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25 pages, 25509 KB  
Article
Mineralogical and Geochemical Features of Sulphide Mineralization: A Comparative Study of Pb-Zn Deposits in the Laki Ore District, Central Rhodopes, Bulgaria
by Georgi Milenkov, Sylvina Georgieva, Rossitsa D. Vassileva, Yana Georgieva and Elitsa Stefanova
Minerals 2026, 16(6), 616; https://doi.org/10.3390/min16060616 - 8 Jun 2026
Viewed by 1025
Abstract
The Djurkovo and Govedarnika deposits represent hydrothermal Pb-Zn systems spatially associated with the Eocene–Oligocene tectono-magmatic evolution of the Rhodope Metamorphic Complex. This study presents new mineralogical and geochemical data for galena, sphalerite, pyrite, and chalcopyrite obtained by electron probe microanalysis (EPMA) and LA-ICP-MS [...] Read more.
The Djurkovo and Govedarnika deposits represent hydrothermal Pb-Zn systems spatially associated with the Eocene–Oligocene tectono-magmatic evolution of the Rhodope Metamorphic Complex. This study presents new mineralogical and geochemical data for galena, sphalerite, pyrite, and chalcopyrite obtained by electron probe microanalysis (EPMA) and LA-ICP-MS in order to evaluate the compositional variations of sulphides among the vein and metasomatic mineralization types and between the two deposits. The analysed sulphides exhibit distinct compositional signatures reflecting the different mineralization stages and hydrothermal environments. Sphalerite from the Govedarnika metasomatic ores is enriched in Mn (up to 5200 ppm), Fe (up to 5.13 wt.%) and Co due to interaction with Mn-rich skarn assemblages, whereas Djurkovo sphalerite shows elevated Cd (up to 3000 ppm), In and Hg concentrations. Trace-element systematics indicate coupled Fe-Mn incorporation, competitive Cd-Fe substitution and local re-equilibration processes associated with “chalcopyrite disease” textures. Late pyrite from the quartz-carbonate stage is enriched in As (up to 3.87 wt.%), Au (up to 78 ppm), Ag, Se, Sb and Tl, with positive Au-As and Au-Ag correlations suggesting invisible gold and possible submicroscopic precious-metal inclusions. The obtained data demonstrate prolonged hydrothermal evolution and highlight the potential role of the studied sulphides as concentrators of economically important elements. Full article
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20 pages, 7697 KB  
Article
The Nam Xan Gold Deposit, Laos: Evidence for a Distal Intrusion-Related Gold System in the Truong Son Fold Belt
by Bounheuang Phanpasert, Ruidong Yang, Jun Chen, Patthana Bounliyong, Yifan Wen and Xinzheng Li
Minerals 2026, 16(6), 600; https://doi.org/10.3390/min16060600 - 3 Jun 2026
Viewed by 919
Abstract
The Nam Xan gold deposit is located in the central Truong Son Fold Belt of Laos. It is a newly identified distal intrusion-related gold system (IRGS) in a continental arc setting. This study uses whole-rock geochemistry, Pb and S isotope systematics, and mineral-scale [...] Read more.
The Nam Xan gold deposit is located in the central Truong Son Fold Belt of Laos. It is a newly identified distal intrusion-related gold system (IRGS) in a continental arc setting. This study uses whole-rock geochemistry, Pb and S isotope systematics, and mineral-scale analyses to trace magmatic evolution and ore-forming processes. Whole-rock data indicate that the associated intrusive suite is a calc-alkaline volcanic-arc granite (VAG) series, derived from a subduction-modified mantle source with notable crustal contributions. Pb isotopes reveal mixing arrays rather than true isochrons. Monte Carlo modeling shows binary mantle–crust mixing for igneous rocks and ternary mixing with an additional radiogenic component in ore samples, indicating enhanced fluid–rock interaction during mineralization. Sulfur isotope data show a shift from magmatic sulfur (δ34S ≈ −5‰) in early skarn-stage pyrite to heavier values (δ34S ≈ +6‰) in gold-bearing stages, reflecting fluid evolution driven by cooling and redox changes. Mineral chemistry data demonstrate that gold is present both as invisible gold within arsenian pyrite and as free gold in late-stage fractures. Strong correlations between Au and As, along with elevated Co/Ni ratios and enrichments in Bi, W, and F, collectively support a magmatic-hydrothermal origin. These findings define a three-stage mineralization process: an initial phase involving high-temperature magmatic fluids, a main stage characterized by sulfidation and gold deposition, and a final stage marked by polymetallic overprinting. The Nam Xan deposit is therefore interpreted as the distal manifestation of a Permian arc-related magmatic system in which magmatic fluids migrated along structural conduits and precipitated gold through interaction with carbonate host rocks. The identification of these intrusions in the distal IRGS at Nam Xan informs regional exploration models in the Truong Son Fold Belt, demonstrating the potential of carbonate platforms near Permian intrusions for future mineral exploration. Full article
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30 pages, 1867 KB  
Article
Asymmetric and Time-Varying Lag Structures in Bitcoin’s Kimchi Premium: Rolling-Window Evidence from Granger Causality and Transfer Entropy
by Insu Choi
Mathematics 2026, 14(9), 1501; https://doi.org/10.3390/math14091501 - 29 Apr 2026
Cited by 2 | Viewed by 1723
Abstract
The Kimchi Premium—the persistent price wedge between Bitcoin on Korean and global exchanges—has resisted standard no-arbitrage explanations for over seven years, raising the question of how macro-financial shocks transmit into this segmented market. Prior work relies on static, linear estimators applied over short [...] Read more.
