Search Results (31)

The dissimilar combination of NiTi shape memory alloy and Ti6Al4V titanium alloy offers superelasticity, biocompatibility and high specific strength, showing broad application prospects in aerospace and medical fields. However, when fabricating NiTi/Ti6Al4V composite components by multi-material laser powder bed fusion (MM-LPBF), brittle cracks or even complete delamination easily occur at the interface. In this paper, without relying on intermediate interlayer materials, we innovatively propose a root-inspired three-dimensional bio-interlocking interface structure. By means of macroscopic three-dimensional geometric interlocking, the crack propagation path and load transfer mode are forced to change. Using the branching angle (45°, 60°) and the structural size multiplier (1.2, 1.5) as variables, the influence of the bio-inspired geometric parameters on the interfacial forming quality, microstructure and mechanical properties was systematically investigated. The results show that the branching angle is the primary factor determining the performance. The 45° low-angle branched specimens exhibit overall brittle delamination along the flat metallurgical reaction interface under shear loading, with an average shear strength of only 17.47 MPa. In contrast, the 60° high-angle branched specimens, owing to their larger normal embedding depth, exhibit a failure mode transitioning to a mixed mode that includes crack deflection, branch shearing and plastic tearing of the Ti6Al4V matrix. Although TEM confirms that a continuous Ti₂Ni brittle phase still exists at the interface, the optimised 60–1.5 structure increases the average shear strength to 128.37 MPa, which is more than six times higher than that of the 45–1.2 group (17.47 MPa). This “geometrical constraint toughening” strategy provides a new paradigm for the interfacial strengthening of dissimilar metals without relying on metallurgical modification. Full article

Semiconductor-based photocatalytic water splitting is a promising pathway for sustainable hydrogen production; however, the reported performance depends not only on the intrinsic properties of the photocatalyst but also on reactor configuration and operating conditions. This systematic technical review examines the interplay between nanostructured semiconductor photocatalysts and the principal engineering variables governing photocatalytic hydrogen evolution. Particular attention is given to particle size, morphology, surface area, defect density, heterojunction design, cocatalyst incorporation, aggregation, and catalyst immobilization, as well as their interaction with reactor geometry, optical path length, photon distribution, catalyst loading, working volume, pH, sacrificial agents, mixing, thermal control, gas purging, and product quantification. The reviewed evidence indicates that these material and reactor parameters jointly determine light absorption, charge-carrier separation and transfer, suspension turbidity, mass transport, catalyst recovery, stability, and the measured hydrogen evolution rate. Batch slurry reactors remain the most widely used laboratory configuration, whereas annular, flat-panel, microreactor, fixed-bed, continuous-flow, and photofluidized systems offer specific advantages for photon utilization, catalyst reuse, product removal, and scale-up. The review also emphasizes the need to distinguish overall water splitting from sacrificial-agent-assisted hydrogen evolution. Standardized reporting of photocatalyst properties, irradiance, spectral distribution, illuminated area, reactor dimensions, reaction atmosphere, and gas-analysis procedures is essential to improve reproducibility and enable reliable comparisons among nanostructured photocatalytic systems. Full article

Variable sediment supply and widely graded bed materials modify boulder–bar development, sediment transport and bar evolution in mountain mixed-size reaches. To elucidate the evolution characteristics of bars in boulder-strewn mountain river segments, this study conducted flume experiments. By adjusting parameters including discharge, boulder position, and boulder protrusion height, the paper analyzes bed scour and deposition deformations under various conditions. Results show discharge growth intensifies bed deformation: Both bar area and volume increase with rising discharge, with longer downstream bar extension and a positive correlation between bar length–width ratio and velocity. Higher boulder protrusion height and exposure amplify scour depth, expand bars laterally and reduce scour pit width–depth ratios. Boulders at bar heads migrate furthest downstream; moving boulders toward bar tails increases bar area/volume while bar height peaks then declines. Bar scale follows mid-channel bar head > bar tail > side anabranches. Boulder embedding depth linearly rises with exposure, both parameters positively linked to post-scour bar volume loss. The stable co-evolutionary relationship between scour depth and extent (R² = 0.849) confirms their synchronized development under varying flow and boulder conditions. Boulders limit downstream bar elongation, flat beds boost scour diffusion, and scour pit width–depth ratio positively correlates with flow velocity. This work offers experimental and mechanistic references for mountain river geomorphic prediction. Full article

