Search Results (29)

This research assesses the impacts of five cleaner production (CP) profiles of soap products and the overall equipment effectiveness (OEE) of liquid detergent production lines. A simulation model was built to depict the “As-Is” condition, and then the overall equipment effectiveness was calculated. Results showed high rejection rates and bottlenecks, resulting in long average cycle times and waiting times, as well as low production rates and machine utilization. Consequently, lean, agile, and resilient actions were utilized to enhance the OEE of the line’s processes. The improvement results showed that the bottle placement, filling, labeling, and taping processes were enhanced by 237%, 4.67%, 5.41%, and 26.02%, respectively. Moreover, the smallest percentages of availability, quality, and performance were 97.46%, 99.82%, and 81.56%, respectively, indicating a considerable enhancement in the performance of the line’s processes. Further, cleaner production assessment was performed on soap products to estimate environmental profile indices for raw material, energy, product, waste, and packaging. The estimated overall environmental index was 107.93, with liquid waste contributing the largest index value. Therefore, a proposal for a water treatment system was suggested and then assessed. In conclusion, lean, agile, and resilient actions were found to be effective in enhancing the OEE of production processes. Moreover, cleaner production provided valuable support to decision-makers in determining the appropriate actions for improving the OEE and environmental performance of the technological processes and products of detergent production lines. Full article

In the silk production process, cocoons from Bombyx mori worm are degummed and separated from their components. This step generates large residual quantities of an aqueous solution containing various chemical substances, including sericin—a protein that, when discarded improperly, negatively impacts the environment. Sodium bicarbonate and coconut soap are commonly used in the degumming process. The phosphates in the soap and the sodium bicarbonate increase the biological oxygen demand (BOD) and chemical oxygen demand (COD), leading to water contamination. In this study, a Box–Behnken experimental design was used to maximize the extraction of sericin through a conventional extraction under chemical-free conditions. From a total of 45 experiments, the optimal extraction conditions were identified as a solid-to-liquid ratio of 1:20 w/v, a temperature of 120 °C, and 90 min of extraction time. Sericin yields ranged from 9% to 18%. Infrared spectroscopic characterization of the extracted sericin confirmed the presence of protein-specific functional groups and common interactions associated with β-sheet structures. Fractions of high molecular weight (50 kDa to 200 kDa), identified by means of Sodium dodecyl sulfate–polyacrylamide gel electrophoresis (SDS-PAGE) analysis, demonstrate the potential functionality of extracted sericin for the development of biopolymer films useful in biomedical and food industry applications. The optimized methodology is a good alternative to recycle the waste of sericulture chain for obtaining extracts enriched in sericin, as well as to promote the mechanization of artisanal production processes. Full article

This research aims to investigate and quantify the possible presence of microplastics (MPs) in usual skin-cleansing products (i.e., liquid soap, micellar water, and micellar cleansing oil), the most popular from the market in terms of brand and customer confidence. Therefore, optical microscopy and micro-Fourier transform infrared spectroscopy (micro-FTIR) were used to determine the MPs’ number, color, shape, size, and chemical composition. For the first time, the results were correlated with the possible exposure paths (i.e., inhalation, ingestion, or adsorption) to assess the human health risk of the analyzed micellar-based cleansers in terms of chronic total exposure dose to microplastics. Finally, a statistical analysis was added to this study for source prediction of MPs in skin-cleansing samples in terms of morphology, chemical composition, and other factors (i.e., brand, packaging, etc.). The various exposures and toxicities of MPs were assessed in terms of potential health risk, knowing that their toxic effect depends on the polymeric structure strongly linked with the size, shape, and concentration in the products. Full article

