Search Results (1,002)

Liquid electrolytes in conventional lithium-ion batteries pose safety risks associated with flammability, leakage, and explosion, whereas solid polymer electrolytes are generally limited by insufficient ionic conductivity at ambient temperature, restricting the development of high-energy lithium batteries. To address these issues, flexible poly (vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP)-based gel polymer electrolyte membranes (GPEs) were prepared via a slit-coating process combined with UV curing. NASICON-type lithium aluminum titanium phosphate (Li_1.3Al_0.3Ti_1.7P₃O₁₂, LATP) and garnet-type tantalum-doped lithium lanthanum zirconate (Li_6.4La₃Zr_1.4Ta_0.6O₁₂, LLZTO) were introduced as inorganic ceramic fillers to improve the ion-transport and interfacial properties of the GPE. Among the investigated samples, the PVDF-HFP-based GPE containing 10 wt% LLZTO exhibited the best overall performance, with an ionic conductivity of 3.40 × 10⁻⁴ S·cm⁻¹ at ambient temperature and a Li⁺ transference number of 0.77. Cyclic voltammetry results showed that the LLZTO-modified electrolyte membrane exhibited sharper and more symmetric redox peaks, higher peak current response, and better curve overlap during repeated cycles, indicating improved electrochemical reversibility and interfacial stability. In addition, LLZTO incorporation enhanced the mechanical strength, broadened the electrochemical stability window, and improved the flame-retardant behavior of the membrane. The LiFePO₄/GPE/Li cell assembled with the optimized membrane delivered an initial discharge capacity of 160 mAh·g⁻¹ at 0.1 C and maintained 80 mAh·g⁻¹ at 1 C, demonstrating good rate capability. Moreover, a capacity retention of 96% was maintained after 100 cycles at 0.1 C, confirming excellent cycling stability. Therefore, this work provides an effective strategy for the structural optimization and scalable preparation of high-performance gel polymer electrolyte membranes for lithium battery applications. Full article

Short circuits and subsequent fires resulting from objects impacting the bottom of vehicle power battery packs considerably jeopardize electric vehicle (EV) operations. This study investigated underbody impacts in EVs and the overall mechanical properties of battery cells. Key features of road debris were extracted and simplified to establish a geometric parameter structure model and determine realistic battery pack responses to debris impact. Quasi-static compression and dynamic impact tests on a prismatic lithium-ion battery (LIB) and power battery pack followed. Macroscopic mechanical responses, deformation failure modes, and internal jellyroll damage of cells and packs were evaluated, and constitutive equations and failure parameters were derived to develop a finite element model, whose effectiveness and reliability were verified by comparing simulation results with experimental data. Finally, a homogenized model of the prismatic LIB and power battery pack was constructed, which effectively predicted the macroscopic mechanical response and internal short-circuit failure under mechanical loading. However, simulation and test results revealed certain deviations in cell indentations under battery pack bottom impacts, presumably because the FEMs neglect the dynamic strain rate effects of electrolyte and cooling liquid. Overall, this study elucidates safety risks to cells and their key components under power battery pack bottom impacts. Full article

Lithium-ion batteries (LIBs) are widely used across a range of applications; however, they degrade over time due to various factors, including repeated charge–discharge cycling, material aging, and environmental conditions. Degradation models play a crucial role in predicting the lifespan of LIBs and in optimizing their design and operational strategies. This paper presents a comprehensive review of state-of-the-art degradation models for LIBs. The reviewed models primarily address key degradation mechanisms, including solid electrolyte interphase (SEI) formation, lithium plating, and particle fracture. For each mechanism, the underlying modeling approaches, their development, advantages, limitations, and associated challenges are critically discussed. Finally, this review identifies existing gaps in battery degradation modeling and proposes the Unified Mechanics Theory (UMT), which is the unification of laws of Newton and the second law of thermodynamics, and uses entropy as a degradation metric, as a promising alternative framework for capturing the coupled and multifaceted nature of battery degradation processes. Full article

