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Keywords = lead-bismuth eutectic (LBE)

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12 pages, 3008 KiB  
Article
Structural, Thermophysical, and Radiation Shielding Properties of Lead–Bismuth Eutectic (LBE) Synthesized by Induction Melting
by Radu Cristian Gavrea, Emanoil Surducan, Răzvan Hirian, Mioara Zagrai and Vasile Rednic
Crystals 2025, 15(6), 581; https://doi.org/10.3390/cryst15060581 - 19 Jun 2025
Viewed by 323
Abstract
Lead–bismuth eutectic alloy (LBE, Pb44.5Bi55.5) has emerged as a promising candidate for use in advanced nuclear and solar energy systems due to its favorable thermophysical characteristics and radiation shielding capabilities. The aim of this research is to assess the [...] Read more.
Lead–bismuth eutectic alloy (LBE, Pb44.5Bi55.5) has emerged as a promising candidate for use in advanced nuclear and solar energy systems due to its favorable thermophysical characteristics and radiation shielding capabilities. The aim of this research is to assess the applicability of the induction melting technique to synthesize LBE. This paper presents a comprehensive evaluation of the structural, thermophysical, and radiation shielding properties of the obtained LBE sample. Various techniques were employed to investigate the solid-to-liquid eutectic transformation, phase composition, morphology, and homogeneity of the obtained material. Experimental and theoretical determinations on density, void, molar volume, thermal conductivity, heat capacity, thermal diffusivity, and electrical conductivity were performed. Radiation shielding performance over photon energies ranging from 0.015 to 15 MeV was simulated using the Phy-X/PSD program. The results revealed the eutectic structure comprising Pb7Bi3 and Bi phases with near-ideal stoichiometry and a melting point of 127.6 °C. The alloy demonstrated a small void that corresponds to a high degree of sample compaction, high specific heat capacity, moderate thermal conductivity, low thermal diffusivity, and effective radiation shielding. These findings confirm that LBE obtained by the induction melting technique possesses the necessary structural stability and functional properties for integration into nuclear reactor and solar thermal technologies. Full article
(This article belongs to the Special Issue Exploring New Materials for the Transition to Sustainable Energy)
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16 pages, 11780 KiB  
Article
The Effect of Aging on the Microstructure and Mechanical Properties of Solidified Lead-Bismuth Eutectic Alloy
by Hailuo Zhong, Sijuan Chen, Weibing Liao, Jiawei Zhang, Xuan Xiao and Xi Huang
Materials 2025, 18(9), 2001; https://doi.org/10.3390/ma18092001 - 28 Apr 2025
Viewed by 347
Abstract
Lead-bismuth eutectic (LBE) is a eutectic alloy of lead (44.5 at%) and bismuth (55.5 at%) that can be used as the coolant for the fast nuclear reactors. In the event of specific conditions or even accidents of the reactors, the temperature of liquid [...] Read more.