The Kimchi Premium—the persistent price wedge between Bitcoin on Korean and global exchanges—has resisted standard no-arbitrage explanations for over seven years, raising the question of how macro-financial shocks transmit into this segmented market. Prior work relies on static, linear estimators applied over short lag horizons, leaving the timing, nonlinearity, and regime dependence of the Premium’s adjustment largely untested. We address this gap using daily data from December 2017 to December 2025 (T=2105) and rolling windows of 60, 120, and 240 trading days. Linear dynamics are tested with Granger causality (GC) and—because our return series are strongly leptokurtic (Bitcoin excess kurtosis =7.29, S&P 500 =14.77)—complemented by the Kraskov k-nearest-neighbor transfer entropy (TE) estimator, which captures conditional dependence in higher moments. Inference rests on a stationary bootstrap with pre-specified lag grids to avoid optimistic argmax bias, block-permutation tests for window-level detection rates, and Benjamini–Hochberg and Storey q-value corrections for multiple testing. Robustness is examined through conditional GC and conditional TE controlling for USD/KRW as a common factor, Toda–Yamamoto tests on price levels, a percentage-premium specification, a U.S. trading-day shift to address asynchrony, and winsorization sensitivity. We deliberately adopt a conservative inference stance at the panel level: window-level detection rates and pointwise bootstrap p-values are reported, but claims of “causality” are reserved for the within-window descriptive ranking of channels and horizons, with the panel-level null assessed by block-permutation and Benjamini–Hochberg corrections. Four empirical patterns emerge under this framing. First, Johansen tests identify a single cointegrating vector between Korean and global Bitcoin prices (trace =91.99 vs. 5% critical value 15.49), establishing the Premium as a stationary deviation from long-run parity, while none of the four macro indicators cointegrate with global Bitcoin. Second, GC detection rates for the Premium concentrate at the 240-day horizon: Gold → Premium reaches 23.3% (95% Wilson CI [19.3%,27.8%]), KOSPI 200 → Premium 16.3%, and USD/KRW → Premium 16.8%. Third, the Kraskov TE reveals an asymmetry invisible to linear tests: for Gold → Premium at w=240, the median optimal lag is five days, against one day for Gold → Bitcoin (chi-square p=0.017). Percentage-premium detection rates are substantially higher (e.g., 59.1% for Gold → Premium at w=240), indicating that the dollar-wedge specification understates causal strength. Fourth, block-permutation tests do not reject the global null of no window-level excess rejection, and Benjamini–Hochberg rejects no pair at α=0.05; we therefore read the detection-rate evidence as descriptive of localized, crisis-dependent transmission episodes rather than as panel-level rejection of pointwise non-causality, and the paper’s contribution is accordingly positioned at the level of channel ranking, lag structure, and regime decomposition rather than at the level of blanket causality claims. Crisis decomposition shows transmission is concentrated in the ETF-Halving regime (29.8% mean GC detection) and below 4% during the Terra–Luna (2.9%) and Russia–Ukraine (3.6%) episodes. The findings situate the Premium as a stationary error-correction term whose adjustment is dominated by exchange-rate and commodity channels rather than U.S. equities, with implications for arbitrage models, regulatory monitoring, and information-flow analyses of segmented crypto markets. Full article
(This article belongs to the Special Issue Advances in Data-Driven Modeling: Theory and Applications)
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26 pages, 4860 KB  
Article
Trace-Element Systematics and Multivariate Insights into Gold Fertility of Arsenopyrite from the Um Rus Orogenic Gold Deposit, Central Eastern Desert, Egypt
by ElSayed A. Saber, H. M. Hamouda, A. S. Hamid and Ahmed A. El-Sheikh
Minerals 2026, 16(5), 439; https://doi.org/10.3390/min16050439 - 23 Apr 2026
Viewed by 626
Abstract
Arsenopyrite (FeAsS) is an important sulfide that holds gold in orogenic systems. Its arsenic content is often used as a proxy for gold fertility. However, arsenopyrite from the Um Rus gold deposit in Egypt’s Central Eastern Desert shows a complicated gold distribution that [...] Read more.