Conventional chemical gel plugging materials often suffer from poor high-temperature stability and inadequate mechanical properties. To address these issues, this study developed a high-performance composite gel material using a multi-component hybrid crosslinking strategy. The material employs γ-methacryloxypropyltrimethoxysilane (MPTMS) as the silica source, which hydrolyzes in situ to generate SiO₂, thereby enhancing temperature resistance. Laponite nanoplatelets are incorporated as a toughening agent and physical crosslinking points, while a self-synthesized reactive microgel (BWL) serves as the organic crosslinking core. Through copolymerization with monomers such as acrylamide (AM) and methacrylic acid (MAA), a triple-crosslinked network structure is constructed. Compared with conventional gels, the synthesized hybrid crosslinked composite gel maintains a high storage modulus and loss modulus after aging at 140 °C and exhibits excellent tensile and compressive properties. Furthermore, the gel was processed into particle-based lost circulation materials with different particle sizes. High-temperature and high-pressure plugging experiments demonstrate that when using a mixed system of 40–60 mesh, 20–40 mesh, and 10–20 mesh gel particles with a total concentration of 2%, it can effectively seal highly permeable sand beds and fractures with apertures up to 5 mm. This meets the engineering requirements for lost circulation materials with high strength and high stability in deep, high-temperature formations. Full article

This paper examines the study of an advanced design for a continuously operating fluidized bed reactor applied to sunflower husk torrefaction in a superheated steam environment, which is simulated in a cold model of the reactor. The simulated reactor has a diameter of 0.3 m and contains six vertical baffles installed along the reactor walls, providing loop-like movement of crushed husk particles from the reactor loading point to the reactor biomass unloading point. The residence time of crushed sunflower husk biomass particles in the reactor was studied by introducing colored biomass particles into the bed; these particles had the same mass and size as the undyed material. According to modeling results, replacing superheated steam with room-temperature air in the “cold” model may not lead to significant changes in the hydrodynamics of the fluidized bed or their effect on particle mixing. Experiments were conducted at an air velocity of 0.6 m/s relative to the cross-section of the empty apparatus, which is 3.5-fold greater than the minimum fluidization velocity. Samples were collected at the reactor outlet and dissolved in distilled water. The transparency of the resulting solution was measured using a KFK-3 photometer, and the amount of colored substance in each sample was determined accordingly. The most probable average residence time of biomass particles in the cold model amounted to 6–8 min at a Peclet number of 47. To ensure full operation of the torrefaction reactor under ideal plug-flow conditions, the reactor must be equipped with 24 baffles. The residence time of biomass particles required for optimal operation of the reactor was estimated to 24–32 min, which may be sufficient to produce biochar with a high calorific value, suitable for co-firing with coal. Full article

Patient-specific lattice implants (PSLIs) and modular porous scaffolds have emerged as promising solutions for treating diaphyseal segmental defects of the femur and tibia, particularly where conventional reconstruction methods fall short. This second part of our two-part review focuses on how current studies transform computed tomography (CT) and $\mathsf{\mu }$CT datasets into architected lattice implants, as well as how these constructs are fabricated and numerically, mechanically, biologically, and clinically verified. We outline imaging pipelines, including Digital Imaging and Communications in Medicine (DICOM) acquisition, segmentation, contralateral mirroring, and Hounsfield Units (HU)–density–elasticity mapping, and show how these choices impact finite element (FE) models and print-ready geometries. Next, lattice design strategies and mixed-material concepts are compared and linked to specific additive manufacturing routes in metals, polymers, and bioceramics, such as laser powder bed fusion (LPBF), electron beam melting (EBM), fused deposition modeling (FDM), material jetting, and extrusion-based bioprinting. Methodological overviews of linear–elastic models and homogenized finite element (FE) models, along with bench-top mechanical tests, in vitro cell assays, in vivo animal studies, and early clinical series, are utilized to categorize the studies into four pathways: simulation (S), mechanical (E_mech), biological (E_bio), and validation (V). Based on the reviewed literature, we establish a general workflow for CT implants. We identify common gaps in the process, observe insufficient reporting of imaging and modeling details, note a lack of data on fatigue and remodeling, and recognize the limited size of clinical cohorts. Additionally, we provide practical recommendations for developing more standardized and scalable planning pipelines. Part 1 of this two-part review studied defect patterns, anatomical location, and fixation strategies for patient-specific lattice implants used in femoral and tibial segmental reconstruction, with emphasis on how defect morphology and subregional anatomy influence construct selection and mechanical behavior. It established a defect- and fixation-centered review that provides the clinical and anatomical context for the workflow and validation analysis presented in Part 2. Full article

