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Keywords = long-fiber-reinforced resins

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11 pages, 2735 KiB  
Case Report
Management of a Complicated Crown Fracture in a 16-Year-Old Patient: A Case Report
by Ralitsa Bogovska-Gigova
Reports 2025, 8(3), 132; https://doi.org/10.3390/reports8030132 - 1 Aug 2025
Viewed by 189
Abstract
Background and Clinical Significance: Traumatic dental injuries, particularly complicated crown fractures of permanent incisors, are common in adolescents, with maxillary central incisors most frequently affected due to their prominent position. These injuries, often resulting from sports or accidents, require prompt management to [...] Read more.
Background and Clinical Significance: Traumatic dental injuries, particularly complicated crown fractures of permanent incisors, are common in adolescents, with maxillary central incisors most frequently affected due to their prominent position. These injuries, often resulting from sports or accidents, require prompt management to prevent complications such as pulp necrosis or infection, which can compromise long-term prognosis. Fragment reattachment offers a conservative, esthetically favorable approach when the fractured segment is intact, with outcomes comparable to composite restorations. This case report underscores the importance of timely intervention and advanced restorative techniques in pediatric dentistry. Case Presentation: A 16-year-old male presented with a complicated crown fracture of the upper left central incisor sustained during a soccer game. The fracture extended subgingivally with pulp exposure. The patient preserved the fragment in saline. Treatment involved fragment reattachment using a dentin bonding agent and flowable composite resin, followed by single-visit root canal therapy due to delayed presentation (48 h). A glass fiber post was placed to reinforce the restoration due to significant coronal loss. Three years of follow-up visits (1, 3, 6, 12, 24, and 36 months) revealed no clinical or radiographic complications, with the tooth remaining asymptomatic and functional. Conclusions: This case underscores the effectiveness of fragment reattachment when combined with meticulous technique and long-term monitoring. Full article
(This article belongs to the Special Issue Oral Disorders in the Pediatric Population)
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15 pages, 2854 KiB  
Review
A Review on the Applications of Basalt Fibers and Their Composites in Infrastructures
by Wenlong Yan, Jianzhe Shi, Xuyang Cao, Meng Zhang, Lei Li and Jingyi Jiang
Buildings 2025, 15(14), 2525; https://doi.org/10.3390/buildings15142525 - 18 Jul 2025
Viewed by 363
Abstract
This article presents a review on the applications of basalt fibers and their composites in infrastructures. The characteristics and advantages of high-performance basalt fibers and their composites are firstly introduced. Then, the article discusses strengthening using basalt fiber sheets and BFRP bars or [...] Read more.
This article presents a review on the applications of basalt fibers and their composites in infrastructures. The characteristics and advantages of high-performance basalt fibers and their composites are firstly introduced. Then, the article discusses strengthening using basalt fiber sheets and BFRP bars or grids, followed by concrete structures reinforced with BFRP bars, asphalt pavements, and cementitious composites reinforced with chopped basalt fibers in terms of mechanical behaviors and application examples. The load-bearing capacity of the strengthened structures can be increased by up to 60%, compared with those without strengthening. The lifespan of the concrete structures reinforced with BFRP can be extended by up to 50 years at least in harsh environments, which is much longer than that of ordinary reinforced concrete structures. In addition, the fatigue cracking resistance of asphalt can be increased by up to 600% with basalt fiber. The newly developed technologies including anchor bolts using BFRPs, self-sensing BFRPs, and BFRP–concrete composite structures are introduced in detail. Furthermore, suggestions are proposed for the forward-looking technologies, such as long-span bridges with BFRP cables, BFRP truss structures, BFRP with thermoplastic resin matrix, and BFRP composite piles. Full article
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18 pages, 5009 KiB  
Article
Preparation of Glass Fiber Reinforced Polypropylene Bending Plate and Its Long-Term Performance Exposed in Alkaline Solution Environment
by Zhan Peng, Anji Wang, Chen Wang and Chenggao Li
Polymers 2025, 17(13), 1844; https://doi.org/10.3390/polym17131844 - 30 Jun 2025
Viewed by 311
Abstract
Glass fiber reinforced polypropylene composite plates have gradually attracted more attention because of their repeated molding, higher toughness, higher durability, and fatigue resistance compared to glass fiber reinforced thermosetting composites. In practical engineering applications, composite plates have to undergo bending effect at different [...] Read more.