Lead-bismuth eutectic (LBE) is a eutectic alloy of lead (44.5 at%) and bismuth (55.5 at%) that can be used as the coolant for the fast nuclear reactors. In the event of specific conditions or even accidents of the reactors, the temperature of liquid LBE decreases, and it may undergo solidification and volume expansion during the aging process after solidification, which can easily cause damage to the reactor’s internal structure as well as the reactor vessels. In this study, the microstructure and mechanical properties of solidified LBE obtained at different cooling rates are systematically investigated after different aging times. It was found that the internal structure of LBE after aging remained a eutectic microstructure, consisting of the γ-phase (Bi-rich phase) and β-phase (Pb7Bi3). After a long period of static aging, the white γ-phase precipitated into the black β-phase, which further confirms the phase transition mechanism. Meanwhile, the acceleration of the cooling rate can aggravate volume expansion. As the aging time increases, there is no significant difference in the compressive yield strength σ of the LBE samples with the same cooling rate and only a certain degree of fluctuation. The elastic modulus E also shows similar results, indicating that aging time has a minor effect on the compressive yield strength σ and elastic modulus E of the LBE. With the increase in cooling rate, the compressive yield strength σ shows an upward trend, while the elastic modulus E is not significantly affected, with a small amplitude of fluctuation. Meanwhile, the hardness of LBE samples after long-term aging treatment is enhanced. After long-term aging, the overall density of the LBE samples shows a decreasing trend, the density fluctuation range of the fast cooling rates (5 K/min and 10 K/min) are significantly larger than that of the slow cooling rates. The decrease in density leads to volume expansion of the LBE during the aging process after solidification. Full article
(This article belongs to the Section Metals and Alloys)
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19 pages, 16839 KiB  
Article
Study on the Unsteady Pressure Fluctuations and Radial Forces in a Vaned-Diffuser Heavy-Liquid-Metal Centrifugal Pump
by Xudan Ma, Hui Sheng, Chenyang Wang, Yao Lu and Kefeng Lyu
Energies 2025, 18(7), 1698; https://doi.org/10.3390/en18071698 - 28 Mar 2025
Viewed by 372
Abstract
Lead–Bismuth Eutectic (LBE) is a very dense medium whose specific gravity is more than 10 times that of water. The unsteady hydraulic exciting force generated by the rotor–stator interaction (RSI) is significantly increased in the LBE pump, which has an important influence on [...] Read more.
Lead–Bismuth Eutectic (LBE) is a very dense medium whose specific gravity is more than 10 times that of water. The unsteady hydraulic exciting force generated by the rotor–stator interaction (RSI) is significantly increased in the LBE pump, which has an important influence on the stable operation of the pump. The clearance between the vaned diffuser inlet and the impeller outlet has great influence on the rotor–stator interaction. This paper studies the unsteady flow characteristics in pumps with different rotor–stator clearance in different flow rates and transported mediums. The results show that at the design point, the head and efficiency of the pump when transporting LBE are 3.52% and 8.05% higher than those when transporting water. The pressure fluctuation distribution is similar at different positions inside the pump when transporting LBE and water, but the dimensionless pressure fluctuation coefficient is slightly larger when transporting water. The radial force in the pump shows a larger amplitude of 6BPF frequency with small clearance ratios, and the frequency is related to the guide vane number. When the clearance ratio increases from 1.03 to 1.13, the amplitude of 6BPF keeps decreasing. The amplitude at a clearance ratio of 1.13 decreased to 4.7% of that at 1.03. The research presented in this paper could provide some references for the design of the clearance between the rotor–stator parts in the LBE pump. Full article
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21 pages, 14415 KiB  
Article
Corrosion Resistance of Mn-Containing AFA Alloys in LBE at 550 °C with Controlled Oxygen Concentration of 10−6 wt.%
by Menghe Tu, Yajie He, Zihui Liu, Xiaogang Fu and Lingzhi Chen
Materials 2025, 18(6), 1328; https://doi.org/10.3390/ma18061328 - 17 Mar 2025
Viewed by 492
Abstract
Alumina-forming austenitic steels (AFA steels) exhibit excellent creep resistance and oxidation capabilities, making them a strong candidate for cladding materials in lead-cooled fast reactors. This study investigates the corrosion resistance of Mn-containing AFA steels in lead–bismuth eutectic (LBE) at 550 °C with a [...] Read more.
