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Search Results (462)

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22 pages, 3858 KiB  
Article
Thermodynamic Performance and Parametric Analysis of an Ice Slurry-Based Cold Energy Storage System
by Bingxin Zhao, Jie Li, Chenchong Zhou, Zicheng Huang and Nan Xie
Energies 2025, 18(15), 4158; https://doi.org/10.3390/en18154158 - 5 Aug 2025
Abstract
Subcooling-based ice slurry production faces challenges in terms of energy efficiency and operational stability, which limit its applications for large-scale cold energy storage. A thermodynamic model is established to investigate the effects of key control parameters, including evaporation temperature, condensation temperature, subcooling degree, [...] Read more.
Subcooling-based ice slurry production faces challenges in terms of energy efficiency and operational stability, which limit its applications for large-scale cold energy storage. A thermodynamic model is established to investigate the effects of key control parameters, including evaporation temperature, condensation temperature, subcooling degree, water flow rate, type of refrigerant, and adiabatic compression efficiency. The results show that using the refrigerant R161 achieves the highest energy efficiency, indicating that R161 is the optimal refrigerant in this research. When the evaporation and condensation temperatures are −10 °C and 30 °C, respectively, the system achieves the maximum comprehensive performance coefficient of 2.43. Moreover, under a flow velocity of 0.8 m/s and a temperature of 0.5 °C, the system achieves a peak ice production rate of 45.28 kg/h. A high water temperature and high flow velocity would significantly degrade the system’s ice production capacity. This research provides useful guidance for the design, optimization, and application of ice slurry-based cold energy storage systems. Full article
(This article belongs to the Section D: Energy Storage and Application)
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17 pages, 1546 KiB  
Article
Design and Optimization of Valve Lift Curves for Piston-Type Expander at Different Rotational Speeds
by Yongtao Sun, Qihui Yu, Zhenjie Han, Ripeng Qin and Xueqing Hao
Fluids 2025, 10(8), 204; https://doi.org/10.3390/fluids10080204 - 1 Aug 2025
Viewed by 107
Abstract
The piston-type expander (PTE), as the primary output component, significantly influences the performance of an energy storage system. This paper proposes a non-cam variable valve actuation system for the PTE, supported by a mathematical model. An enhanced S-curve trajectory planning method is used [...] Read more.
The piston-type expander (PTE), as the primary output component, significantly influences the performance of an energy storage system. This paper proposes a non-cam variable valve actuation system for the PTE, supported by a mathematical model. An enhanced S-curve trajectory planning method is used to design the valve lift curve. The study investigates the effects of various valve lift design parameters on output power and efficiency at different rotational speeds, employing orthogonal design and SPSS Statistics 27 (Statistical Product and Service Solutions) simulations. A grey comprehensive evaluation method is used to identify optimal valve lift parameters for each speed. The results show that valve lift parameters influence PTE performance to varying degrees, with intake duration having the greatest effect, followed by maximum valve lift, while intake end time has the least impact. The non-cam PTE outperforms the cam-based PTE. At 800 rpm, the optimal design yields 7.12 kW and 53.5% efficiency; at 900 rpm, 8.17 kW and 50.6%; at 1000 rpm, 9.2 kW and 46.8%; and at 1100 rpm, 12.09 kW and 41.2%. At these speeds, output power increases by 18.37%, 11.42%, 11.62%, and 9.82%, while energy efficiency improves by 15.01%, 15.05%, 14.24%, and 13.86%, respectively. Full article
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21 pages, 5215 KiB  
Article
Evaluation of Seismicity Induced by Geothermal Development Based on Artificial Neural Network
by Kun Shan, Yanhao Zheng, Wanqiang Cheng, Zhigang Shan and Yanjun Zhang
Energies 2025, 18(15), 4004; https://doi.org/10.3390/en18154004 - 28 Jul 2025
Viewed by 276
Abstract
The process of geothermal energy development may cause induced seismic activities, posing a potential threat to the sustainable utilization and safety of geothermal energy. To effectively evaluate the danger of induced seismic activities, this paper establishes an artificial neural network model and selects [...] Read more.
