Search Results (191)

Polycyclic aromatic hydrocarbons (PAHs) are persistent organic pollutants with significant ecological and public health implications, particularly in urban wetlands exposed to chronic anthropogenic stress. This study evaluates the occurrence, spatial distribution, seasonal variability, and ecological risk of three low molecular weight PAHs—naphthalene (NAP), phenanthrene (PHEN), and anthracene (ANT)—in surface waters of Caño La Malaria, the main freshwater source of Cucharillas Marsh, Puerto Rico’s largest urban wetland. Surface water samples were collected at four locations during both wet- and dry-season campaigns. Samples were extracted and quantified by GC-MS. NAP was the dominant compound, Σ3PAHs concentrations ranging from 7.4 to 2198.8 ng/L, with higher wet-season levels (mean = 745.79 ng/L) than dry-season levels (mean = 186.71 ng/L); most wet-season samples fell within the mild-to-moderate contamination category. Compositional shifts indicated increased levels of PHEN and ANT during the wet season. No significant spatial differences were found (p = 0.753), and high correlations between sites (r = 0.96) suggest uniform input sources. Diagnostic ratios, inter-species correlations, and principal component analysis (PCA) consistently indicated a predominant pyrogenic origin, with robust PHEN–ANT correlation (r = 0.824) confirming shared combustion-related sources. PCA revealed a clear separation between dry- and wet-season samples, with the latter showing greater variability and stronger associations with NAP and ANT. Ecological risk assessment using hazard quotients (HQ_water) indicated negligible acute toxicity risk across all sites and seasons (<0.01); the highest HQ_water (0.0095), observed upstream during the wet season, remained within this range. However, benchmark exceedances by PHEN and ANT suggest potential chronic risks not captured by the acute ERA framework. These findings support integrated watershed management practices to mitigate PAH pollution and strengthen long-term ecological health in tropical urban wetlands. Full article

Urban park green space (UPGS) is a key component of urban green infrastructure, yet it faces multiple contradictions, such as insufficient quantity and uneven distribution. Taking Zhengzhou City as a case study, this research explored the impacts of temporal thresholds and the modifiable areal unit problem (MAUP) on UPGS accessibility and equity. An improved multi-modal Gaussian two-step floating catchment area (G2SFCA) method was employed to measure UPGS accessibility, while the Gini coefficient and Lorenz curve were used to analyze its equity. The results show that (1) UPGS presents a dual-core agglomeration feature, with accessibility blind spots surrounding the edge of the study area and relatively low equity in the western and southern regions; (2) changes in temporal thresholds and spatial scales have a significant impact on UPGS accessibility (p < 0.001), whereas their impact on equity is minor; and (3) UPGS distribution suffers from spatial imbalance, with a huge disparity in resource allocation. This study overcomes the limitations of traditional evaluation methods that rely on a single mode or ignore scale effects and provides a more scientific analytical framework for accurately identifying the spatial heterogeneity of UPGS accessibility and the imbalance between supply and demand. Full article

Water is a critical resource for both environmental integrity and human health. This study assessed the concentrations of potentially toxic elements (PTEs)—Pb, Cd and Hg—in surface waters adjacent to six urban settlements within the Barranca de Metztitlán Biosphere Reserve (MBR), Mexico. Ecological and health risks were evaluated for vulnerable groups, including children, adolescents, and the elderly. Cd and Hg water concentrations surpassed the national and international water quality criteria at three locations. Ecological and health risk analysis of Pb was not conducted as Pb concentrations were below LOD (0.02 ppm). Ecological risk analysis revealed a low potential risk for Cd exposure but a high risk for Hg at its highest concentration in the reserve. Health risk assessment revealed that Cd and Hg pose a non-carcinogenic risk, particularly to children under three years old. Hazard quotients (HQ) and cumulative risk indices (HI) exceeded safe thresholds at multiple sites. Infants (0–11 months) were the most susceptible, even at contaminant levels near detection limits. These findings emphasize the importance of routine monitoring and early intervention strategies to mitigate exposure risks, especially in vulnerable populations within the MBR. Full article