Arsenopyrite (FeAsS) is an important sulfide that holds gold in orogenic systems. Its arsenic content is often used as a proxy for gold fertility. However, arsenopyrite from the Um Rus gold deposit in Egypt’s Central Eastern Desert shows a complicated gold distribution that makes simple Au-As correlations hard to make. Integrated electron microprobe analysis (EMPA), laser ablation ICP-MS, and principal component analysis (PCA) reveal three unique textural and geochemical domains. Fine-grained arsenopyrite inclusions within pyrite aggregates (28–31 at% As) are devoid of detectable gold; PCA elucidates 84% of their variance through Fe–S versus Co-As substitution (PC1: 61.8%) and Pb-decoupled variability (PC2: 22.2%), suggesting crystallization from a Co-rich, Au-poor fluid. On the other hand, coarse oscillatory-zoned arsenopyrite can hold up to 6154 ppm of invisible gold. This is because of a moderate Au-As substitution (R = 0.41063, p = 0.08074) that was overprinted by a separate Au-Ag-Sb-Te hydrothermal pulse (Au–Ag: R = 0.97762; Au–Sb: R = 0.97608). PCA finds four parts (72.8% variance): Ag-Cu-As associations (PC1: 25.1%), Te versus Bi-Au signatures (PC2: 17.8%), Fe–S stoichiometry (PC3: 17.1%), and an Au versus Pb-decoupled event (PC4: 12.9%). This shows that minerals formed in more than one stage. Irregular As-rich overgrowths, containing ≤950 ppm gold and lacking significant Au–As correlation (R = −0.14011, p = 0.56726), show PCA (74.3% variance) that highlights S-As contrasts (PC1: 25.2%), Co-Ni enrichment (PC2: 18.8%), Cu-Fe-Ni associations (PC3: 16.2%), and a late Au-decoupled event (PC4: 14.2%), indicating barren recrystallization. These results show that just adding arsenic is not a good way to tell if gold is fertile. The highest amounts of invisible gold, on the other hand, are found in oscillatory-zoned domains with Ag-Sb-Te signatures. This research highlights the importance of combining PCA, geochemistry, and microtextures to differentiate auriferous from barren arsenopyrite, thereby enhancing exploration methodologies for structurally intricate orogenic gold systems. Full article
(This article belongs to the Special Issue Gold–Polymetallic Deposits in Convergent Margins)
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21 pages, 9466 KB  
Article
Mineralogy and In Situ Sulfur Isotope Geochemistry of Pyrite: Implications for Ore-Forming Processes of the Moshan Gold Deposit, Jiaodong Peninsula, North China
by Faqiang Zhao, Zhimin Li, Tongliang Tian, Peng Guo, Bin Li, Huaidong Luo, Yongliang Qi, Jiepeng Tian and Pengpeng Zhang
Minerals 2026, 16(4), 344; https://doi.org/10.3390/min16040344 - 24 Mar 2026
Cited by 1 | Viewed by 655
Abstract
The Jiaodong gold-mineralized area is one of the most significant gold districts in China. The newly discovered Moshan gold deposit is hosted in the Late Jurassic Queshan granite, previously considered a prospecting blind zone. In this study, pyrite from the Moshan gold deposit [...] Read more.
The Jiaodong gold-mineralized area is one of the most significant gold districts in China. The newly discovered Moshan gold deposit is hosted in the Late Jurassic Queshan granite, previously considered a prospecting blind zone. In this study, pyrite from the Moshan gold deposit is examined as the primary research subject. To elucidate the ore-forming processes and genetic mechanisms of this deposit, we conducted a comprehensive mineralogical and geochemical study on pyrite, the principal gold-bearing mineral. EPMA and LA-MC-ICP-MS analyses reveal that the pyrite is slightly sulfur-deficient (average S/Fe ratio of 1.976) and exhibits trace element variations (As, Co, and Ni) strongly correlated with distinct metallogenic stages. Gold occurs in various forms, including visible inclusion gold, fracture gold, and invisible nano-particulate gold (Au0). The in situ sulfur isotope δ34S values range from 7.11‰ to 9.40‰ (average 8.00‰), displaying high homogeneity and a positive deviation from the troilite in the Canyon Diablo iron meteorite. By integrating pyrite S-Fe relationships, Co-Ni-As systematics, and sulfur isotope characteristics, the study indicates that the Moshan gold deposit originates from a magmatic-hydrothermal source. The ore-forming materials predominantly derive from Mesozoic granite-derived magmatic-hydrothermal fluids, with a minor contribution from crustal basement materials. The depth of mineralization is interpreted as mid-shallow. These findings not only highlight the metallogenic potential of the Queshan granite and clarify the genetic relationship between the Moshan gold deposit and other regional gold deposits but also provide a novel theoretical foundation and technical support for deep gold exploration in the Jiaodong region. Full article
(This article belongs to the Section Mineral Deposits)
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37 pages, 33342 KB  
Article
In Situ Analyses of Sulphides from the Tomingley Gold Project, Central-West NSW, Australia: Pathfinder Textures and Trace Elements
by Muhammad Fariz Bin Md Nasir, Indrani Mukherjee, Alexander Cherry, Ian Graham, Karen Privat and Ivan Belousov
Minerals 2026, 16(3), 335; https://doi.org/10.3390/min16030335 - 21 Mar 2026
Viewed by 885
Abstract
This study investigated sulphide textures and trace element chemistry from the Tomingley Gold Project (TGP) region of Central-West NSW, eastern Australia, using in situ techniques. In particular, the study focused on pyrite and arsenopyrite to gain insights into ore-forming processes and determine which [...] Read more.