Slips and fall-related accidents cause a significant number of injuries in hospitals. Due to constant movement of doctors and nurses across different departments in hospitals such as OPD, trauma centres, and ICUs, there are possible interactions of their footwear with slippery floorings (e.g., wet or with soap suds), which may cause unexpected slips. To date, there is a lack of understanding on the traction of different footwear worn by hospital staff. This impedes the selection of appropriate floorings and footwear for preventing slips and falls in hospitals. In this work, the traction performances of twelve common footwear designs, worn by hospital staff, were tested on three different floorings at important locations, i.e., an outpatient department, trauma centre, and ICU entrance, at a busy public hospital. Oblique tread patterns are recommended for moderately rough floors under dry and Lizol conditions. Horizontally oriented patterns are better for smoother floors in dry conditions, while vertically oriented patterns are ideal for areas with frequent contaminant exposure. No specific recommendation can be made for soap-contaminated floors due to the contaminant’s high viscosity. The results also indicated the strong influence of flooring roughness on the measured traction, over footwear tread parameters. Also, liquid soaps were observed to significantly reduce footwear–floor traction. The findings are anticipated to be valuable to hospital management for the selection of appropriate high-traction floorings, and provide important guidelines for footwear selection, for the mitigation of slips and falls in hospitals. Full article

Gelled fuels are rheologically complex, non-Newtonian fluids. They combine the benefits of both liquid and solid states, reducing risks of leakage, spilling, and sloshing during storage while maintaining the ability to be sprayed inside a combustion chamber. Additionally, suspending energetic particles, such as metal powders of aluminum and boron, can significantly enhance their energy density compared to conventional liquid fuels. In this study, several kerosene-based and ethanol-based formulations were experimentally investigated, using both organic and inorganic gelling agents. The compositions were optimized in terms of the gellant amount and manufacturing process. Some of the most promising gellants for kerosene include fatty acids, such as Thixcin^® R or THIXATROL^® ST, and metallic soaps, such as aluminum stearate and zinc stearate. The effects of various co-solvents were assessed, including ketones (methyl isoamyl ketone, methyl ethyl ketone, and acetone) and alcohols (ethanol and octadecanol). Sugar polymers like hydroxypropyl cellulose were tested as gelling agents for ethanol. A preliminary rheological analysis was conducted to characterize their behavior at rest and under shear stress. Finally, a novel approach was introduced to study the stability of the gels under vibration, which was derived from a realistic mission profile of a ramjet. Finally, the ideal gravimetric specific impulse was evaluated through ideal thermochemical computations. The results showed that promising formulations can be found in both kerosene-based and ethanol-based gels. Such compositions are of interest in practical airbreathing applications as they have demonstrated excellent stability under vibration, ideal combustion properties, and pronounced shear-thinning behavior. Full article

In this study, online ambient volatile organic compounds (VOCs) were collected at an urban site of Zhengzhou in Central China during February 2018. The VOCs characteristics, source contributions and the Chinese New Year (CNY) effects have been investigated. During the sampling period, three haze periods have been identified, with the corresponding VOCs concentrations of (92 ± 45) ppbv, (62 ± 18) ppbv and (83 ± 34) ppbv; in contrast, the concentration during non-haze days was found to be (57 ± 27) ppbv. In addition, the festival effects of the CNY were investigated, and the concentration of particulate matter precursor decreased significantly. Meanwhile, firework-displaying events were identified, as the emission intensity had been greatly changed. Both potential source contribution function (PSCF) and the concentration weighted trajectory (CWT) models results indicated that short-distance transportation was the main influencing factor of the local VOCs pollution, especially by transport from the northeast. Source contribution results by the positive matrix factorization (PMF) model showed that vehicle exhaust (24%), liquid petroleum gas and natural gas (LPG/NG, 23%), coal combustion (21%), industrial processes (16%) and solvent usages (16%) were the major sources of ambient VOCs. Although industry and solvents have low contribution to the total VOCs, their secondary organic aerosol (SOA) contribution were found to be relatively high, especially in haze-1 and haze-3 periods. The haze-2 period had the lowest secondary organic aerosol potential (SOAp) during the sampling period; this is mainly caused by the reduction of industrial and solvent emissions due to CNY. Full article

