Search Results (122)

The global transition toward net-zero emissions by 2050, encompassing the International Energy Agency’s Roadmap for the energy sector, the IMO’s revised strategy for the maritime industry, and broader climate guidelines, necessitates a profound transformation of both global energy systems and the shipping sector. In this context, energy vectors such as Liquefied Natural Gas, Green Hydrogen, and Ammonia are emerging as key elements for this shift. This review article proposes a comprehensive analysis of these vectors, contrasting their roles: Liquefied Natural Gas as a transitional solution and Hydrogen and Ammonia as long-term pillars for decarbonization. The research moves beyond a simple comparative analysis, offering a detailed mapping and evaluation of the global port infrastructure required for their safe handling, cryogenic storage, and bunkering operations. We examine their technical specifications, decarbonization potential, and the challenges related to operational feasibility, costs, regulation, and sustainability. The objective is to provide a critical perspective on how the evolution of maritime ports into energy hubs is a sine qua non condition for the secure and efficient management of these vectors, thereby ensuring the sector effectively meets the Net Zero 2050 climate goals. Full article

Greenhouse gas (GHG) emissions from maritime transport account for nearly 3% of global totals, making the decarbonisation of this sector a critical priority. In response, the International Maritime Organization (IMO) adopted the GHG Strategy, targeting the full decarbonisation of international shipping by 2050, with interim milestones in 2030 and 2040. This study evaluates the greenhouse gas fuel intensity of three representative vessel types, an oil tanker, a container ship, and a bulk carrier, using one-year operational fuel consumption data in line with the Regulations of the IMO Net-Zero Framework. Both conventional fuels, including conventional marine fuels, and alternative options, encompassing liquefied natural gas (LNG), e-hydrogen, e-ammonia, e-methanol, and biodiesel, are assessed for compliance during 2028–2035. The findings reveal that conventional fuels are unable to meet future targets, resulting in significant compliance deficits and balancing costs of remedial units. LNG provides short-term benefits but is limited by methane slip. In contrast, e-hydrogen and e-ammonia enable long-term compliance and generate surplus units. E-methanol shows a partial potential, while biodiesel delivers only modest improvements. The results underscore the need for a transition toward near-zero-well-to-wake-emission fuels. This study contributes by combining life cycle assessments with regulatory compliance analysis, offering insights for policymakers and industry stakeholders. Full article

Europe’s energy transition beyond 2025 faces a resilience gap as reconfigured pipeline flows, stricter methane rules, and rising variable renewables increase the need for seasonal flexibility and system adequacy. This study examines how Ukraine’s gas transmission network and underground gas storage—among the largest in Europe—can serve as a “seasonal battery” for the EU. We integrate a policy and market review with quantitative scenarios for 2026–2030. Methods include security-of-supply indicators (the rule that the system must keep operating even if its largest single infrastructure element fails, peak-day coverage, and winter adequacy), estimates of market-accessible storage volumes and withdrawal rates for European market participants, and a techno-economic screening of hydrogen-readiness comparing repurposing with new-build options. Methane intensity constraints and compliance with monitoring, reporting, and verification and leak detection and repair requirements are applied. The results indicate that reallocating part of Europe’s seasonal balancing to Ukrainian underground gas storage can enhance resilience to extreme winter demand and liquefied natural gas price shocks, reduce price volatility and the curtailment of variable renewables, and enable phased, cost-effective hydrogen corridors via repurposable pipelines and compressors. We outline a policy roadmap specifying transparent access rules, interoperable gas quality and methane standards, and risk mitigation instruments needed to operationalise cross-border storage and hydrogen-ready investments without carbon lock-in. Full article

