Chin
Processes 2025, 13(8), 2443; https://doi.org/10.3390/pr13082443 (registering DOI) - 1 Aug 2025
Abstract
This paper addresses the trajectory tracking control problem of underactuated ships in ocean engineering, which faces the dual challenges of tracking error time–performance regulation and robustness design due to the system’s underactuated characteristics, model uncertainties, and external disturbances. Aiming to address the issues [...] Read more.
This paper addresses the trajectory tracking control problem of underactuated ships in ocean engineering, which faces the dual challenges of tracking error time–performance regulation and robustness design due to the system’s underactuated characteristics, model uncertainties, and external disturbances. Aiming to address the issues of traditional finite-time control (convergence time dependent on initial states) and fixed-time control (control chattering and parameter conservativeness), this paper proposes a predefined-time adaptive control framework that integrates an event-triggered mechanism and neural networks. By constructing a Lyapunov function with time-varying weights and designing non-periodic dynamically updated dual triggering conditions, the convergence process of tracking errors is strictly constrained within a user-prespecified time window without relying on initial states or introducing non-smooth terms. An adaptive approximator based on radial basis function neural networks (RBF-NNs) is employed to compensate for unknown nonlinear dynamics and external disturbances in real-time. Combined with the event-triggered mechanism, it dynamically adjusts the update instances of control inputs, ensuring prespecified tracking accuracy while significantly reducing computational resource consumption. Theoretical analysis shows that all signals in the closed-loop system are uniformly ultimately bounded, tracking errors converge to a neighborhood of the origin within the predefined-time, and the update frequency of control inputs exhibits a linear relationship with the predefined-time, avoiding Zeno behavior. Simulation results verify the effectiveness of the proposed method in complex marine environments. Compared with traditional control strategies, it achieves more accurate trajectory tracking, faster response, and a substantial reduction in control input update frequency, providing an efficient solution for the engineering implementation of embedded control systems in unmanned ships. Full article
(This article belongs to the Special Issue Design and Analysis of Adaptive Identification and Control)
23 pages, 888 KiB  
Article
Correlations Between Coffee Intake, Glycemic Control, Cardiovascular Risk, and Sleep in Type 2 Diabetes and Hypertension: A 12-Month Observational Study
by Tatiana Palotta Minari, José Fernando Vilela-Martin, Juan Carlos Yugar-Toledo and Luciana Pellegrini Pisani
Biomedicines 2025, 13(8), 1875; https://doi.org/10.3390/biomedicines13081875 (registering DOI) - 1 Aug 2025
Abstract
Background: The consumption of coffee has been widely debated regarding its effects on health. This study aims to analyze the correlations between daily coffee intake and sleep, blood pressure, anthropometric measurements, and biochemical markers in individuals with type 2 diabetes (T2D) and hypertension [...] Read more.
Background: The consumption of coffee has been widely debated regarding its effects on health. This study aims to analyze the correlations between daily coffee intake and sleep, blood pressure, anthropometric measurements, and biochemical markers in individuals with type 2 diabetes (T2D) and hypertension over a 12-month period. Methods: An observational study was conducted with 40 participants with T2D and hypertension, comprising 20 females and 20 males. Participants were monitored for their daily coffee consumption over a 12-month period, being assessed every 3 months. Linear regression was utilized to assess interactions and relationships between variables, providing insights into potential predictive associations. Additionally, correlation analysis was performed using Pearson’s and Spearman’s tests to evaluate the strength and direction of linear and non-linear relationships. Statistical significance was set at p < 0.05. Results: Significant changes were observed in fasting blood glucose (FBG), glycated hemoglobin (HbA1c), body weight, body mass index, sleep duration, nocturnal awakenings, and waist-to-hip ratio (p < 0.05) over the 12-month study in both sexes. No significant differences were noted in the remaining parameters (p > 0.05). The coffee consumed