This paper defines the term “graffiti” and outlines the origins of this concept. The terminological arrangement allowed for the subject of this research, i.e., illegal graffiti, to be situated in reality, i.e., an urban space. It was assumed that the existence of the tag was associated with a disturbance of spatial order and had an impact on safety in a space. This, in turn, is related to whether the principles of sustainable development in the social dimension are applied. This paper makes reference to theories of security in a space (the “broken windows” theory and the strategy of Crime Prevention Through Environmental Design, CPTED) and shows the problem of illegal graffiti against the background of these theories. A new research aspect of the occurrence of illegal graffiti (scribbles and tags) within urban space is the features that determine its emergence in a spatial dimension. The aim of the analyses in this paper is to obtain information on which geospatial features are generators of illegal graffiti. The research field was limited to the space of one city—Olsztyn—with the assumption that the proposed research methodology would be useful for the spaces of other cities. The research methodology consists of several steps: firstly, we determined a list of features in the surroundings of illegal graffiti using direct interviews, and secondly, we analyzed the frequency of occurrence of these features in the researched locations in space. The next step was to standardize the obtained results using the quotient transformation method with respect to a reference point, where the reference point is the sum of all observations. After that, we assigned ranks for standardized results. The last stage involved an analysis using the GRA type of grey systems to obtain a sequence of strengths of relationships. This sequence allowed us to determine which of the features adopted for analysis have the greatest impact on the creation of illegal graffiti in a space. As indicated by the strength of the relationship, in the analyses conducted, geospatial features such as poor sidewalk condition and neglected greenery have the greatest impact on the occurrence of illegal graffiti. Other features that influence the occurrence of illegal graffiti in a given space include a lack of visibility from neighboring windows and the proximity of a two-way street. It can be assumed that these features are generators of illegal graffiti in the studied area and space. The poor condition of the facade has the least impact on the possibility of illegal graffiti occurring in a given space. Full article

Toponym groups are fundamental units of quantitative spatial analysis of toponyms. Using suitable technical methods to investigate the spatial distribution and co-occurrence characteristics of these groups has significant implications for identifying cultural regions within geographical spaces and elucidating spatial differentiation and integration of regional cultural characteristics underlying toponyms. Existing research has mainly relied on traditional spatial distribution models such as standard deviation ellipse (SDE) and kernel density estimation (KDE) to analyse the characters used in toponyms. In addition, few quantitative studies exist on the co-occurrence of multiple types of toponym groups from the perspective of words used in toponyms. This study introduced methods, including the local co-location quotient, to propose a general framework for toponymic co-occurrence research and a new toponymic co-occurrence index (TCOI). Data from 64,981 village toponyms in Liaoning Province, China, were used to analyse spatial co-occurrence characteristics of five high-frequency two-character village toponym groups. In addition, two high-frequency single-character toponym groups and three low-frequency two-character toponym groups were used for verification, with a simultaneous comparison of the SDE and KDE methods. The findings indicated that: (1) the proposed general framework and TCOI effectively support toponymic spatial measurement and have good applicability and expansibility; (2) the TCOI enables a more accurate scientific assessment of co-occurrence characteristics of toponymic groups at different scales, thereby enhancing the technical level of toponymic spatial measurement; (3) the TCOI for Liaoning Province was 28.63%, indicating that toponym groups exhibited a partially integrated yet relatively exclusive spatial distribution pattern. The spatial differentiation patterns of rural toponym cultural landscapes in Liaoning Province provide a scientific basis for promoting cultural geography research and strengthening toponym protection. Full article

This study investigates the concentrations of essential and trace elements (Ni, Cu, Fe, Zn, Mn, and Al) in packaged ice cream samples collected from markets in Kırşehir province, located in Central Anatolia, Turkey, aiming to assess potential health risks associated with their consumption. Among the detected trace elements, Al (3.21–16.6 mg/kg) and Fe (2.03–24.0 mg/kg) had the highest concentrations, followed by Zn (0.56–3.00 mg/kg), Ni (0.84–4.84 mg/kg), Cu (1.15–3.46 mg/kg), and Mn (0.18–1.56 mg/kg). To explore the relationships between trace elements and identify possible contamination sources, chemometric approaches including principal component analysis, correlation matrices, and hierarchical cluster analysis (Ward’s method) were applied. Human health risk assessment was conducted by calculating Estimated Daily Intake (EDI), Target Hazard Quotient (THQ), Hazard Index (HI), and Carcinogenic Risk (CR), with uncertainty evaluated through Monte Carlo Simulation (10,000 iterations). HI values above 1 in children and adults indicate that trace element exposure through ice cream consumption may pose a health risk. High Al-THQ and Ni-CR values in children may require stricter monitoring and regulatory measures in case of long-term and regular consumption. Full article