The objective of this study was to develop effervescent cleansing tablets that can be dissolved and turned into liquid soap, which can be used for bathing or soaking the body. The asiatic-acid-loaded solid lipid microparticles (AASLMs) were prepared via the hot emulsification method followed by cold re-solidification and then freeze-dried to obtained dry powder. The physicochemical properties such as morphology and % entrapment efficiency (%EE) were evaluated. The results revealed that AASLMs have an irregular shape, and the %EE for the resulting AASLMs was 92.04 ± 3.43%. The tablets were manufactured via the direct compression technique. The compatibility test was conducted to ensure that the excipients are compatible with the active ingredient. The angle of repose, Carr’s index, and Hausner’s ratio were studied to evaluate the flowability of the powder blend before compression. The weight of each tablet was set to 1000 mg, and physicochemical characteristics, in vitro dissolution, ex vivo cleansing efficacy, and stability were evaluated. The results showed that the active ingredient was compatible with other excipients, as the results obtained from FTIR spectra indicated the absence of potential chemical interaction between the active ingredient and excipients used in this study. Additionally, all formulations had good flow properties. The effervescence times of selected formulations, F2 and F3, were <5 min, with favorable pH and hardness values. The friability values of all formulations exceeded 1% because the excipients used in effervescent tablets are very fragile. The release of asiatic acid (AA) from the tablets was dependent on the concentration of SLS. In an ex vivo test, it was discovered that the developed products F2 and F3 showed much more effective cleansing efficacy than water. Nevertheless, brown spots appeared in the tablets and the AA content was significantly decreased in both tested formulations after 3 months’ storage at 40 ± 2 °C/75% RH ± 5% RH. The stability study revealed that the developed products were not stable at high temperature and humidity. Therefore, it is recommended that the developed effervescent tablets are not stored at a high temperature. Full article

Antiseptics, disinfectants, and hand hygiene products can act as reservoirs of Gram-negative bacteria causing healthcare-associated infections. This problem is rarely documented in low- and middle-income countries, particularly in sub-Saharan Africa. In a cross-sectional survey, we assessed the bacterial contamination of antiseptics, disinfectants, and hand hygiene products in two university hospitals in Burkina Faso and Benin. During ward visits and staff interviews, in-use products were cultured for the presence of Gram-negative bacteria. The growth of Gram-negative bacteria was absent or rare in alcohol-based products, povidone iodine, and Dakin solution. Contamination was highest (73.9% (51/69)) for liquid soap products (versus antiseptic/disinfectants (4.5%, 7/157) (p < 0.0001)), mostly used in high-risk areas and associated with high total bacterial counts (>10,000 colony-forming units/mL). Contaminating flora (105 isolates) included Enterobacterales and the Vibrio non-cholerae/Aeromonas group (17.1%) and non-fermentative Gram-negative rods (82.8%). Multidrug resistance was present among 9/16 Enterobacterales (Klebsiella and Enterobacter spp.) and 3/12 Acinetobacter spp., including carbapenem resistance (Acinetobacter baumannii: NDM, Pseudomonas stutzeri: VIM). The risk factors for contamination included the type of product (cleaning grade and in-house prepared liquid soap), use of recycled disposable containers and soft drink bottles, absence of labeling, topping-up of containers, dilution with tap water (pharmacy and ward), and poor-quality management (procurement, stock management, expiry dates, and period after opening). Full article

We conducted a systematic review of healthcare-associated outbreaks and cross-sectional surveys related to the contamination of antiseptics, disinfectants, and hand hygiene products in healthcare settings in low- and middle-income countries (PROSPERO CRD42021266271). Risk of bias was assessed by selected items of the ORION and MICRO checklists. From 1977 onwards, 13 outbreaks and 25 cross-sectional surveys were found: 20 from Asia and 13 from Africa. Products most associated with outbreaks were water-based chlorhexidine, chlorhexidine-quaternary ammonium compound combinations (7/13), and liquid soap products (4/13). Enterobacterales (including multidrug-resistant Enterobacter cloacae, Klebsiella pneumoniae, and Serratia marcescens) and non-fermentative Gram-negative rods were found in 5 and 7 outbreaks and in 34.1% and 42.6% of 164 isolates, respectively, from cross-sectional surveys. Risk factors included preparation (place, utensils, or tap water high and incorrect dilutions), containers (reused, recycled, or inadequate reprocessing), and practices (topping-up or too long use). Potential biases were microbiological methods (neutralizers) and incomplete description of products’ identity, selection, and denominators. External validity was compromised by low representativeness for remote rural settings and low-income countries in sub-Saharan Africa. Outstanding issues were water quality, biofilm control, field-adapted containers and reprocessing, in-country production, healthcare providers’ practices, and the role of bar soap. A list of “best practices” to mitigate product contamination was compiled. Full article

