Search Results (40)

This research investigates resonator width optimization for simultaneously enhancing electrical performance and mechanical reliability in wideband RF MEMS filters through systematic evaluation of three configurations: 0% (L1), 60% (L2), and 100% (L3) matching ratios between cap and bottom wafers using Au-Au thermocompression bonding. The study demonstrates that resonator width alignment significantly influences both electromagnetic field coupling and bonding interface integrity. The L3 configuration with complete width matching achieved optimal RF performance, demonstrating 3.34 dB insertion loss across 4.5 GHz bandwidth (25% fractional bandwidth), outperforming L2 (3.56 dB) and L1 (3.10 dB), while providing enhanced electromagnetic wave coupling and minimized contact resistance. Mechanical reliability testing revealed superior bonding strength for the L3 configuration, withstanding up to 7.14 Kgf in shear pull tests, significantly exceeding L1 (4.22 Kgf) and L2 (2.24 Kgf). SEM analysis confirmed uniform bonding interfaces with minimal void formation (~180 nm), while Q-factor measurements showed L3 achieved optimal loaded Q-factor (Q_L = 3.31) suitable for wideband operation. Comprehensive environmental testing, including thermal cycling (−50 °C to +145 °C) and humidity exposure per MIL-STD-810E standards, validated long-term stability across all configurations. This investigation establishes that complete resonator width matching between cap and bottom wafers optimizes both electromagnetic performance and mechanical bonding reliability, providing a validated framework for developing high-performance, reliable RF MEMS devices for next-generation communication, radar, and sensing applications. Full article

Recent studies primarily focus on how the fiber content and curing age influence the pore structure and strength of concrete. However, The interfacial bonding mechanism in basalt-fiber-reinforced concrete hydration remains unclear. The lack of a long-term performance-prediction model and insufficient research on multi-field coupling effects form key knowledge gaps, hindering the systematic optimal design and wider engineering applications of such materials. By integrating X-ray computed tomography (CT) with the watershed algorithm, this study proposes an innovative gray scale threshold method for pore quantification, enabling a quantitative analysis of pore structure evolution and its correlation with mechanical properties in basalt-fiber-reinforced concrete (BFRC) and normal concrete (NC). The results show the following: (1) Mechanical Enhancement: the incorporation of 0.2% basalt fiber by volume demonstrates significant enhancement in the mechanical performance index. At 28 days, BFRC exhibits compressive and splitting tensile strengths of 50.78 MPa and 4.07 MPa, surpassing NC by 19.88% and 43.3%, respectively. The early strength reduction in BFRC (13.13 MPa vs. 22.81 MPa for NC at 3 days) is attributed to fiber-induced interference through physical obstruction of cement particle hydration pathways, which diminishes as hydration progresses. (2) Porosity Reduction: BFRC demonstrates a 64.83% lower porosity (5.13%) than NC (11.66%) at 28 days, with microscopic analysis revealing a 77.5% proportion of harmless pores (<1.104 × 10⁷ μm³) in BFRC versus 67.6% in NC, driven by densified interfacial transition zones (ITZs). (3) Predictive Modeling: a two dimensional strength-porosity model and a three-dimensional age-dependent model are developed. The proposed multi-factor model demonstrates exceptional predictive capability (R² = 0.9994), establishing a quantitative relationship between pore micro structure and mechanical performance. The innovative pore extraction method and mathematical modeling approach offer valuable insights into the micro-structural evolution mechanism of fiber concrete. Full article

