Search Results (89)

Samples of H13 tool steel were produced using the LENS^® laser additive manufacturing technique. Three variants of samples were produced such that during and 2 h after deposition, both the substrate and sample temperatures were maintained at 80, 180, and 350 °C. After the samples were produced, the effect of the substrate temperature on their metallurgical quality, microstructure, and mechanical properties was determined. No segregation of alloying elements was observed. The test results indicate that, depending on the temperature used, the structure of the H13 alloy is martensitic or martensitic-bainitic with a slight residual austenite content of up to 2.1%. Owing to structural changes, the obtained alloy is characterized by lower impact strength compared with conventionally produced alloys and high brittleness, particularly when using an annealing temperature of 350 °C. Isothermal annealing above the martensite start temperature results in extreme brittleness due to a partial structural transformation of martensite into bainite and probable carbide precipitation processes at the nanoscale. Full article

This study investigates the transformation behavior of advanced high-strength dual-phase (DP) steel subjected to thermal cycling, aiming to support improved automotive steel-processing technologies in terms of properties, cost, and speed. The heat treatment applied consisted of 1–7 cycles through the intercritical region at a conventional heating rate. Results were compared with the conventional dual-phase steel treatment currently used in industry, as well as with variants that combine thermal cycling and fast heating, the latter offering potential for carbon-free methods. The goal is to gain a deeper understanding of the transformations that occur in the material and the potential benefits that may result. Characterization was performed using dilatometry, electron microscopy techniques, and Vickers hardness testing. Findings show the initial ferrite–martensite microstructure remained largely unchanged after cycling, though preferential austenite nucleation within ferrite and Mn segregation remained. The resulting microstructure consisted of ferrite, bainite, martensite, and retained austenite. Crystallographic orientation analysis revealed texture memory effects, with preferred orientations persisting after multiple cycles. Grain refinement occurred mainly in transformed zones, while ferrite showed slight growth with more cycles, correlating with a reduced bainite/martensite fraction. Hardness increased significantly after the first cycle but declined with subsequent cycles, reflecting a reduction in bainite/martensite fraction. It is found that when up to two cycles are used, the process can be beneficial for the steel properties; otherwise, other alternatives, such as fast heating, can be applied to optimize production. Full article

Structural applications that use High-Strength Low-Alloy (HSLA) steels require detailed microstructural analysis to manufacture welded components that combine strength and weldability. The balance of these properties depends on both the chemical composition and the welding parameters. Moreover, in multi-pass welds, thermal cycling results in a complex Heat-Affected Zone (HAZ), characterized by sub-regions with a multitude of microstructural constituents, including brittle phases. This study investigates the influence of Vanadium addition on the microstructure and performance of the HAZ. Multi-pass welded joints were manufactured on 15 mm thick S355 steels with different Vanadium contents using a robotic GMAW process. A steel variant containing both Vanadium and Niobium was also considered, and the results were compared to those of standard S355 steel. Moving through the different sub-regions of the welded joints, the results show a heterogeneous microstructure characterized by ferrite, bainite and martensite/austenite (M/A) islands. The presence of Vanadium reduces carbon solubility during the phase transformations involved in the welding process. This results in the formation of very fine (average size 11 ± 4 nm) and dispersed precipitates, as well as a lower percentage of the brittle M/A phase, in the variant with a high Vanadium content (0.1 wt.%), compared to the standard S355 steel. Despite the presence of the brittle phase, the micro-alloyed variants exhibit strengthening without loss of ductility. The combined presence of both hard and soft phases in the HAZ provides stress-damping behavior, which, together with the very fine precipitates, promises improved resistance to crack propagation under different loading conditions. Full article

