Search Results (12)

In light of rising environmental concerns, the rapid industrial recycling of building demolition waste material (BDWM) is now capable of supporting sustainable development in metropolitan regions. From this perspective, the current study investigated the geotechnical properties and applications of BDWMs as substitutes for natural materials (NMs) in road engineering infrastructures. For this purpose, the physical and geotechnical characteristics of both types of materials were initially examined, and then compared using laboratory-scale material comprehensive assessments such as sieve analysis (SA), the flakiness index (FI), the specific gravity test (Gs), the Los Angeles abrasion test (LAAT), Atterberg limits (AL), the water absorption test (WAT), the California bearing ratio (CBR), the direct shear test (DST), and the Proctor soil compaction test (PSCT). The BDWMs were collected from two locations in Iran. According to the results, the collected samples consisted of concrete, bricks, mortar, tile materials, and others. The CBR values for the waste material from the two sites were 69 and 73%, respectively. Furthermore, the optimum water content (OWC) and maximum dry unit weight (MDD) from the two sites were reported as 9.3 and 9.9% and 20.8 and 21 kN/m³, respectively, and the hydrogen potential (pH) as 9 and 10. The shear strength and CBR values indicated that the BDWM had a suitable strength compared to the NM. In terms of road infrastructure applications, the shear strengths were adequate for the analysis of common sub-base materials used in filling and road construction. Furthermore, the study’s findings revealed that BDWMs were suitable replacements for the NM used in road engineering operations and could make a significant contribution to sustainable development. Full article

This study focused on the preparation and investigation of g-C₃N₄/TiO₂ photocatalysts using different TiO₂ morphologies (anatase nanoparticles (TPs), poorly crystalline nanotubes (aTTs), and well-crystalline anatase nanorods (TRs)) and self-synthesized g-C₃N₄ (CN). The synthesis of the g-C₃N₄/TiO₂ composites was carried out using a mortar mixing technique and a g-C₃N₄ to TiO₂ weight ratio of 1:1. In addition, the g-C₃N₄/TiO₂ composites were annealed in a muffle furnace at 350 °C for 2 h in air. The successful formation of a g-C₃N₄/TiO₂ composite with a mesoporous structure was confirmed using the results of XRD, N2 physisorption, and FTIR analyses, while the results of microscopic analysis techniques confirmed the preservation of TiO₂ morphology in all g-C₃N₄/TiO₂ composites investigated. UV-Vis DR measurements showed that the investigated g-C₃N₄/TiO₂ composites exhibited visible-light absorption due to the presence of CN. The results of solid-state photoluminescence and electrochemical impedance spectroscopy showed that the composites exhibited a lower charge recombination compared to pure TiO₂ and CN. For example, the charge transfer resistance (RCT) of the CNTR/2 composite of TR and CN calcined in air for 2 h was significantly reduced to 0.4 MΩ, compared to 0.9 MΩ for pure TR and 1.0 MΩ for pure CN. The CNTR/2 composite showed the highest photocatalytic performance of the materials tested, achieving 30.3% degradation and 25.4% mineralization of bisphenol A (BPA) dissolved in water under visible-light illumination. In comparison, the pure TiO₂ and CN components achieved significantly lower BPA degradation rates (between 2.4 and 11.4%) and mineralization levels (between 0.6 and 7.8%). This was due to (i) the presence of Ti³⁺ and O-vacancies in the TR, (ii) enhanced heterojunction formation, and (iii) charge transfer dynamics enabled by a dual mixed type-II/Z scheme mechanism. Full article

Cement composites containing different carbon nanomaterials, namely graphene technical grade, graphene super grade, and graphene oxide, up to 1.0% by weight of cement, were prepared. Ultrasonic, chemical, and thermochemical treatments were applied to improve the stability of the dispersions containing the graphene-based nanomaterials. Their exfoliation was analyzed using Raman spectroscopy, and the stability of the dispersions was quantitatively investigated by means of the static multiple light scattering (SMLS) technique. The sonication process enhanced the intensity of the 2D band of graphene technical grade, suggesting a partial degree of exfoliation, while the hydrothermal treatment with sodium cholate significantly promoted the stability of its dispersion. The effect of the addition of selected graphene-based nanomaterials in mortars was evaluated in terms of fresh state properties, mechanical strength, capillary water absorption, and pore size distribution. Workability decreased with the increase in the amount of carbon nanomaterials. Field emission scanning electron microscopy (FESEM) was also employed to characterize the microstructure of pristine graphene-based nanomaterials and their inclusion within the cement matrix. Our results suggest that mechanical properties are only moderately affected by the inclusion of all additives, whereas the introduction of graphene significantly influences the coefficient of capillary water absorption. Specifically, a reduction of about 20% in the capillary water absorption coefficient was observed at the concentration of 1.0 wt% of graphene technical grade, which is ascribed to a refinement of the porosity. Full article