Decades of unregulated zinc mining activities in the Mae Tao watershed, located in Mae Sot District, Tak Province, northern Thailand, have resulted in the pervasive contamination of agricultural soils with heavy metals, particularly cadmium (Cd), zinc (Zn), lead (Pb), and manganese (Mn). This legacy pollution has significantly impacted multiple environmental compartments—including surface water, groundwater, and sediments—and poses chronic health risks to local populations. This study investigates the key geochemical and physicochemical factors governing the leachability and mobility of these metals from contaminated soils and evaluates the associated human health risks. Controlled leaching experiments demonstrated that ionic strength exerts a more pronounced influence on metal mobilization than pH or other tested variables, suggesting that the electrolyte composition of pore water plays a dominant role in heavy metal transport. Despite elevated total concentrations of Cd, Zn, Pb, and Mn in the soils, hazard quotient (HQ) calculations indicated no significant non-carcinogenic risk under typical exposure scenarios. However, Cd exhibited a carcinogenic risk above the acceptable threshold at both average and peak soil concentrations, underscoring its potential to adversely affect human health. These findings enhance the understanding of heavy metal behavior in contaminated agroecosystems and provide a scientific basis for targeted risk management and long-term monitoring strategies in the Mae Sot region. Full article

In response to the European Union’s revised Urban Wastewater Treatment Directive, which mandates enhanced monitoring and advanced treatment of micropollutants, this study was conducted. It took place within the Coastal Landscape Park (CLP), a Natura 2000 protected area in northern Poland. The focus was on the municipal wastewater treatment plant in Jastrzębia Góra, located in a region exposed to seasonal tourist pressure and discharging effluent into the Czarna Wda River. A total of 90 wastewater samples were collected during five monitoring campaigns (July, September 2021; February, May, July 2022) and analysed for 13 pharmaceuticals and personal care products (PPCPs) using ultra-high-performance liquid chromatography tandem mass spectrometry with electrospray ionisation (UHPLC-ESI-MS/MS). The monitoring included both untreated (UTWW) and treated wastewater (TWW) to assess the PPCP removal efficiency and persistence. The highest concentrations in the treated wastewater were observed for metoprolol (up to 472.9 ng/L), diclofenac (up to 3030 ng/L), trimethoprim (up to 603.6 ng/L) and carbamazepine (up to 2221 ng/L). A risk quotient (RQ) analysis identified diclofenac and LI-CBZ as priority substances for monitoring. Multivariate analyses (PCA, HCA) revealed co-occurrence patterns and seasonal trends. The results underline the need for advanced treatment solutions and targeted monitoring, especially in sensitive coastal catchments with variable micropollutant presence. Full article

Spatial association analysis is essential for understanding interdependencies, spatial proximity, and distribution patterns within spatial data. The spatial scale is a key factor that significantly affects the result of spatial association mining. Traditional methods often rely on a fixed distance threshold (bandwidth) to define the scale effect, which can lead to scale sensitivity and discontinuity results. To address these limitations, this study introduces the Fuzzy Geographically Weighted Colocation Quotient (FGWCLQ) method. By integrating fuzzy theory, FGWCLQ replaces binary distance cutoffs with continuous membership functions, providing a more flexible and stable approach to spatial association mining. Using Point of Interest (POI) data from the Beijing urban area, FGWCLQ was applied to explore both intra- and inter-category spatial association patterns among star hotels, transportation facilities, and tourist attractions at different fuzzy neighborhoods. The results indicate that FGWCLQ can reliably discover global prevalent spatial associations among diverse facility types and visualize the spatial heterogeneity at various spatial scales. Compared to the deterministic GWCLQ method, FGWCLQ delivers more stable and robust results across varying spatial scales and generates more continuous association surfaces, which enable clear visualization of hierarchical clustering. Empirical findings provide valuable insights for optimizing the location of star hotels and supporting decision-making in urban planning. The method is available as an open-source Matlab package, providing a practical tool for diverse spatial association investigations. Full article