Glass fiber reinforced polypropylene composite plates have gradually attracted more attention because of their repeated molding, higher toughness, higher durability, and fatigue resistance compared to glass fiber reinforced thermosetting composites. In practical engineering applications, composite plates have to undergo bending effect at different angles in corrosive environment of concrete, including bending bars from 0~90°, and stirrups of 90°, which may lead to long-term performance degradation. Therefore, it is important to evaluate the long-term performance of glass fiber reinforced polypropylene composite bending plates in an alkali environment. In the current paper, a new bending device is developed to prepare glass fiber reinforced polypropylene bending plates with the bending angles of 60° and 90°. It should be pointed out that the above two bending angles are simulated typical bending bars and stirrups, respectively. The plate is immersed in the alkali solution environment for up to 90 days for long-term exposure. Mechanical properties (tensile properties and shear properties), thermal properties (dynamic mechanical properties and thermogravimetric analysis) and micro-morphology analysis (surface morphology analysis) were systematically designed to evaluate the influence mechanism of bending angle and alkali solution immersion on the long-term mechanical properties. The results show the bending effect leads to the continuous failure of fibers, and the outer fibers break under tension, and the inner fibers buckle under compression, resulting in debonding of the fiber–matrix interface. Alkali solution (OH ions) corrode the surface of glass fiber to form soluble silicate, which is proved by the mass fraction of glass fiber decreased obviously from 79.9% to 73.65% from thermogravimetric analysis. This contributes to the highest degradation ratio of tensile strength was 71.6% (60° bending) and 65.6% (90° bending), respectively, compared to the plate with bending angles of 0°. A high curvature bending angle (such as 90°) leads to local buckling of fibers and plastic deformation of the matrix, forming microcracks and fiber–resin interface bonding at the bending area, which accelerates the chemical erosion and debonding process in the interface area, bringing about an additional maximum 10.56% degradation rate of the shear strength. In addition, the alkali immersion leads to the obvious degradation of storage modulus and thermal decomposition temperature of composite plate. Compared with the other works on the long-term mechanical properties of glass fiber reinforced polypropylene, it can be found that the long-term performance of glass fiber reinforced polypropylene composites is controlled by the corrosive media type, bending angle and immersion time. The research results will provide durability data for glass fiber reinforced polypropylene composites used in concrete as stirrups. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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36 pages, 4774 KiB  
Review
Exploring the Role of Advanced Composites and Biocomposites in Agricultural Machinery and Equipment: Insights into Design, Performance, and Sustainability
by Ehsan Fartash Naeimi, Kemal Çağatay Selvi and Nicoleta Ungureanu
Polymers 2025, 17(12), 1691; https://doi.org/10.3390/polym17121691 - 18 Jun 2025
Viewed by 758
Abstract
The agricultural sector faces growing pressure to enhance productivity and sustainability, prompting innovation in machinery design. Traditional materials such as steel still dominate but are a cause of increased weight, soil compaction, increased fuel consumption, and corrosion. Composite materials—and, more specifically, fiber-reinforced polymers [...] Read more.