The process of geothermal energy development may cause induced seismic activities, posing a potential threat to the sustainable utilization and safety of geothermal energy. To effectively evaluate the danger of induced seismic activities, this paper establishes an artificial neural network model and selects nine influencing factors as the input parameters of the neurons. Based on the results of induced seismic activity under different parameter conditions, a sensitivity analysis is conducted for each parameter, and the influence degree of each parameter on the magnitude of induced seismic activity is ranked from largest to smallest as follows: in situ stress state, fault presence or absence, depth, degree of fracture aggregation, maximum in situ stress, distance to fault, injection volume, fracture dip angle, angle between fracture, and fault. Then, the weights of each parameter in the model are modified to improve the accuracy of the model. Finally, through data collection and the literature review, the Pohang EGS project in South Korea is analyzed, and the induced seismic activity influencing factors of the Pohang EGS site are analyzed and evaluated using the induced seismic activity evaluation model. The results show that the induced seismicity are all located below 3.7 km (drilling depth). As the depth increases, the seismicity magnitude also shows a gradually increasing trend. An increase in injection volume and a shortening of the distance from faults will also lead to an increase in the seismicity magnitude. When the injection volume approaches 10,000 cubic meters, the intensity of the seismic activity sharply increases, and the maximum magnitude reaches 5.34, which is consistent with the actual situation. This model can be used for the induced seismic evaluation of future EGS projects and provide a reference for project site selection and induced seismic risk warning. Full article
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26 pages, 9566 KiB  
Article
How Does Energy Harvesting from a Fluttering Foil Influence Its Nonlinear Dynamics?
by Dilip Thakur, Faisal Muhammad and Muhammad Saif Ullah Khalid
Energies 2025, 18(15), 3897; https://doi.org/10.3390/en18153897 - 22 Jul 2025
Viewed by 223
Abstract
This study investigates the nonlinear aeroelastic behavior and energy harvesting performance of a two-degrees-of-freedom NACA 0012 airfoil under varying reduced velocities and electrical load resistances. The system exhibits a range of dynamic responses, including periodic and chaotic states, governed by strong fluid–structure interactions. [...] Read more.
This study investigates the nonlinear aeroelastic behavior and energy harvesting performance of a two-degrees-of-freedom NACA 0012 airfoil under varying reduced velocities and electrical load resistances. The system exhibits a range of dynamic responses, including periodic and chaotic states, governed by strong fluid–structure interactions. Nonlinear oscillations first appear near the critical reduced velocity Ur*=6, with large-amplitude limit-cycle oscillations emerging around Ur*=8 in the absence of the electrical loading. As the load resistance increases, this transition shifts to higher Ur*, reflecting the damping effect of the electrical load. Fourier spectra reveal the presence of odd and even superharmonics in the lift coefficient, indicating nonlinearities induced by fluid–structure coupling, which diminishes at higher resistances. Phase portraits and Poincaré maps capture transitions across dynamical regimes, from periodic to chaotic behavior, particularly at a low resistance. The voltage output correlates with variations in the lift force, reaching its maximum at an intermediate resistance before declining due to a suppressing nonlinearity. Flow visualizations identify various vortex shedding patterns, including single (S), paired (P), triplet (T), multiple-pair (mP) and pair with single (P + S) that weaken at higher resistances and reduced velocities. The results demonstrate that nonlinearity plays a critical role in efficient voltage generation but remains effective only within specific parameter ranges. Full article
(This article belongs to the Section A3: Wind, Wave and Tidal Energy)
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27 pages, 16278 KiB  
Article
Optimization of the Archimedean Spiral Hydrokinetic Turbine Design Using Response Surface Methodology
by Juan Rengifo, Laura Velásquez, Edwin Chica and Ainhoa Rubio-Clemente
Sci 2025, 7(3), 100; https://doi.org/10.3390/sci7030100 - 21 Jul 2025
Viewed by 309
Abstract
This research investigates enhancing the performance of an Archimedes screw-type hydrokinetic turbine (ASHT). A 3D transient computational model employing the six degrees of freedom (6-DOF) methodology within the ANSYS Fluent software 2022 R1, was selected for this purpose. A central composite design (CCD) [...] Read more.