It is most effective to reduce floor impact noise as close to the sound source as possible. In apartments, there are multiple layers in the floor system, from floor finishing to the structural concrete slab. Apart from the floor finishing, mortar lies at the top layer of the floor system, followed by autoclaved lightweight concrete, insulation, and the concrete slab. The present study aims to identify the reduction characteristics of light and heavy floor impact noises by changing the glass transition temperature of an SBR (styrene–butadiene rubber) latex mortar. To achieve this, structural tests were undertaken to find the appropriate mix proportions of SBR latex in the mortar, meeting the glass transition temperature based on the physical test results regarding the latex mortar. As seen in the study method and process, because this study aimed to both increase and decrease the strength compared to general mortar, a 7% mixture ratio of Tg 4 °C SBR latex was decided upon for the strength increase, while a 5% mixture ratio of Tg −16 °C SBR latex was chosen for the strength reduction. A mock-up specimen was created using the SBR latex-modified mortar according to the identified mix proportions, and the characteristics of light- and heavy-weight floor impact noises of the SBR latex-modified mortar were then examined. Comprehensive analysis of the reduction performance of the floor impact noise revealed that the Tg −16 °C SBR latex-mixed mortar showed a reduction effect of about 2–5 dB for light-weight impact noise and about 7–10 dB for heavy-weight impact noise. Full article

The circular economy (CE) is widely known for its emphasis on reducing waste and maximizing the use of resources by reusing, recycling, and repurposing materials to create a sustainable and efficient system. The CE is based on 3R—reuse, reduce, and recycle. The aim of this article is to use styrene butadiene rubber dust (SBR) in building material, constituting secondary waste in the production of SBR, which is currently disposed of as landfill. SBR is partly intended to replace the natural raw material sand. The purpose of the final material is to use it for its light weight, insulating properties, or ability to absorb vibrations and sounds. Various shares of SBR dust in mortars were tested. Some of the mortars used SBR thermal pre-treatment at temperatures of 200, 275, and 350 °C. The strength and SEM results are presented. The best pre-treatment for SBR dust is thermal treatment at 275 °C. The maximum usage of rubber dust with thermal treatment is 60% as a sand substitute. The novel finding of this study is the possibility to use more than 30% rubber dust (as a substitute for sand) thanks to pre-treatment, whereby 30% is a common maximum ratio in mortars. Full article

In this study, the photocatalytic activity of coating mortars with synthetized and commercial TiO₂ nanoparticles added has been evaluated at 2, 3 and 5% by weight of cement by calculating the degradation efficiency of methyl orange and red wine dyes exposed to both visible-light and UV radiation; also, the self-cleaning effect of coatings exposed to weather conditions (warm sub-humid climate) was assessed. TiO₂ nanoparticles were synthesized via the sol–gel method to a low synthesis temperature and characterized via X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). The results show synthesized TiO₂ particles in anatase phase with a crystallite size of 14.69 nm, and hemispherical particles with sizes of submicron order. The addition percentage with the best performance in the coating mortars was 3%, with both commercial and synthesized TiO₂; however, coating mortars with synthesized TiO₂ exhibited the highest degradation efficiency for both dyes when they were exposed to visible light, while mortars with commercial TiO₂ exhibited the highest degradation efficiency when exposed to UV radiation. In addition, in coating mortars with synthesized TiO₂, the self-cleaning effect was evident from the beginning of exposure to weather, reaching the largest dye-free surface at the end of exposure. The compressive strength increased significantly in mortars with TiO₂ addition. Full article

The present study concerns the application of nano-/micro-sized fibers (bio-char of Santa Maria feverfew) in cementitious mortars. The bio-char was added @ 0, 0.05 and 0.1% by mass of cement. The addition of bio-char did not affect the setting and consistency of the mortars. The fresh density was reduced by 11%, while the followability decreased by 50%. It is concluded that the bio-char results in a light-weight cementitious material, without affecting the setting time or consistency. Bio-char produces carbon-rich materials, the use of which as building materials adds to carbon sequestration in accordance with the Sustainable Development Goals of the UNO. Full article

Recycled rubber aggregate (RRA) made from ground tire rubber has been promoted for its light weight and shock resistance. The high alkalinity of alkali-activated slag mortar has a modification effect on the surface of RRA. This paper studies the performance of alkali-activated slag mortar using RRA as aggregate (RASM), which has significance for applications in low-carbon building materials. The orthogonal test analysis method was used to analyze the significance and correlation of the main variables of the test. The dynamic energy absorption capacity and crushing state of RASM under the synergistic effect of various factors were studied using the separating Hopkinson pressure bar (SHPB) test system. The energy absorption characteristics and failure modes of RASM were analyzed by SEM and microscopic pore characterization. The results show that the increase of the alkali equivalent of the mix ratio will increase the peak value of the absorption energy of the specimen. When the size of the RRA is between 0.48 mm~0.3 mm, the dynamic energy absorption of the specimen will reach its peak value. Although the increase in the total volume of RRA will reduce the energy absorption capacity of RASM specimens, its crack resistance is enhanced. Full article