The agricultural sector faces growing pressure to enhance productivity and sustainability, prompting innovation in machinery design. Traditional materials such as steel still dominate but are a cause of increased weight, soil compaction, increased fuel consumption, and corrosion. Composite materials—and, more specifically, fiber-reinforced polymers (FRPs)—offer appealing alternatives due to their high specific strength and stiffness, corrosion resistance, and design flexibility. Meanwhile, increasing environmental awareness has triggered interest in biocomposites, which contain natural fibers (e.g., flax, hemp, straw) and/or bio-based resins (e.g., PLA, biopolyesters), aligned with circular economy principles. This review offers a comprehensive overview of synthetic composites and biocomposites for agricultural machinery and equipment (AME). It briefly presents their fundamental constituents—fibers, matrices, and fillers—and recapitulates relevant mechanical and environmental properties. Key manufacturing processes such as hand lay-up, compression molding, resin transfer molding (RTM), pultrusion, and injection molding are discussed in terms of their applicability, benefits, and limits for the manufacture of AME. Current applications in tractors, sprayers, harvesters, and planters are covered in the article, with advantages such as lightweighting, corrosion resistance, flexibility and sustainability. Challenges are also reviewed, including the cost, repairability of damage, and end-of-life (EoL) issues for composites and the moisture sensitivity, performance variation, and standardization for biocomposites. Finally, principal research needs are outlined, including material development, long-term performance testing, sustainable and scalable production, recycling, and the development of industry-specific standards. This synthesis is a practical guide for researchers, engineers, and manufacturers who want to introduce innovative material solutions for more efficient, longer lasting, and more sustainable agricultural machinery. Full article
(This article belongs to the Special Issue Biopolymers for Food Packaging and Agricultural Applications)
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21 pages, 303 KiB  
Review
Cytotoxicity and Endocrine Disruption in Materials Used for Removable Orthodontic Retainers: A Comprehensive Review
by Katarzyna Chojnacka and Marcin Mikulewicz
Dent. J. 2025, 13(6), 269; https://doi.org/10.3390/dj13060269 - 17 Jun 2025
Cited by 1 | Viewed by 756
Abstract
Objective: To evaluate the cytotoxicity and endocrine-disrupting potential of materials used in removable orthodontic retainers. Methods: A literature search (2015–2025) covered in vitro cytotoxicity, estrogenicity, in vivo tissue responses, and clinical biomarkers in PMMA plates, thermoplastic foils, 3D-printed resins, PEEK, and fiber-reinforced composites. [...] Read more.
Objective: To evaluate the cytotoxicity and endocrine-disrupting potential of materials used in removable orthodontic retainers. Methods: A literature search (2015–2025) covered in vitro cytotoxicity, estrogenicity, in vivo tissue responses, and clinical biomarkers in PMMA plates, thermoplastic foils, 3D-printed resins, PEEK, and fiber-reinforced composites. Results: Thirty-eight in vitro and ten clinical studies met inclusion criteria, identified via a structured literature search of electronic databases (2015–2025). Photopolymer resins demonstrated the highest cytotoxicity, whereas thermoplastics and PMMA exhibited predominantly mild effects, which diminished further following 24 h water storage. Bisphenol-type compound release was reported, but systemic exposure remained below regulatory limits. No statistically significant mucosal alterations or endocrine-related effects were reported in clinical studies. Conclusions: Retainer materials are generally biocompatible, though data on long-term endocrine effects are limited. Standardized biocompatibility assessment protocols are necessary to enable comparative evaluation across diverse orthodontic materials. Single-use thermoplastics contribute to microplastic release and pose end-of-life management challenges, raising concerns regarding environmental sustainability. Full article
(This article belongs to the Special Issue Dental Materials Design and Innovative Treatment Approach)
21 pages, 3701 KiB  
Article
The Nanomechanical Performance and Water Uptake of a Flowable Short Fiber Composite: The Influence of Bulk and Layering Restorative Techniques
by Tamás Tarjányi, András Gábor Jakab, Márton Sámi, Krisztián Bali, Ferenc Rárosi, Maja Laura Jarábik, Gábor Braunitzer, Dániel Palkovics, Lippo Lassila, Edina Lempel, Márk Fráter and Sufyan Garoushi
Polymers 2025, 17(11), 1553; https://doi.org/10.3390/polym17111553 - 2 Jun 2025
Viewed by 754
Abstract
This study aimed to evaluate the nanomechanical surface properties and water uptake of a flowable short-fiber-reinforced composite (SFRC) using various restorative techniques in order to assess its potential as a standalone restorative material. Nanoindentation and compressive creep testing were employed to characterize material [...] Read more.