This study investigated sulphide textures and trace element chemistry from the Tomingley Gold Project (TGP) region of Central-West NSW, eastern Australia, using in situ techniques. In particular, the study focused on pyrite and arsenopyrite to gain insights into ore-forming processes and determine which trace elements within these minerals can be used as potential pathfinder elements for mineral exploration in the TGP. A total of 41 drill core samples from a variety of lithologies (volcaniclastic, monzodiorite, graphitic siltstone, dacite, andesite) were described and analysed using reflected light microscopy, high-resolution microscopy (via Scanning Electron Microscope or SEM), elemental mapping (via Electron Probe Micro Analysis or EPMA) and targeted trace element analysis of sulphide grains (via Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry or LA-ICP-MS). Findings show that pyrite and arsenopyrite are the major sulphides that host fracture-fill/inclusions of native gold and ‘invisible gold’. Pyrite rich in groundmass inclusions should be evaluated due to their characteristic high concentrations of both As and Au. Pyrite trace element chemistry (Sn, Bi, W, Sb, Au and Se) was able to delineate mineralised from unmineralised samples in volcaniclastics, graphitic siltstones and andesites but was much more challenging for lithologies like dacites and monzodiorites. The study also found that Au may have been introduced into the system earlier and existed as ‘invisible gold’ in earlier generations of pyrite. This study highlighted the utility of in situ techniques to discriminate mineralised signatures from unmineralised samples, and this has proven to be far more effective compared to whole-rock techniques, emphasising the benefits of such datasets in mineral exploration. Full article
(This article belongs to the Special Issue Gold Deposits: From Primary to Placers and Tailings After Mining)
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18 pages, 5504 KB  
Article
Genesis of the Yawan Gold Deposit, West Qinling Orogen: Insights from Calcite U-Pb Geochronology and Geochemistry of Sulfides
by Chang-Qing Dong, Zhao-Hua Bai, Ke Yang, Meng-Zhen Hao, Jia-Yi Wang, Hao Zhou and Jia-Nan Fu
Minerals 2026, 16(1), 114; https://doi.org/10.3390/min16010114 - 22 Jan 2026
Viewed by 1076
Abstract
The Yawan gold deposit, located in the Western Qinling Orogen, contains gold mineralisation that is predominantly controlled by approximately east-west-trending fault systems. This study integrates field geology, petrography, cathodoluminescence imaging, electron probe microanalysis of gold-bearing minerals (pyrite and arsenopyrite), and in situ laser [...] Read more.
The Yawan gold deposit, located in the Western Qinling Orogen, contains gold mineralisation that is predominantly controlled by approximately east-west-trending fault systems. This study integrates field geology, petrography, cathodoluminescence imaging, electron probe microanalysis of gold-bearing minerals (pyrite and arsenopyrite), and in situ laser ablation U-Pb dating of calcite to constrain the timing of mineralisation and to elucidate the mechanisms of gold enrichment. This study reveals that the deposit is significantly structurally controlled and comprises two discrete mineralisation stages: a quartz-pyrite (Py1)-arsenopyrite (Apy1)-chalcopyrite assemblage (Stage 1), and a quartz-calcite-pyrite (Py2)-arsenopyrite (Apy2)-stibnite-sphalerite-galena assemblage (Stage 2). Py1 displays distinct zonation, with rim As contents notably higher than core values, while Co and Ni contents gradually decrease from core to rim. Py2 is characterised by high As (0.00%–4.72%), low Fe/S ratios, and a porous texture, containing gold and arsenopyrite inclusions. Invisible gold occurs in lattice-bound form in both Py1 and Py2. The As-Fe-S ternary diagram of pyrite indicates that Au+ likely entered the crystal lattice as a solid solution. Arsenopyrite geothermometry yields a mineralisation temperature of 389 ± 44 °C, and sulfur fugacity (ƒS2) decreased markedly from Stage 1 to Stage 2. Combined with the S and Fe characteristics of pyrite, these features support a medium-temperature metamorphic hydrothermal environment. U-Pb dating of calcite from Stage 2 yields an age of 215.6 ± 7.1 Ma. In summary, the Yawan gold deposit belongs to the orogenic gold system, with its gold precipitation and enrichment controlled by sulfidation triggered by Late Triassic tectono-fluid activity. Full article
(This article belongs to the Special Issue Gold–Polymetallic Deposits in Convergent Margins)
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18 pages, 69163 KB  
Article
Mechanisms of Gold Enrichment and Precipitation at the Sawayardun Gold Deposit, Southwestern Tianshan, Xinjiang, China
by Weiyu Ding, Lin Meng, Jiangang Ding, Shengtao Li, Xiuzhi Yang, Xiaoyi Hou and Wenjie Yu
Minerals 2026, 16(1), 39; https://doi.org/10.3390/min16010039 - 29 Dec 2025
Viewed by 1232
Abstract
The mechanisms of massive gold migration and enrichment are challenging issues in mineral deposit research. The evolution of the elements and structures of gold-bearing minerals is the key to revealing the mechanisms of gold enrichment and migration. The Sawayardun gold deposit has an [...] Read more.