Sediment transport in alluvial channels is strongly controlled by the grain-size distribution of bed and suspended materials. This, in turn, influences river morphology by modifying the cross-sectional area and course of the channel. Statistical parameters such as mean, standard deviation, skewness, and kurtosis provide quantitative indicators of the energy conditions that control sediment transport and deposition. This study examines the depositional characteristics of sediments in the Ganga River in Varanasi City, India, employing a novel combination of linear discriminant function (LDF) and sediment transport index (STI). The LDF results reveal distinct depositional environments: Y₁ and Y₂ values indicate deposition in a low-energy fluvial environment similar to beaches, Y₃ values suggest shallow marine settings, and Y₄ values point to mixed deltaic and turbid current depositional environments. Additionally, CM diagrams show rolling and suspension as the dominant sediment transport mechanisms. Shear stress analysis combined with STI highlights significant depositional features, with minimal erosion observed throughout the study area. The study provides an operational framework for mapping erosion-deposition patterns on alluvial point bars that are transferable to other sand-bed rivers worldwide where detailed hydraulic data are limited but detailed grain-size and DEM information are available. Full article

In dredging operations, the efficient transportation of dredged materials presents a significant and intricate challenge. This study focuses on the motion and resistance characteristics of coarse-grained dredged materials during pipeline conveyance. A specialized simulation experiment platform was developed to investigate the horizontal pipeline transport of coarse-grained materials. The experimental design encompassed varying particle diameters, material volume concentrations, and mixed average flow rates to analyze the motion and resistance characteristics of these materials in horizontal pipelines. Three distinct particle beds were identified based on different coarse particle motion states. This study statistically analyzed the impact of the particle diameter and material volume concentration on the transport efficiency of coarse particle populations. The key findings indicate that the mixed mean flow rate significantly influences the transportation efficiency of coarse particle groups, whereas the particle diameter and material volume concentration have a minimal effect. Specifically, coarse particles with a diameter of 0.9 mm demonstrated optimal water flow following, and higher mixed mean flow rates correlated with increased transportation efficiency of the coarse particle group. The transition speed of the coarse particle group flow type was notably affected by the material volume concentration and particle diameter, exhibiting a linear relationship. Therefore, when the particle size of the dredged material increases or the concentration increases, the average flow rate of the mixture is appropriately increased to ensure that the flow pattern of the dredged material in the pipeline remains in a non-homogeneous suspended flow pattern, thereby improving the efficiency and stability of the transportation system. By optimizing the conveying characteristics of coarse-grained materials, the pipeline conveying efficiency can be improved and the risk of pipeline wear and clogging can be reduced, thus lowering engineering costs and energy consumption and promoting technological innovation in related industries. In addition, this research can enhance engineering safety, reduce resource waste and environmental pollution, promote sustainable development, and provide important theoretical support and practical guidance for emerging fields such as deep-sea mining and environmental engineering. Full article

The particle size distribution (PSD) is a crucial parameter used to characterize the material composition of debris-flow deposits which determines their hydraulic permeability, affecting the mobility of debris flows and, hence, the sustainable development of debris-flow fans. Three types of graded bedding structures—normal, reverse, and mixed graded bedding structures—are characterized by discontinuous gradation within a specific deposit thickness. A series of permeability tests were conducted to study the effects of bed sediment composition, particularly coarse grain sizes and fine particle contents, on the permeability and migration of fine particles in discontinuous debris-flow deposits. An increase in fine particles within the discontinuously graded bed sediment led to a power-law decrease in the average permeability coefficient. With fine particle contents of 10% and 15% in the bed sediments, the final permeability coefficient consistently exceeded the initial value. However, this trend reversed when the fine particle contents were increased to 20%, 25%, and 30%. Lower fine particle contents indicated enhanced permeability efficiency due to more interconnected voids within the coarse particle skeleton. Conversely, an increase in fine particle content reduced the permeability efficiency, as fine particles tended to aggregate at the lower section of the seepage channel. An increase in coarse particle size decreased the formation of flow channels at the coarse–fine particle interface, causing fine particles to move slowly along adjacent or clustered slow flow channels formed by fine particles, resulting in decreased permeability efficiency. Three formulae are proposed to calculate the permeability coefficients of discontinuously graded bed sediments, which may aid in understanding the initiation mechanism of channel deposits. Based on experimental studies and field investigations, it is proposed that achieving sustainable development of debris-flow fans requires a practical approach that integrates three key components: spatial land-use planning, in situ monitoring of debris flows and the environment, and land-use adjustment and management. This comprehensive and integrated approach is essential for effectively managing and mitigating the risks associated with debris flows, ensuring sustainable development in vulnerable areas. Full article