Polybenzimidazole (PBI) is a promising separator for lithium-ion batteries (LIBs) owing to its excellent thermal/chemical stability and mechanical strength, but its application is limited by poor solubility and processability. Herein, a novel ether-functionalized PBI was synthesized, and three-layer composite separators (PBIPHPE) were fabricated by electrospinning PBI/PVDF-HFP blends onto polyethylene (PE) substrate. The PBIPHPE separator exhibits high porosity (73.1%), superior electrolyte uptake (211.2%), and excellent ionic conductivity (1.125 mS/cm), with no dimensional change after thermal treatment at 150 °C for 0.5 h. Lithium-ion batteries assembled with PBIPHPE deliver an initial specific capacity of 157.7 mAh/g, retain 86.0% capacity after 400 cycles at 2 C, and show only 15.7% capacity decay from 0.2 C to 5 C. Molecular dynamics simulations of the composite separator–electrolyte system were performed to reveal Li⁺ transport behaviors. The results confirm that ether-functionalized PBIPHPEs enhance Li⁺ transport and cycling stability, providing a promising route for high-performance separators. Full article

Understanding lithium distribution and transport within Li-ion battery components is critical in improving battery longevity, safety and performance. This study investigates lithium concentration profiles across the interface of an aluminum-doped Li₇La₃Zr₂O₁₂ (Al-LLZO) solid electrolyte and a lithium metal anode using Nuclear Reaction Analysis (NRA), a non-destructive depth-profiling technique. The Al-LLZO electrolyte was synthesized via electrospinning, producing nanofibers, which were subsequently sintered into pellets of average thickness 380 µm. These pellets were integrated into a Li|Al-LLZO|NMC-111 half-cell and cycled at 0.1 C for 1, 3, and 10 cycles, indicating pronounced lithium accumulation at the electrolyte–anode interface. Using NRA, this study provided a clear pathway for better understanding lithium transport and interfacial behavior, by quantitatively measuring the lithium distribution at the Al-LLZO electrolyte–electrode interface, and to look at the changes at this interface over the battery cycles. Full article

Solid-state batteries (SSBs) are emerging as a transformative alternative to conventional lithium-ion batteries (LIBs) for next-generation electric vehicles (EVs) by replacing flammable liquid electrolytes with solid-state materials. Compared with current LIB systems delivering approximately 160–300 Wh/kg at the pack level, SSBs are projected to achieve 400–800 Wh/kg, enabling improvements in driving range of nearly 50–100% while simultaneously reducing battery pack mass by 10–30%. These improvements directly enhance vehicle-level energy efficiency by lowering energy consumption from typical values of 150–180 Wh/km in present EVs to projected levels of 110–140 Wh/km in optimized SSB-based architectures. Furthermore, reduced internal resistance and improved electrochemical stability can increase round-trip efficiency from approximately 85–95% in conventional LIBs to values approaching 95–98% under optimized solid-state configurations. The enhanced thermal stability of solid electrolytes significantly reduces the need for active cooling systems, decreasing parasitic thermal-management energy consumption from 10–30% of total vehicle energy demand to below 5–15% in advanced SSB systems. Fast-charging capability is also substantially improved, with projected charging times decreasing from 20–40 min to approximately 10–15 min for 10–80% state-of-charge operation, while maintaining improved safety and reduced risk of thermal runaway. In addition, SSBs demonstrate projected cycle lifetimes exceeding 3000–5000 cycles, compared with 1000–2000 cycles for conventional LIBs, thereby lowering battery replacement frequency and lifecycle energy losses. This paper examines the electrochemical fundamentals, thermal behavior, charging/discharging efficiency, and vehicle-level implications of SSB technology for EV applications. Comparative analyses demonstrate that replacing LIBs with SSBs can increase EV driving range from approximately 400 km to 700–800+ km under equivalent battery mass conditions, while also improving coulombic efficiency beyond 99.5% and reducing self-discharge rates to below 1–2% per month. Current industrial case studies from Toyota, Factorial Energy, Mercedes-Benz, CATL, BYD, QuantumScape, and Samsung SDI further confirm accelerating commercialization pathways toward 2027–2030. Overall, the study demonstrates that SSBs are not merely incremental battery improvements but represent a system-level efficiency technology capable of simultaneously enhancing energy density, reducing thermal and electrical losses, extending vehicle range, accelerating charging, and improving long-term sustainability. Despite persistent challenges related to manufacturing scalability, interfacial resistance, and cost, SSBs are positioned to become a critical enabler of highly efficient, long-range, and safer electric mobility systems beyond 2030. Full article