Vegetables and fruits grown in urban areas pose a potential threat to human health due to contamination with heavy metals (HMs). This study aimed to identify and quantify the concentrations of heavy metals (Fe, Mn, Zn, Cu, Pb, Cd) in tomatoes, leafy vegetables, and fruits collected from 16 allotment gardens (AGs) located in Warsaw. A total of 112 samples were analyzed (72 vegetable and 40 fruit samples). Vegetables from AGs accumulated significantly higher levels of HMs than fruits. Leafy vegetables, particularly those cultivated near high-traffic roads, exhibited markedly elevated levels of Pb, Cd, and Zn compared to those grown in peripheral areas. Lead concentrations exceeded permissible limits by six to twelve times, cadmium by one to thirteen times, and zinc by 0.7 to 2.4 times. Due to high levels of Pb and Cd, tomatoes should not be cultivated in urban environments. Regardless of location, only trace amounts of HMs were detected in fruits. The greatest health risk is associated with the consumption of leafy vegetables. Lettuce should be considered an indicator plant for assessing environmental contamination. The obtained Hazard Index (HI) values indicate that only the tested fruits are safe for consumption. Meanwhile, the values of the Hazard Quotient (HQ) indicate no health risk associated with the consumption of lettuce, cherries, and red currants. Among the analyzed elements, Pb showed a higher potential health risk than other metals. This study emphasizes the need for continuous monitoring of HM levels in urban soils and the establishment of baseline values for public health purposes. Remediation of contaminated soils and the implementation of safer agricultural practices are recommended to reduce the exposure of urban populations to the risks associated with the consumption of contaminated produce. In addition, the safety of fruits and vegetables grown in urban areas is influenced by the location of the AGs and the level of industrialization of the agglomeration. Therefore, the safety assessment of plant products derived from AGs should be monitored on a continuous basis, especially in vegetables. Full article

Residential segregation remains a persistent challenge in European urban environments and is an increasing focal point in urban policy debates. This study investigates the changing geographies of ethnic diversity and residential segregation in Riga, the capital city of Latvia. The research addresses the complex dynamics of ethnic residential patterns within the distinctive context of post-socialist urban transformation, examining how historical legacies of ethnic diversity interact with contemporary migration flows to reshape neighborhood ethnic composition. Using geo-referenced data from 2000, 2011, and 2021 census rounds, we examined changes in the spatial distribution of five major ethnic groups. Our analysis employs the Dissimilarity Index to measure ethnic residential segregation and the Location Quotient to identify the residential concentration of ethnic groups across the city. The findings reveal that Riga’s ethnic landscape is undergoing a gradual yet impactful transformation. The spatial distribution of ethnic groups is shifting, with the increasing segregation of certain groups, particularly traditional ethnic minorities, coupled with a growing concentration of Europeans and non-Europeans in the inner city. The findings reveal distinctive patterns of ethnic diversification and demographic change, wherein long-term trends intersect with contemporary migration dynamics to produce unique trajectories of ethnic residential segregation, which differ from those observed in Western European contexts. However, the specific dynamics in Riga, particularly the persistence of traditional ethnic minority communities and the emergence of new ethnic groups, highlight the unique context of post-socialist urban landscapes. Full article

This study evaluated the phenolic, carotenoid, and elemental compositions of three hawthorn species—Crataegus: C. tanacetifolia (yellow), C. orientalis (orange), and C. microphylla (red)—collected from Şebinkarahisar, Türkiye. Liquid chromatography tandem mass spectrometry (LC-MS-MS) analysis revealed that C. microphylla had the highest phenolic content, notably epicatechin, gallic acid, and quercetin. It also showed the highest levels of β-carotene and lutein, highlighting its nutraceutical potential. C. orientalis was rich in rutin and taxifolin. Inductively coupled plasma mass spectrometry (ICP-MS) results showed significant mineral content, including Fe, Mn, Ca, and Se. About 60 g of dried hawthorn could meet 7–8% of daily selenium needs. In C. tanacetifolia, toxicological tests showed no substantial health hazards, with target hazard quotient (THQ) values below 1 and carcinogenic risk (CR) values within tolerable levels (e.g., Ni-CR: 4.68 × 10⁻⁵). Lead (Pb) and arsenic (As) levels were below detection thresholds in all samples, indicating that hawthorn fruits from this location are safe. The study also shows how species-specific and geographical factors affect hawthorn fruit nutrition and safety. Full article