This research investigates enhancing the performance of an Archimedes screw-type hydrokinetic turbine (ASHT). A 3D transient computational model employing the six degrees of freedom (6-DOF) methodology within the ANSYS Fluent software 2022 R1, was selected for this purpose. A central composite design (CCD) methodology was applied within the response surface methodology (RSM) to enhance the turbine’s power coefficient (Cp). Key independent factors, including blade length (L), blade inclination angle (γ), and external diameter (De), were systematically varied to determine their optimal values. The optimization process yielded a maximum Cp of 0.337 for L, γ, and De values of 168.921 mm, 51.341°, and 245.645 mm, respectively. Experimental validation was conducted in a hydraulic channel, yielding results that demonstrated a strong correlation with the numerical predictions. This research underscores the importance of geometric design optimization in improving the energy capture efficiency of the ASHT, contributing to its potential viability as a competitive renewable energy solution in the pre-commercial phase of development. Full article
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18 pages, 8032 KiB  
Article
Liquefaction Response and Reinforcement Effect of Saturated Soil Treated by Dynamic Compaction Based on Hydro-Mechanically Coupled Explicit Analysis
by Sihan Ma, Guo Zhao, Xiaoyuan Yang, Run Xu, Zhiqiang Weng, Jiawei Liu, Chong Zhou and Chao Li
Buildings 2025, 15(14), 2527; https://doi.org/10.3390/buildings15142527 - 18 Jul 2025
Viewed by 260
Abstract
In order to accurately analyze the liquefaction and the reinforcement effect of saturated silty and sandy soils treated by dynamic compaction, a hydro-mechanically coupled explicit analysis method was proposed. The method, in combination with the cap model, was carried out using the Abaqus [...] Read more.
In order to accurately analyze the liquefaction and the reinforcement effect of saturated silty and sandy soils treated by dynamic compaction, a hydro-mechanically coupled explicit analysis method was proposed. The method, in combination with the cap model, was carried out using the Abaqus finite element software. Then, parametric analysis was carried out by means of the development and dissipation of excess pore water pressure, effective soil stress and the relative reinforcement degree. And the effects of the drop energy, tamper radius and soil permeability on the liquefaction zone and soil improvement of saturated soil were examined. The results demonstrated that the liquefaction zone and the effective reinforcement were determined by the drop energy rather than the permeability or tamper radius. A 2.5-times increase in drop energy can increase the maximum liquefaction depth by 1.1 m (4.6 m to 5.7 m) and the effective reinforcement depth (Ir ≥ 0.08) by 0.6 m (1.2 m to 1.8 m). It is recommended that the reinforcement effect should be improved by a lower drop energy with a low drop height and a heavy tamper in actual projects. It should also be noted that a smaller tamper radius was conducive to local soil improvement but also generated higher localized excess pore water pressures. Soil permeability critically controls liquefaction potential and excess pore water pressure dissipation. Low permeability soils experienced significant liquefaction depths and slower consolidation, whereas high permeability gravels (k = 10−2 m/s) showed minimal liquefaction and great improvements in depth. To diminish the effect of the underground water, the gravel cushions should be used to drain pore water out before dynamic compaction. Full article
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16 pages, 5452 KiB  
Article
Study on the Solidification and Heat Release Characteristics of Flexible Heat Storage Filled with PCM Composite
by Tielei Yan, Gang Wang, Dong Zhang, Changxin Qi, Shuangshuang Zhang, Peiqing Li and Gaosheng Wei
Energies 2025, 18(14), 3760; https://doi.org/10.3390/en18143760 - 16 Jul 2025
Viewed by 308
Abstract
Phase change materials (PCMs) have significant potential for utilization due to their high energy storage density and excellent safety in energy storage. In this research, a flexible heat storage device using the stable supercooling of sodium acetate trihydrate composite is developed, enabling on-demand [...] Read more.
