In response to the environmental impacts of conventional polyurethane adhesives derived from fossil fuels, this study introduces a sustainable alternative utilizing lignin-based polyols extracted from rice straw through a process developed at INESCOP...
Lignin-based polyol was obtained via oxyalkylation reaction with propylene carbonate using eucalyptus kraft lignin isolated from the industrial cooking liquor by the Lignoboost® procedure. This lignin-based polyol (LBP) was used without purificat...
Food packaging is the largest segment of the global plastics market, yet its low degradability and limited performance in preserving perishable goods highlight the need for more sustainable alternatives. This study investigates the use of industrial...
This study aimed to develop new rigid polyurethane foams (RPUFs) for thermal insulation based on kraft lignin, the main by-product of the pulp and paper industry. Crude lignin-based polyol (LBP) was obtained via the oxyalkylation of kraft lignin usin...
Rigid polyurethane foams (RPUFs) were synthesized using exclusively lignin-based polyol (LBP) obtained via the oxyalkylation of kraft lignin with propylene carbonate (PC). Using the design of experiments methodology combined with statistical analysis...
In this study, we introduce a novel approach for synthesizing lignin-incorporated castor-oil-based cationic waterborne polyurethane (CWPU-LX), diverging significantly from conventional waterborne polyurethane dispersion synthesis methods. Our innovat...
This study developed bio-based waterborne polyurethane (BWPU) dispersions containing lignin as a sustainable filler with castor oil (CO), polycaprolactone diol (PCL), or poly(trimethylene ether) glycol (PO3G). The effects of the polyol structure and...
Valorization of industrial low-value side-streams are of great interest, contributing to boosts in the circular economy. In this context, lignin side-streams of the pulp and paper industry were oxypropylated to produce biobased polyols and tested in...
Oxyalkylation with propylene carbonate (PC) is a safe process to convert lignin into a reactive liquid polyol to be used in polyurethane formulations. In this study, the effect of operating conditions of oxyalkylation (temperature, time and quantify...
The packaging sector presents a significant sustainability challenge, particularly due to the prevalence of plastic packaging. There is a growing interest in sustainable packaging alternatives. The main challenge is to develop packaging with comparab...
Phenolic foams (PFs) are lightweight (<200 kg/m3), high-quality, and inexpensive thermal insulation materials whose heat and fire resistance are much better than those of foam plastics such as polyurethane and polystyrene. They are especially suit...
Lignin-based polyurethanes represent a promising strategy for developing more sustainable wood coatings by partially replacing fossil-derived polyols with renewable aromatic biopolymers. In this study, a polyurethane formulated with organosolv lignin...
Several efforts have been dedicated to the development of lignin-based polyurethanes (PU) in recent years. The low and heterogeneous reactivity of lignin hydroxyl groups towards diisocyanates, arising from their highly complex chemical structure, lim...
Three different formulations of bio-based polyurethane (PU), varying the weight ratio between Organosolv lignin and a commercial isocyanate, were synthesized. The coating formulations were characterized by SEM, pyrolysis-GC/MS, FTIR spectroscopy and...
In this study, lignin isolated and fractionated from black liquor was used as a pre-polymer to prepare bio-polyurethane (Bio-PU) resin, and the resin was impregnated into ramie fiber (Boehmeria nivea (L.) Gaudich) to improve its thermal and mechanica...
Lignin-based polyols were synthesized through microwave-assisted liquefaction under different microwave heating times (5–30 min). The liquefaction reactions were carried out using polyethylene glycol (PEG-400)/glycerol as liquefying solvents and 97 w...
Short jute fiber-reinforced acetylated lignin-based thermoplastic polyurethane (JF reinforced ASKLTPU) was prepared and characterized as a short-fiber-reinforced elastomer with carbon-neutrality and biodegradability. The acetylated softwood kraft lig...
The study presents the results of research on the preparation of biopolyols based on organosolv lignin and their application in the synthesis of rigid polyurethane foams. The research was conducted in order to develop a sustainable alternative to the...
The depletion of natural resources and increasing environmental apprehension regarding the reduction of harmful isocyanates employed in manufacturing polyurethanes (PUs) have generated significant attention from both industrial and academic sectors....
This review article aims to summarize the potential of using renewable natural resources, such as lignin and tannin, in the preparation of NIPUs for wood adhesives. Polyurethanes (PUs) are extremely versatile polymeric materials, which have been wide...
Currently, the pulp and paper industry generates around 50–70 million tons of lignin annually, which is mainly burned for energy recovery. Lignin, being a natural aromatic polymer rich in functional hydroxyl groups, has been drawing the interes...
We report the preparation of lignin-based rigid polyurethane (RPU) foams from surface functionalized kraft lignin via a simple and environmentally benign process. Lignin was functionalized with polyisocyanate at 80 °C for 1 h, the resulting ligni...
Polyurethanes (PU) have drawn great attention due to their excellent mechanical properties and self-healing and recyclable abilities. Lignin is a natural and renewable raw material in nature, composed of a large number of hydroxyl groups, and has a g...
This study reports the synthesis of polyurethane–lignin copolymer blended with carbon multilayer nanotubes to be used in all-solid-state potentiometric chemical sensors. Known applicability of lignin-based polyurethanes doped with carbon nanotu...
In this study, nineteen unmodified lignins from various sources (hardwood, softwood, wheat straw, and corn stover) and isolation processes (kraft, soda, organosolv, sulfite, and enzymatic hydrolysis) were used to replace 30 wt.% of petroleum-based po...