Lithium-ion batteries have been widely used as energy storage and power batteries due to their unique advantages. However, with increasing demands for battery performance and application scenarios, battery safety has become a significant obstacle to their application. To address this issue, this paper proposes and fabricates an advanced polyimide (PI) separator material with high porosity and excellent thermal stability. By introducing sodium chloride (NaCl) as a pore-forming template into a polyamic acid (PAA) precursor, a PI-based separator with a uniformly interpenetrating sponge-like pore structure was successfully constructed. The obtained PI-NaCl separator exhibits outstanding thermal structural stability, maintaining dimensional integrity without significant thermal shrinkage even when tested at temperatures as high as 250 °C. Furthermore, the porous structure of the PI-NaCl separator demonstrates excellent electrolyte wettability, as the electrolyte rapidly spreads upon contact (contact angle approaching 0°), which is significantly superior to commercial separators. In lithium symmetric cell tests, this separator achieves long-term stable stripping/plating cycling by virtue of its outstanding ionic conductivity, effectively mitigating interfacial side reactions with lithium metal. In LiFePO₄||C full-cell applications, the PI-NaCl-based battery exhibits good rate capability and cycling stability. Additionally, in an open-circuit voltage (OCV) monitoring experiment at a high temperature of 80 °C, the voltage of the PI-NaCl-based battery remained stable continuously for 8 h in comparison to that of the commercial separator-based battery. Full article

Spent lithium-ion battery electrolytes contain fluorine-, sulfur-, and phosphorus-bearing toxins, necessitating deep detoxification and directional conversion into C₁–C₆ light hydrocarbons. To elucidate the specific catalytic roles and sequential activation of cathode metals (Li, Ni, Co, Mn), this work systematically deconvolutes their mono- and multi-metallic migration mechanisms over a CaO-ZSM-5* catalyst during vacuum catalytic pyrolysis (530 °C, 100 Pa). Results reveal that Li⁺ and Ni²⁺ dominate C–O bond cleavage in carbonates and CaO-ZSM-5*-assisted decarboxylation and oxygen fixation, significantly increasing the relative hydrocarbon content. Conversely, Co^2/3+ and Mn⁴⁺ release reactive oxygen species, causing deep oxidation of hydrocarbons into CO₂ and antagonizing the targeted conversion. In multi-metallic systems, forming composite metal oxides (M_xN_yO_z) increases the energy barrier for releasing active catalytic ions, hindering carbonate cleavage and leaving unreacted carbonate feedstocks. For detoxification, F and P are effectively immobilized as CaF₂ and Ca₂P₂O₇. The relative content of detected gas-phase nitriles is minimized to <2% due to the strong antagonistic effect of Ni²⁺ on Li⁺-promoted hexanedinitrile cleavage, while sulfur species derived from 1,3-propane sultone are converted to SO₂ and ultimately mineralized as calcium and metal-sulfur salts. Mechanistically, product distributions and crystallographic properties suggest a hypothesized sequential activation model—Li⁺ → Ni²⁺ → Mn⁴⁺—governing reactivity, whereas Co^2/3+ does not participate in the synergistic detoxification and selective upgrading process. This migration–reaction coupling framework provides critical insights for cathode-assisted in situ catalytic pyrolysis and closed-loop electrolyte recycling. Full article