Phase change materials (PCMs) have significant potential for utilization due to their high energy storage density and excellent safety in energy storage. In this research, a flexible heat storage device using the stable supercooling of sodium acetate trihydrate composite is developed, enabling on-demand heat release through controlled solidification initiation. The solidification and heat release characteristics are investigated in experiments. The results indicate that the heat release characteristics of this heat storage device are closely linked to the crystallization process of the PCM. During the experiment, based on whether external intervention was needed for the solidification process, the PCM manifested two separate solidification modes—specifically, spontaneous self-solidification and triggered-solidification. Meanwhile, the heat release rates, temperature changes, and crystal morphologies were observed in the two solidification modes. Compared with spontaneous self-solidification, triggered-solidification achieved a higher peak surface temperature (53.6 °C vs. 46.2 °C) and reached 45 °C significantly faster (5 min vs. 15 min). Spontaneous self-solidification exhibited slower, uncontrollable heat release with dendritic crystals, while triggered-solidification provided rapid, controllable heat release with dense filamentous crystals. This controllable switching between modes offers key practical advantages, allowing the device to provide either rapid, high-power heat discharge or slower, sustained release as required by the application. According to the crystal solidification theory, the different supercooling degrees are the main reasons for the two solidification modes exhibiting different solidification characteristics. During solidification, the growth rate of SAT crystals exhibits substantial disparities across diverse experiments. In this research, the maximum axial growth rate is 2564 μm/s, and the maximum radial growth rate is 167 μm/s. Full article
(This article belongs to the Special Issue Heat Transfer Principles and Applications)
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18 pages, 1184 KiB  
Article
A Confidential Transmission Method for High-Speed Power Line Carrier Communications Based on Generalized Two-Dimensional Polynomial Chaotic Mapping
by Zihan Nie, Zhitao Guo and Jinli Yuan
Appl. Sci. 2025, 15(14), 7813; https://doi.org/10.3390/app15147813 - 11 Jul 2025
Viewed by 303
Abstract
The deep integration of smart grid and Internet of Things technologies has made high-speed power line carrier communication a key communication technology in energy management, industrial monitoring, and smart home applications, owing to its advantages of requiring no additional wiring and offering wide [...] Read more.
The deep integration of smart grid and Internet of Things technologies has made high-speed power line carrier communication a key communication technology in energy management, industrial monitoring, and smart home applications, owing to its advantages of requiring no additional wiring and offering wide coverage. However, the inherent characteristics of power line channels, such as strong noise, multipath fading, and time-varying properties, pose challenges to traditional encryption algorithms, including low key distribution efficiency and weak anti-interference capabilities. These issues become particularly pronounced in high-speed transmission scenarios, where the conflict between data security and communication reliability is more acute. To address this problem, a secure transmission method for high-speed power line carrier communication based on generalized two-dimensional polynomial chaotic mapping is proposed. A high-speed power line carrier communication network is established using a power line carrier routing algorithm based on the minimal connected dominating set. The autoregressive moving average model is employed to determine the degree of transmission fluctuation deviation in the high-speed power line carrier communication network. Leveraging the complex dynamic behavior and anti-decoding capability of generalized two-dimensional polynomial chaotic mapping, combined with the deviation, the communication key is generated. This process yields encrypted high-speed power line carrier communication ciphertext that can resist power line noise interference and signal attenuation, thereby enhancing communication confidentiality and stability. By applying reference modulation differential chaotic shift keying and integrating the ciphertext of high-speed power line carrier communication, a secure transmission scheme is designed to achieve secure transmission in high-speed power line carrier communication. The experimental results demonstrate that this method can effectively establish a high-speed power line carrier communication network and encrypt information. The maximum error rate obtained by this method is 0.051, and the minimum error rate is 0.010, confirming its ability to ensure secure transmission in high-speed power line carrier communication while improving communication confidentiality. Full article
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21 pages, 9386 KiB  
Article
Structural Characterization and Segmental Dynamics Evaluation in Eco-Friendly Polymer Electrospun Fibers Based on Poly(3-hydroxybutyrate)/Polyvinylpyrrolidone Blends to Evaluate Their Sustainability
by Svetlana G. Karpova, Anatoly A. Olkhov, Ivetta A. Varyan, Ekaterina P. Dodina, Yulia K. Lukanina, Natalia G. Shilkina, Anatoly A. Popov, Alexandre A. Vetcher, Anna G. Filatova and Alexey L. Iordanskii
J. Compos. Sci. 2025, 9(7), 355; https://doi.org/10.3390/jcs9070355 - 8 Jul 2025
Viewed by 362
Abstract
Ultrafine fibers from poly(3-hydroxybutyrate) (PHB) and polyvinylpyrrolidone (PVP) and their blends with different component ratios in the range of 0/100 to 100/0 wt.% were obtained, and their structure and dynamic properties were studied. The polymers were obtained via electrospinning in solution mode. The [...] Read more.