In this study, the effect of aging heat treatment on the superelastic properties and microstructure of [001]-oriented Fe₄₁Ni₂₈Co₁₇Al_11.5Ti_1.25Nb_1.25 (at.%) single crystals was investigated using the cyclic superelastic strain test and a transmission electron microscope (TEM). The TEM results reveal that the average precipitate size is around 3–5 nm in the 600 °C/24 h samples, 6–8 nm in the 600 °C/48 h samples, and 10–12 nm in the 600 °C/72 h samples. The results indicate that precipitate size increases as aging time increases from 24 to 72 h. EDS analysis results show decreased Fe and increased Ni when the analyzed line crosses the precipitate region. The diffraction pattern results show that the precipitate has an L1₂ crystal structure. The thermo-magnetization curves of single crystals under the three aging conditions (600 °C/24 h, 600 °C/48 h, and 600 °C/72 h) show that the values of the transformation temperatures increased from 24 to 72 h. Magnetization was saturated at 140 emu/g under the magnetic field of 7 Tesla. When increasing the magnetic field from 0.05 to 7 Tesla, the transformation temperatures rose. The results indicate that magnetic fields can activate martensitic transformation. From the results of the superelasticity test at room temperature, [001]-oriented FeNiCoAlTiNb single crystals aged at 600 °C for 24, 48, and 72 h presented recoverable strains of 3%, 5.1%, and 2.6%, respectively. Digital image correlation (DIC) results of the aged samples show that two martensite variants were activated during the superelasticity test. The two variants form corresponding variant pairs (CVPs) and improve the recoverable strain of superelasticity. Although maximum recoverable strain was obtained for the 600 °C/48 h samples, the samples show poor cyclic stability at room temperature after applying the 6% strain. According to the DIC results, the retained martensite, which is pinned by dislocations, was observed after the test. The irrecoverable strain was attributed to the residual martensite. For the 600 °C/72 h samples, the large size of the precipitates poses an obstacle to dislocation transformation and formation. The dislocations increase the stress hysteresis width and stabilize the martensite, causing poor recoverability. Full article

S1100QL and S1300QL steels are classified as fine-grained steels with a low-carbon martensitic structure. Tandem welding is a method of creating a joint by melting two electrode wires in a one-behind-the-other configuration. This article presents the effects of creating dissimilar joints, elements of varying thicknesses made from S1100QL and S1300QL steels. The analysis focused on temperature changes in the heat-affected zone (HAZ) during welding, as well as the macro and microstructure, and the properties of the joints created at welding speeds of 80, 90, and 100 cm/min. The shortest cooling time (t8/5) in the HAZ for S1300QL steel was 9.4 s, while the longest was 12.4 s. Thermal cycle simulations were performed for the analyzed materials, with a cooling time of 5 s. The test results demonstrated that TWIN welding was stable, and an optimum welding speed is 80 cm/min. The HAZ microstructure for the highest cooling speed (t8/5 = 5 s) of S1100QL steel contains, in addition to martensite, lower bainite, while S1300QL steel consists of martensite. Tempered martensite was also detected at slower cooling rates. For all speed variants, the impact energy is above 27 J at a test temperature of −40 °C. In turn, hardness tests showed that the base material for both steels has the highest hardness. However, the lowest hardness was found for the weld. Full article

This study elucidates the influence of rapid heating (300 °C/s) on martensitic transformation pathways, crystallographic variant selection, and the resulting mechanical performance in a medium-carbon steel. Compared with conventional heating, rapid heating markedly refines the prior austenite grain (PAG) and martensitic substructures, reducing the mean PAG size from 16.08 μm to 5.06 μm and the martensitic block size from 4.24 μm to 2.41 μm. The accelerated austenitizing and quenching promote a higher density of high-angle grain boundaries (HAGBs) and favor variant selection dominated by the closely packed (CP) group. Σ3 twin boundaries are also found to assist variant nucleation and contribute to microstructural complexity. Despite a marginal decrease in tensile strength, rapid-heated steels exhibit significantly enhanced ductility and a 28.3% increase in the product of strength and elongation (PSE) compared to their conventionally treated counterparts. These findings demonstrate that rapid heating not only enables effective refinement of martensitic substructures but also offers a powerful means of controlling variant evolution, thereby achieving a superior strength–ductility synergy in martensitic steels. Full article

This work investigated changes in the microstructure and local mechanical properties after the application of selected heat treatments to EN-GJL-300 grey cast iron. The main goal was to optimize heat treatment to achieve increased mechanical properties and subsequently wear resistance. The heat and heat–mechanical treatment were investigated by using a dilatometer as a physical simulator of treatment on real samples. Continuous cooling with three different rates and two other non-continuous treatments (austempering and ausforming) were used to treat the experimental samples. The research was focused on modification of the matrix microstructure, initially pearlitic. No change in the shape or morphology of the graphitic lamellae was required to preserve the damping properties. The results showed that, in terms of the specified conditions, heat treatment with continuous cooling at a rate of 10 °C s⁻¹ appeared to be optimal. This variant showed the presence of bainite and martensite in the microstructure with high hardness measured by nanoindentation as well as the optimal value of general Brinell hardness. Full article