Alumina-forming austenitic steels (AFA steels) exhibit excellent creep resistance and oxidation capabilities, making them a strong candidate for cladding materials in lead-cooled fast reactors. This study investigates the corrosion resistance of Mn-containing AFA steels in lead–bismuth eutectic (LBE) at 550 °C with a controlled oxygen concentration of 10−6 wt.%. The results demonstrate that under these experimental conditions, the addition of Al enhances the material’s resistance to lead–bismuth corrosion. Moreover, Mn incorporation significantly improves corrosion resistance, with the optimal composition being an AFA alloy containing 16 wt.% Ni, 12 wt.% Cr, 3 wt.% Al, and 4 wt.% Mn. Mn addition alters the type of oxide product formed on the alloy surface, shifting from Fe3O4 or (Fe, Cr)xOy to (Cr, Mn)xOy. Full article
(This article belongs to the Section Corrosion)
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15 pages, 8279 KiB  
Article
Study on Liquid Metal Embrittlement Susceptibility of T91 Exposed to Liquid Lead-Bismuth Eutectic
by Jie Zhang, Bo Qin and Bin Long
Metals 2025, 15(2), 206; https://doi.org/10.3390/met15020206 - 15 Feb 2025
Viewed by 723
Abstract
In this study, slow strain rate tensile tests (SSRT) were performed on T91 in lead-bismuth eutectic (LBE) with saturated oxygen to investigate the effects of temperature (350 °C, 450 °C, and 550 °C), strain rate (1 × 10−5/s and 2 × [...] Read more.
In this study, slow strain rate tensile tests (SSRT) were performed on T91 in lead-bismuth eutectic (LBE) with saturated oxygen to investigate the effects of temperature (350 °C, 450 °C, and 550 °C), strain rate (1 × 10−5/s and 2 × 10−6/s) and pre-exposure conditions (time, oxygen concentration) on the sensitivity to liquid metal embrittlement (LME). The results revealed that the embrittlement sensitivity of T91 in LBE is significantly influenced by temperature. LME was observed in T91 at 350 °C and disappeared when the temperature increased to 550 °C. Additionally, T91 exhibited increased sensitivity to LME at low strain rates, indicating that low strain rates promoted the occurrence of LME. Finally, through different pre-exposure conditions, it was found that the obvious LME phenomenon would only occur when the oxygen concentration was poor and the pre-exposure time was long (48 h), indicating that pre-exposure conditions have a crucial impact on the occurrence of LME. Full article
(This article belongs to the Section Corrosion and Protection)
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23 pages, 14284 KiB  
Article
Development and Performance Analysis of an Electromagnetic Pump for a Thermal Hydraulic Experimental Loop of a Lead-Cooled Fast Reactor
by Zi’ang Li, Lanfei Yuan, Chenglong Wang, Suizheng Qiu and Ying Li
Energies 2025, 18(3), 750; https://doi.org/10.3390/en18030750 - 6 Feb 2025
Viewed by 956
Abstract
With the advancement of lead–bismuth fast reactors, there has been increasing attention directed towards the design of and manufacturing technology for electromagnetic pumps employed to drive liquid lead–bismuth eutectic (LBE). These electromagnetic pumps are characterized by a simple structure, effective sealing, and ease [...] Read more.
With the advancement of lead–bismuth fast reactors, there has been increasing attention directed towards the design of and manufacturing technology for electromagnetic pumps employed to drive liquid lead–bismuth eutectic (LBE). These electromagnetic pumps are characterized by a simple structure, effective sealing, and ease of flow control. They exploit the excellent electrical conductivity of liquid metals, allowing the liquid metal to be propelled by Lorentz forces generated by the traveling magnetic field within the pump. To better understand the performance characteristics of electromagnetic pumps and master the techniques for integrated manufacturing and performance optimization, this study conducted fundamental research, development of key components, and the assembly of the complete pump. Consequently, an annular linear induction pump (ALIP) suitable for liquid lead–bismuth eutectic was developed. Additionally, within the lead–bismuth thermal experimental loop, startup and preheating experiments, performance tests, and flow-head experiments were conducted on this electromagnetic pump. The experimental results demonstrated that the output flow of the electromagnetic pump increased linearly with the input current. When the input current reached 99 A, the loop achieved a maximum flow rate of 8 m3/h. The efficiency of the electromagnetic pump also increased with the input current, with a maximum efficiency of 5.96% during the experiments. Finally, by analyzing the relationship between the flow rate and the pressure difference of the electromagnetic pump, a flow-head model specifically applicable to lead–bismuth electromagnetic pumps was established. Full article
(This article belongs to the Special Issue Thermal Hydraulics and Safety Research for Nuclear Reactors)
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16 pages, 1898 KiB  
Article
Comparative Analysis on the Characteristics of Liquid Lead and Lead–Bismuth Eutectic as Coolants for Fast Reactors
by Mian Xing, Jihong Fan, Feng Shen, Daogang Lu, Linsen Li, Hui Yu and Jin Fan
Energies 2025, 18(3), 596; https://doi.org/10.3390/en18030596 - 27 Jan 2025
Cited by 2 | Viewed by 1547
Abstract
With the increasing global demand for sustainable energy, the importance of advanced nuclear technologies, such as fourth-generation reactors, has become increasingly prominent. Fourth-generation reactors often use non-water coolants, among which liquid lead and lead–bismuth eutectics (LBEs) are highly promising, making lead-cooled fast reactors [...] Read more.