Global carbon emissions are driving the maritime industry toward cleaner fuels, with LNG already established as a transitional option that reduces SOx, NOx, and particulate emissions relative to conventional marine fuels and in line with decarbonisation strategies. This research aimed to explore the transition of offshore and marine platforms from conventional marine fuels to cleaner alternatives, with liquefied natural gas (LNG) emerging as the principal transitional fuel. Subsequently, floating liquefied natural gas (FLNG) platforms are increasingly being deployed to harness offshore gas resources, yet they face critical challenges related to weight, space, and energy efficiency. The study proposes pathways for transitioning FLNG energy systems from LNG to zero-carbon fuels, such as hydrogen derived directly from LNG resources, to optimise fuel supply under the unique operational constraints of FLNG units. The work unifies the independent domains of pure-fuel and blending-fuel processes for LNG and hydrogen, viewed in the context of thermodynamic processes, to optimise hydrogen–LNG co-firing gas turbine performance and meet the base power line of 50 MW. Furthermore, the research article will contribute to the development of other floating production platforms, such as FPSOs and FSRUs. It will be committed to clean energy policies that mandate support for green alternatives to hydrocarbon fuels. Full article

The problem of global climate change is becoming increasingly serious, drawing worldwide attention to the need for carbon emissions reduction. As a primary mode of transport, maritime shipping accounts for 2% of global carbon emissions. Therefore, researchers have turned their attention to marine carbon emissions. Specifically, lifecycle assessment (LCA) has attracted wide attention due to its comprehensiveness and objectivity. This article reviews alternate fuels like biodiesel, liquefied natural gas (LNG), methanol, ammonia, and hydrogen. These fuels generate fewer Tank-to-Wake (TTW) carbon emissions than conventional diesel but higher emissions in the Well-to-Tank (WTT) stage owing to production-related emissions, resulting in varying overall carbon footprints. Most carbon emissions in marine transportation come from fuel consumption. Selecting the shortest route can cut fuel use and emissions. Port greening and electrification are vital for emission cuts. Current marine LCA research exhibits key gaps, including fragmented case studies, a lack of methodological standardization, and insufficient dynamic predictive capacity, severely constraining its guiding value for industry decarbonization pathways. This study systematically reviews and categorizes marine LCA research from the past decade in both Chinese and English from the Web of Science and CNKI databases through a Ship-Route-Port framework. Specifically, 34 papers underwent quantitative or qualitative analysis, comprehensively comparing the full lifecycles of six mainstream marine alternative fuels: biodiesel, LNG, methanol, ammonia, hydrogen, and electricity. This study also underscores the need for unified standards to boost low-carbon fuel use and explores the unique challenges and uncertainties involved in applying LCA to the marine sector. LCA applied to the maritime sector shows promise as a valuable tool for guiding low-carbon transition strategies. Full article

According to the International Maritime Organization, transitioning to alternative fuels is essential to achieving net-zero carbon emissions. Seafarers are at the frontline of this transition, and in this study, their attitude toward this strategy is analyzed using the technology acceptance model. The alternative fuels analyzed are liquefied natural gas (LNG) and methanol as short-term options and hydrogen and ammonia as long-term options. The analyzed seafarers are from South Korea, where alternative fuels are actively incorporated into shipbuilding and training. Across all fuels, perceived ease of use (PEOU) positively affected perceived usefulness (PU). PEOU and PU positively influenced attitude toward using (ATT). ATT and trust (TRU) significantly increased behavioral intention (BI), a finding that aligns with those of prior studies, while operational safety risk (OSR) also showed a positive effect on ATT. This indicates that seafarers became more aware of the need to use alternative fuels and expected improvements in managing related risks. Unlike OSR, environmental risk (ER) negatively affected ATT for hydrogen, consistent with prior risk perception studies. These findings suggest that to encourage alternative fuel use during the shipping industry’s energy transition, operational ease, enhanced risk management systems, and basic competency training and incentives are necessary to positively shape seafarers’ attitudes and behavioral intentions. Full article