Fusion welding easily causes microstructural coarsening and tempering softening in the heat-affected zone (HAZ) of high-strength pipeline steel joints, which considerably deteriorates the strength and toughness. Here, X80 pipeline steel was subjected to friction stir welding (FSW), and external cooling was used to tailor the microstructure to optimize the strength–ductility combination of the nugget zone (NZ). Coarse granular bainite (GB) appeared at air cooling, whereas a fine ferrite/martensite microstructure was achieved at solid CO₂ cooling. The highest ratio of high-angle boundaries was obtained at solid CO₂ cooling because the variants were evenly distributed within the four close-packed (CP) groups. The low yield strength (YS) of 595 MPa was obtained in the NZ under air cooling, whereas a high YS of 755 MPa was achieved in the NZ under solid CO₂ cooling due to dislocation strengthening and fine-grain strengthening. Furthermore, an ultra-high tensile strength of 910 MPa and utilizable elongation of 15% were obtained in the NZ under solid CO₂ cooling, which was attributed to the fine effective grains and ferrite/martensite microstructure facilitating a ductile fracture. Full article

Acoustic emission, AE, belonging to a rubber-like deformation in a martensitic state after the stabilization aging of the stress-induced martensite (SIM aging) of Ni₅₁Fe₁₈Ga₂₇Co₄ single crystals in compression, were investigated. AE activity in the plateau regions of the stress–strain loop is due to a massive reorientation from the variants produced by SIM aging to the variants preferred by the compressive stress (perpendicular to the stress used in SIM aging) and vice versa. For unloading, the large AE activity just at the knee point of the stress–stain curve is attributed to the difficulty of the re-nucleation of the SIM aging-stabilized martensite variant. The amplitude, peak energy, and area of signals can be described by power-like distributions and the characteristic exponents are in good agreement with data obtained in other alloys. Power law cross-correlations between the energy, E, and amplitude, A, as well as between the area, S, and the amplitude, A, were also analyzed. It was found that the exponents are given by $3-\phi$ as well as $2-\phi$, respectively, with $\phi \cong 0.7.$ Normalized universal temporal shapes of avalanches (i.e., the ${\displaystyle \frac{U}{A}}$ versus ${\displaystyle \frac{t}{A^{1-\phi }}}$ plots, where U is the detected voltage) for a fixed area scale very well together. The tail of the normalized temporal shape decays more slowly than the theoretical prediction, which can be attributed to an intrinsic absorption of AE signals and/or to the overlap of sub-avalanches. Full article

The microstructural and mechanical features were investigated for the alloy Ti-36.5Nb-4.5Zr-3Ta-0.16O (wt.%) subjected to thermo-mechanical processing consisting of a series of hot and cold rolling combined with solution treatments with particular parameters. The objective was to find the optimal thermo-mechanical treatment variant to improve the mechanical properties, and namely, to increase the yield tensile strength (YTS) and the ultimate tensile strength (UTS), with a low modulus of elasticity and with an adequate ductility in order to obtain a good biomaterial appropriate for use in hard tissue implants. X-ray diffraction and SEM microscopy served to investigate the microstructural features: the type of formed phases with their morphology, dimensions, and distribution. The experimental alloy presented mainly a β-phase with some α″-Ti martensitic phase in particular stages of the processing scheme. The main mechanical properties were found by applying a tensile test, from which were determined the yield tensile strength [MPa], the ultimate tensile strength [MPa], Young’s modulus of elasticity [GPa], and the elongation to fracture (%). Full article

In the present study, microstructure and cyclic tensile tests were used to measure the superelastic responses of Fe_40.95Ni₂₈Co₁₇Al_11.5Ta_2.5B_0.05 (at.%) shape memory alloys after 97% cold rolling. Cold-rolled samples underwent annealing heat treatment (1250 °C/1 h) followed by quenching in water or aging heat treatment (700 °C/6 h and 700 °C/12 h) followed by quenching in water. The microstructure results showed that the average grain size increased from 210 μm to 1570 μm as annealing times increased from 0.5 h to 1 h. X-ray diffraction (XRD) spectra for FeNiCoAlTaB (NCATB) showed that in cold-rolled alloys after solution, the strong peak was in the face-centered cubic (γ, FCC) <111> structure. In aged samples, a new peak (γ’, FCC) emerged, the intensity of which increased as aging times rose from 6 to 12 h. Transmission electron microscope (TEM) images showed that the average precipitate size was around 10 nm in 700 °C/6 h specimens and 18 nm in 700 °C/12 h specimens. The precipitate was enriched in Ni, Al, and Ta elements and exhibited an L1₂ crystal structure. Tensile samples aged at 700 °C for 6 and 12 h exhibited recoverable strains of 1% and 2.6%, respectively, at room temperature. Digital image correlation (DIC) results for the sample aged at 700 °C for 12 h showed that two martensite variants were activated during the superelastic test. Such variants can form corresponding variant pairs (CVPs), which promote tensile deformation. The tensile sample exhibited a gradual cyclic degradation, and a large irrecoverable strain was observed after the test. This irrecoverable strain was the result of residual martensite, which was pinned by dislocations. Full article