With the increasing global demand for sustainable energy, the importance of advanced nuclear technologies, such as fourth-generation reactors, has become increasingly prominent. Fourth-generation reactors often use non-water coolants, among which liquid lead and lead–bismuth eutectics (LBEs) are highly promising, making lead-cooled fast reactors (LFRs) a popular area of research internationally. On the basis of extensive analysis and comparison conducted previously, this article summarizes and analyzes the advantages, problems, and differences in lead and LBE as LFR coolants. Overall, both lead and LBE have excellent neutronic characteristics, good heat transfer performance, and chemical inertness, and make LFRs highly efficient in nuclear fuel utilization, inherently safe, and relatively simplified in design. However, both of them corrode materials severely and produce highly toxic 210Po, which are the problems that need to be considered for further engineering development. Moreover, LBE has a lower melting point, which allows a wider temperature range and lower insulation requirements in its design, making it easier to achieve engineering and miniaturization under the same conditions. Lead has a lower cost, is less corrosive to materials, and produces less 210Po, which makes it a more ideal coolant for future development. Full article
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20 pages, 2602 KiB  
Article
Collaborative Control and Intelligent Optimization of a Lead–Bismuth Cooled Reactor Based on a Modified PSO Method
by Shoujun Yan, Lijie Zhou, Lifeng Song, Huiyu Guo, Junliang Wu, Run Luo and Fuyu Zhao
Energies 2025, 18(3), 567; https://doi.org/10.3390/en18030567 - 25 Jan 2025
Cited by 2 | Viewed by 639
Abstract
Accelerator-driven subcritical (ADS) reactors with lead–bismuth eutectic (LBE) coolants are some of the Gen-IV nuclear energy systems that can generate clean electricity and potentially transmute spent fuel. The dynamic characteristics and control strategy of an ADS reactor are substantially different from those of [...] Read more.
Accelerator-driven subcritical (ADS) reactors with lead–bismuth eutectic (LBE) coolants are some of the Gen-IV nuclear energy systems that can generate clean electricity and potentially transmute spent fuel. The dynamic characteristics and control strategy of an ADS reactor are substantially different from those of traditional nuclear reactors. In this paper, a new collaborative control strategy is proposed using an accelerator beam and a control rod, and the control system’s parameters are optimized using a modified particle swarm optimization (PSO) method. To test the control performance, a simulation platform is developed with a nonlinear reactor dynamic model, a power compensation control system and a coolant temperature control system. Four typical control transients are used, including a ±10% full-power (FP) step change load and a ±5% FP/min linear variable load. The simulation results show that the collaborative control strategy has a better load tracking capability and a higher power control accuracy than the beam single-control strategy and the rod single-control strategy. The results also show that the performance of the collaborative control system in terms of the reactor’s power and coolant temperature is significantly improved based on the modified PSO parameter optimization. Full article
(This article belongs to the Special Issue Advanced Technologies in Nuclear Engineering)
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16 pages, 14579 KiB  
Article
Corrosion Resistance of Cr2O3, ZrO2, and Mn3O4 Oxide Films to Lead–Bismuth Eutectic: A Comparative Study
by Tao Liu, Wenguan Liu, Chongdou Yang, Penghui Lei, Di Yun and Jie Qiu
Materials 2024, 17(23), 5694; https://doi.org/10.3390/ma17235694 - 21 Nov 2024
Viewed by 1109
Abstract
In this study, the stability of Cr2O3, ZrO2, and Mn3O4 oxide films in high-temperature liquid lead–bismuth eutectic (LBE) was systematically investigated using both experimental and first principles calculation methods. The research findings indicated that [...] Read more.