In response to the International Maritime Organization (IMO)’s greenhouse gas reduction targets and the growing demand for decarbonization in the maritime sector, the development of hydrogen-fueled ship technologies has gained increasing attention. Liquid hydrogen (LH₂) is regarded as a promising marine fuel due to its high energy density per unit volume when liquefied at −253 °C, enabling large-scale storage and transportation. However, critical technical challenges remain in cryogenic storage, transfer, vaporization processes, and safety assurance. This study proposes a conceptual pre-standardization framework for land-based evaluation of LH₂ fuel tank and supply systems, supported by preliminary validation using LN₂ surrogate tests. The protocol is established through a reinterpretation of existing international and domestic standards (KGS AC111, ISO/TR 15916, CGA H-3) and adapted to Korean demonstration environments. Test items were categorized into (i) supply performance (flow and pressure), (ii) vaporization and heating performance (temperature), and (iii) safety functions, with acceptance criteria benchmarked against international guidelines. To overcome the significant safety and cost constraints of handling actual LH₂, liquid nitrogen (LN₂) was applied as a surrogate medium to enable preliminary validation under safe and practical conditions, and process simulations are proposed as a future pathway for comprehensive verification. The results highlight not only the application but also the localization and refinement of global standards into a practical protocol for small- to medium-sized ship applications. This protocol is expected to serve as a critical reference for subsequent sea trials and commercialization, thereby contributing to the advancement of eco-friendly marine fuel technologies and strengthening international competitiveness in the hydrogen powered shipping sector. Full article

With growing global demand for sustainable decarbonization, hydrogen energy systems have emerged as a key pillar in achieving carbon neutrality. This study assesses the greenhouse gas (GHG) reduction efficiency of Republic of Korea’s hydrogen ecosystem from a life-cycle perspective, focusing on production and utilization stages. Using empirical data—including the national hydrogen supply structure, fuel cell electric vehicle (FCEV) deployment, and hydrogen power generation records, the analysis compares hydrogen-based systems with conventional fossil fuel systems. Results show that current hydrogen production methods, mainly by-product and reforming-based hydrogen, emit an average of 6.31 kg CO₂-eq per kg H₂, providing modest GHG benefits over low-carbon fossil fuels but enabling up to a 77% reduction when replacing high-emission sources like anthracite. In the utilization phase, grey hydrogen-fueled stationary fuel cells emit more GHGs than the national grid. By contrast, FCEVs demonstrate a 58.2% GHG reduction compared to internal combustion vehicles, with regional variability. Importantly, this study omits the distribution phase (storage and transport) due to data heterogeneity and a lack of reliable datasets, which limits the comprehensiveness of the LCA. Future research should incorporate sensitivity or scenario-based analyses such as comparisons between pipeline transport and liquefied hydrogen transport to better capture distribution-phase impacts. The study concludes that the environmental benefit of hydrogen systems is highly dependent on production pathways, end-use sectors, and regional conditions. Strategic deployment of green hydrogen, regional optimization, and the explicit integration of distribution and storage in future assessments are essential to enhancing hydrogen’s contribution to national carbon neutrality goals. Full article

In response to the IMO’s decarbonisation strategy, hydrogen—especially green hydrogen—becomes a promising alternative fuel in shipping. This article provides a comparative analysis of two hydrogen propulsion technologies suitable for a service vessel (SOV) operating in offshore wind farms: hydrogen fuel cells and hydrogen-powered internal combustion engines. This study focuses on the use of liquid hydrogen (LH₂) stored in cryogenic tanks and fuel cells as an alternative to the previously considered solution based on compressed hydrogen (CH₂) stored in high-pressure cylinders (700 bar) and internal combustion engines. The research aims to examine the feasibility of a fully hydrogen-powered SOV energy system. The analyses showed that the use of liquefied hydrogen in SOVs leads to the threefold reduction in tank volume (1001 m³ LH₂ vs. 3198 m³ CH₂) and the weight of the storage system (243 t vs. 647 t). Despite this, neither of the technologies provides the expected 2-week autonomy of SOVs. LH₂ storage allows for a maximum of 10 days of operation, which is still an improvement over the CH₂ gas variant (3 days). The main reason for this is that hydrogen tanks can only be located on the open deck. Although hydrogen fuel cells take up on average 13.7% more space than internal combustion engines, they are lower (by an average of 24.3%) and weigh less (by an average of 50.6%), and their modular design facilitates optimal arrangement in the engine room. In addition, the elimination of the exhaust system and lubrication simplifies the engine room layout, reducing its weight and space requirements. Most importantly, however, the use of fuel cells eliminates exhaust gas emissions into the atmosphere. Full article