Due to their long history and extensive applications within modern society, foams have always been a popular topic of study. These systems are present everywhere in our life. They are also valuable in many industrial applications. For this reason, it is essential to continue investigating their properties and develop new materials to fabricate them. In this paper, we demonstrate a new way to create 3D foams by using an ordered viscoelastic material, the smectic liquid crystal (LC). Because of their lamellar structure, which is similar to soap, and their tunable properties that can be controlled via geometric confinement and external fields, smectic LCs are suitable for the fabrication of bubbles and foams. In this work, we present a compelling study of the parameters that influence the fabrication of LC foams in 3D. Particularly, we analyze the effects of the airflow rate and the geometry of confining boundaries on the assembly of their cells. We also compare our results to foams made with sodium dodecyl sulfate (SDS) and discuss the difference between their behaviors. Finally, we discuss how LC elasticity can substantially affect the stability and organization of foams. This work paves the way to exploiting new materials to fabricate foams with better monodispersity, uniformity, and controlled ordering that are useful in a wide range of industrial applications for which the tuning of properties is required. This includes the fields of oil recovery, decontamination, architecture, and design. Full article

Anthocyanins from juçara fruits were extracted by pressurized liquid extraction (PLE) or ultrasound-assisted extraction (UAE), using aqueous solutions of 1,2-alkanediols and glycerol ethers as biobased solvents. The PLE (100 bar, 13 min, 1 mL/min flow rate) in the optimal extraction conditions originated 23.1 mg_anthocyanins·g_{dry biomass}⁻¹. On the other hand, the UAE was 10 min long, and the optimal conditions using 1,2-propanediol were 42.6 wt%, 160 W, and pH 7.0, leading to 50 mg_anthocyanins·g_{dry biomass}⁻¹. Extractions at the UAE optimized conditions, with aqueous solutions of five different 1,2-alkanediols and three glycerol ethers were performed, and compared to water and ethanolic extracts. The biobased solvent solutions presented anthocyanin yields up to 33% higher than water, and were shown to be as efficient as ethanol/water, but generated extracts with higher antioxidant capacity. The anthocyanin-rich extract of juçara, obtained with 1,2-propanediol, was used in the production of a natural soap and incorporated into a cream, showing that the addition of the juçara extract resulted in an antioxidant capacity in both products. Full article

Owing to their low cost and environmentally friendly nature, water-based lubricants have benefits over oil-based ones. However, the appropriate additive package is indispensable in improving its tribological properties. In the current study, we have investigated the friction and wear reduction ability of bis(2-hydroxyethyl) ammonium oleate protic ionic liquid (PIL) in a glycerol aqueous lubricating fluid. The tribo-tests were performed using a ruby–steel friction pair acting in reciprocation mode. The coefficient of friction and wear were the main characteristics of the evaluation. Analysis of the physical properties of the investigated lubricating samples and worn surface analysis were performed to reveal a more detailed picture. The study shows that the investigated PIL can significantly reduce friction and wear. The most suitable concentration of PIL was 0.5%, where friction and wear were reduced 2.6 and 15.8 times, respectively. Using the investigated PIL facilitates a sliding coefficient of friction as low as 0.039. It was hypothesized that the formation of the adsorption layer and metal soap was responsible for this. Further studies could be directed toward higher load and speed applications. Full article