Lignin, an abundant and renewable biopolymer, has gained significant attention as a sustainable modifier and building block in polymeric materials. Recent advancements highlight its potential to tailor mechanical, thermal, and barrier properties of p...
Biobased organic diols derived from the phenolic aldehyde by-products in the depolymerization of lignin (4-hydroxybenzaldehyde, vanillin, and syringaldehyde) for the synthesis of polyesters and polyurethanes is described. Methods to prepare lignin-ba...
In this study, corn stalk lignin was used to react with non-volatile and non-toxic glyoxal under the catalysis of a sodium hydroxide solution, and a wood adhesive based on glyoxalated corn stalk lignin was prepared. The effect of the hydroxylation re...
Due to global ecological and economic challenges that have been correlated to the transition from fossil-based to renewable resources, fundamental studies are being performed worldwide to replace fossil fuel raw materials in plastic production. One a...
Lignin was utilized as an environmentally friendly synergistic agent to augment the fire resistance and mechanical characteristics of rigid polyurethane foam (PUF)/melamine–formaldehyde resin ammonium polyphosphate (MFAPP). The incorporation of...
Lignin is the most abundant aromatic biopolymer and is the sustainable feedstock most likely to supplant petroleum-derived aromatics and downstream products. Rich in functional groups, lignin is largely peerless in its potential for chemical modifica...
The development of controlled-release fertilizers (CRFs) has faced significant challenges due to high hydrophilicity and short release lifespan of bio-based materials, as well as non-renewable and high cost of polyester polyols (PPs). In this study,...
Polyurethane chemistry can yield diverse sets of polymeric materials exhibiting a wide range of properties for various applications and market segments. Utilizing lignin as a polyol presents an opportunity to incorporate a currently underutilized ren...
The quest for converting lignin into high-value products has been continuously pursued in the past few decades. In its native form, lignin is a group of heterogeneous polymers comprised of phenylpropanoids. The major commercial lignin streams, includ...
Bio-based nanomaterials (B-NMs), such as silica oxide (SiO2)- and lignin (Lig)- based nanoparticles (NPs) derived from biomass waste, have gained attention in the last few years in the view of promoting the sustainability principles in several applic...
The design and preparation of polymers by using biobased chemicals is regarded as an important strategy towards a sustainable polymer chemistry. Herein, two aromatic diols, 4-(hydroxymethyl)-2-methoxyphenol and 2-(4-(hydroxymethyl)-2-methoxyphenoxy)e...
A significant amount of Kraft lignin (KL) is produced each year, but only a small portion is repurposed to create higher-value products. KL was purified (PKL, ≈2300 g/mol, 4.1 mmol/g total OH) and used as a polyol in the synthesis of polyuretha...
Lignin is a renewable aromatic feedstock for wood adhesives, but its structural heterogeneity complicates control over curing and water resistance. This review examines how lignin structure and functionalization govern curing reactions, kinetics, and...
Lignin used in this work was isolated from sapele (Entandrophragma cylindricum) wood through a hybrid pulping process using soda/ethanol as pulping liquor and denoted soda-oxyethylated lignin (SOL). SOL was mixed with a polyethylene glycol (PEG)&ndas...
The present review is devoted to the description of the state-of-the-art techniques and procedures concerning treatments and modifications of lignocellulosic materials in order to use them as precursors for biomaterials, biochemicals and biofuels, wi...
The construction sector is responsible for substantial energy consumption, greenhouse gas emissions, and resource depletion, driving the search for sustainable alternatives to conventional petroleum-based insulation materials. Lignocellulosic biomass...
Raising the awareness of carbon dioxide emissions, climate global warming and fossil fuel depletion has renewed the transition towards a circular economy approach, starting by addressing active bio-economic precepts that all portion amounts of wood a...
Bio-based alternatives to conventional rigid foams have proven to be good substitutes owing to their enhanced sustainability and competitive performance. However, because their manufacturing processes are complex and destructive testing is often impr...
The textile industries need an alternative to cotton since its supply is unable to keep up with the growing global demand. The ramie (Boehmeria nivea (L.) Gaudich) fiber has a lot of potential as a renewable raw material but has low fire-resistance,...
The purpose of this study was to prepare low-viscosity lignin-based polyurethane (LPU) resins for the modification of ramie (Boehmeria nivea (L.) Gaudich) fiber via impregnation to improve the fiber’s thermal and mechanical properties. Low-visc...
This study explores the innovative potential of native lignin as a sustainable biopolyol for synthesizing polyurethane aerogels with variable microstructures, significant specific surface areas, and high mechanical stability. Three types of lignin&md...
A bio-epoxy surface adhesive for adherence of the metal component species to glass substrate with desirable adhesion strength, converted controlled removal upon request, and bio-based resource inclusion was developed. For the development of resin, th...
In this study, lignosulfonate (LS) from the acid sulfite pulping of eucalypt wood was used to synthesize LS-based polyurethanes (PUs) doped with multiwalled carbon nanotubes (MWCNTs) within the range of 0.1–1.4% w/w, yielding a unique conducting copo...
Amid environmental pollution and resource depletion, developing and utilizing biomass resources as alternatives to petroleum is a prominent research focus. Driven by environmental protection and sustainable development, the shift from petroleum-based...
With the expansion of modern protected agriculture, the amount of post-harvest tomato biomass has increased sharply. Conventional unmanaged disposal practices disrupt carbon flows and cause substantial environmental emissions. Tomato plant residues (...
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