Polymer electrolytes (PEs) provide enhanced safety for high–energy–density lithium metal batteries (LMBs), yet their practical application is hampered by intrinsically low ionic conductivity and insufficient electrochemical stability, primarily stemming from suboptimal Li⁺ solvation environments and transport pathways coupled with slow polymer dynamics. Herein, we demonstrate a molecular design strategy to overcome these limitations by regulating the Li⁺ solvation structure through the synergistic interplay of conventional Lewis acid–base coordination and engineered hydrogen bond (H–bond) networks, achieved by incorporating specific H–bond donor functionalities (N,N′–methylenebis(acrylamide), MBA) into the polymer architecture. Computational modeling confirms that the introduced H–bonds effectively modulate the Li⁺ coordination environment, promote salt dissociation, and create favorable pathways for faster ion transport decoupled from polymer chain motion. Experimentally, the resultant polymer electrolyte (MFE, based on MBA) enables exceptionally stable Li metal cycling in symmetric cells (>4000 h at 0.1 mA cm⁻²), endows LFP|MFE|Li cells with long–term stability, achieving 81.0% capacity retention after 1400 cycles, and confers NCM622|MFE|Li cells with cycling endurance, maintaining 81.0% capacity retention after 800 cycles under a high voltage of 4.3 V at room temperature. This study underscores a potent molecular engineering strategy, leveraging synergistic hydrogen bonding and Lewis acid–base interactions to rationally tailor the Li⁺ solvation structure and unlock efficient ion transport in polymer electrolytes, paving a promising path towards high–performance solid–state lithium metal batteries. Full article

Ionizing radiations are responsible for bond scission, radical formation, and oxidative degradation of polymer matrices. This study focuses on the effects of gamma irradiation on solid propellant binders, targeting a comprehensive chemical and mechanical characterization of different formulations. Samples were produced either by conventional methods based on hydroxyl-terminated polybutadiene and standard polyaddition reaction using isocyanates, or innovative approaches involving UV-driven radical curing. The samples were irradiated for comparison and to study their evolution as a function of three absorbed doses (25, 45, 130 kGy) for preliminary characterization studies, using a 60-Co gamma source. Samples were irradiated in air at uncontrolled room temperature. The coupling of spectroscopy techniques (Fourier transform infrared—FTIR, Raman and electron paramagnetic resonance—EPR) and dynamic mechanical analysis (DMA) highlighted the key role of antioxidant agents in tailoring mechanical changes in the binder phase. The absence of antioxidants enhances radical formation, oxidation, and cross-linking. These processes lead to progressively increased rigidity and reduced flexibility as a function of the absorbed dose. Complex interactions between photocured components largely influence radical stabilization and material degradation. These findings provide valuable insights for designing novel radiation-resistant binders, enabling the development of solid propellants tailored for reliable, long-term permanence in space, and advancing the knowledge on the applicability of 3D-printed propellants. Full article

Hydraulic concrete is subject to severe durability challenges when abraded by the high-speed flow of sandy water. Conventional concrete frequently needs to be repaired because of its high brittleness and insufficient abrasion resistance, while granular rubber can easily be dislodged from the matrix during abrasion, forming a new source of abrasion and increasing the damage to the matrix. For this reason, we used fibrous rubber concrete to systematically study the mechanisms of the influence of the dosage of nitrile rubber (5%, 10%, and 15%) and fiber length (6, 12, and 18 mm) on resistance to impact and abrasion performance. Through mechanical tests, underwater steel ball abrasion tests, three-dimensional morphology measurements, and fractal dimension analysis, the law behind the damage evolution of fibrous rubber concrete was revealed. The results show that concrete with 15% NBR and 12 mm fibers yielded the best performance, and its 144-hour abrasion resistance reached 25.0 h/(kg/m²), which is 163.7% higher than that for the baseline group. Fractal dimension analysis (D = 2.204 for the optimum group vs. 2.356 for the benchmark group) showed that the fiber network effectively suppressed surface damage extension. The long-term mass loss rate was only 2.36% (5.82% for the benchmark group), and the elastic energy dissipation mechanism remained stable under dynamic loading. The results of a microanalysis showed that the high surface roughness of NBR enhances interfacial bonding, which synergizes with crack bridging and stress dispersion and, thus, forms a multiscale anti-impact abrasion barrier. This study provides a new material solution for the design of durable concrete for use in high-impact and high-abrasion environments, which combines mechanical property preservation and resource recycling value. However, we did not systematically examine the evolution of the performance of fiber rubber concrete concrete under long-term environmental coupling conditions, such as freeze–thaw cycles, ultraviolet aging, or chemical attacks, and there are limitations to our assessment of full life-cycle durability. Full article