by the participants was of the “traditional type” and contained sugar (2g per cup) for 100% of the participants. An intake of 4.17 ± 0.360 cups per day was found at baseline and 5.41 ± 0.316 cups at 12 months (p > 0.05). Regarding correlation analysis, a higher coffee intake was significantly associated with shorter sleep duration in women (r = −0.731; p = 0.037). Conversely, greater coffee consumption correlated with lower LDL cholesterol (LDL-C) levels in women (r = −0.820; p = 0.044). Additionally, a longer sleep duration was linked to lower FBG (r = -0.841; p = 0.031), HbA1c (r = -0.831; p = 0.037), and LDL-C levels in women (r = -0.713; p = 0.050). No significant correlations were observed for the other parameters in both sexes (p > 0.05). Conclusions: In women, coffee consumption may negatively affect sleep duration while potentially offering beneficial effects on LDL-C levels, even when sweetened with sugar. Additionally, a longer sleep duration in women appears to be associated with improvements in FBG, HbA1c, and LDL-C. These correlations emphasize the importance of a balanced approach to coffee consumption, weighing both its potential health benefits and drawbacks in postmenopausal women. However, since this study does not establish causality, further randomized clinical trials are warranted to investigate the underlying mechanisms and long-term implications—particularly in the context of T2D and hypertension. Full article
(This article belongs to the Special Issue Diabetes: Comorbidities, Therapeutics and Insights (3rd Edition))
15 pages, 1635 KiB  
Article
Modeling the Abrasive Index from Mineralogical and Calorific Properties Using Tree-Based Machine Learning: A Case Study on the KwaZulu-Natal Coalfield
by Mohammad Afrazi, Chia Yu Huat, Moshood Onifade, Manoj Khandelwal, Deji Olatunji Shonuga, Hadi Fattahi and Danial Jahed Armaghani
Mining 2025, 5(3), 48; https://doi.org/10.3390/mining5030048 (registering DOI) - 1 Aug 2025
Abstract
Accurate prediction of the coal abrasive index (AI) is critical for optimizing coal processing efficiency and minimizing equipment wear in industrial applications. This study explores tree-based machine learning models; Random Forest (RF), Gradient Boosting Trees (GBT), and Extreme Gradient Boosting (XGBoost) to predict [...] Read more.
Accurate prediction of the coal abrasive index (AI) is critical for optimizing coal processing efficiency and minimizing equipment wear in industrial applications. This study explores tree-based machine learning models; Random Forest (RF), Gradient Boosting Trees (GBT), and Extreme Gradient Boosting (XGBoost) to predict AI using selected coal properties. A database of 112 coal samples from the KwaZulu-Natal Coalfield in South Africa was used. Initial predictions using all eight input properties revealed suboptimal testing performance (R2: 0.63–0.72), attributed to outliers and noisy data. Feature importance analysis identified calorific value, quartz, ash, and Pyrite as dominant predictors, aligning with their physicochemical roles in abrasiveness. After data cleaning and feature selection, XGBoost achieved superior accuracy (R2 = 0.92), outperforming RF (R2 = 0.85) and GBT (R2 = 0.81). The results highlight XGBoost’s robustness in modeling non-linear relationships between coal properties and AI. This approach offers a cost-effective alternative to traditional laboratory methods, enabling industries to optimize coal selection, reduce maintenance costs, and enhance operational sustainability through data-driven decision-making. Additionally, quartz and Ash content were identified as the most influential parameters on AI using the Cosine Amplitude technique, while calorific value had the least impact among the selected features. Full article
(This article belongs to the Special Issue Mine Automation and New Technologies)
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18 pages, 1584 KiB  
Article
What Determines Carbon Emissions of Multimodal Travel? Insights from Interpretable Machine Learning on Mobility Trajectory Data
by Guo Wang, Shu Wang, Wenxiang Li and Hongtai Yang
Sustainability 2025, 17(15), 6983; https://doi.org/10.3390/su17156983 (registering DOI) - 31 Jul 2025
Abstract
Understanding the carbon emissions of multimodal travel—comprising walking, metro, bus, cycling, and ride-hailing—is essential for promoting sustainable urban mobility. However, most existing studies focus on single-mode travel, while underlying spatiotemporal and behavioral determinants remain insufficiently explored due to the lack of fine-grained data [...] Read more.