The mechanisms of massive gold migration and enrichment are challenging issues in mineral deposit research. The evolution of the elements and structures of gold-bearing minerals is the key to revealing the mechanisms of gold enrichment and migration. The Sawayardun gold deposit has an ore reserve of 127 t located in the southwestern Tianshan, Xinjiang, China. It is an ideal place for studying the mechanisms of massive gold migration and precipitation. However, the occurrence and distribution of gold are unclear, preventing an understanding of the massive gold enrichment and precipitation mechanism in the Sawayardun gold deposit. Therefore, in this study, the microscopic structural characteristics and chemical compositions of sulfides and gold minerals in the deposit were comprehensively analyzed using scanning electron microscopy (SEM) and electron probe microanalysis (EPMA) techniques. The mineralization evolution is divided into a metamorphosed sedimentary period and a hydrothermal mineralization period, with the latter further subdivided into four mineralization stages: the quartz–pyrite stage, the arsenopyrite–pyrite stage, the polymetallic sulfide stage, and the carbonate stage. EPMA analysis reveals no clear compositional trends among different pyrite generations. Arsenopyrite (Apy) is more enriched in Au and Sb than pyrite. Overall, arsenopyrite is S-rich and As-deficient. Compared to Apy2, Apy1 is enriched in Fe and S but depleted in As. Stibnite is closely associated with native gold and contains elevated Au (up to 3.63%). Invisible gold exists in a form that is visible at the micrometer-to-atomic scale within pyrite and is lattice-bound in arsenopyrite. Visible gold occurs as native grains in quartz fractures or within sulfides. The composition of pyrite indicates that the Sawayardun gold deposit formed in a reducing, medium-depth, meso-epithermal environment. Au extraction by Sb-rich melts, dissolution–reprecipitation, and adsorption by As-bearing pyrite were the primary mechanisms for Au migration and precipitation. This study contributes to understanding the enrichment and precipitation processes of gold in orogenic-gold deposits in southwestern Tianshan. Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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27 pages, 13692 KB  
Article
Evolution of the Hydrothermal Fluids Inferred from the Occurrence and Isotope Characteristics of the Carbonate Minerals at the Pogo Gold Deposit, Alaska, USA
by Yuichi Morishita and Jamie R. Rogers
Minerals 2025, 15(1), 67; https://doi.org/10.3390/min15010067 - 12 Jan 2025
Cited by 1 | Viewed by 3191
Abstract
Pogo is identified as a deep-seated, intrusion-related gold deposit. Carbonate minerals have a close spatial relationship to hydrothermal gold mineralization in all of its principal ore zones. The carbon and oxygen isotopic ratios of carbonate minerals (siderite, ankerite, and calcite) present within the [...] Read more.
Pogo is identified as a deep-seated, intrusion-related gold deposit. Carbonate minerals have a close spatial relationship to hydrothermal gold mineralization in all of its principal ore zones. The carbon and oxygen isotopic ratios of carbonate minerals (siderite, ankerite, and calcite) present within the deposit illustrate the isotopic evolution of the ore-forming fluid. The initial hydrothermal fluid phase is interpreted to be magmatic in origin. The fluid evolution was characterized by a gradual decrease in δ18O and a slight increase in δ13C with decreasing temperature. The dominant carbon-bearing species was CO2, with methane introduced sporadically. Siderite is associated with early-stage mineralization and occurs with ankerite in main-stage ore assemblages. Calcite is recognized in the later stages of mineralization. Gold in the Pogo deposit occurs as native gold, Au-Bi-Te minerals, inclusions in sulfide minerals, or as “invisible gold”. The latter is found in pyrite, chalcopyrite, arsenopyrite, and quartz, based on ion microprobe analysis. The presence of invisible gold in these minerals has significant metallurgical implications for gold processing at the Pogo mine. Full article
(This article belongs to the Special Issue Geochemistry and Genesis of Hydrothermal Ore Deposits)
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26 pages, 20145 KB  
Article
In Situ Compositional and Sulfur Isotopic Analysis of Sphalerite from the Erdaodianzi Gold Deposit in Southern Jilin Province, Northeast China
by Qingqing Shang, Fengdi Ren, Qun Yang and Bin Wang
Minerals 2025, 15(1), 57; https://doi.org/10.3390/min15010057 - 7 Jan 2025
Cited by 7 | Viewed by 2244
Abstract
The newly discovered Erdaodianzi gold deposit in southern Jilin Province, Northeast China, is located in the eastern segment of the northern margin of the North China Craton (NCC). It is a large-scale gold deposit with reserves of 38.4 tons of gold. Gold mineralization [...] Read more.