This study aimed to evaluate the nanomechanical surface properties and water uptake of a flowable short-fiber-reinforced composite (SFRC) using various restorative techniques in order to assess its potential as a standalone restorative material. Nanoindentation and compressive creep testing were employed to characterize material performance. Three resin composites were examined: a flowable SFRC (everX Flow), a bulk-fill particulate filler composite (PFC), and a conventional PFC. Five experimental groups were established based on the restorative technique: layered PFC, layered SFRC, bulk SFRC, bulk PFC, and a bi-structure combining SFRC and PFC. Ninety standardized specimens (n = 18/group) were fabricated. Static and creep nanoindentation tests were conducted to assess surface properties, and water uptake was measured over a 30-day period. Data were analyzed using one-way ANOVA and Bonferroni post hoc tests. Nanoindentation revealed significant differences in hardness, with bulk PFC exhibiting the lowest values (p < 0.001). Creep testing indicated changes in modulus and viscosity following water storage. Notably, bulk SFRC showed the lowest water absorption (p < 0.001). Overall, bulk-applied SFRC demonstrated favorable nanomechanical properties and reduced water uptake, demonstrating its suitability as a standalone restorative material. Further clinical investigations are recommended to validate its long-term performance. Full article
(This article belongs to the Special Issue Advanced Polymeric Materials for Dental Applications III)
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25 pages, 40746 KiB  
Article
Effect of Silane-Modified Nano-Al2O3-Reinforced Vinyl Ester Resin on the Flexural Properties of Basalt Fiber Composites
by Yuehai Wei, Yongda Miao, Leilei Ma, Wei Tian and Chenyan Zhu
Materials 2025, 18(8), 1727; https://doi.org/10.3390/ma18081727 - 10 Apr 2025
Viewed by 573
Abstract
This study incorporated silane coupling agent KH550-modified nano-alumina (KH550-Al2O3) into vinyl ester resin (VER) for modification. The effect of KH550-Al2O3 on the flexural properties of VER and basalt fiber-reinforced vinyl ester resin (BF/VER) composites was investigated. [...] Read more.
This study incorporated silane coupling agent KH550-modified nano-alumina (KH550-Al2O3) into vinyl ester resin (VER) for modification. The effect of KH550-Al2O3 on the flexural properties of VER and basalt fiber-reinforced vinyl ester resin (BF/VER) composites was investigated. In addition, dynamic mechanical analysis (DMA) and long-term elevated temperature aging of the composites were performed. The surface functionalization of KH550-Al2O3 was confirmed by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and energy-dispersive X-ray spectroscopy (EDS). It was revealed by scanning electron microscopy (SEM) that the aggregation of KH550-Al2O3 had been reduced within the VER matrix, the resin was effectively enhanced, and the fiber–matrix interfacial bonding was improved. Based on the experimental results, the optimal filler loading of KH550-Al2O3 was 1.5 wt%. Compared with the control group, the resin matrix exhibited 18.1% and 22.7% improvements in flexural strength and modulus, respectively, while the composite showed increases of 9.3% and 7.6% in these properties. At 30 °C, the storage modulus of the composites increased by 11.5%, with the glass transition temperature rising from 111.0 °C to 112.5 °C. After 60 days of thermal aging at 120 °C, the retained flexural strength and modulus were 64.3% and 87.4%, respectively. Full article
(This article belongs to the Section Advanced Composites)
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15 pages, 1550 KiB  
Article
Optimization of Injection Molding Process for High-Strength and Lightweight Back Rest of Firefighters Using Carbon Fiber Composites of Long Fiber Thermoplastic with Flame Retardants
by Kyoung-Jae Min, Joon-Hyuk Song, Hyun Tak and Bhum-Keun Song
Materials 2025, 18(5), 1112; https://doi.org/10.3390/ma18051112 - 28 Feb 2025
Viewed by 722
Abstract
This study focuses on reducing the weight of oxygen respirators in firefighters’ personal protective equipment (PPE), which currently accounts for about 56% of the total weight. The heavy PPE, weighing between 20 and 25 kg, restricts movement and can lead to musculoskeletal injuries. [...] Read more.