Cement-based materials modified with 3D BiOX (X = I, Cl) microspheres at different percentages (1, 5 and 10% by weight of the cement binder) were prepared to investigate the durability of the photocatalytic NO_x removal under outdoor conditions. Weathering—corresponding to a period of 13 months outdoors—was studied in terms of NO removal efficiency under visible and UVA light irradiation for BiOI and BiOCl mortars, respectively. Following this period, the samples were protected from the environment for four years, and NO_x removal and selectivity to nitrates were assessed. BiOI and BiOCl mortar samples were initially photocatalytically active; NO_x removal performance increased as BiOX content increased. There was good photocatalyst dispersion, and compressive strength was not significantly impacted. The BiOI mortars had nearly completely lost their activity after 5 years from casting, whereas mortars containing 10% BiOCl had maintained about 7% of initial performance. The results suggest that mortar deactivation is due to surface dirt and nitrates accumulation from NO_x oxidation on the surface rather than carbonation. An internal self-deactivation mechanism that affects BiOI in mortar matrix has also been postulated. Full article

Sand contaminated with crude oil is becoming a major environmental issue around the world, while at the same time, fly ash generated by coal-fired power stations is having a detrimental effect on the environment. Previous studies showed that combining these two waste materials can result in an environmentally sustainable geopolymer concrete. Incorporating sand contaminated with crude oil up to a certain level (4% by weight) can improve the mechanical properties of the produced geopolymer concrete but beyond this level can have a detrimental effect on its compressive strength. To overcome this challenge, this study introduces short fibres to enhance the mechanical properties of geopolymer mortar containing fine sand contaminated with 6% by weight of light crude oil. Four types of short fibres, consisting of twisted polypropylene (PP) fibres, straight PP fibres, short glass fibres and steel fibres in different dosages (0.1, 0.2, 0.3, 0.4 and 0.5% by volume of geopolymer mortar) are considered. The optimum strength was obtained when straight PP fibres were used wherein increases of up to 39% and 74% of the compressive and tensile strength, respectively, of the geopolymer mortar were achieved. Moreover, a fibre dosage of 0.5% provided the highest enhancement in the mechanical properties of the geopolymer mortar with 6% crude oil contamination. This result indicates that the reduction in strength of geopolymer due to the addition of sand with 6% crude oil contamination can be regained by using short fibres, making this new material from wastes suitable for building and construction applications. Full article

Alkali activated materials as possible sustainable alternative to cementitious binders showed competitive performances in terms of mechanical and durability properties and high temperature stability. For this reason, light weight fly-ash based mortars have already been optimized as passive fire protective coating for steel structures. However, a lack of information about the durability of these innovative systems in terms of steel corrosion resistance is still present. Thus, this study aims at investigating the durability of steel coated with a 20-mm thick light weight mortar layer in a neutral environment (tap water) and in presence of chloride-containing solution (0.2 M NaCl). In addition, the influence of pore solution chemistry and pH was discussed through electrochemical testing in leachate pore solution and NaOH aqueous solutions at different concentrations. It was found that almost complete protection ability of light weight mortar was obtained when coated steel is exposed to neutral solution for 60 days, while in presence of chlorides, steel is more susceptible to corrosion already after 40 days of exposure. In addition, the developed open porosity of the light weight mortars, it was found that pH and the chemistry of the pore solution in contact with steel strongly influenced the steel corrosion resistance. Full article

The multi-physical properties of the building envelope play a major role in the energy efficiency of buildings. Translucent concrete panels (TCPs) with various volumetric ratios of optical fibers (OFs) were cast. To understand the multi-physical properties of the TCP for the building envelope, compressive strength, thermal and light transmittance tests were carried out. The compressive strength test showed that TCP with light-weight mortar (LWM) has higher strength compared to that with normal-weight mortar (NWM), but it did not exhibit an apparent ductile behavior. The U-values of the plain panel were 4.25 and 5.45 W/(m² K) for TCPs with the LWM and NWM, respectively. The existence of the OFs improved the thermal insulation property. The K-values of the LWM TCP were smaller than that of the common façade, which proved its excellent energy-efficient performance. The solar heat gain coefficients (G-values) of the two tested TCP types—LWM and NWM—were 0.198 and 0.242, respectively. The visible light transmission test showed that the light transmitted by the TCP was proportional to the density of the OFs in a matrix of concrete. The experimental light acceptance angle of the OF was close to the computational value (35 °C). Therefore, all the experimental results demonstrated that TCPs can improve the energy efficiency of buildings. Full article