The newly discovered Erdaodianzi gold deposit in southern Jilin Province, Northeast China, is located in the eastern segment of the northern margin of the North China Craton (NCC). It is a large-scale gold deposit with reserves of 38.4 tons of gold. Gold mineralization in the ore district primarily occurs in gold-bearing quartz–sulfide veins. The gold ore occurs mainly as vein, veinlet, crumby, and disseminated structures. The hydrothermal process can be divided into three stages: stage I, characterized by quartz, arsenopyrite, and pyrite; stage II, featuring quartz, arsenopyrite, pyrite, pyrrhotite, chalcopyrite, sphalerite, and native gold; and stage III, consisting of quartz, pyrite, sphalerite, galena, electrum (a naturally occurring Au–Ag alloy), and calcite. Electrum and native gold primarily occur within the fissures of the polymetallic sulfides. To determine the enrichment mechanism of the Au element and the genetic types of ore deposits in the Erdaodianzi deposit, sourcing in situ trace element data, element mapping and sulfur isotope analysis were carried out on sphalerites from different stages using LA-ICP-MS. Minor invisible gold, in the form of Au–Ag alloy inclusions, is present within sphalerites, as revealed by time-resolved depth profiles. The LA-ICP-MS trace element data and mapping results indicate that trivalent or quadrivalent cations, such as Sb3+ and Te4+, exhibit a strong correlation with Au. This correlation can be explained by a coupled substitution mechanism, where these cations (Sb3+ and Te4+) replace zinc ions within the mineral structure, resulting in a strong association with Au. Similarly, the element Pb exhibits a close relationship with Au, which can be attributed to the incorporation of tetravalent cations like Te4+ into the mineral structure. The positive correlation between Hg and Au can be attributed to the formation of vacancies and defects within sphalerite, caused by the aforementioned coupled substitution mechanism. A slight positive relationship between Au and other divalent cations, including Fe2+, Mn2+, and Cd2+, may result from these cations simply replacing Zn within the sphalerite lattice. The crystallization temperatures of the sphalerite, calculated via the Fe/Zn ratio, range from 238 °C to 320 °C. The δ34S values are divided into two intervals: one ranging from −1.99 to −1.12‰ and the other varying from 10.96 to 11.48‰. The sulfur isotopic analysis revealed that the ore-forming materials originated from magmatic rock, with some incorporation of metamorphic rock. Comparative studies of the Erdaodianzi gold deposit and other gold deposits in the Jiapigou–Haigou gold belt have confirmed that they are all mesothermal magmatic–hydrothermal lode gold deposits formed at the subduction of the Paleo-Pacific Plate beneath the Eurasian Plate during the Middle Jurassic. The Jiapigou–Haigou gold belt extends northwest to the Huadian area of Jilin province. This suggests potential for research on gold mineralization in the northwest of the belt and indicates a new direction for further gold prospecting in the region. Full article
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20 pages, 14201 KB  
Article
The Study of Gold Mineralization at the Polymetallic Dapingzhang VMS-Type Copper–Gold Deposit, Yunnan Province, China
by Shanshan Ru, Guo Li, Chuandong Xue, Feng Li, Shunhong Zou, Wei Wang and Honglin Zhou
Minerals 2025, 15(1), 54; https://doi.org/10.3390/min15010054 - 7 Jan 2025
Cited by 2 | Viewed by 3115
Abstract
The Dapingzhang Cu-polymetallic deposit in Yunnan is a volcanic massive sulfide (VMS) deposit, located on the western edge of the Lanping–Simao block. Recently, gold-rich polymetallic orebodies with significant economic value have been discovered. However, the occurrence and enrichment mechanisms of the gold remain [...] Read more.
The Dapingzhang Cu-polymetallic deposit in Yunnan is a volcanic massive sulfide (VMS) deposit, located on the western edge of the Lanping–Simao block. Recently, gold-rich polymetallic orebodies with significant economic value have been discovered. However, the occurrence and enrichment mechanisms of the gold remain unclear. This study investigates the massive sulfide orebodies (V1) through detailed geological surveys. Techniques such as optical microscopy, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and electron probe microanalysis (EPMA) were used to clarify the occurrence of gold, and to reveal the enrichment mechanisms. The genesis of the orebodies consists of three stages: (I) pyrite–quartz, (II) pyrite–chalcopyrite–sphalerite–galena–quartz, and (III) pyrite–chalcopyrite–sphalerite–galena–quartz–calcite. Gold precipitated during each of these mineralization stages, and it may be described as multiphase mineralization. Gold predominantly exists as invisible gold (≤0.1 μm), with minor visible gold as native gold and independent minerals (küstelite, electrum, calaverite). Invisible gold mainly occurs as gold microinclusions (Au+) in pyrite, chalcopyrite, and sphalerite. Combined with the previous research, comprehensive analysis determined that deep-circulating seawater, driven by a magmatic hydrothermal system, leaches and dissolves mineralizing materials from underlying volcanic rocks. The mineralizing fluid, mixed with magmatic fluid, migrates upward through volcanic conduits or is expelled to the seafloor. Changes in physicochemical conditions lead to the co-precipitation of gold and sulfides, forming a mineralization structure with lower channel facies and upper eruptive facies. Full article
(This article belongs to the Section Mineral Deposits)
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26 pages, 9981 KB  
Article
Ore Formation and Mineralogy of the Alattu–Päkylä Gold Occurrence, Ladoga Karelia, Russia
by Vasily I. Ivashchenko
Minerals 2024, 14(11), 1172; https://doi.org/10.3390/min14111172 - 18 Nov 2024
Viewed by 1704
Abstract
The Alattu–Päkylä gold occurrence is located in the Northern Lake Ladoga area, in the Raaha-Ladoga suprasubduction zone, at the Karelian Craton (AR)—Svecofennian foldbelt (PR1) boundary. Its gold ore mineral associations are of two types of mineralization: (1) copper–molybdenum–porphyry with arsenopyrite and [...] Read more.