Ultrafine fibers from poly(3-hydroxybutyrate) (PHB) and polyvinylpyrrolidone (PVP) and their blends with different component ratios in the range of 0/100 to 100/0 wt.% were obtained, and their structure and dynamic properties were studied. The polymers were obtained via electrospinning in solution mode. The structure, morphology, and segmental dynamic behavior of the fibers were determined using optical microscopy, SEM, EPR, DSC, and IR spectroscopy. The low-temperature maximum on the DSC endotherms provided information on the state of the PVP hydrogen bond network, which made it possible to determine the enthalpies of thermal destruction of these bonds. The PHB/PVP fiber blend ratio significantly affected the structural and dynamic parameters of the system. Thus, at low concentrations of PVP (up to 9%) in the structure of ultra-fine fibers, the distribution of this polymer occurs in the form of tiny particles, which are crystallization centers, which causes a significant increase in the degree of crystallinity (χ) activation energy (Eact) and slowing down of molecular dynamics (τ). At higher concentrations of PVP, loose interphase layers were formed in the system, which caused a decrease in these parameters. The strongest changes in the concentration of hydrogen bonds occurred when PVP was added to the composition from 17 to 50%, which was due to the formation of intermolecular hydrogen bonds both in PVP and during the interaction of PVP and PHB. The diffusion coefficient of water vapor in the studied systems (D) decreased as the concentration of glassy PVP in the composition increased. The concentration of the radical decreased with an increase in the proportion of PVP, which can be explained by the glassy state of this polymer at room temperature. A characteristic point of the 50/50% mixture component ratio was found in the region where an inversion transition of PHB from a dispersion material to a dispersed medium was assumed. The conducted studies made it possible for the first time to conduct a comprehensive analysis of the effect of the component ratio on the structural and dynamic characteristics of the PHB/PVP fibrous material at the molecular scale. Full article
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21 pages, 3340 KiB  
Article
Influence of Operating Conditions on the Energy Consumption of CO2 Supermarket Refrigeration Systems
by Ionuț Dumitriu and Ion V. Ion
Processes 2025, 13(7), 2138; https://doi.org/10.3390/pr13072138 - 4 Jul 2025
Viewed by 406
Abstract
Integrating ejectors into CO2 transcritical refrigeration systems to reduce energy consumption has been performed successfully throughout the industry in recent years. The objective of the present work is to investigate the effect of indoor and outdoor operating conditions on the energy efficiency [...] Read more.
Integrating ejectors into CO2 transcritical refrigeration systems to reduce energy consumption has been performed successfully throughout the industry in recent years. The objective of the present work is to investigate the effect of indoor and outdoor operating conditions on the energy efficiency of ejector expansion supermarket refrigeration plants. The analysis uses the measured energy consumptions and loads for two supermarket refrigeration plants operating in two cities in the Republic of Moldova (Chisinau and Balti). A model for the prediction of the plant’s annual energy consumption and the loads of the refrigeration and freezing compressors is developed using experimental results. Although there are theoretical and experimental analyses of the investigated systems in the specialized literature, no studies were found in the specialized literature regarding energy consumption increase due to pressure losses through the pipe route in transcritical CO2 refrigeration installations with an ejector for supermarkets. The results indicate that refrigeration compressors have a greater increase in energy consumption than freezing compressors with increases in the outdoor temperature. The study shows that the additional drop in evaporating pressure at the compressor rack due to incorrect sizing of the pipe route leads to higher energy consumption compared to what the same plant would consume if the pipe route were correctly sized and executed. For every one-degree increase in temperature loss due to additional pressure drop through the pipeline, the entire plant consumes around 1.5% more energy. Knowledge of these performance data of real systems provides designers and manufacturers with clues to understand the importance of the correct design of the pipe route to obtain maximum energy efficiency. Full article
(This article belongs to the Topic Sustainable Energy Technology, 2nd Edition)
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24 pages, 3754 KiB  
Article
Route Optimization of Multimodal Transport Considering Regional Differences under Carbon Tax Policy
by Liqing Gao and Miaomiao Zhan
Sustainability 2025, 17(13), 5743; https://doi.org/10.3390/su17135743 - 22 Jun 2025
Viewed by 494
Abstract
Environmental sustainability is receiving growing global attention, making the development of low-carbon and green transportation increasingly important. Low-carbon policies offer significant advantages in incentivizing energy conservation and reducing emissions in the transportation sector; however, it is vital to consider the impacts of regional [...] Read more.