A Fe-30.5wt%Ni-0.155wt%C alloy was annealed at two different temperatures to produce two different austenite grain sizes. In the coarse-grained specimen, hierarchical configurations of variants are formed and carefully analyzed using EBSD. These typical patterns result from the alternate formation of two perpendicular plate groups of variants over several length scales, and two distinct types of mechanical couplings are shown to occur sequentially in the process of the transformation of an austenitic grain. In the fine-grained specimen, the martensite start temperature is depressed below liquid nitrogen temperature, and the martensitic transformation can only occur under stress assistance. Grain size reduction brings about a dramatic change in the morphology of martensite and its configurations. Martensite is fully twinned, and martensite variants arrange themselves into self-accommodating configurations involving all four variants of the same plate group. Those specific configurations share striking similarities with those usually encountered in conventional shape memory alloys. The reversion of such microstructures upon heating is believed to be at the origin of the observed shape memory effect. Full article

Shape memory alloys (SMAs) represent an exceptional class of smart materials as they are able to recover their shape after mechanical deformation, making them suitable for use in actuators, sensors and smart devices. These unique properties are due to the thermoelastic martensitic transformation that can occur during both thermal and mechanical deformation. Cu-based SMAs, especially those incorporating Al and Ag, are attracting much attention due to their facile production and cost-effectiveness. Among them, Cu-Al-Ag SMAs stand out due to their notably high temperature range for martensitic transformation. In this study, a Cu-based SMA with a new ternary composition of Cu-10Al-7Ag wt.% was prepared by arc melting and the samples cut from this casting alloy were quenched in water. Subsequently, the phase composition and the development of the microstructure were investigated. In addition, the morphology of the martensite was studied using advanced techniques such as electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM). The analyzes confirmed the presence of martensitic structures in both samples; mainly 18R (β_1′) martensite was present but a small volume fraction of (γ_1′) martensite also was noticed in the as-quenched sample. The observation of fine, twinned martensite plates in the SMA alloy with symmetrically occurring basal plane traces between the twin variants underlines the inherent correlation between microstructural symmetry and the properties of the material and provides valuable insights into its behavior. The hardness of the quenched sample was found to be lower than the as-cast counterpart, which can be linked to the solutioning of Ag particles during the heat treatment. Full article

Laser welding of the near α-phase titanium alloy Ti-4Al-2V, used for complex components in the nuclear industry, has been rarely reported. In this study, butt weld joints made of Ti-4Al-2V alloy plates under different parameters, including the laser power, the welding speed, and the defocus distance, were manufactured and analyzed. The results showed that adjusting the combination of 4.2 kW of laser power, a 20 mm/s welding speed, and a −2 mm defocus distance could achieve a penetration depth exceeding 6 mm. Porosity defects were prone to forming in the middle and bottom parts of the fusion zone, due to rapid cooling. The microstructure of the fusion zone was mainly needle-like α martensite, which precipitated in the form of specific clusters. The interior of a cluster was composed of three types of variants with <11−20>/60° phase interfaces to achieve the lower boundary’s energy. Affected by the microstructure and welding defects, the strength of the weld joint was basically similar under different welding conditions, namely about 720 MPa, slightly higher than that of the base metal, while the rupture elongation at breaking decreased by more than 50%. The micro-Vickers hardness of the weld joints was about 50–60 HV higher than that of the base metal, while the impact toughness was about 40 KJ, almost half that of the base metal. This research lays a solid foundation for the engineering application of laser welding of Ti-4Al-2V alloys. Full article

Explaining the crystallography of iron alloys martensite with a {225}_γ habit plane remains a challenging task within the phenomenological theory of martensite crystallography. The purpose of this study is to re-examine the martensite formed in a Fe-8Cr-1.1C alloy using EBSD, which has a better angular resolution than the conventional transmission electron diffraction techniques previously used. The results show that the single morphological plates, which hold a near {225}_γ habit plane, are bivariant composites made up of two twin-related variants. It is shown that a {113}_γ plane is systematically parallel to one of the three common ${\left\{112\right\}}_{\alpha }$ planes between the two twin-related crystals. This observation suggests that the lattice invariant strain of transformation occurs through a dislocation glide on the {113}_γ ⟨110⟩_γ system, rather than through twinning as is commonly accepted. Based on this assumption, the predictions of Bowles and Mackenzie’s original theory are in good agreement with the crystallographic features of {225}_γ martensite. Unexpectedly, it is the high shear solution of the theory that gives the most accurate experimental predictions. Full article