Search Results (69)

The shear characteristics of the frozen soil–concrete interface are core parameters in frost heave resistance design in cold-region engineering, and the influence mechanism of interface roughness on these characteristics is not clear. In this study, the regulatory effect of different roughness levels (R-0 to R-4) on the interfacial freezing strength was quantitatively analyzed for the first time through direct shear tests, and the evolution characteristics of the contribution ratio of the ice cementation strength were revealed. The results show that the peak shear strength of the interface increases significantly with the roughness (when the normal stress is 400 kPa and the water content is 14%, the increase in R-4 is 47.7% compared with R-0); the ice cementation strength increases synchronously and its contribution ratio increases with the increase in roughness. Although the absolute value of the residual strength increase is small, the relative amplitude is larger (178.5% increase under the same working conditions). The peak cohesion increased significantly with the roughness (R-0 to R-4 increased by 268.6%), while the residual cohesion decreased. The peak and residual internal friction angle increased slightly with the roughness. The study clarifies the differential influence mechanism of roughness on the interface’s shear parameters and provides a key quantitative basis for the anti-frost heave design of engineering interfaces in cold regions. Full article

In engineering practice, liquid droplet impingement typically occurs at an oblique angle relative to the target surface, yet the influence of impact orientation on damage outcomes remains contentious and exhibits target-material dependency. In this paper, a typical single-waterjet-generating technique is applied to liquid impact tests on a unidirectional carbon fiber-reinforced polymer (CFRP) laminate, with special focus on the effects of the impingement angle and the fiber orientation. Finite-element simulation is employed to help reveal the failure mechanism of oblique impacts. The results show that, in most cases, the damage caused by a 15° oblique impact is slightly larger than that of a normal impact, while the increase amplitude varies with different impact speeds. Resin removal is more prone to occur when the projection of the waterjet velocity on the impact surface is perpendicular (marked as the fiber orientation PE) rather than parallel (marked as the fiber orientation PA) to the fiber direction of the top layer. A PE fiber orientation can lead to mass material peeling in comparison with PA, and the damage range is even much larger than for a normal impact. The underlying mechanism can be attributed to the increased lateral jet-particle velocity and resultant shear stress along the impact projection direction. The distinct damage modes observed on the CFRP laminate with the different fiber orientations PE and PA originate from the asymmetric tensile properties in the longitudinal/transverse directions of laminates coupled with dissimilar fiber–matrix interfacial characteristics. A theoretical model for the surface damage area under a single-jet impact was established through experimental data fitting based on a modified water-hammer pressure contact-radius formulation. The model quantitatively characterizes the influence of critical parameters, including the jet velocity, diameter, and impact angle, on the central area of the surface failure ring. Full article

By applying different heat treatment processes (furnace cooling, air cooling, and water cooling), the stress–strain behavior of the localized interfacial region in weathering steel–stainless steel clad plates was investigated using nanoindentation, along with an analysis of interfacial microstructure formation and strengthening mechanisms. The results show that samples in the as-rolled (R), furnace-cooled (FC), air-cooled (AC), and water-cooled (WC) conditions exhibit distinct interfacial morphologies and local mechanical properties. A well-defined interfacial layer forms between the base and cladding materials, where a high density of dislocations, grain boundaries, precipitates, and nanoscale oxides significantly enhances interfacial strength, resulting in a yield strength (R_p0.2) much higher than that of either adjacent metal. Across the transition from weathering steel to stainless steel, the interfacial region consists of ferrite—interfacial layer—“new austenite”—stainless steel austenite. Its formation is predominantly governed by element diffusion, which is strongly influenced by the applied heat treatment. Variations in diffusion behavior significantly affect the microstructural evolution of the dual-phase transition zone at the interface, thereby altering the local mechanical response. Full article