Over the past few years, laser structuring of electrodes has been shown as a powerful tool to significantly improve the rate capability and cycling ability of lithium-ion batteries. However, the impact of anode/cathode pattern combinations on electrochemical performance in full-cell configurations remains poorly understood. This work investigated for the first time the influence of laser structuring strategies and pattern combinations on the laser processing rate as well as the electrochemical performance of full cells containing NMC 811 cathodes and graphite anodes. Meanwhile, the mass losses due to laser ablation with different strategies were kept similar for cathodes and anodes. The line-patterning process exhibited a processing rate that was an order of magnitude higher than that for blind hole drilling. Moreover, line patterning of graphite anodes with an average laser power of 5.0 W showed a two to five times higher laser processing rate than with 2.5 W. Subsequently, the structured electrodes were cross-combined and assembled into full cells. All cells with laser-structured electrodes exhibited improved rate performance, reduced ionic resistance, and a shift in the onset of lithium plating to higher C-rates in comparison to the reference cells with unstructured electrodes. In particular, the cells with “Line 5 W” electrodes demonstrated excellent rate performance, delivering an increase of 72 mAh g⁻¹ in discharge capacity compared to the reference cells at 5C and achieving 80% state of charge in 18 min. The results indicated that line patterns enhance rate performance more effectively than hole patterns. Furthermore, wider grooves in the electrodes were produced using higher average laser power, which may provide larger electrolyte reservoirs. This could support the rewetting processes of the electrolyte in the electrodes during electrochemical cycling and thus significantly improve rate performance and cell lifetime. Full article

Lithium-ion batteries (LIBs) release significant amounts of toxic, corrosive, and flammable gases when they enter thermal runaway (TR). These emissions can be hazardous to human health, damage nearby equipment, pose fire and explosion risks, and degrade air quality. This study measured concentrations for a range of hazardous gases released from TR-driven combustion of cylindrical lithium iron phosphate (LFP) and pouch-style lithium cobalt oxide (LCO) LIB cells. Gas emissions were measured by dedicated analyzers and Fourier transform infrared spectroscopic (FTIR) analysis, and emission factors were calculated. Dangerous concentrations of hydrogen fluoride (HF) were observed, reaching up to 50 ppm from the combustion of single LIB cells. Large amounts of combustible electrolyte solvents and light hydrocarbons were released in some cases, depending on cell combustion behavior. Electrolyte solvents, hydrogen chloride (HCl), and particles were released earlier than other species and should be targeted for early TR detection. Gas emissions were correlated with cell state of charge (SOC) and combustion behavior. Cells at high SOCs had higher peak concentrations of HF, HCl, CO, and flammable hydrocarbons, and these peaks happened sooner after cell failure than for low-SOC tests. Full article

This study presents a novel approach to the use of kraft lignin in electrochemical energy sources, with a focus on its use as anode material. The key novelty of this study is the use of natural casein as an innovative binder in electrode production, offering a sustainable and efficient alternative to conventional binders. The carbonaceous material was obtained from kraft lignin by two heat treatments at a relatively low temperature of 300 °C—one in a nitrogen atmosphere and the other in air. The results indicate that carbonization at this lower temperature provides promising electrochemical properties while improving cost-effectiveness and energy efficiency compared to higher temperature processes. Additionally, wettability analysis based on contact-angle measurements revealed substantially improved electrolyte affinity for casein-based electrodes, which correlates with their enhanced electrochemical performance. The study showed promising performance of the developed electrodes as follows: a capacity of 67 F g⁻¹ for supercapacitor applications, 250 mAh g⁻¹ for lithium-ion batteries, and 50 mAh g⁻¹ for sodium-ion batteries. These results confirm that kraft lignin, in combination with casein as a binder, is an environmentally friendly and economically viable alternative to traditional electrode materials. Full article