Background/Objectives: Conventional solid dispersion methods face significant industrial limitations, including thermal degradation, residual organic solvents, and complex preparation processes. This study presents a novel decrystallizing formulation using poloxamer and propylene glycol that remains solid during storage but liquefies at physiological temperature (37 °C). Methods: Decrystallizing formulations containing various poloxamer types (407 and 188) at different concentrations (5–25% w/w) were prepared and assessed for decrystallization temperature, decrystallization time, and drug solubility. The optimal formulation was further characterized using FTIR analysis, as well as in vitro liquefaction performance and dissolution studies. Finally, the industrial sustainability of the decrystallizing formulation was assessed against conventional methods. Results: Poloxamer 407 exhibited higher decrystallization temperature, longer decrystallization time, and superior solubilization capacity compared to Poloxamer 188. Maximum drug solubility (5.51 ± 0.08 mg/g) was achieved at 20% w/w of poloxamer 407 with a decrystallization temperature of 37 °C, and it took 216 s for decrystallization. FTIR spectroscopy confirmed hydrogen bonding interactions, which are responsible for temperature-dependent phase transitions. The decrystallizing formulation showed remarkable improvement in dissolution efficiency (80.6 ± 3.9%) compared to the raw drug (1.8 ± 0.8%), a physical mixture (11.1 ± 6.0%), and a marketed tablet (30.8 ± 2.2%). Conclusions: The current decrystallizing formulation offers a promising approach for improving the bioavailability of poorly water-soluble drugs and tackling the limitations of conventional methods. Moreover, it provides additional advantages in terms of industrial sustainability for continuous production compared to conventional approaches. Full article

The adoption of low-carbon fuels in maritime propulsion requires operational autonomy, material suitability, and compliance with safety standards, making liquid fuels like LNG and LH₂ the most viable options. LNG is widely used for reducing GHG, NOx, and SOx emissions, while LH₂, though new to the maritime sector, leverages aerospace experience. This paper explores the operational requirements and challenges of LH₂ cryogenic handling systems using LNG practices as a reference. Key comparisons are made between LNG and LH₂ supply systems, focusing on cryogenic materials, hydrogen embrittlement, and structural integrity under maritime conditions. Most maritime-approved materials are suitable for cryogenic use, and hydrogen embrittlement is less critical at cryogenic temperatures due to reduced atomic mobility. Risk assessments suggest LH₂’s safety record stems from limited operational data rather than superior inherent safety. The paper also addresses crucial safety and regulatory considerations for both fuels, underscoring the need for strict adherence to standards to ensure the safe and compliant integration of LH₂ in the maritime industry. Full article

This article presents the development, integration, and experimental validation of a modular microgrid for sustainable hydrogen production, addressing global electricity demand and environmental challenges. The system was designed for initial validation in a thermoelectric power plant environment, with scalability to other applications. Centered on a six-compartment skid, it integrates photovoltaic generation, battery storage, and a liquefied petroleum gas generator to emulate typical cogeneration conditions, together with a high-purity proton exchange membrane electrolyzer. A supervisory control module ensures real-time monitoring and energy flow management, following international safety standards. The study also explores the incorporation of blockchain technology to certify the renewable origin of hydrogen, enhancing traceability and transparency in the green hydrogen market. The experimental results confirm the system’s technical feasibility, demonstrating stable hydrogen production, efficient energy management, and islanded-mode operation with preserved grid stability. These findings highlight the strategic role of hydrogen as an energy vector in the transition to a cleaner energy matrix and support the proposed architecture as a replicable model for industrial facilities seeking to combine hydrogen production with advanced microgrid technologies. Future work will address large-scale validation and performance optimization, including advanced energy management algorithms to ensure economic viability and sustainability in diverse industrial contexts. Full article