Natural polymer-based nanoparticles have emerged as promising stabilizers for Pickering emulsions, offering biocompatibility, environmental sustainability, and improved protection of active compounds. This study developed chitosan/gum arabic (CH/GA) nanoparticles as solid stabilizers for quercetin-loaded Pickering emulsions to enhance the stability and antioxidant bioactivity of quercetin (QE), a plant-derived flavonoid known for its potent radical-scavenging activity but limited by oxidative degradation. A systematic formulation strategy was employed to evaluate the effects of CH/GA concentration (0.5–2.0% w/v), oil type (olive, soybean, sunflower, and coconut), and oil volume fraction (ϕ = 0.5–0.7) on emulsion stability. The formulation containing 1.5% CH/GA and olive oil at ϕ = 0.6 exhibited optimal physical and interfacial stability. Quercetin (0.1% w/w) was incorporated into the optimized emulsions and characterized for long-term stability, particle size, droplet morphology, rheology, antioxidant activity (DPPH), cytocompatibility, and intracellular reactive oxygen species (ROS) protection using HaCaT keratinocytes. The olive oil-based formulation (D1-QE) exhibited greater viscosity retention and antioxidant stability than its soybean-based counterpart (E2-QE) under both room temperature (RT) and accelerated heating–cooling (H/C) storage conditions. Confocal microscopy confirmed the accumulation of CH/GA nanoparticles at the oil–water interface, forming a dense interfacial barrier and enhancing emulsion stability. HPLC analysis showed that D1-QE retained 92.8 ± 0.5% of QE at RT and 82.8 ± 1.5% under H/C conditions after 30 days. Antioxidant activity was largely preserved, with only 4.7 ± 1.7% and 14.9 ± 4.8% loss of DPPH radical scavenging activity at RT and H/C, respectively. Cytotoxicity testing in HaCaT keratinocytes confirmed that the emulsions were non-toxic at 1 mg/mL QE and effectively reduced H₂O₂-induced oxidative stress, decreasing intracellular ROS levels by 75.16%. These results highlight the potential of CH/GA-stabilized Pickering emulsions as a polymer-based delivery system for maintaining the stability and functional antioxidant activity of QE in bioactive formulations. Full article

This study investigates the industrial potential of red gypsum (RG), a major by-product of titanium dioxide (TiO₂) production, for the development of thermoplastic polypropylene (PP)-based composites via melt extrusion, targeting agricultural applications. Prior to compounding, RG was thermally treated at approximately 200 °C to remove residual moisture and chemically bound water, resulting in its anhydrous form (CaSO₄). PP/RG composites were then formulated with RG loadings up to 20 wt.%, employing stearic acid (SA) as a compatibilizer. The resulting materials were thoroughly characterized and successfully processed through industrial-scale injection molding up to 250 °C. Morphological and FTIR analyses confirmed the role of SA in enhancing both filler dispersion and interfacial adhesion between RG and the PP matrix. SEM images revealed finer and more uniformly distributed RG particles, resulting in a reduced loss of ductility and elongation at break typically associated with filler addition. Specifically, the Young’s Modulus increased from 1.62 GPa (neat PP) up to 3.21 GPa with 20 wt.% RG and 0.6 wt.% SA. The addition of 0.6 wt.% SA also helped limit the reduction in stress at break from 46.68 MPa (neat PP) to 34.05 MPa and similarly mitigated the decrease in Charpy impact energy, which declined slightly from 2.66 kJ/m² (neat PP) to 2.24 kJ/m² for composites containing 20 wt.% RG. Preliminary phytotoxicity was assessed using germination tests on Lepidium sativum L. seeds. Eluates from both untreated and SA-treated RG powders resulted in germination indices below 80%, indicating phytotoxicity likely due to high sulfate ion concentrations. In contrast, eluates from composite pellets exhibited germination indices equal to or exceeding 100%, demonstrating the absence of phytotoxic effects. These results highlight the suitability of the developed composites for applications in floriculture and horticulture. The optimized composite pellets were successfully processed via injection molding to manufacture plant pots, which exhibited a dark brown coloration, confirming the effective pigmenting function of RG. These results demonstrate the potential of red gypsum to serve both as a functional filler and pigment in PP composites, providing a sustainable alternative to iron oxide pigments and promoting the valorization of industrial waste through resource recovery. Full article

With growing emphasis on sustainable construction, fiber-reinforced polymer (FRP) bars are increasingly being used as alternatives to steel rebars due to their high strength-to-weight ratio, corrosion resistance, and environmental benefits. This study has investigated the bond behavior between FRP bars and concrete of different strength grades under dynamic loading conditions. To analyze the microscopic properties of FRP bar surfaces, the study employs a variety of techniques, including scanning electron microscopy (SEM), atomic force microscopy (AFM), and non-contact surface profilometry. In addition, X-ray photoelectron spectroscopy (XPS), water contact angle (WCA) measurements, and energy dispersive spectrometry (EDS) are used to further investigate surface characteristics. The results reveal a direct correlation between the resin surface roughness of FRP bars and their wettability characteristics, which in turn influence the cement hydration process. Pull-out tests under different loading rates and concrete strength grades have been conducted to evaluate the bond–slip behavior and failure modes. The results indicate that bond strength increases with increasing concrete strength. Dynamic pull-out tests further reveal that higher loading rates generate heterogeneous stress fields, which limit the deformation of FRP bars and consequently diminish the contribution of mechanical interlock to interfacial bonding. Full article