This study focuses on reducing the weight of oxygen respirators in firefighters’ personal protective equipment (PPE), which currently accounts for about 56% of the total weight. The heavy PPE, weighing between 20 and 25 kg, restricts movement and can lead to musculoskeletal injuries. To address this, the study investigates using a carbon fiber-reinforced composite for the backrest of the oxygen respirator to reduce weight while maintaining strength. The backrest was fabricated using a long-fiber thermoplastic (LFT) composite made with PA66 resin and 30wt.% carbon fiber content. Initially, the injection-molding process conditions were identified to achieve a tensile strength of 85 MPa or higher. Additionally, flame retardants were added to improve fire resistance, with AF-480 at 5 wt.% found to be the best option. Subsequently, optimal injection conditions were set by fabricating the back rest with the composite by applying the Taguchi method to satisfy the required tensile strength. As a result, the composite material achieved a 12.8% weight reduction while maintaining the required strength. This development is expected to significantly improve firefighter safety, leading to more effective firefighting and reduced human and property damage. Full article
(This article belongs to the Section Carbon Materials)
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12 pages, 3907 KiB  
Article
A Bioartificial Device for the Encapsulation of Pancreatic β-Cells Using a Semipermeable Biocompatible Porous Membrane
by Nicola Cuscino, Salvatore Castelbuono, Claudio Centi, Rosaria Tinnirello, Maura Cimino, Giovanni Zito, Andrea Orlando, Massimo Pinzani, Pier Giulio Conaldi, Alessandro Mattina and Vitale Miceli
J. Clin. Med. 2025, 14(5), 1631; https://doi.org/10.3390/jcm14051631 - 27 Feb 2025
Viewed by 1217
Abstract
Background/Objectives: Type 1 diabetes (T1D) is a chronic autoimmune condition characterized by the destruction of pancreatic β-cells, leading to insulin deficiency. Current therapies, such as islet transplantation, face significant challenges, including limited donor availability and the need for lifelong immunosuppression. Encapsulation technologies [...] Read more.
Background/Objectives: Type 1 diabetes (T1D) is a chronic autoimmune condition characterized by the destruction of pancreatic β-cells, leading to insulin deficiency. Current therapies, such as islet transplantation, face significant challenges, including limited donor availability and the need for lifelong immunosuppression. Encapsulation technologies offer a promising alternative, providing immune protection and maintaining β-cell viability. In this study, we propose an encapsulation device featuring a spiral tubular semipermeable polyethersulfone (PES) membrane reinforced with a rigid biocompatible resin scaffold. Methods: The PES membrane was engineered with a tailored porosity of 0.5 µm, enabling efficient nutrient and oxygen exchange while preventing immune cell infiltration. Using INS-1E insulin-secreting cells aggregated into size-controlled islet-like spheroids (ILSs), we evaluated the device’s performance. Results: The device achieved high ILS viability and insulin secretion over 48 h at therapeutic densities, maintaining functionality comparable to free-floating ILSs (control). The PES membrane, with its mechanical stability and biocompatibility, ensured durability without compromising diffusion dynamics, overcoming a critical limitation of other encapsulation approaches. Importantly, the device geometry allowed for the encapsulation of up to 356,000 islet equivalents (IEQs) in a single capillary fiber, reaching therapeutic thresholds for T1D patients. Conclusions: this device, with its innovative design, enables high-density encapsulation while preserving ILS functionality and scalability, making it a potential platform for clinical application. This work highlights the potential of PES-based encapsulation devices to overcome key barriers in T1D treatment, paving the way for personalized, long-term solutions to restore insulin independence. Full article
(This article belongs to the Section Endocrinology & Metabolism)
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19 pages, 3979 KiB  
Article
The Fossil, the Green, and the In-Between: Life Cycle Assessment of Manufacturing Composites with Varying Bio-Based Content
by Ulrike Kirschnick, Bharath Ravindran, Manfred Sieberer, Ewald Fauster and Michael Feuchter
J. Compos. Sci. 2025, 9(3), 93; https://doi.org/10.3390/jcs9030093 - 20 Feb 2025
Viewed by 893
Abstract
Bio-based composites offer potential environmental benefits over fossil-based materials, but limited research exists on manufacturing processes with varying material combinations. This study performs a cradle-to-grave Life Cycle Assessment of five composite types to evaluate the role of fully and partially bio-based composites, focusing [...] Read more.