Long-term irrational farming practices and low return of organic materials to the fields in the black soil area have led to reduced soil carbon and nitrogen stability and nutrient imbalance, which in turn affect soil fertility and crop yields. Straw return is an effective way to enhance soil organic matter and crop productivity, but the effects of long-term straw return under tilling practices on carbon and nitrogen sequestration and soil microbial stoichiometric equilibrium in black soil need to be further investigated. This study investigated the physical, chemical and biological properties of the 0–60 cm soil layer under deep tillage with straw return to the field (DTS), deep harrow with straw return to the field (DHS), rotary tillage with straw return to the field (RTS), no tillage with straw return to the field (NTS), and conventional tillage with straw removal (CT) on the basis of seven consecutive years of tillage pattern location trials in the black soil area of eastern Inner Mongolia. The results showed that DTS and NTS significantly increased the soil organic carbon (SOC), soil total nitrogen (TN), soil microbial biomass carbon (MBC), soil microbial biomass nitrogen (MBN) contents, and the SOC/TN ratio in the 0–40 cm soil layer, enhancing soil carbon and nitrogen sequestration capacity, while the concomitant increase in the average MBC/MBN ratio in the plow layer from 6.8 to 8.2. The soil microbial quotient increased by 29.0% and 26.2%, respectively, and the stoichiometric imbalance ratio decreased by 7.9% and 5.7%, respectively. Meanwhile, in terms of maize yield from 2018 to 2024, DTS showed the most stable and significant yield increase with 41.53%. Whereas NTS showed a higher yield increase potential with a 27.36% increase in yield as the number of years of straw return increased. Therefore, DTS and NTS are superior tillage methods to improve the quality of the black soil tillage layer, to promote soil microbial carbon and nitrogen balance, and to increase crop yields. Full article

This article examines the relevance of Smart Specialisation Strategies (RIS3) in structurally weak but non-peripheral regions, using Poland’s Lubusz Voivodeship as a case study. Based on employment data from 2009 and 2021, this study uses Location Quotient (LQ) analysis to evaluate the alignment between the region’s economic structure and its RIS3 domains: Innovative Industry, Health and Quality of Life, and Green Economy. The findings show that while Innovative Industry and Health and Quality of Life strengthened their relative specialisation, the Green Economy domain made only limited progress. Notably, sectors such as metal fabrication and social care services emerged as new specialisations, while several traditional industries declined. These results support the hypothesis that RIS3 priorities only partially reflect endogenous economic strengths, and they highlight the challenges of implementing innovation strategies in territorially fragmented and capacity-constrained regions. This article calls for dynamic priority reviews, improved multi-level coordination, and targeted instruments to better align RIS3 frameworks with the structural realities of “in-between” regions in the EU. Full article

Culture represents the core and ultimate value of a city, serving as a foundation for its economic and social development. However, with rapid urban expansion and increasing globalization, issues related to the spatial distribution pattern, accessibility and equity of cultural resources have become more prominent. This study proposes an integrated GIS-based framework combining ANN, Kernel Density, accessibility, and LQ analyses. It evaluates cultural service coverage across walking, cycling, and driving modes under varying travel durations (5–30 min). Both area-based accessibility and residential-based accessibility are considered. Additionally, the study incorporates Location Quotient (LQ) Analysis for low-income communities across these travel modes and accessibility types to assess spatial equity. The framework is validated through a case study of red cultural resources in Shanghai (China). The results show significant mismatches between area accessibility and residential accessibility in certain administrative districts, particularly highlighting disparities in cultural service provision for disadvantaged populations. These findings suggest incorporating residential-oriented accessibility and equity-based metrics into planning practices. This method supports more accurate and equitable allocation of cultural resources and informs evidence-based decisions in facility planning, urban function optimization, and spatial management. Full article