Electrolysis desaturation has emerged as an innovative technique to mitigate liquefaction risk by reducing soil saturation in liquefiable foundations. This study evaluated the effectiveness of horizontal electrolysis on calcareous sandy foundations in marine environments by employing 35‰ NaCl solution as pore fluid under different current intensities (1A, 2A, and 4A). Experimental results demonstrated that hydrogen gas was generated at the cathode, while chlorine gas was produced at the anode, with peak gas retention rates of 100%, 90.83%, and 63.26% for 1A; 97.61%, 79.04%, and 60.94% for 2A; and 95.37%, 48.49%, and 42.81% for 4A over three electrolysis cycles. Three key findings emerged from our investigation: First, the resistivity of calcareous sand displayed a three-stage variation pattern, primarily governed by temperature and gas content evolution. Second, the temperature-corrected resistivity model provided reliable saturation data, revealing that electrode-adjacent soil layers exhibited significantly greater saturation reduction compared to intermediate layers. The average saturation variation during a single electrolysis cycle reached 3.2%, 2.6%, and 4.4% for 1A, 2A, and 4A, respectively, in the soil layers near the electrodes, compared to 2.1%, 1.7%, and 3.3% in the middle soil layers under the same current intensities. Third, upon stopping electrolysis, gas redistribution led to decreased saturation in upper soil layers, with lower current intensities more effective in retaining gases within the soil matrix. Based on these findings, an electrolytic influence coefficient for calcareous sand applicable to Archie’s formulation is proposed. This study enhances the understanding of the mechanism of electrolysis desaturation and provides a theoretical basis for the effectiveness of electrolysis desaturation on calcareous sand foundations. Full article

The accumulation of polyolefin waste, particularly high-density polyethylene (HDPE), presents a growing environmental challenge due to limited recycling options and poor end-of-life recovery. This study explores a strategy to convert HDPE into mesophase pitch (MP), a valuable carbon precursor, by integrating polyolefin recycling with the mild solvolysis liquefaction (MSL) of low-rank coals. HDPE was first hydrogenolyzed into a hydrogen-rich aromatic liquid (HDPE-liquid), which was then used as the liquefaction solvent. Under identical conditions (400 °C, 60 min), Utah Sufco coal co-liquefied with HDPE-liquid produced tar that formed mesophase pitch with a higher mesophase content (84.5% vs. 78.6%) and a lower softening point (~302 °C vs. >350 °C) compared to pitch from conventional tetralin (THN). The approach was extended to Illinois #6 and Powder River Basin coals, increasing the mesophase content from 12.4% to 32.6% and 17.8% to 62.1%, respectively. These improvements are attributed to differences in tar composition: HDPE-derived tars had lower terminal methyl (Hγ) contents, reducing cross-linking during thermal upgrading. This work demonstrates that HDPE-derived liquids can act as functional solvents for coal liquefaction, enabling an effective route to recycle polyolefin waste into durable carbon products, while also reducing reliance on fossil-based solvents for mesophase pitch production. Full article

Hydrogen is a key energy carrier, playing a vital role in sustainable energy systems. This review provides a comparative analysis of physical, chemical, and innovative hydrogen storage methods from technical, environmental, and economic perspectives. It has been identified that compressed and liquefied hydrogen are predominantly utilized in transportation applications, while chemical transport is mainly supported by liquid organic hydrogen carriers (LOHC) and ammonia-based systems. Although metal hydrides and nanomaterials offer high hydrogen storage capacities, they face limitations related to cost and thermal management. Furthermore, artificial intelligence (AI)- and machine learning (ML)-based optimization techniques are highlighted for their potential to enhance energy efficiency and improve system performance. In conclusion, for hydrogen storage systems to achieve broader applicability, it is recommended that integrated approaches be adopted—focusing on innovative material development, economic feasibility, and environmental sustainability. Full article