Magnesium alloys, renowned for their lightweight yet high-strength characteristics, with exceptional mechanical properties, are highly coveted for numerous applications. The emergence of magnesium alloy additive manufacturing (Mg AM) has further propelled their popularity, offering advantages such as unparalleled precision, swift production rates, enhanced design freedom, and optimized material utilization. This technology holds immense potential in fabricating intricate geometries, complex internal structures, and performance-tailored microstructures, enabling groundbreaking applications. In this paper, we delve into the core processes and pivotal influencing factors of the current techniques employed in Mg AM, including selective laser melting (SLM), electron beam melting (EBM), wire arc additive manufacturing (WAAM), binder jetting (BJ), friction stir additive manufacturing (FSAM), and indirect additive manufacturing (I-AM). Laser powder bed fusion (LPBF) excels in precision but is limited by a low deposition rate and chamber size; WAAM offers cost-effectiveness, high efficiency, and scalability for large components; BJ enables precise material deposition for customized parts with environmental benefits; FSAM achieves fine grain sizes, low defect rates, and potential for precision products; and I-AM boasts a high build rate and industrial adaptability but is less studied recently. This paper attempts to explore the possibilities and challenges for future research in AM. Among them, two issues are how to mix different AM applications and how to use the integration of Internet technologies, machine learning, and process modeling with AM, which are innovative breakthroughs in AM. Full article

Green roofs (GRs) are a widely recognized green infrastructure (GI) strategy that helps reduce runoff volume and runoff pollution caused by the significant increase in impervious urban areas. However, the leaching of several nutrients from GR substrates is a growing concern. Biochar, a carbon-rich material, possesses advantageous properties that can help address such environmental challenges associated with GRs. Therefore, this paper aimed to undertake a field study to investigate the impacts of various biochar application methods, particle sizes, and amendment rates on the quality of runoff from GRs. Observational data of runoff quality were collected over a two-month period from five newly established 1 m × 1 m biochar-amended GR test beds and a control test bed without biochar, with all test beds subjected to artificially simulated rainfall. The results indicated that the addition of biochar did not result in a significant improvement in runoff pH, whereas the electrical conductivity (EC) was higher in runoff from GRs with biochar-amended substrates. When comparing the total nitrogen (TN) concentration in runoff from the non-biochar GR (ranging from 3.7 to 31 mg/L), all biochar test beds exhibited higher TN release (4.8 to 58 mg/L), except for the bed where medium biochar particles were applied at the bottom of the substrate (ranging from 2.2 to 21 mg/L). Additionally, all biochar-amended GRs exhibited higher TP concentrations in runoff (0.81 to 2.41 mg/L) when compared to the control GR (0.35 to 0.67 mg/L). Among the different biochar setups, GR with fine biochar particles applied to the surface of the substrate had the poorest performance in improving runoff water quality. Despite these mixed results, biochar holds significant potential to improve runoff quality by significantly increasing water retention, thereby reducing pollutant loads. Full article

Iron oxide assemblages are central to many pursuits, ranging from Mars exploration to environmental remediation. Oxides and oxyhydroxides of iron both carry the special properties of color and magnetism. In this paper, we use visible-light spectroscopy and rock magnetic data collected at varying temperatures (~77–973 K) to analyze the concentrations and identities of iron oxides found in natural hematite-dominated samples that were obtained from a scientific drill core of Late Triassic red beds in the American Southwest. Our results suggest that hematite colorization of Earth materials varies from red to blue/purple as crystal size increases. Second-derivative analysis of the collected visible-light spectra allows this variation to be measured through the characteristic wavelength band position. Magnetic coercivity data indicate “hardness” differences that also may suggest smaller grain sizes are associated with redder colors. Yellowish maghemite and goethite have overlapping characteristic wavelength band positions that make it challenging to distinguish their contributions to mixed assemblages from visible-light data alone. Remanent magnetizations acquired at ~77 K and room temperature suggest the presence of hematite and a low-coercivity phase that may be maghemite and/or oxidized magnetite. However, we interpret this phase as maghemite in order to explain the changes in iron oxide concentrations indicated by visible-light intensities near ~425 nm and because the thermal demagnetization data suggest that goethite is absent from the samples. Future research that increases the resolution of hematite, maghemite, and goethite detection in experimental and natural samples will provide opportunities to refine the study of past climates and constrain soil iron availability under future changes in global moisture and temperature. Multimethod datasets improve understanding of environmental conditions that cause iron oxides assemblages to shift in phase dominance, grain size, and crystallinity. Full article