Understanding the carbon emissions of multimodal travel—comprising walking, metro, bus, cycling, and ride-hailing—is essential for promoting sustainable urban mobility. However, most existing studies focus on single-mode travel, while underlying spatiotemporal and behavioral determinants remain insufficiently explored due to the lack of fine-grained data and interpretable analytical frameworks. This study proposes a novel integration of high-frequency, real-world mobility trajectory data with interpretable machine learning to systematically identify the key drivers of carbon emissions at the individual trip level. Firstly, multimodal travel chains are reconstructed using continuous GPS trajectory data collected in Beijing. Secondly, a model based on Calculate Emissions from Road Transport (COPERT) is developed to quantify trip-level CO2 emissions. Thirdly, four interpretable machine learning models based on gradient boosting—XGBoost, GBDT, LightGBM, and CatBoost—are trained using transportation and built environment features to model the relationship between CO2 emissions and a set of explanatory variables; finally, Shapley Additive exPlanations (SHAP) and partial dependence plots (PDPs) are used to interpret the model outputs, revealing key determinants and their non-linear interaction effects. The results show that transportation-related features account for 75.1% of the explained variance in emissions, with bus usage being the most influential single factor (contributing 22.6%). Built environment features explain the remaining 24.9%. The PDP analysis reveals that substantial emission reductions occur only when the shares of bus, metro, and cycling surpass threshold levels of approximately 40%, 40%, and 30%, respectively. Additionally, travel carbon emissions are minimized when trip origins and destinations are located within a 10 to 11 km radius of the central business district (CBD). This study advances the field by establishing a scalable, interpretable, and behaviorally grounded framework to assess carbon emissions from multimodal travel, providing actionable insights for low-carbon transport planning and policy design. Full article
(This article belongs to the Special Issue Sustainable Transportation Systems and Travel Behaviors)
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26 pages, 3711 KiB  
Article
Probability Characteristics of High and Low Flows in Slovakia: A Comprehensive Hydrological Assessment
by Pavla Pekárová, Veronika Bačová Mitková and Dana Halmová
Hydrology 2025, 12(8), 199; https://doi.org/10.3390/hydrology12080199 - 31 Jul 2025
Abstract
Frequency analysis is essential for designing hydraulic structures and managing water resources, as it helps assess hydrological extremes. However, changes in river basins can impact their accuracy, complicating the link between discharge and return periods. This study aims to comprehensively assess the probability [...] Read more.
Frequency analysis is essential for designing hydraulic structures and managing water resources, as it helps assess hydrological extremes. However, changes in river basins can impact their accuracy, complicating the link between discharge and return periods. This study aims to comprehensively assess the probability characteristics of long-term M-day maximum/minimum discharges in the Carpathian region of Slovakia. We analyze the long-term data from 26 gauging stations covering 90 years of observation. Slovak rivers show considerable intra-annual variability, especially between the summer–autumn (SA) and winter–spring (WS) seasons. To allow consistent comparisons, we apply a uniform methodology to estimate T-year daily maximum and minimum specific discharges over durations of 1 and 7 days for both seasons. Our findings indicate that 1-day maximum specific discharges are generally higher during the SA season compared to the WS season. The 7-day minimum specific discharges are lower during the WS season compared to the SA season. Slovakia’s diverse orographic and climatic conditions cause significant spatial variability in extreme discharges. However, the estimated T-year 7-day minimum and 1-day maximum specific discharges, based on the mean specific discharge and the altitude of the water gauge, exhibit certain nonlinear dependences. These relationships could support the indirect estimation of T-year M-day discharges in regions with similar runoff characteristics. Full article
(This article belongs to the Section Water Resources and Risk Management)
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20 pages, 3903 KiB  
Article
Void Detection of Airport Concrete Pavement Slabs Based on Vibration Response Under Moving Load
by Xiang Wang, Ziliang Ma, Xing Hu, Xinyuan Cao and Qiao Dong
Sensors 2025, 25(15), 4703; https://doi.org/10.3390/s25154703 - 30 Jul 2025
Abstract
This study proposes a vibration-based approach for detecting and quantifying sub-slab corner voids in airport cement concrete pavement. Scaled down slab models were constructed and subjected to controlled moving load simulations. Acceleration signals were collected and analyzed to extract time–frequency domain features, including [...] Read more.