Palm oil is, from an economic, environmental, and social point of view, a vegetable oil with great potential and the state of Pará-Brazil is Brazil’s great producer. In addition, soap phase residue or palm oil neutralization sludge (PONS), a byproduct of the neutralization step of the chemical refinement of palm oil, is produced, posing a huge problem for waste disposal and management in the production process of refined palm oil (RPO). In this context, this work aims to systematically investigate the economic analysis of the thermal–catalytic process of crude palm oil (CPO) and palm oil neutralization sludge (PONS). The thermocatalytic processes of CPO and PONS carried out at pilot scale and their economic feasibility were analyzed. The yields of biofuels produced by fractional distillation were also presented. The physicochemical properties of CPO and PONS, as well as those of organic liquid products obtained by the thermal–catalytic process of CPO and PONS were taken into account in the economic analysis. In addition, the chemical composition organic liquid products obtained by thermal–catalytic process of CPO and PONS, as well as its distillation fractions (green gasoline, green kerosene, green light diesel and heavy diesel), used as key factors/indicators on the economic analysis. The analysis of the key factors/indicators from the thermocatalytic processes of CPO and PONS showed economic viability for both crude palm oil (Elaeis guineensis, Jacq) and palm oil neutralization sludge. The minimum fuel selling price (MFSP) obtained in this work for the biofuels was 1.59 USD/L using crude palm oil (CPO) and 1.34 USD/L using palm oil neutralization sludge (PONS). The best breakeven point obtained was of 1.24 USD/L considering the PONS. The sensibility analysis demonstrated that the pyrolysis and distillation yields are the most important variables that affect the minimum fuel-selling price (MFSP) in both economic analyses. Full article

Chrypthecodinium cohnii lipids have been almost exclusively used as a source of Docosahexaenoic acid (DHA). Such an approach wastes the remaining microalgal lipid fraction. The present work presents a novel process to produce C. cohnii biomass, using low-cost industrial by-products (raw glycerol and corn steep liquor), in a 7L-bioreactor, under fed-batch regime. At the end of the fermentation, the biomass concentration reached 9.2 g/L and the lipid content and lipid average productivity attained 28.0% (w/w dry cell weight) and 13.6 mg/L h, respectively. Afterwards the microalgal biomass underwent a saponification reaction to produce fatty acid (FA) soaps, which were further converted into FA ethyl ester (FA EE). C. cohnii FA EE mixture was then fractionated, using the urea complexation method at different temperatures, in order to obtain a polyunsaturated fatty acid ethyl ester (PUFA EE) rich fraction, that could be used for food/pharmaceutical/cosmetic purposes, and a saturated fatty acid ethyl ester (SAT EE) rich fraction, which could be used as biodiesel. The temperature that promoted the best separation between PUFA and SAT EE, was −18 °C, resulting in a liquid fraction with 91.6% (w/w) DHA, and a solid phase with 88.2% of SAT and monounsaturated fatty acid ethyl ester (MONOUNSAT), which could be used for biodiesel purposes after a hydrogenation step. Full article

Liquid soaps are the basic cosmetics used to clean the skin of the hands. Frequent hand washing prevents viral contamination but may damage the skin’s hydro-lipid layer, leading to various types of irritation. Therefore, four liquid soap formulas were developed with three amphoteric surfactants: Cocamidopropyl Betaine (LS II), CocamidopropylHydroxysultaine (LS III), and newly synthesized Evening PrimroseaamidopropylSulfobetaine (LS IV). We evaluated the skin irritating potential (zein number, bovine albumin test) and cytotoxicity (AlamarBlue™, Cell viability, and Cell cycle assays) on HaCaT cell line. We observed lower values of the zein number and bovine albumin tests after adding soaps with surfactants (the highest differences in LS IV) compared to the base soap (LS I). However, LS I and LS II did not differ in cytotoxic assays. Therefore, adding LS III and LS IV seems potentially more dangerous to the cells. However, it should be noted that cells were continuously exposed to liquid soaps for more than 24 h, so its cytotoxic effects after dermal use in humans may be unnoticeable. Concluding, results suggest that the newly synthesized LS IV should improve the safety of liquid hand washing soaps. Full article