This work studied the microstructure and mechanical properties of Ti-6Al-4V in situ alloyed with 3 wt% Cr by laser powder bed fusion (LPBF). Specimens with a relative density of 99.14 ± 0.11% were produced, showing keyhole and lack of fusion pores. Due to incomplete mixing of the components during melting, chemical inhomogeneities were observed in the solidified material. The addition of Cr promoted thermal supercooling during solidification and induced a reduction in the primary β grain size in the longitudinal direction and a weakening of the otherwise strong ⟨100⟩_β texture, both typical issues for Ti-6Al-4V produced by LPBF. The primary β at first transformed martensitically to α’, but by preheating the substrate plate to 500 °C and cyclically reheating the material by melting subsequent layers, in situ martensite decomposition was achieved, resulting in a fine lamellar α + β microstructure. In addition, the B19 phase was detected in the β matrix, presumably caused by Fe impurities in the Cr powder feedstock. Specimens exhibited a hardness of 402 ± 18 HV₁₀, and an excellent ultimate tensile strength of 1450 ± 22 MPa at an elongation at break of 4.5 ± 0.2%. Full article

Bedload transport in a river is a deeply analyzed problem, with many methodologies available in the literature. However, most of the existing methods were developed for reaches of rivers rather than for confluences and are suitable for a particular type of material, which makes them very inaccurate in cases where the sediments are comprised of a mix of different types of soil. This study considers the effect of two different bed sediment sizes, gravel and sand, in relation to bed load transport in a confluence. Five well-known and validated equations (namely Meyer-Peter and Müller, Parker + Engelund and Hansen, Ackers and White, and Yang) are applied to the case study of the Tagus–Alberche rivers confluence (in Talavera de la Reina, Spain), where main and tributary rivers transport different materials (sand and gravel). Field works in the area of the confluence were conducted, and a set of alluvial samples were collected and analyzed. The previously mentioned methods were employed to analyze the geomorphology in the confluence area and downstream of it under different flooding scenarios, concluding different trends in terms of deposition/erosion in the area under historic flooding scenarios. When the trends show erosion, all methods are very consistent in terms of numerical predictions. However, the results present high disparity in the estimated values when the predictions suggest deposition, with Parker + Engelund and Hansen yielding the highest volumes and Meyer-Peter and Müller the lowest (the latter being around 1% of the former). Yang and Ackers and White predict deposits in the same range in all cases (around 15% of Parker and Engelund Hansen). Yang’s formula was found to be suitable for the confluences of rivers with different materials, allowing for the estimation of sediment transport for different grain sizes. The effect of different flow regimes has been analyzed with the application of Yang’s formula to the Tagus-Alberche confluence. Full article

Diamond/SiC (Dia/SiC) composites possess excellent properties, such as high thermal conductivity and low thermal expansion coefficient. In addition, they are suitable as electronic packaging materials. This study mainly optimized the diamond particle size packing and liquid-phase silicon infiltration processes and investigated a method to prevent the adhesion of the product to molten silicon. Based on the Dinger–Funk particle stacking theory, a multiscale diamond ratio optimization model was established, and the volume ratio of diamond particles with sizes of D20, D50, and D90 was optimized as 1:3:6. The method of pressureless silicon infiltration and the formulas of the composites were investigated. The influences of bedding powder on phase composition and microstructure were studied using X-ray diffraction and scanning electron microscopy, and the optimal parameters were obtained. The porosity of the preform was controlled by regulating the feeding amount through constant volume molding. Dia/SiC-8 exhibited the highest density of 2.73 g/cm³ and the lowest porosity of 0.6%. To avoid adhesion between the sample and buried powder with the bedding silicon powder, a mixed powder of α-Si₃N₄ and silicon was used as the buried powder and the related mechanisms of action were discussed. Full article