Hydraulic concrete is subject to severe durability challenges when abraded by the high-speed flow of sandy water. Conventional concrete frequently needs to be repaired because of its high brittleness and insufficient abrasion resistance, while granular rubber can easily be dislodged from the matrix during abrasion, forming a new source of abrasion and increasing the damage to the matrix. For this reason, we used fibrous rubber concrete to systematically study the mechanisms of the influence of the dosage of nitrile rubber (5%, 10%, and 15%) and fiber length (6, 12, and 18 mm) on resistance to impact and abrasion performance. Through mechanical tests, underwater steel ball abrasion tests, three-dimensional morphology measurements, and fractal dimension analysis, the law behind the damage evolution of fibrous rubber concrete was revealed. The results show that concrete with 15% NBR and 12 mm fibers yielded the best performance, and its 144-hour abrasion resistance reached 25.0 h/(kg/m²), which is 163.7% higher than that for the baseline group. Fractal dimension analysis (D = 2.204 for the optimum group vs. 2.356 for the benchmark group) showed that the fiber network effectively suppressed surface damage extension. The long-term mass loss rate was only 2.36% (5.82% for the benchmark group), and the elastic energy dissipation mechanism remained stable under dynamic loading. The results of a microanalysis showed that the high surface roughness of NBR enhances interfacial bonding, which synergizes with crack bridging and stress dispersion and, thus, forms a multiscale anti-impact abrasion barrier. This study provides a new material solution for the design of durable concrete for use in high-impact and high-abrasion environments, which combines mechanical property preservation and resource recycling value. However, we did not systematically examine the evolution of the performance of fiber rubber concrete concrete under long-term environmental coupling conditions, such as freeze–thaw cycles, ultraviolet aging, or chemical attacks, and there are limitations to our assessment of full life-cycle durability. Full article

We systematically investigated the anchorage performance of self-drilling anchor bolts in strongly weathered dolomite through integrated field pull-out tests and FLAC3D numerical modeling. The study incorporates symmetry principles in both experimental design and numerical simulations to ensure balanced force distribution and model simplification. Experimental data collected from a slope reinforcement project demonstrated that grouting parameters of 0.8 MPa pressure and 0.8 water–cement ratio achieved an interfacial bond strength of 0.147 MPa, surpassing the recommended value by 22.5%. A modified FLAC3D pile element, calibrated against RS6-01 anchor bolt test data, exhibited improved alignment with load–displacement curves, converging to 272 kN ultimate capacity at 26.1 mm displacement. Symmetrical anchor configurations in the numerical model reduced computational complexity while maintaining accuracy in stress distribution analysis. Through orthogonal experimental design, symmetry-driven parameter optimization identified a 7 m bolt length, 30° installation angle, and 2 m spacing as the most effective configuration. This solution increased the slope safety factor by 19.98% while reducing displacements by 46–62%. The symmetry in anchor spacing and angular alignment contributed to uniform stress redistribution, enhancing slope stability. The findings highlight the synergy between symmetry principles and geotechnical reinforcement strategies. Full article

To investigate the lubrication mechanism of phytic acid (PA) solution, a “copper–PA solution–copper” confined model with varying concentrations was established. Molecular dynamics (MD) simulations were employed to model the behavior of compression and the confined shear process. By examining the variations in key parameters such as dynamic viscosity, compressibility, radial distribution function, relative concentration distribution, and velocity distribution of PA solutions under different normal loads or shear rates, we elucidated the lubrication mechanism of PA solutions at the molecular level. The results demonstrate that under standard loading conditions, higher PA concentrations facilitate the formation of denser hydrated layers with decreased compressibility compared to free water, thereby significantly enhancing the load-bearing capacity. The shear stress at the solution–copper interface exhibits a substantial increase as the shear rate rises. This phenomenon originates from shear-driven migration of PA to the copper interface, disrupting the hydration layers and weakening hydrogen bonds. Consequently, this reduction in PA–water interactions amplifies slip velocity differences, ultimately elevating interfacial shear stress. The load-bearing capacity of the PA solution and the interfacial shear stress between the PA and copper are critical factors that influence the lubrication mechanism at the PA/Cu interface. This study establishes a theoretical foundation for the design and application of PA solution as a water-based lubricant, which holds significant importance for advancing the development of green lubrication technology. Full article