Silicone structural glazing (SSG) sealants are crucial sealing materials in modern building curtain walls, whose performance degradation may lead to functional and safety issues, posing significant challenges to building safety maintenance. This study comprehensively investigated the effects of temperature, humidity, stress, and ultraviolet (UV) irradiance on the durability of SSG sealants through multi-gradient matrix aging tests, revealing the influence patterns of these four aging factors on tensile bond strength (TBS). Based on aging test data and degradation patterns, a novel degradation model for TBS aging was established by incorporating all four aging factors as variables, enabling the model to reflect their combined effects on TBS degradation. The unknown parameters in the model were calculated using the Markov chain Monte Carlo (MCMC) algorithm and validated against experimental data. A recursive algorithm was developed to predict TBS degradation under actual service conditions based on the degradation model and environmental records, with verification through outdoor aging tests. This study established a service life prediction methodology that combines the degradation model with environmental data through recursive computation and standard-specified strength limits. The results demonstrate that increasing temperature, humidity, stress, and UV irradiation accelerates TBS changes, with influence intensity ranking as UV irradiation > temperature > humidity > stress. Synergistic effects exist among all four factors, where UV irradiation shows the most significant coupling effect by amplifying other factors’ combined impacts, while UV’s primary influence manifests through such synergies rather than independent action. Among temperature, humidity, and stress combined effects, temperature contributes approximately 50%, temperature–humidity interaction about 35%, with temperature-related terms collectively accounting for 90%. The degradation model calculation results show excellent agreement with experimental data (R² > 0.9, MAE = 0.019 MPa, RMSE = 0.0245 MPa). The characteristic TBS minimum value considering material discreteness and strength assurance rate serves as a reliable criterion for service life evaluation. The proposed prediction method provides essential theoretical and methodological foundations for ensuring long-term safety and maintenance strategies for glass curtain walls. Full article

In plasma-enhanced chemical vapor deposition (PECVD) processes, thin films can accumulate on the inner chamber walls, resulting in particle contamination and process drift. In this study, we investigate the physical and chemical properties of these wall-deposited films to understand their spatial variation and impact on chamber maintenance. A 6-inch capacitively coupled plasma (CCP)-type PECVD system was used to deposit SiO₂ films, whilst long silicon coupons were attached vertically to the chamber side walls to collect contamination samples. The collected contamination samples were comparatively analyzed in terms of their chemical properties and surface morphology. The results reveal significant differences in hydrogen content and Si–O bonding configurations compared to reference films deposited on wafers. The top chamber wall, located near the plasma region, exhibited higher hydrogen incorporation and larger Si–O–Si bonding angles, while the bottom wall exhibited rougher surfaces with larger particulate agglomerates. These variations were closely linked to differences in gas flow dynamics, precursor distribution, and the energy state of the plasma species at different chamber heights. The findings indicate that top-wall contaminants are more readily cleaned due to their high hydrogen content, while bottom-wall residues may be more persistent and pose higher risks for particle generation. This study provides insights into wall contamination behavior in PECVD systems and suggests strategies for spatially optimized chamber cleaning and conditioning in high-throughput semiconductor processes. Full article