This study proposes a vibration-based approach for detecting and quantifying sub-slab corner voids in airport cement concrete pavement. Scaled down slab models were constructed and subjected to controlled moving load simulations. Acceleration signals were collected and analyzed to extract time–frequency domain features, including power spectral density (PSD), skewness, and frequency center. A finite element model incorporating contact and nonlinear constitutive relationships was established to simulate structural response under different void conditions. Based on the simulated dataset, a random forest (RF) model was developed to estimate void size using selected spectral energy indicators and geometric parameters. The results revealed that the RF model achieved strong predictive performance, with a high correlation between key features and void characteristics. This work demonstrates the feasibility of integrating simulation analysis, signal feature extraction, and machine learning to support intelligent diagnostics of concrete pavement health. Full article
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16 pages, 1833 KiB  
Article
Prediction of Waste Generation Using Machine Learning: A Regional Study in Korea
by Jae-Sang Lee and Dong-Chul Shin
Urban Sci. 2025, 9(8), 297; https://doi.org/10.3390/urbansci9080297 - 30 Jul 2025
Viewed by 26
Abstract
Accurate forecasting of household waste generation is essential for sustainable urban planning and the development of data-driven environmental policies. Conventional statistical models, while simple and interpretable, often fail to capture the nonlinear and multidimensional relationships inherent in waste production patterns. This study proposes [...] Read more.
Accurate forecasting of household waste generation is essential for sustainable urban planning and the development of data-driven environmental policies. Conventional statistical models, while simple and interpretable, often fail to capture the nonlinear and multidimensional relationships inherent in waste production patterns. This study proposes a machine learning-based regression framework utilizing Random Forest and XGBoost algorithms to predict annual household waste generation across four metropolitan regions in South Korea Seoul, Gyeonggi, Incheon, and Jeju over the period from 2000 to 2023. Independent variables include demographic indicators (total population, working-age population, elderly population), economic indicators (Gross Regional Domestic Product), and regional identifiers encoded using One-Hot Encoding. A derived feature, elderly ratio, was introduced to reflect population aging. Model performance was evaluated using R2, RMSE, and MAE, with artificial noise added to simulate uncertainty. Random Forest demonstrated superior generalization and robustness to data irregularities, especially in data-scarce regions like Jeju. SHAP-based interpretability analysis revealed total population and GRDP as the most influential features. The findings underscore the importance of incorporating economic indicators in waste forecasting models, as demographic variables alone were insufficient for explaining waste dynamics. This approach provides valuable insights for policymakers and supports the development of adaptive, region-specific strategies for waste reduction and infrastructure investment. Full article
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17 pages, 1207 KiB  
Article
Assessing Critical Risk Factors to Sustainable Housing in Urban Areas: Based on the NK-SNA Model
by Guangyu Sun and Hui Zeng
Sustainability 2025, 17(15), 6918; https://doi.org/10.3390/su17156918 - 30 Jul 2025
Viewed by 72
Abstract
Housing sustainability is a cornerstone element of sustainable economic and social development. This is particularly true for China, where high-rise residential buildings are the primary form of housing. In recent years, China has experienced frequent housing-related accidents, resulting in a significant loss of [...] Read more.
Housing sustainability is a cornerstone element of sustainable economic and social development. This is particularly true for China, where high-rise residential buildings are the primary form of housing. In recent years, China has experienced frequent housing-related accidents, resulting in a significant loss of life and property damage. This study aims to identify the key factors influencing housing sustainability and provide a basis for the prevention and control of housing-related safety risks. This study has developed a housing sustainability evaluation indicator system comprising three primary indicators and 16 secondary indicators. This system is based on an analysis of the causes of over 500 typical housing accidents that occurred in China over the past 10 years, employing research methods such as literature reviews and expert consultations, and drawing on the analytical frameworks of risk management theory and system safety theory. Subsequently, the NK-SNA model, which significantly outperforms traditional models in terms of adaptive learning and optimization, as well as the explicit modeling of complex nonlinear relationships, was used to identify the key risk factors affecting housing sustainability. The empirical results indicate that the risk coupling value is correlated with the number of risk coupling factors; the greater the number of risk coupling factors, the larger the coupling value. Human misconduct is prone to forming two-factor risk coupling with housing, and the physical risk factors are prone to coupling with other factors. The environmental factors easily trigger ‘physical–environmental’ two-factor risk coupling. The key factors influencing housing sustainability are poor supervision, building facilities, the main structure, the housing height, foundation settlement, and natural disasters. On this basis, recommendations are made to make full use of modern information technologies such as the Internet of Things, big data, and artificial intelligence to strengthen the supervision of housing safety and avoid multi-factor coupling, and to improve upon early warnings of natural disasters and the design of emergency response programs to control the coupling between physical and environmental factors. Full article
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13 pages, 1172 KiB  
Article
Informatics-Based Design of Virtual Libraries of Polymer Nano-Composites
by Qinrui Liu and Scott R. Broderick
Int. J. Mol. Sci. 2025, 26(15), 7344; https://doi.org/10.3390/ijms26157344 - 30 Jul 2025
Viewed by 123
Abstract
The purpose of this paper is to use an informatics-based analysis to develop a rational design approach to the accelerated screening of nano-composite materials. Using existing nano-composite data, we develop a quantitative structure–activity relationship (QSAR) as a function of polymer matrix chemistry and [...] Read more.