The Alattu–Päkylä gold occurrence is located in the Northern Lake Ladoga area, in the Raaha-Ladoga suprasubduction zone, at the Karelian Craton (AR)—Svecofennian foldbelt (PR1) boundary. Its gold ore mineral associations are of two types of mineralization: (1) copper–molybdenum–porphyry with arsenopyrite and gold (intrusion-related) and (2) gold–arsenopyrite–sulfide in shear zones. Optical and scanning electron microscopy, X-ray fluorescence spectrometry, inductively coupled plasma mass spectrometry (ICP-MS), instrumental neutron activation analysis (INAA) and fire analysis with AAS finishing were used to study them. Type 1 was provoked by shallow-depth tonalite intrusion (~1.89 Ga) and type 2 by two stages of Svecofennian metamorphism (1.89–1.86 and 1.83–1.79 Ga) with the possible influence of the impactogenesis of the Janisjärvi astrobleme (age ~1 Ga). Intrusive and host rocks were subjected to shearing accompanied by the formation of ore-bearing metasomatic rocks of the propylite-beresite series (depending on substrate) and quartz–sericite, quartz and sericite–tourmaline veins and streaks. Ore mineralization is present as several consecutive mineral associations: pyritic–molybdenite with arsenopyrite and gold; gold–arsenopyrite; quartz–arsenopyrite with antimony sulfosalts of lead; gold–polysulfide with tetrahedrite –argentotetrahedrite series minerals and gold–antimony with Pb–Sb–S system minerals and native antimony. Arsenopyrite contains invisible (up to 234 ppm) and visible gold. Metamorphosed domains in arsenopyrite and rims with visible gold around it are usually enriched in As, indicating higher (up to >500 °C) temperatures of formations than original arsenopyrite with invisible gold (<500 °C). A paragenetic sequence associated with the deposition of invisible and visible gold established at the Alattu–Päkylä ore occurrence: pyrrhotite + unaltered arsenopyrite (with invisible gold) → altered arsenopyrite (As-enriched) + pyrite ± pyrrhotite + visible gold. Gold, associated with gudmundite, sphalerite and native antimony, seems to be due to cainotypic rhyodacitic porphyry cutting tonalite intrusion or with a retrograde stage in post-Svecofennian metamorphism. The isotopic composition of Pb and 238U/204Pb (9.4–9.75) for the feldspar of the tonalite intrusion and the pyrite of gold mineralization, εNd (−4 up to −5) for tonalites and ẟ34S values of −2.10–+4.99 for arsenopyrite, indicate the formation of gold occurrence provoked by Svecofennian magmatic and tectono-thermal processes with the involvement of matter from a mantle-lower crustal reservoir into magma formation and mineralization. Full article
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19 pages, 8741 KB  
Article
Genesis of Xinjiazui Gold Deposit: In Situ Geochemical Constraints from Arsenopyrite
by Ji Liu, Shaolei Kou, Zhanbin Wang, Yixiang Zhang, Yuan Pan, Dongping Ji, Yuan Tian, Hao Chen and Chao Gao
Minerals 2024, 14(10), 1031; https://doi.org/10.3390/min14101031 - 15 Oct 2024
Cited by 4 | Viewed by 2062
Abstract
The Xinjiazui gold deposit marks a notable significance in prospecting within the Back-Longmenshan tectonic belt, located on the northwest margin of the Yangtze Block, China. Despite the extensive studies conducted on this deposit, the source of the ore-forming materials remains unclear, leading to [...] Read more.