Bio-based composites offer potential environmental benefits over fossil-based materials, but limited research exists on manufacturing processes with varying material combinations. This study performs a cradle-to-grave Life Cycle Assessment of five composite types to evaluate the role of fully and partially bio-based composites, focusing on the manufacturing stage. The composite materials include glass or flax fiber-based reinforcements embedded in polymer matrices based on a fossil epoxy, a partially bio-based epoxy, or epoxidized linseed oil, fabricated using vacuum-assisted resin infusion. Flax fibers in a partially bio-based epoxy achieve the lowest environmental impacts in most categories when assessed at equal geometry. Glass fiber composites exhibit a higher fiber volume content and material properties and thus demonstrate competitive environmental performance at equal absolute and normalized tensile strength. Composites using epoxidized linseed oil are the least advantageous, with the manufacturing stage contributing a majority of the environmental impacts due to their comparatively long curing times. These results are based on methodological choices and technical constraints which are discussed together with benchmarking against previous studies. While partially bio-based materials can provide a middle ground for enhancing composite environmental performance, the further optimization of bio-based material functionality regarding material properties and processability is pivotal to exploit the full potential of bio-based composites. Full article
(This article belongs to the Special Issue Feature Papers in Journal of Composites Science in 2024)
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26 pages, 6595 KiB  
Review
Reviews of Fiber-Reinforced Phenolic Resin-Based Thermal Protection Materials for Aircraft
by Xuenan Wang, Qianghui Xu, Qiang Zheng, Yi Shao and Jun Shen
Energies 2025, 18(4), 819; https://doi.org/10.3390/en18040819 - 10 Feb 2025
Cited by 3 | Viewed by 1635
Abstract
As advancements in aerospace technology continue, reentry conditions pose increasingly rigorous requirements for thermal protection materials. Among these, fiber-reinforced phenolic resin composites have drawn substantial interest for their robust thermal insulation capabilities and enhanced ablation resistance, mechanical strength, and long-term reliability. This paper [...] Read more.
As advancements in aerospace technology continue, reentry conditions pose increasingly rigorous requirements for thermal protection materials. Among these, fiber-reinforced phenolic resin composites have drawn substantial interest for their robust thermal insulation capabilities and enhanced ablation resistance, mechanical strength, and long-term reliability. This paper provides a comprehensive review of recent developments in fiber-reinforced phenolic resin composites, examining factors such as resin density, nanopore size within the matrix, resin cross-linking density, fiber–resin interfacial bonding, fiber length, fiber crystallization degree, and fiber weave structures that collectively influence composite performance. The typical applications of these composites in ultrahigh-speed aircraft are also discussed. Furthermore, the paper offers recommendations for future advancements focusing on optimizing mechanical, ablative, and insulation properties to meet the multifunctional demands of thermal protection materials. Full article
(This article belongs to the Section J1: Heat and Mass Transfer)
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17 pages, 1208 KiB  
Systematic Review
Revolutionizing Restorative Dentistry: The Role of Polyethylene Fiber in Biomimetic Dentin Reinforcement—Insights from In Vitro Research
by Álvaro Ferrando Cascales, Andrea Andreu Murillo, Raúl Ferrando Cascales, Rubén Agustín-Panadero, Salvatore Sauro, Carmen Martín Carreras-Presas, Ronaldo Hirata and Artiom Lijnev
J. Funct. Biomater. 2025, 16(2), 38; https://doi.org/10.3390/jfb16020038 - 22 Jan 2025
Cited by 2 | Viewed by 3251
Abstract
Recent advancements in biomimetic dentistry have introduced innovative materials designed to better simulate natural dentin. One such material is Ribbond®, long polyethylene fiber. It is particularly effective in absorbing and redistributing masticatory forces in teeth with substantial dentin loss. This review [...] Read more.