In this study, the stability of Cr2O3, ZrO2, and Mn3O4 oxide films in high-temperature liquid lead–bismuth eutectic (LBE) was systematically investigated using both experimental and first principles calculation methods. The research findings indicated that Cr2O3 demonstrated superior structural integrity at corrosion temperatures of both 600 °C and 700 °C and displayed exceptional resistance to LBE corrosion. ZrO2 demonstrates resistance to LBE infiltration. However, the emergence of cracks in the vicinity of the ZrO2 layer and the metal interface undermines the protective layer’s integrity. Mn3O4 exhibits susceptibility to corrosion by LBE and lacks resistance to its effects. First principles calculations indicate that Pb and Bi atoms are most readily adsorbed onto the Mn3O4 surface, promoting the detachment of Mn atoms. The results show that the corrosion resistance of the three oxide films is ranked in the following order: Cr2O3 > ZrO2 > Mn3O4. Full article
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15 pages, 11180 KiB  
Article
Numerical Study on Characteristics of Lead-Bismuth Lubricated Hydrodynamic Bearing Considering Non-Condensable Gas
by Kefeng Lyu, Yuanyuan Zhang, Xudan Ma and Zude Cheng
Lubricants 2024, 12(9), 326; https://doi.org/10.3390/lubricants12090326 - 23 Sep 2024
Cited by 1 | Viewed by 982
Abstract
Lead-Bismuth Eutectic (LBE) is an interesting candidate as a coolant for Generation IV nuclear power plants. Lead-bismuth lubricated radial guide bearing is the key component of the mechanical pump in a lead-bismuth coolant system. In this paper, the transient calculation model of multiphase [...] Read more.
Lead-Bismuth Eutectic (LBE) is an interesting candidate as a coolant for Generation IV nuclear power plants. Lead-bismuth lubricated radial guide bearing is the key component of the mechanical pump in a lead-bismuth coolant system. In this paper, the transient calculation model of multiphase lubrication flow field of journal bearing is established by using Singhal full cavitation model and structured dynamic grid technique. Due to the saturated vapors of LBE being very low, the effects of different Non-Condensable Gas (NCG) contents on the characteristics of lead-bismuth lubricated journal bearing systems were analyzed. The results show that the NCG content has an obvious influence on the working state of the bearing. With the increase in NCG content, the bearing load capacity decreases. Under the same load, with the increase in NCG content, the eccentricity of the static equilibrium position will be larger, which will increase the risk of bearing contact with the bearing bush. Moreover, the increase of NCG content will lead to the increase of tangential oil film force work, which is helpful to improve rotor stability. Full article
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22 pages, 16474 KiB  
Article
Microstructure, Mechanical Properties, and Lead–Bismuth Eutectic Corrosion Behaviors of FeCrAlY-Al2O3 Nanoceramic Composite Coatings
by Qingyu Li, Yilong Zhong, Wei Zhang, Hao Liu, Jian Yang, Changda Zhu, Jiuguo Deng, Sha Zhao, Yuxin Zhong, Mingyang Zhou, Xi Qiu and Jijun Yang
Coatings 2024, 14(4), 393; https://doi.org/10.3390/coatings14040393 - 27 Mar 2024
Cited by 2 | Viewed by 1948
Abstract
Seven FeCrAlY-Al2O3 nanoceramic composite coatings are deposited on F/M steel via plasma spraying and laser remelting. A systematic investigation is conducted to examine the dependence of microstructure, mechanical properties, and lead–bismuth eutectic (LBE) corrosion resistance on the nano-Al2O [...] Read more.