The purpose of this paper is to use an informatics-based analysis to develop a rational design approach to the accelerated screening of nano-composite materials. Using existing nano-composite data, we develop a quantitative structure–activity relationship (QSAR) as a function of polymer matrix chemistry and nano-additive volume, with the property predicted being electrical conductivity. The development of a QSAR for the electrical conductivity of nano-composites presents challenges in representing the polymer matrix chemistry and backbone structure, the additive content, and the interactions between the components while capturing the non-linearity of electrical conductivity with changing nano-additive volume. An important aspect of this work is designing chemistries with small training data sizes, as the uncertainty in modeling is high, and potentially the representated physics may be minimal. In this work, we explore two important components of this aspect. First, an assessment via Uniform Manifold Approximation and Projection (UMAP) is used to assess the variability provided by new data points and how much information is contributed by data, which is significantly more important than the actual data size (i.e., how much new information is provided by each data point?). The second component involves assessing multiple training/testing splits to ensure that any results are not due to a specific case but rather that the results are statistically meaningful. This work will accelerate the rational design of polymer nano-composites by fully considering the large array of possible variables while providing a high-speed screening of polymer chemistries. Full article
(This article belongs to the Section Molecular Informatics)
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17 pages, 4176 KiB  
Article
Hydrochemical Characterization and Predictive Modeling of Groundwater Quality in Karst Aquifers Under Semi-Arid Climate: A Case Study of Ghar Boumaaza, Algeria
by Sabrine Guettaia, Abderrezzak Boudjema, Abdessamed Derdour, Abdessalam Laoufi, Hussein Almohamad, Motrih Al-Mutiry and Hazem Ghassan Abdo
Sustainability 2025, 17(15), 6883; https://doi.org/10.3390/su17156883 - 29 Jul 2025
Viewed by 190
Abstract
Understanding groundwater quality in karst environments is essential, particularly in semi-arid regions where water resources are highly vulnerable to both climatic variability and anthropogenic pressures. The Ghar Boumaaza karst aquifer, located in the semi-arid Tlemcen Mountains of Algeria, represents a critical yet understudied [...] Read more.
Understanding groundwater quality in karst environments is essential, particularly in semi-arid regions where water resources are highly vulnerable to both climatic variability and anthropogenic pressures. The Ghar Boumaaza karst aquifer, located in the semi-arid Tlemcen Mountains of Algeria, represents a critical yet understudied water resource increasingly threatened by climate change and human activity. This study integrates hydrochemical analysis, multivariate statistical techniques, and predictive modeling to assess groundwater quality and characterize the relationship between total dissolved solids (TDSs) and discharge (Q). An analysis of 66 water samples revealed that 96.97% belonged to a Ca2+–HCO3 facies, reflecting carbonate rock dissolution, while 3% exhibited a Cl–HCO3 facies associated with agricultural contamination. A principal component analysis identified carbonate weathering (40.35%) and agricultural leaching (18.67%) as the dominant drivers of mineralization. A third-degree polynomial regression model (R2 = 0.953) effectively captured the nonlinear relationship between TDSs and flow, demonstrating strong predictive capacity. Independent validation (R2 = 0.954) confirmed the model’s robustness and reliability. This study provides the first integrated hydrogeochemical assessment of the Ghar Boumaaza system in decades and offers a transferable methodological framework for managing vulnerable karst aquifers under similar climatic and anthropogenic conditions. Full article
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18 pages, 288 KiB  
Article
Functional Differential Equations with Non-Canonical Operator: Oscillatory Features of Solutions
by Asma Al-Jaser, Faizah Alharbi, Dimplekumar Chalishajar and Belgees Qaraad
Axioms 2025, 14(8), 588; https://doi.org/10.3390/axioms14080588 - 29 Jul 2025
Viewed by 63
Abstract
This study focuses on investigating the asymptotic and oscillatory behavior of a new class of fourth-order nonlinear neutral differential equations. This research aims to achieve a qualitative advancement in the analysis and understanding of the relationships between the corresponding function and its derivatives. [...] Read more.