Recent advancements in biomimetic dentistry have introduced innovative materials designed to better simulate natural dentin. One such material is Ribbond®, long polyethylene fiber. It is particularly effective in absorbing and redistributing masticatory forces in teeth with substantial dentin loss. This review aims to analyze the literature on the biomimetic restorative technique using long polyethylene fiber and assess its benefits and indications relative to traditional cusp coverage restorations. Methods: A search was conducted in the PubMed database until March 2024. The authors selected in vitro studies that studied long polyethylene fiber as a dentin reinforcement. Results: From 247 potentially relevant articles, eighteen studies were included in the review. A detailed analysis of the reviewed literature was summarized into three principal sections involving the use of long polyethylene fiber in restorative dentistry. Conclusions: Long polyethylene fibers improve fracture resistance and promote favorable fracture modes, helping to mitigate the shrinkage forces in composite restorations. However, their clinical significance over traditional cusp coverage is unclear. Full article
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39 pages, 11956 KiB  
Review
Comprehensive Review: Optimization of Epoxy Composites, Mechanical Properties, & Technological Trends
by Jozef Jaroslav Fekiač, Michal Krbata, Marcel Kohutiar, Róbert Janík, Lucia Kakošová, Alena Breznická, Maroš Eckert and Pavol Mikuš
Polymers 2025, 17(3), 271; https://doi.org/10.3390/polym17030271 - 22 Jan 2025
Cited by 15 | Viewed by 5287
Abstract
Epoxy composites play a crucial role in modern materials technologies, with their exceptional properties such as high strength and thermal and chemical resistance, making them ideal for a wide range of industrial applications, including aerospace, automotive, construction, and energy. This review article provides [...] Read more.
Epoxy composites play a crucial role in modern materials technologies, with their exceptional properties such as high strength and thermal and chemical resistance, making them ideal for a wide range of industrial applications, including aerospace, automotive, construction, and energy. This review article provides a comprehensive overview of the current trends and advancements in epoxy composites, focusing on mechanical properties and their optimization. Attention is given to technological innovations, including the use of nanotechnologies, hybrid reinforcement, and eco-friendly materials, which are key to enhancing the performance and sustainability of these materials. The analysis shows that the introduction of nanomaterials, such as graphene, titanium dioxide, and silicon dioxide, can significantly improve the strength, fatigue resistance, and electrical properties of epoxy composites, opening new possibilities in advanced technologies. Another significant contribution is the development of hybrid composites, which combine different types of fibers, such as carbon, aramid, and glass fibers, enabling the optimization of key properties, including interlayer strength and delamination resistance. The article also highlights the importance of environmental innovations, such as bio-based resins and self-healing mechanisms, which enable more sustainable and long-term effective use of composites. The combination of theoretical knowledge with practical applications provides valuable guidance for designing materials with precisely defined properties for future industrial use. This text thus offers a comprehensive view of the possibilities of epoxy composites in the context of increasing demands for performance, reliability, and environmental sustainability. Full article
(This article belongs to the Special Issue Advances in High-Performance Polymer Materials)
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17 pages, 31563 KiB  
Article
The Influence of pH Environments on the Long-Term Durability of Coir Fiber-Reinforced Epoxy Resin Composites
by Liangyong Li, Juntong Wang and Tianxiang Peng
Sustainability 2025, 17(1), 364; https://doi.org/10.3390/su17010364 - 6 Jan 2025
Cited by 1 | Viewed by 1664
Abstract
This study investigates the effects of different pH environments on the durability of coir fiber-reinforced epoxy resin composites (CFRERCs). The CFRERCs were prepared by combining alkali-treated coir fibers with epoxy resin and exposing them to acidic, alkaline, pure water, and seawater environments for [...] Read more.