Environmental sustainability is receiving growing global attention, making the development of low-carbon and green transportation increasingly important. Low-carbon policies offer significant advantages in incentivizing energy conservation and reducing emissions in the transportation sector; however, it is vital to consider the impacts of regional differences on the implementation effect of low-carbon policies. This paper explores multimodal transportation route optimization under a carbon tax policy. First, a bi-objective route optimization model is constructed, with the goal of minimizing total transportation cost and time, while accounting for uncertain demand, fixed departure schedules, and regional differences. Trapezoidal fuzzy numbers are used to represent uncertain demand, and a fuzzy adaptive non-dominated sorting genetic algorithm is designed to solve the bi-objective optimization model. The algorithm is then tested on differently sized networks and on real-world transportation networks in eastern and western China to validate its effectiveness and to assess the impacts of regional differences. The experimental results show the following. (1) When considering transportation tasks at different network scales, the proposed fuzzy adaptive non-dominated sorting genetic algorithm outperforms the NSGA-II algorithm, achieving minimum differences in percentages of cost and time of 9.25% and 7.72%, respectively. (2) For transportation tasks assessed using real-world networks in eastern and western China, an increase in the carbon tax rate significantly affects carbon emissions, costs, and time. The degree of carbon emission reduction varies depending on the development of the regional transportation network. In the more developed eastern region, carbon emissions are reduced by up to 44.17% as the carbon tax rate increases. In the less developed western region, the maximum reduction in carbon emissions is 14.37%. The carbon tax policy has a more limited impact in the western region compared to the eastern one. Therefore, formulating differentiated carbon tax policies based on local conditions is an effective way to maximize the economic and environmental benefits of multimodal transportation. Full article
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22 pages, 3161 KiB  
Article
Experimental Investigation into the Energy Performance of a Biomass Recuperative Organic Rankine Cycle (ORC) for Micro-Scale Applications in Design and Off-Design Conditions
by Luigi Falbo, Angelo Algieri, Pietropaolo Morrone and Diego Perrone
Energies 2025, 18(12), 3201; https://doi.org/10.3390/en18123201 - 18 Jun 2025
Cited by 1 | Viewed by 310
Abstract
Increasing energy efficiency and promoting the use of sustainable energy sources are crucial for addressing global energy challenges. Organic Rankine cycle (ORC) technology offers a promising route for efficient decentralised power generation. This study examines the energy performance of a biomass-fired recuperative ORC [...] Read more.