Around the world, a large number of stone artifacts have been exposed to air for long periods of time, showing multiple types of deterioration that have attracted widespread attention. Among them, there is an often overlooked deterioration of stone artifacts, i.e., black stains on the surface of the calcareous stone, which are tightly bonded to the substrate as a result of the long-term deposition of air pollution. However, due to the current lack of a clear understanding of the black stains, people often tend to use the wrong cleaning and conservation methods, which is not conducive to sustainable conservation. Therefore, there is an urgent need to comprehensively recognize the black stains in terms of material properties and environmental sustainability to guide scientific sustainable conservation methods. To this end, in this paper, we take the black stains observed on marble buildings in the Xianling Tomb, China, as an example, and for the first time, we aim to create a comprehensive understanding of black deposition from the aspects of material properties and environmental characteristics. Multi-analytical approaches, including polarized light microscopy, X-ray fluorescence (XRF), and scanning electron microscopy with energy dispersive X-ray spectrometry (SEM-EDS), were employed to discern the differences between the substrate and black stains. The results revealed that the formation of black stains was attributed to prolonged exposure to various air pollutants (PM, SO₂, NO₂, CO, and O₃). Subsequently, observational data from 2015 to 2023 were utilized to investigate the temporal evolution of local air pollutants and their coupled resonances. Multi-scale variations (annual, seasonal, monthly, weekly, and daily) of pollutant concentration sequences were identified, which helps us to have a clearer perception and to proactively control air pollutants in the region from different cycles. In addition, wavelet coherence (WTC) demonstrated significant time-scale dependency in correlation with air pollutants, which provides effective data support for the coordinated control of air pollutants. This study reveals the mechanism of black stain deterioration on stone artifact surfaces, provides data support for the control and prediction of air pollutants oriented to the sustainable conservation of stone artifacts, and provides a novel and comprehensive approach to the scientific knowledge and sustainable conservation of stone artifacts. Full article

This study incorporated silane coupling agent KH550-modified nano-alumina (KH550-Al₂O₃) into vinyl ester resin (VER) for modification. The effect of KH550-Al₂O₃ on the flexural properties of VER and basalt fiber-reinforced vinyl ester resin (BF/VER) composites was investigated. In addition, dynamic mechanical analysis (DMA) and long-term elevated temperature aging of the composites were performed. The surface functionalization of KH550-Al₂O₃ was confirmed by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and energy-dispersive X-ray spectroscopy (EDS). It was revealed by scanning electron microscopy (SEM) that the aggregation of KH550-Al₂O₃ had been reduced within the VER matrix, the resin was effectively enhanced, and the fiber–matrix interfacial bonding was improved. Based on the experimental results, the optimal filler loading of KH550-Al₂O₃ was 1.5 wt%. Compared with the control group, the resin matrix exhibited 18.1% and 22.7% improvements in flexural strength and modulus, respectively, while the composite showed increases of 9.3% and 7.6% in these properties. At 30 °C, the storage modulus of the composites increased by 11.5%, with the glass transition temperature rising from 111.0 °C to 112.5 °C. After 60 days of thermal aging at 120 °C, the retained flexural strength and modulus were 64.3% and 87.4%, respectively. Full article

Ships and offshore equipment operating in marine environments often face issues such as seawater corrosion and biofouling, leading to significant economic losses. To address the corrosion problems of ships and offshore equipment, heavy-duty anticorrosive coatings are widely used for corrosion protection in marine environments due to their long-term effectiveness, cost-efficiency, and excellent applicability. In this study, silane coupling agent (KH-560) was employed to modify sodium silicate, and the modified sodium silicate was then incorporated as a reinforcing phase into polyurethane to ultimately prepare a modified sodium silicate/polyurethane coating. The feasibility of the modified sodium silicate/polyurethane coating was investigated by characterizing its conventional physicochemical properties, weather resistance, acid and alkali resistance, and salt spray corrosion resistance. Experimental results indicate that the silane coupling agent acts as a bridge between the organic and inorganic interfaces through the hydrolysis and condensation reactions of its bifunctional groups, forming an interfacial layer connected by hydrogen bonds and covalent bonds, thereby improving the compatibility between the organic resin and inorganic sodium silicate. Comprehensive performance analysis revealed that when the content of modified sodium silicate was 60 wt%, the coating hardness reached 4H. Additionally, electrochemical tests demonstrated that the coating exhibited higher impedance (9.62 × 10⁴ Ω/cm²) and lower corrosion current density (5.82 × 10⁻⁷ A/cm²). This study provides a theoretical and experimental basis for the development of high-performance anticorrosive coatings for marine applications. Full article