This study advances the theory of power-law fluid infiltration grouting by developing spherical and columnar diffusion models rooted in fractal porous media theory and power-law rheological equations. An analytical solution for determining the slurry diffusion radius is derived and validated through laboratory experiments and numerical simulations. Key findings include the following: (1) The fractal permeability constant demonstrates an exponential dependence on the rheological index (n), with a critical threshold at n = 0.4. Below this threshold, the constant asymptotically approaches zero (slope < 0.1), while beyond it, sensitivity intensifies exponentially, attaining 0.48 at n = 0.9. (2) Non-linear positive correlations exist between the slurry diffusion radius and both the grouting pressure (P) and the water–cement ratio (W/C). Spherical diffusion dominates over columnar diffusion, with their ratio shifting from 1:0.96 at P = 0.1 MPa to 1:0.82 at P = 0.5 MPa. The diffusion distance differential increases from 22 mm to 38 mm as the W/C rises from 0.5 to 0.7, attributable to reduced interfacial shear resistance from decreasing slurry viscosity and yield stress. (3) Experimental validation confirms exponentially decaying model errors: spherical grouting errors decrease from 21.54% (t = 5 s) to 8.43% (t = 15 s) and columnar errors from 25.45% to 10.17%, both within the 50% engineering tolerance. (4) Numerical simulations show that the meander fractal dimension (48 mm) demonstrates a higher sensitivity than the volume fractal dimension (37 mm), with both dimensions reaching maximum values. These findings establish a theoretical framework for optimizing grouting design in heterogeneous porous media. Full article

The entire deformation and overturning of numerous engineering structures commence from the failure of the interface between engineering structures and environmental soils, and the shear band formed by such failure results in variations in the water transfer law within the soil. In this study, a direct shear test was carried out to analyze the alterations in dry density of the soil both inside and outside the shear band before and after the disruption of the interface between lean clay and structure bodies, and the effect of the shear band on water migration in lean clay in the interface area under different shear displacements and normal stress values was examined. A numerical model of water transfer in lean clay with the shear band was constructed to predict the soil water distribution in the interfacial band across various temporal and spatial conditions. The results indicated that the existence of the shear band in the interface delayed the water migration; shear displacement and normal stress substantially affected the rate of water migration and volumetric water content in the interface region. The established water migration model could effectively simulate the migration patterns of water in the interface region and model the entire process of changes in free water in the soil under different spatial and temporal conditions. The research findings can provide a reference for the evaluation of structural permeability stability in hydraulic engineering. Full article

In the waterway construction projects of the upper reaches of the Yangtze River, crushed mudstone particles are widely used to backfill the foundations of rock-socketed concrete-filled steel tube (RSCFST) piles, a structure widely adopted in port constructions. In these projects, the steel–mudstone interfaces experience complex loading conditions, and the surface profile tends to vary within certain ranges during construction and operation. The changes in boundary conditions and material profile significantly impact the bearing performance of these piles when subjected to cyclic loads, such as ship impacts, water level fluctuations, and wave-induced loads. Therefore, it is necessary to investigate the shear characteristics of the RSCFST pile–soil interface under cyclic vertical loading, particularly in relation to varying deformation levels in the steel casing’s outer profile. In this study, a series of cyclic direct shear tests are carried out to investigate the influential mechanisms of roughness on the cyclic behavior of RSCFST pile–soil interfaces. The impacts of roughness on shear stress, shear stiffness, damping ratio, normal stress, and particle breakage ratio are discussed separately and can be summarized as follows: (1) During the initial phase of cyclic shearing, increased roughness correlates with higher interfacial shear strength and anisotropy, but also exacerbates interfacial particle breakage. Consequently, the sample undergoes more significant shear contraction, leading to reduced interfacial shear strength and anisotropy in the later stages. (2) The damping ratio of the rough interface exhibits an initial increase followed by a decrease, while the smooth interface demonstrates the exact opposite trend. The variation in damping ratio characteristics corresponds to the transition from soil–structure to soil–soil interfacial shearing. (3) Shear contraction is more pronounced in rough interface samples compared to the smooth interface, indicating that particle breakage has a greater impact on soil shear contraction compared to densification. Full article