Sodium-ion batteries (SIBs) are emerging as a viable alternative to lithium-ion batteries (LIBs) due to their material sustainability and cost-effectiveness, helping address the high costs, supply limits, and environmental concerns associated with lithium. This paper reviews SIB materials, designs, and applications, and surveys their electrochemical performance, challenges, and future prospects. Recent advances in electrode materials (e.g., layered oxides, hard carbon composites, metallic alloys) are greatly improving SIB stability, conductivity, capacity, and cycle life. Improvements in both solid-state and liquid electrolytes have likewise enhanced ionic conductivity, capacity retention, thermal stability, and safety. Despite their lower energy density, SIBs tolerate wider temperature ranges and carry a significantly lower risk of thermal runaway compared to lithium-based systems, making them attractive for industrial, transportation, and large-scale power storage. Continuous progress in materials and cell engineering is narrowing the performance gap between SIBs and LIBs. Meanwhile, nascent battery recycling strategies for SIBs show promise for economic and environmental viability. Overall, SIBs represent a promising option for safer, more accessible, and more sustainable energy storage technology. Full article

Prussian blue (PB) nanocubes have been explored as promising cathode materials for high-performance sodium-ion (SIBs) and lithium-ion batteries (LIBs). These nanostructures exhibit good cycling stability and electrochemical resilience. They are synthesized through a co-precipitation method followed by vacuum drying, resulting in a porous and conductive nanocube framework. This architecture facilitates efficient ion diffusion, enhanced electrolyte accessibility, and effective mitigation of volume changes during cycling. In SIB applications, the PB nanocubes maintain stable performance over 300 and 400 cycles at current densities of 0.05 and 0.1 A g⁻¹, respectively, and deliver a capacity of 26.2 mAh g⁻¹ at 2.0 A g⁻¹. For LIBs, they exhibit sustained cycling over 200 and 300 cycles under similar conditions, with a capacity of 20.2 mAh g⁻¹ at 2.0 A g⁻¹. These findings underscore the structural benefits of PB nanocubes for dual-ion battery systems. Full article

Thermal runaway (TR) remains a critical bottleneck for the safe application of lithium-ion battery (LIB) in large-scale energy storage systems, arising from the instability of battery materials under high temperatures. This review systematically summarizes materials design strategies to suppress TR, focusing on modifications of cathodes, anodes, separators, and electrolytes. For cathodes, surface coating and bulk doping enhance the structural stability and thermal decomposition temperature of high-Ni materials, while nanoscale engineering and carbon networks improve the electronic conductivity and interfacial stability of LiFePO₄ (LFP). For anodes, surface modification of graphite suppresses solid-electrolyte interphase degradation, and nanostructured silicon-based composites mitigate thermal failure caused by volume expansion. Separator functionalization, including ceramic coating, inorganic separators, and thermal shutdown separators, enhances thermo-mechanical stability and enables thermally triggered ion blocking. Flame-retardant electrolytes incorporate phosphorus-based, organosilicon, and halogenated additives that act through combined gas- and condensed-phase mechanisms. The review further discusses challenges in interfacial compatibility, system integration, and trade-offs among multiple performance metrics. Future efforts should focus on integrating intrinsic thermal stability with smart safety functions to achieve both high energy density and inherent safety. This review provides a systematic reference for the design and industrialization of high-safety materials for LIBs. Full article

The growing penetration of renewable energy sources has intensified the demand for safe, sustainable, and cost-effective energy-storage technologies. Aqueous lithium-ion batteries are promising candidates because of their intrinsic safety and high ionic conductivity, though their deployment is limited by narrow electrochemical stability window of water. Lithium titanate oxide (LTO) has emerged as an ideal anode material for aqueous systems because of its exceptional structural stability, negligible volume change during lithiation/delithiation, and relatively high operating potential that suppresses hydrogen evolution. This review examines the peer-reviewed literature (2010–2026) on LTO-based aqueous lithium-ion batteries, focusing on the interdependence between material synthesis, electrode fabrication, electrolyte engineering, and electrochemical performance. Scalable fabrication techniques, such as spray deposition and tape casting, are discussed alongside their pact on electrode quality. Attention is given to water-in-salt, gel-polymer, and localized high-concentration electrolytes that expand the stability window and improve interfacial behavior. Overall, the review highlights how electrolyte design, electrode architecture, and processing methods can be jointly tailored to support stable and scalable LTO-based aqueous lithium-ion batteries systems. Full article