Lined pipes are widely used in oil and gas transportation systems due to their excellent corrosion resistance and cost-effectiveness. However, current design codes often oversimplify their mechanical behavior by treating them as single-layer systems, neglecting the complex interactions between the liner and outer pipes under temperature–pressure coupling. To address this gap, this study develops a finite element model for a Φ323.8 × (10 + 3) mm X60-825 lined pipe under elastic laying conditions. The model evaluates stress distribution, bonding strength, and liner deformation under varying operational conditions, including temperatures ranging from 20 °C to 80 °C and internal pressures from 0 MPa to 14 MPa. Key findings reveal that the liner pipe approaches its yield strength (241 MPa) under high-pressure conditions, with a maximum Tresca stress of 238.81 MPa, while the outer pipe reaches 286.51 MPa. Internal pressure significantly enhances bonding strength, increasing it from an initial 0.85 MPa to 11.86 MPa at 14 MPa, thereby reducing the risk of delamination. Simplified single-layer models, which ignore the liner’s pressure-bearing effect, underestimate stress interactions, resulting in a 16.63% error in outer pipe stress under extreme conditions. These results underscore the limitations of simplified models and highlight the importance of considering multi-field coupling effects in pipeline design. This study provides critical insights for optimizing laying radii and ensuring the long-term integrity of lined pipe systems. Future work should focus on experimental validation and microstructural analysis to further refine the design guidelines. Full article

Natural gas hydrates represent a promising clean energy source with vast reserves. Their efficient development is crucial for ensuring the sustainable advancement of human society. However, wellhead instability occurred in the long-term development, which poses a significant challenge that impacts its commercial development. In the present work, the properties of hydrate-bearing sediments were experimentally investigated. It was found that the elastic modulus, cohesion, and internal friction angle of hydrate-bearing sediments exhibit an increase with the effective stress. As an example, when the effective stress increases from 0 MPa to 25 MPa, the normalized elastic modulus exhibits a rise from 1.00 to 1.36. Conversely, the Poisson’s ratio, permeability, and porosity demonstrate a decline in accordance with this trend. As an example, both normalized porosity and permeability decrease to values below 0.40 as the effective stress increases to 25 MPa. Based on the experimental results and previous work, a comprehensive model for describing the effect of both hydrate saturation and effective stress on physical parameters was obtained. Subsequently, a multi-field coupled investigation methodology was developed to evaluate wellhead stability during the long-term development of hydrate-bearing sediments, and the evolution characteristics and mechanisms of wellhead instability were numerically explored. It reveals that development operation using the vertical wellbore decomposes hydrates in the surrounding sediments only within a radius of 19.52 m, which significantly undermines the wellhead stability. Moreover, the wellhead system not only sinks with sediment subsidence but also experiences additional sinking due to the failure of bonding between the wellhead system and sediments. Furthermore, the latter accounts for a significant portion, amounting to approximately 68.15% of the total sinking under the research conditions. This study can provide methodological prerequisites for exploring the impact of various factors on wellhead stability during the long-term hydrate development process. Full article

The aim of this study was to compare the long-term bonding performance to lithium disilicate (LDS) ceramic between one-bottle and two-bottle bonding agents. Bonding performance was investigated under these LDS pretreatment conditions: with hydrofluoric acid (HF) only, without HF, with a two-bottle bonding agent (Tokuyama Universal Bond II) only. Shear bond strengths between LDS and nine resin cements (both self-adhesive and conventional adhesive types) were measured at three time periods: after one-day water storage (Base), and after 5000 and 20,000 thermocycles (TC 5k and TC 20k respectively). Difference in degradation between one- and two-bottle bonding agents containing the silane coupling agent was compared by high-performance liquid chromatography. With HF pretreatment, bond strengths were not significantly different among the three time periods for each resin cement. Without HF, ESTECEM II and Super-Bond Universal showed significantly higher values than others at TC 5k and TC 20k when treated with the recommended bonding agents, especially at TC 20k. Difference in degradation between one- and two-bottle bonding agents containing the silane coupling agent was compared by high-performance liquid chromatography (HPLC). For both cements, these values at TC 20k were also not significantly different from pretreatment with only Tokuyama Universal Bond II. For LDS, long-term bond durability could be maintained by pretreatment with Tokuyama Universal Bond II instead of the hazardous HF. Full article