The viability of using Juncus acutus fibers as reinforcement material for developing lightweight sustainable non-structural construction materials in compliance with the valorization of local by-products has been investigated in this work. This study aims to investigate the effect of the chemical treatment of Juncus acutus fibers on the mechanical and hygric properties of bio-sourced clay–sand–Juncus acutus fiber composite. This lightweight specimen has been produced from a mixture of 60% natural clay and 40% sand by mass, as a matrix, and reinforced with different amounts of Juncus fibers. The fibers were used as a partial replacement of sand in the mixture by volume at 0% (control specimen), 5%, 10%, and 20%. In order to enhance interfacial bonding between the fibers and the binder matrix, which seriously limits the strength development of the composite, the fibers have undergone an NaOH alkali treatment with different concentrations of 1 and 2 wt. %. Morphological and elementary chemical component evaluations based on SEM micrographs and EDX analyses revealed that the 1 wt. % NaOH alkali treatment exhibited the most beneficial effect due to the removal of impurity deposits without significant surface damage to the fibers. This finding was highlighted through the tensile tests carried out which showed the tensile stress value of 81.97 MPa compared to those of the treated fibers with 2% NaOH (74.45 MPa) and the untreated fibers (70.24 MPa). However, mechanical test results, carried out according to the European Standard EN 196-1, highlighted the beneficial effect of the fiber alkali treatment on both the compressive and flexural strengths, particularly for the fiber contents of 5% and 10%, which corresponds to a strengthening rate of 25% and 30%, respectively. The examination of the hygroscopic properties of the samples, including capillary water absorption, water diffusivity, and moisture buffering capacity under the dynamic conditions have indicated that the specimen containing treated fibers exhibited a better moisture regulating property than that obtained with untreated fibers. However, the specimens with treated fibers are classified as excellent hygric regulators based on their moisture buffer values (MBV > 2 g/(m².%RH)), according to the NORDTEST classification. The results also indicated that the capillary water absorption and the apparent moisture diffusivity of composites were lowered due to high fiber-matrix interfacial bond after fiber treatment. Consequently, the composite with treated fibers is less diffusive compared to that with untreated fibers, and thus expected to be more durable in a humid environment. Full article

This study investigates the tensile behavior of carbon-fiber-reinforced polymer (CFRP) and textile-reinforced mortar (TRM) under various design variables to enhance understanding and application in construction structures. TRM reinforced with CFRP grids is highly effective for strengthening existing structures due to its lightweight nature, durability, ease of installation, and corrosion resistance. The research aims to evaluate how design parameters such as the CFRP grid type, mortar matrix strength (influenced by the water-to-cement ratio), specimen length, and grid width affect TRM’s mechanical properties. Through the direct tensile test using a universal testing machine, TRM specimens were subjected to load until failure, with data collected on stress–strain relationships, crack patterns, and strengths. Specimens included untreated CFRP grids (Groups KC, Q47, and Q85) and sand-coated CFRP grids (Specimens AQ47_7 and AQ85_7), each tested under controlled laboratory conditions. The results indicate that crack formation significantly influenced load transfer mechanisms within the specimens, with longitudinal strands bearing load as cracks propagated through the mortar matrix. The presence of sand-coated CFRP grids notably enhanced interfacial bond strength, leading to increased cracking strength and ultimate strength compared with their untreated counterparts. The findings underscore the importance of the surface treatment of CFRP grids for improving TRM performance, with implications for enhancing structural integrity and durability in practical applications. The results provide valuable insights into optimizing TRM design for better crack control and mechanical efficiency in infrastructure. Full article

The interface between soil and concrete in cold climates has a significant effect on the structural integrity of embedded structures, including piles, liners, and others. In this study, a novel temperature control system was employed to conduct direct shear tests on this interface. The test conditions included normal stress (25 to 100 kPa), temperature (ranging from 20 to −6 °C), water content (from 10 to 19%), and shear rates (0.1 to 1.2 mm/min). Simultaneously, the deformation process of the interface was continuously photographed using a modified visual shear box, and the non-uniform deformation mechanism of the interface was analyzed by combining digital image correlation (DIC) technology with the photographic data. The findings revealed that the shear stress–shear displacement curves did not exhibit a discernible peak strength at elevated temperatures, indicating deformation behavior characterized by strain hardening. In the frozen state, however, the deformation softened, and the interfacial ice bonding strength exhibited a positive correlation with decreasing temperature. When the initial water content was 16% and the normal stress was 100 kPa, the peak shear strength increased significantly from 99.9 kPa to 182.9 kPa as the test temperature dropped from 20 °C to −6 °C. Both shear rate and temperature were found to have a marked effect on the peak shear strength, with interface cohesion being the principal factor contributing to this phenomenon. At a shear rate of 0.1 mm/min, the curve showed hardening characteristics, but at other shear rates, the curves exhibited strain-softening behavior, with the softening becoming more pronounced as shear rates increased and temperatures decreased. Due to the refreezing of interfacial ice, the residual shear strength increased in proportion to the reduction in shear rate. On a mesoscopic level, it was evident that the displacement of soil particles near the interface exhibited more pronounced changes. At lower shear rates, the phenomenon of interfacial refreezing became apparent, as evidenced by the periodic changes in interfacial granular displacement at the interface. Full article