This study investigates the effects of different pH environments on the durability of coir fiber-reinforced epoxy resin composites (CFRERCs). The CFRERCs were prepared by combining alkali-treated coir fibers with epoxy resin and exposing them to acidic, alkaline, pure water, and seawater environments for a 12-month corrosion test. The results show that an alkaline environment has the most significant impact on the tensile strength of CFRERCs, with a 55.06% reduction after 12 months. The acidic environment causes a 44.87% decrease in strength. In contrast, tensile strength decreases by 32.98% and 30.03% in pure water and seawater environments, respectively. The greatest reduction in tensile strain occurs in the alkaline environment, with a decrease of 36.45%. In the acidic environment, tensile strain decreases by about 25.56%, while in pure water and seawater, the reductions are 18.78% and 22.65%, respectively. In terms of stiffness, the alkaline environment results in a 49.51% reduction, while the acidic environment causes a 54.56% decrease. Stiffness decreases by 43.39% in pure water and 36.72% in seawater. Field emission scanning electron microscope (FE-SEM) analysis shows that corrosive agents in different pH environments cause varying degrees of damage to the microstructure of CFRERCs. In the acidic environment, corrosive agents erode the fiber–resin interface, leading to delamination and fiber breakage. In the alkaline environment, corrosive agents penetrate the fiber interior, increasing surface roughness and porosity. While pure water and seawater also cause some damage, their effects are relatively mild. Full article
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15 pages, 1780 KiB  
Article
Relaxation Modeling of Unidirectional Carbon Fiber Reinforced Polymer Composites Before and After UV-C Exposure
by Flavia Palmeri and Susanna Laurenzi
Fibers 2024, 12(12), 110; https://doi.org/10.3390/fib12120110 - 11 Dec 2024
Cited by 1 | Viewed by 1363
Abstract
Carbon fiber-reinforced polymers (CFRPs) are widely used in aerospace for their lightweight and high-performance characteristics. This study examines the long-term viscoelastic behavior of CFRP after UV-C exposure, simulating low Earth orbit conditions. The viscoelastic properties of the polymer were evaluated using dynamic mechanical [...] Read more.
Carbon fiber-reinforced polymers (CFRPs) are widely used in aerospace for their lightweight and high-performance characteristics. This study examines the long-term viscoelastic behavior of CFRP after UV-C exposure, simulating low Earth orbit conditions. The viscoelastic properties of the polymer were evaluated using dynamic mechanical analysis and the time-temperature superposition principle on both unexposed and UV-C-exposed samples. After UV-C exposure, the polymer’s instantaneous modulus decreased by about 15%. Over a 32-year period, the modulus of the unexposed resin is expected to degrade to approximately 25% of its initial value, while the exposed resin drops to around 15%. These experimental results were incorporated into finite element method models of a unidirectional CFRP representative volume element. The simulations showed that UV-C exposure caused only a slight reduction in the CFRP’s axial relaxation coefficient along the fiber’s axis, with no significant time-dependent degradation, as the fiber dominates this behavior. In contrast, the axial relaxation coefficient perpendicular to the fiber’s axis, as well as the off-diagonal and shear relaxation coefficients, showed more notable changes, with an approximate 10% reduction in their initial values after UV-C exposure. Over 32 years, degradation became much more severe, with differences between the pre- and post-exposure coefficient values reaching up to nearly 60%. Full article
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