Increasing energy efficiency and promoting the use of sustainable energy sources are crucial for addressing global energy challenges. Organic Rankine cycle (ORC) technology offers a promising route for efficient decentralised power generation. This study examines the energy performance of a biomass-fired recuperative ORC for micro-scale applications. The investigation proposes an extensive experimental analysis to characterise the ORC behaviour under design and off-design conditions due to the limited data in the literature. The work examines the impact of different operating parameters (e.g., pump speed, hot source temperature, superheating degree, expander inlet pressure) to provide suitable insights for the efficient design and operation of recuperative micro-generation units fuelled by biomass. The experimental analysis highlights that the micro-scale ORC properly operates under a wide range of operating conditions. Electric power ranges between 0.37 kW and 2.30 kW, and the maximum net electric efficiency reaches 8.55%. The selection of the proper operating conditions guarantees efficiency higher than 7% for power larger than 800 W, demonstrating that biomass-fired recuperative ORC systems represent a valuable option for low-carbon micro-scale generation, with good performance in design and off-design conditions. For this purpose, the pump speed and the superheating degree at the expander inlet are essential parameters to maximise the performance of the investigated recuperative ORC. Full article
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20 pages, 9522 KiB  
Article
Preparation of Low-Salt-Rejection Membrane by Sodium Hypochlorite Chlorination for Concentration of Low-Concentration Magnesium Chloride Solution
by Zhengyang Wu, Zongyu Feng, Longsheng Zhao, Zheng Li, Meng Wang and Chao Xia
Materials 2025, 18(12), 2824; https://doi.org/10.3390/ma18122824 - 16 Jun 2025
Viewed by 370
Abstract
The precipitation process of rare earth from a rare earth chloride solution using magnesium bicarbonate yields a dilute magnesium chloride (MgCl2) solution. The dilute MgCl2 solution can only be concentrated to a maximum concentration of about 70 g/L by conventional [...] Read more.
The precipitation process of rare earth from a rare earth chloride solution using magnesium bicarbonate yields a dilute magnesium chloride (MgCl2) solution. The dilute MgCl2 solution can only be concentrated to a maximum concentration of about 70 g/L by conventional reverse osmosis (RO), which is insufficient for recycling. Low-salt-rejection reverse osmosis (LSRRO) allows for a higher concentration of brine while operating at moderate pressures. However, research on LSRRO for the concentration of MgCl2 solution is still at an initial stage. In this study, polyamide RO membranes were treated with sodium hypochlorite (NaClO) to prepare low-salt-rejection membranes. The effects of NaClO concentration, pH, and chlorination time on the membrane properties were investigated. Under alkaline chlorination conditions, the membrane’s salt rejection decreased, and water flux increased with increasing NaClO concentration and chlorination time. This can be explained by the hydrolysis of polyamide in the alkaline solution to form carboxylic acids and amines, resulting in a decrease in the crosslinking degree of polyamide. The low-salt-rejection membrane was prepared by exposing it to a NaClO solution at a concentration of 15 g/L and a pH of 11 for 3 h, and the salt rejection of MgCl2 was 50.7%. The MgCl2 solution with a concentration of 20 g/L was concentrated using multi-stage LSRRO at the pressure of 5 MPa. The concentration of the concentrated brine reached 120 g/L, which is 87% higher than the theoretical maximum concentration of 64 g/L for conventional RO at the pressure of 5 MPa. The specific energy consumption (SEC) was 4.17 kWh/m3, which decreased by about 80% compared to that of mechanical vapor recompression (MVR). This provides an alternative route for the efficient concentration of a diluted MgCl2 solution with lower energy consumption. Full article
(This article belongs to the Section Materials Chemistry)
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18 pages, 2368 KiB  
Article
The Role of Light-Harvesting Complex II Organization in the Efficiency of Light-Dependent Reactions in the Photosynthetic Apparatus of Pisum sativum L.
by Georgi D. Rashkov, Martin A. Stefanov, Amarendra N. Misra and Emilia L. Apostolova
Plants 2025, 14(12), 1846; https://doi.org/10.3390/plants14121846 - 16 Jun 2025
Viewed by 483
Abstract
In this study, the functions of the photosynthetic machinery were evaluated using chlorophyll a fluorescence technique (PAM and JIP test) in pea plants (Pisum sativum L. cv Borec) and its LHC II oligomerization variants (mutants Costata 2/133 and Coeruleovireus 2 [...] Read more.