The Xinjiazui gold deposit marks a notable significance in prospecting within the Back-Longmenshan tectonic belt, located on the northwest margin of the Yangtze Block, China. Despite the extensive studies conducted on this deposit, the source of the ore-forming materials remains unclear, leading to ongoing debates regarding the genesis of this deposit. This study analyzed in situ (EPMA and LA-ICP-MS) trace elements and S-Pb isotopes of arsenopyrite, solely from the principal metallogenic stage and paragenetic with native gold. The results show that the gold in arsenopyrite occurs as invisible gold (Au3+), with an average concentration of 9.38 ppm, whereas the concentrations of magma-related elements, such as W, Sn, Mo, and Bi, are very low. The sulfur isotopes (34S) of arsenopyrite range from 8.32‰ to 10.16‰, aligning closely with the deep metamorphic basement (Pt3l). Meanwhile, the lead isotopes in arsenopyrite display characteristics typical of those found in orogenic belts. A comprehensive analysis of the abundance of gold indicated that the metallogenic materials (sulfur and gold) primarily originated from Pt3l. Additionally, the arsenopyrite thermobarometer indicated that the Xinjiazui gold deposit formed in a medium–low-temperature, medium metallogenic environment (5.57–8.69 km), with a sulfur fugacity (log f (S2)) below −8.4. Combined with previous research results, this study proposes that the Xinjiazui gold deposit is a subduction-related mesozonal orogenic gold deposit. In gold prospecting and exploration in the Back-Longmenshan tectonic belt, it is essential to focus on the distribution of brittle-ductile shear zones and location of the quartz veins associated with pyrite and arsenopyrite mineralization. Full article
(This article belongs to the Special Issue The Formation and Evolution of Gold Deposits in China)
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20 pages, 15855 KB  
Review
Storytelling of Myocarditis
by Gaetano Thiene
Biomedicines 2024, 12(4), 832; https://doi.org/10.3390/biomedicines12040832 - 9 Apr 2024
Cited by 4 | Viewed by 3474
Abstract
In 1900, Fiedler first reported autopsy cases with peculiar inflammation of the myocardium, which he named interstitial myocarditis. He postulated an isolated cardiac inflammation of the myocardium in the absence of multiorgan involvement and with a poor prognosis due to invisible microorganisms, which [...] Read more.
In 1900, Fiedler first reported autopsy cases with peculiar inflammation of the myocardium, which he named interstitial myocarditis. He postulated an isolated cardiac inflammation of the myocardium in the absence of multiorgan involvement and with a poor prognosis due to invisible microorganisms, which years later would have been identified as viruses. The revision of original histologic sections by Schmorl showed cases with lymphocytes and others with giant-cell inflammatory histotypes. The in vivo diagnosis of myocarditis became possible thanks to right cardiac catheterization with endomyocardial biopsy (EMB). The gold standard for diagnosis was achieved with the employment of immunohistochemistry and molecular investigation by Polymerase Chain Reaction (PCR), which allows for the detection of viruses as causal agents. Both RNA and DNA were revealed to be cardiotropic, with a common receptor (CAR). A protease, coded by coxsackie virus, disrupts the cytoskeleton and accounts for cell death. Unfortunately, vaccination, despite having been revealed to be effective in animal experiments, has not yet entered the clinical field for prevention. Cardiac Magnetic Resonance turned out to be a revolutionary tool for in vivo diagnosis through the detection of edema (inflammatory exudate). Myocarditis may be fulminant in terms of clinical presentation but not necessarily fatal. The application of ExtraCorporeal Membrane Oxygenation (ECMO) allows for relieving the overloaded native heart. Full article
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28 pages, 7482 KB  
Article
Coupled Microstructural EBSD and LA-ICP-MS Trace Element Mapping of Pyrite Constrains the Deformation History of Breccia-Hosted IOCG Ore Systems
by Samuel Anthony King, Nigel John Cook, Cristiana Liana Ciobanu, Kathy Ehrig, Yuri Tatiana Campo Rodriguez, Animesh Basak and Sarah Gilbert
Minerals 2024, 14(2), 198; https://doi.org/10.3390/min14020198 - 15 Feb 2024
Cited by 14 | Viewed by 5461
Abstract
Electron backscatter diffraction (EBSD) methods are used to investigate the presence of microstructures in pyrite from the giant breccia-hosted Olympic Dam iron–oxide copper gold (IOCG) deposit, South Australia. Results include the first evidence for ductile deformation in pyrite from a brecciated deposit. Two [...] Read more.
Electron backscatter diffraction (EBSD) methods are used to investigate the presence of microstructures in pyrite from the giant breccia-hosted Olympic Dam iron–oxide copper gold (IOCG) deposit, South Australia. Results include the first evidence for ductile deformation in pyrite from a brecciated deposit. Two stages of ductile behavior are observed, although extensive replacement and recrystallization driven by coupled dissolution–reprecipitation reaction have prevented widespread preservation of the earlier event. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) element maps of pyrite confirm that many pyrite grains display compositional zoning with respect to As, Co, and Ni, but that the zoning is often irregular, patchy, or otherwise disrupted and are readily correlated with observed microstructures. The formation of ductile microstructures in pyrite requires temperatures above ~260 °C, which could potentially be related to heat from radioactive decay and fault displacements during tectonothermal events. Coupling EBSD methods with LA-ICP-MS element mapping allows a comprehensive characterization of pyrite textures and microstructures that are otherwise invisible to conventional reflected light or BSE imaging. Beyond providing new insights into ore genesis and superimposed events, the two techniques enable a detailed understanding of the grain-scale distribution of minor elements. Such information is pivotal for efforts intended to develop new ways to recover value components (precious and critical metals), as well as remove deleterious components of the ore using low-energy, low-waste ore processing methods. Full article
(This article belongs to the Special Issue Microanalysis Applied to Mineral Deposits)
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