Seven FeCrAlY-Al2O3 nanoceramic composite coatings are deposited on F/M steel via plasma spraying and laser remelting. A systematic investigation is conducted to examine the dependence of microstructure, mechanical properties, and lead–bismuth eutectic (LBE) corrosion resistance on the nano-Al2O3 addition and different Cr and Al contents. With the increase in Al content in FeCrAlY, gradual refinement of the coating grains occurs. The addition of nano-Al2O3 promotes the elemental segregation and precipitation of the second phase. The nano-Al2O3 notably enhances the mechanical properties of the coatings that are primarily attributed to second-phase and fine-grain strengthening. After LBE corrosion tests, intergranular corrosion morphology could be observed, where the contents of Cr and Al significantly influence the corrosion behavior of the coatings at varying temperatures. Full article
(This article belongs to the Section Ceramic Coatings and Engineering Technology)
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21 pages, 69981 KiB  
Article
On the Potential Correlation between Dynamic Strain Aging and Liquid Metal Embrittlement in T91/LBE System
by Cholidah Akbar Fitriani, Lisa Claeys, Serguei Gavrilov and Kim Verbeken
Metals 2024, 14(1), 44; https://doi.org/10.3390/met14010044 - 29 Dec 2023
Cited by 1 | Viewed by 1961
Abstract
In the study of the liquid metal embrittlement (LME) of the T91/lead-bismuth eutectic (LBE) system, it is observed that LME occurs in a temperature interval which is similar to the temperature range where dynamic strain aging (DSA) is observed. However, the potential correlation [...] Read more.
In the study of the liquid metal embrittlement (LME) of the T91/lead-bismuth eutectic (LBE) system, it is observed that LME occurs in a temperature interval which is similar to the temperature range where dynamic strain aging (DSA) is observed. However, the potential correlation between DSA and LME has not yet been satisfactorily investigated. This investigation for the T91/LBE system is exactly the topic of this work. For the evaluation of DSA and LME, slow strain rate tensile tests are conducted in the temperature range between 200 °C and 450 °C with strain rates of 5×105 s1 and 5×106 s1 in reference and a molten oxygen-depleted LBE environment. The resulting tensile properties, as well as the fracture surfaces and lateral surfaces of the failed samples, suggest a correlation between DSA and LME in the T91/LBE system. The maximum mechanical degradation of T91 is observed in the case where the effects of both DSA and LME on material properties are found to be at maximum. However, the observation of DSA was not identified as a prerequisite for LME to take place. Therefore, these results may indicate that DSA partly contributes to the ductility minimum observed in the T91/LBE system. In addition, the results of this work show that changes in the fracture surface and lateral surface are more sensitive features to claim for the potential occurrence of LME than the changes in total elongation. Full article
(This article belongs to the Special Issue Failure and Degradation of Metals)
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14 pages, 3834 KiB  
Article
Large Eddy Simulation of the Inlet Cross-Flow in the CiADS Heat Exchanger Using the Lattice Boltzmann Method
by Lu Liu, Sicheng Wang, Dawei Wang, Dajun Fan and Long Gu
Sustainability 2023, 15(19), 14627; https://doi.org/10.3390/su151914627 - 9 Oct 2023
Cited by 2 | Viewed by 1510
Abstract
The liquid lead-bismuth eutectic (LBE) is the coolant of the heat exchanger in China initiative Accelerator Driven System, which may have a risk of structural failure due to the washout of the coolant in the inlet of the heat exchanger. It is necessary [...] Read more.