Silicon (Si) is one of the main biogenic elements in the aquatic ecosystem of lakes, significantly affecting the primary productivity of lakes. Lake sediment is an important sink of Si, which exists in different Si forms and will be released and participate in the recycling of Si when the sediment environment changes. Compared to carbon (C), nitrogen (N) and phosphorus (P), the understanding of different Si forms in sediments and their biogeochemical cycling is currently insufficient. Dianchi Lake, a typical eutrophic lake in southwest China, was selected as an example, and the contents of different Si forms and biogenic silicon (BSi), as well as their correlations with total organic carbon (TOC), total nitrogen (TN), and chlorophyll a in the surface sediments, were systematically investigated to explore Si’s recycling characteristics. The results showed that the coupling relationship of the four different Si forms in the surface sediments of Dianchi Lake was poor (p > 0.05), indicating that their sources were relatively independent. Moreover, their formation may be greatly influenced by the adsorption, fixation and redistribution of dissolved silicon by different lake substances. The contents of different Si forms in the surface sediments of Dianchi Lake were ranked as iron-manganese-oxide-bonded silicon (IMOF-Si) > organic sulfide-bonded silicon (OSF-Si) > ion-exchangeable silicon (IEF-Si) > carbonate-bound silicon (CF-Si). In particular, the contents of IMOF-Si and OSF-Si reached 2983.7~3434.7 mg/kg and 1067.6~1324.3 mg/kg, respectively, suggesting that the release and recycling of Si in surface sediments may be more sensitive to changes in redox conditions at the sediment–water interface, which become the main pathway for Si recycling, and the slow degradation of organic matter rich in OSF-Si may lead to long-term and continuous endogenous Si recycling. The low proportion (0.3~0.6%) and spatial differences of biogenic silicon (BSi) in the surface sediments of Dianchi Lake, as well as the poor correlation between BSi and TOC, TN, and chlorophyll a, indicated that the primary productivity of Dianchi Lake was still dominated by cyanobacteria and other algal blooms, while the relative abundance of siliceous organisms such as diatoms was low and closer to the central area of Dianchi Lake. Additionally, BSi may have a faster release capability relative to TOC and may participate in Si recycling. Full article

The long-term periodicity and uncontrollable interface properties during the preparation process for silicon carbide fiber reinforced silicon carbide-based composites (SiC_f/SiC CMC) make it difficult to thoroughly investigate their mechanical damage behavior under complex loading conditions. To delve deeper into the influence of the interface strength and toughness on the mechanical response of microscopic representative volume element (RVE) models under complex loading conditions, in this work, based on numerical simulation methods, a microscale representative volume element (RVE) with periodic symmetric boundary conditions for the material is constructed. The phase-field fracture theory and cohesive zone model are coupled to capture the brittle cracking of the matrix and the debonding behavior at the fiber/matrix interface. Simulation analysis is conducted for tensile, compressive, and shear loading as well as combined loading, and the validity of the model is verified based on the Chamis theory. Further investigation is conducted into the mechanical response behavior of the microscale RVE model under complex loading conditions in relation to the interface strength and interface toughness. The results indicate that under uniaxial loading, increasing the interface strength leads to a tighter bond between the fiber and matrix, suppressing crack initiation and propagation, and significantly increasing the material’s fracture strength. However, compared to the transverse compressive strength, increasing the interface strength does not continuously enhance the strength under other loading conditions. Meanwhile, under the condition of strong interface strength of 400 MPa, an increase in the interface toughness significantly increases the transverse compressive strength of the material. When it increases from 2 J/m² to 20 J/m², the transverse compressive strength increases by 28.49%. Under biaxial combined loading, increasing the interface strength significantly widens the failure envelope space under σ₂-τ₂₃ combined loading; with the transition from transverse compressive stress to tensile stress, the transverse shear strength shows a trend of first increasing and then decreasing, and when the ratio of transverse shear displacement to transverse tensile/compressive displacement is −1, it reaches the maximum. This study provides strong numerical support for the investigation of the interface properties and mechanical behavior of SiC_f/SiC composites under complex loading conditions, offering important references for engineering design and material performance optimization. Full article