In this study, the functions of the photosynthetic machinery were evaluated using chlorophyll a fluorescence technique (PAM and JIP test) in pea plants (Pisum sativum L. cv Borec) and its LHC II oligomerization variants (mutants Costata 2/133 and Coeruleovireus 2/16). The oligomeric forms of LHCII increased in the following order: Costata 2/133 < Borec wt < Coeruleovireus 2/16. Data revealed that the mutant with higher LHCII oligomerization (Coeruleovireus 2/16) at low light intensity (LL, 150 µmol photons/m2·s) exhibited the following: (i) decreased energy dissipation and increased electron transport efficiency; (ii) higher reaction center density; (iii) increased amounts of the open reaction centers (qp) and their excitation efficiency (Φexc); and (iv) influenced the reoxidation of QA, alleviating its interaction with plastoquinone. These effects enhanced photosynthetic performance related to PSII photochemistry (PIABS) and overall photosynthetic efficiency (PItotal). High light intensity (HL, 500 µmol photons/m2·s) caused a reduction in open reaction centers (qp), excitation efficiency (Φexc), photochemical energy conversion of PSII (ΦPSII), maximum efficiency of PSII photochemistry in light (Fv′/Fm′), and linear electron transport via PSII, with more pronounced effects observed in membranes with a lower degree of LHCII oligomerization (Costata 2/133). This study provides novel experimental evidence for the pivotal role of the LHCII structural organization in determining the efficiency of light-dependent reactions of photosynthesis. Full article
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21 pages, 4282 KiB  
Article
Stability Assessment of Hazardous Rock Masses and Rockfall Trajectory Prediction Using LiDAR Point Clouds
by Rao Zhu, Yonghua Xia, Shucai Zhang and Yingke Wang
Appl. Sci. 2025, 15(12), 6709; https://doi.org/10.3390/app15126709 - 15 Jun 2025
Viewed by 440
Abstract
This study aims to mitigate slope-collapse hazards that threaten life and property at the Lujiawan resettlement site in Wanbi Town, Dayao County, Yunnan Province, within the Guanyinyan hydropower reservoir. It integrates centimeter-level point-cloud data collected by a DJI Matrice 350 RTK equipped with [...] Read more.
This study aims to mitigate slope-collapse hazards that threaten life and property at the Lujiawan resettlement site in Wanbi Town, Dayao County, Yunnan Province, within the Guanyinyan hydropower reservoir. It integrates centimeter-level point-cloud data collected by a DJI Matrice 350 RTK equipped with a Zenmuse L2 airborne LiDAR (Light Detection And Ranging) sensor with detailed structural-joint survey data. First, qualitative structural interpretation is conducted with stereographic projection. Next, safety factors are quantified using the limit-equilibrium method, establishing a dual qualitative–quantitative diagnostic framework. This framework delineates six hazardous rock zones (WY1–WY6), dominated by toppling and free-fall failure modes, and evaluates their stability under combined rainfall infiltration, seismic loading, and ambient conditions. Subsequently, six-degree-of-freedom Monte Carlo simulations incorporating realistic three-dimensional terrain and block geometry are performed in RAMMS::ROCKFALL (Rapid Mass Movements Simulation—Rockfall). The resulting spatial patterns of rockfall velocity, kinetic energy, and rebound height elucidate their evolution coupled with slope height, surface morphology, and block shape. Results show peak velocities ranging from 20 to 42 m s−1 and maximum kinetic energies between 0.16 and 1.4 MJ. Most rockfall trajectories terminate within 0–80 m of the cliff base. All six identified hazardous rock masses pose varying levels of threat to residential structures at the slope foot, highlighting substantial spatial variability in hazard distribution. Drawing on the preceding diagnostic results and dynamic simulations, we recommend a three-tier “zonal defense with in situ energy dissipation” scheme: (i) install 500–2000 kJ flexible barriers along the crest and upper slope to rapidly attenuate rockfall energy; (ii) place guiding or deflection structures at mid-slope to steer blocks and dissipate momentum; and (iii) deploy high-capacity flexible nets combined with a catchment basin at the slope foot to intercept residual blocks. This staged arrangement maximizes energy attenuation and overall risk reduction. This study shows that integrating high-resolution 3D point clouds with rigid-body contact dynamics overcomes the spatial discontinuities of conventional surveys. The approach substantially improves the accuracy and efficiency of hazardous rock stability assessments and rockfall trajectory predictions, offering a quantifiable, reproducible mitigation framework for long slopes, large rock volumes, and densely fractured cliff faces. Full article
(This article belongs to the Special Issue Emerging Trends in Rock Mechanics and Rock Engineering)
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