The liquid lead-bismuth eutectic (LBE) is the coolant of the heat exchanger in China initiative Accelerator Driven System, which may have a risk of structural failure due to the washout of the coolant in the inlet of the heat exchanger. It is necessary to study the mechanical properties of the heat exchanger bundles of CiADS, especially the fatigue life of the bundle structure in the transverse flow of the LBE. The numerical simulation is the Lattice Boltzmann method combined with the large eddy simulation by Python codes. The velocity distribution of the flow field and the time domain characteristics of the heat exchanger bundles’ force are calculated, and the frequency domain characteristics of the heat exchanger bundles’ vibration are obtained by Fourier transform. The bundles vibrate at high cycle fatigue in turbulent flow at high Reynolds number. The transverse flow of LBE does not affect the fatigue life of the bundle. No structural failure occurs in the CiADS heat exchanger due to the transverse flow of LBE. Full article
(This article belongs to the Special Issue Nuclear Energy and Technology and Its Environmental Impact)
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19 pages, 33047 KiB  
Article
The Corrosion Behavior of Al/Al2O3 Composite Films with Ultra-Dense Structure Exposed to Lead-Bismuth Eutectic at 450 to 650 °C
by Xing Yin, Xiteng Li, Hao Wang, Ke Zhao, Jun Wang, Le Chen, Zhongzhen Wu and Yong Chen
Coatings 2023, 13(7), 1274; https://doi.org/10.3390/coatings13071274 - 20 Jul 2023
Cited by 7 | Viewed by 2602
Abstract
Al2O3 coatings are the most promising candidate material for mitigating (lead-bismuth eutectic) LBE corrosion at elevated temperatures, but preventing inward diffusion of Pb, Bi, and O for the ceramic coating remains a critical challenge. Here, we have fabricated an amorphous [...] Read more.
Al2O3 coatings are the most promising candidate material for mitigating (lead-bismuth eutectic) LBE corrosion at elevated temperatures, but preventing inward diffusion of Pb, Bi, and O for the ceramic coating remains a critical challenge. Here, we have fabricated an amorphous Al2O3 coating with an ultra-dense structure by continuous high-power magnetron sputtering (C-HPMS). After LBE corrosion at 550 °C for 2000 h, nanocavities induced by the phase transformation from amorphous to γ-Al2O3 provide the diffusion path for Fe, O, Pb, and Bi in which the corrosion products, such as Fe3O4, PbO2, or their mixed oxides, form. Furthermore, the diffusion of Pb to the substrate and Cr segregation at the interface between the coating and substrate are observed for the sample exposed to LBE at 550 °C for 4000 h. Additionally, the hardness and interface bonding strength are enhanced after LBE corrosion. Moreover, pit corrosion was found to be the main failure mode of coating, and pits that merged with each other induced large area failure at a temperature of 650 °C. The corrosion mechanism of Al2O3 includes element diffusion, phase transformation, and chemical reaction. This work not only provides a deep understanding of the corrosion mechanism of amorphous Al2O3 coatings, but also shows the optimization method on the corrosion resistance of Al2O3 coating. Full article
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11 pages, 23271 KiB  
Article
Enhanced Corrosion−Resistance of AlTiCrFeMoSi High−Entropy Alloy Coating by Magnetron Sputtering
by Li Zhang, Yunzhu Shi, Qilu Ye and Bin Yang
Coatings 2023, 13(2), 332; https://doi.org/10.3390/coatings13020332 - 1 Feb 2023
Cited by 10 | Viewed by 2139
Abstract
The amorphous AlTiCrFeMoSi high entropy alloy (HEA) coating with high hardness (11.88 GPa) is successfully deposited on T91 substrate by the magnetron sputtering method. Both T91 steel and as−deposited AlTiCrFeMoSi coating samples are exposed to a static liquid lead−bismuth eutectic (LBE) at 550 [...] Read more.
The amorphous AlTiCrFeMoSi high entropy alloy (HEA) coating with high hardness (11.88 GPa) is successfully deposited on T91 substrate by the magnetron sputtering method. Both T91 steel and as−deposited AlTiCrFeMoSi coating samples are exposed to a static liquid lead−bismuth eutectic (LBE) at 550 °C for up to 2000 h. The coating exhibits excellent corrosion resistance against lead−bismuth eutectic (LBE) compared with the uncoated T91 steel. The results show that the AlTiCrFeMoSi HEA coating has great potential in LBE−cooled fast reactor application. Full article
(This article belongs to the Special Issue Advanced High-Entropy Materials and Coatings)
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