This study focuses on investigating the asymptotic and oscillatory behavior of a new class of fourth-order nonlinear neutral differential equations. This research aims to achieve a qualitative advancement in the analysis and understanding of the relationships between the corresponding function and its derivatives. By utilizing various techniques, innovative criteria have been developed to ensure the oscillation of all solutions of the studied equations without resorting to additional constraints. Effective analytical tools are provided, contributing to a deeper theoretical understanding and expanding their application scope. The paper concludes by presenting examples that illustrate the practical impact of the results, highlighting the theoretical value of the research in the field of functional differential equations. Full article
(This article belongs to the Special Issue Difference, Functional, and Related Equations, 2nd Edition)
14 pages, 1015 KiB  
Article
Integrating Dimensional Analysis and Machine Learning for Predictive Maintenance of Francis Turbines in Sediment-Laden Flow
by Álvaro Ospina, Ever Herrera Ríos, Jaime Jaramillo, Camilo A. Franco, Esteban A. Taborda and Farid B. Cortes
Energies 2025, 18(15), 4023; https://doi.org/10.3390/en18154023 - 29 Jul 2025
Viewed by 210
Abstract
The efficiency decline of Francis turbines, a key component of hydroelectric power generation, presents a multifaceted challenge influenced by interconnected factors such as water quality, incidence angle, erosion, and runner wear. This paper is structured into two main sections to address these issues. [...] Read more.
The efficiency decline of Francis turbines, a key component of hydroelectric power generation, presents a multifaceted challenge influenced by interconnected factors such as water quality, incidence angle, erosion, and runner wear. This paper is structured into two main sections to address these issues. The first section applies the Buckingham π theorem to establish a dimensional analysis (DA) framework, providing insights into the relationships among the operational variables and their impact on turbine wear and efficiency loss. Dimensional analysis offers a theoretical basis for understanding the relationships among operational variables and efficiency within the scope of this study. This understanding, in turn, informs the selection and interpretation of features for machine learning (ML) models aimed at the predictive maintenance of the target variable and important features for the next stage. The second section analyzes an extensive dataset collected from a Francis turbine in Colombia, a country that is heavily reliant on hydroelectric power. The dataset consisted of 60,501 samples recorded over 15 days, offering a robust basis for assessing turbine behavior under real-world operating conditions. An exploratory data analysis (EDA) was conducted by integrating linear regression and a time-series analysis to investigate efficiency dynamics. Key variables, including power output, water flow rate, and operational time, were extracted and analyzed to identify patterns and correlations affecting turbine performance. This study seeks to develop a comprehensive understanding of the factors driving Francis turbine efficiency loss and to propose strategies for mitigating wear-induced performance degradation. The synergy lies in DA’s ability to reduce dimensionality and identify meaningful features, which enhances the ML models’ interpretability, while ML leverages these features to model non-linear and time-dependent patterns that DA alone cannot address. This integrated approach results in a linear regression model with a performance (R2-Test = 0.994) and a time series using ARIMA with a performance (R2-Test = 0.999) that allows for the identification of better generalization, demonstrating the power of combining physical principles with advanced data analysis. The preliminary findings provide valuable insights into the dynamic interplay of operational parameters, contributing to the optimization of turbine operation, efficiency enhancement, and lifespan extension. Ultimately, this study supports the sustainability and economic viability of hydroelectric power generation by advancing tools for predictive maintenance and performance optimization. Full article
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