Search Results (38)

This study presents the performance of a multi-gas sensor for greenhouse detection based on quartz-enhanced photoacoustic spectroscopy (QEPAS). The QEPAS sensor exploits an innovative, compact three-wavelength laser module as excitation source. The module integrates three interband cascade laser chips with a beam combining system, all enclosed in a compact metallic package with sizes of 40 × 52 × 17 mm to generate a single output beam. The multi-gas QEPAS sensor was tested in a laboratory environment for the sequential detection of two greenhouse gases, methane (CH₄) and carbon dioxide (CO₂), and a precursor greenhouse gas, carbon monoxide (CO). At an integration time of 100 ms, minimum detection limits of 21 ppb, 363 ppb, and 156 ppb, were estimated for CH₄, CO_2, and CO detection, respectively, all well below their natural abundance in air. Full article

Efficient, reliable, and low-cost mid-infrared interband cascade lasers (ICLs) are needed to meet the growing demands of many useful applications such as chemical sensing, environmental and greenhouse gas monitoring, detection of pipe leaks and explosives, food safety, medical diagnostics, and industrial process control. We review the developments and status of ICLs from a historic perspective, discuss the lessons learnt from experience, and suggest considerations for future research and development. This review endeavors to include the most representative aspects and activities of ICLs, but cannot possibly describe every contribution in the 30 years since the initiation of ICLs. We present an overall picture of the ICL architecture and connect the fundamental principle and underlying physics to future activities. Full article

We numerically investigate the dynamics of an interband cascade laser (ICL) subjected to amplitude-modulated optical injection from a directly modulated master ICL. In comparison with steady-state optical injection, the proposed modulated optical injection significantly enlarges the chaos region. In excess of 10 GHz broadband mid-infrared chaos is obtained at large bias currents and with a high gain stage number for the appropriate choice of master-slave detuning, modulation frequency, and modulation depth. Full article

The long-wave infrared (LWIR) interband cascade detector with type-II superlattices (T2SLs) and a gallium-free (“Ga-free”) InAs/InAsSb (x = 0.39) absorber was characterized by photoluminescence (PL) and spectral response (SR) methods. Heterostructures were grown by molecular beam epitaxy (MBE) on a GaAs substrate (001) orientation. The crystallographic quality was confirmed by high-resolution X-Ray diffraction (HRXRD). Two independent methods, combined with theoretical calculations, were able to determine the transitions between the superlattice minibands. Moreover, transitions from the trap states were determined. Studies of the PL intensity as a function of the excitation laser power allowed the identification of optical transitions. The determined effective energy gap (E_g) of the tested absorber layer was 116 meV at 300 K. The transition from the first light hole miniband to the first electron miniband was red-shifted by 76 meV. The detected defects’ energy states were constant versus temperature. Their values were 85 meV and 112 meV, respectively. Moreover, two additional transitions from acceptor levels in cryogenic temperature were determined by being shifted from blue to E_g by 6 meV and 16 meV, respectively. Full article

Tunable diode laser spectroscopy (TDLS) is a measurement technique with high spectral resolution. It is based on tuning the emission wavelength of a semiconductor laser by altering its current and/or its temperature. However, adjusting the wavelength leads to a change in emission intensity. For applications that rely on modulated radiation, the challenge is to isolate the true spectrum from the influence of extraneous instrumental contributions, particularly residual intensity and wavelength modulation. We present a novel approach combining TDLS with interferometric techniques, exemplified by the use of a Mach–Zehnder interferometer, to enable the separation of intensity and wavelength modulation. With interferometrically enhanced intensity modulation, we reduced the residual wavelength modulation by 83%, and with interferometrically enhanced wavelength modulation, we almost completely removed the residual derivative of the signal. A reduction in residual wavelength modulation enhances the spectral resolution of intensity-modulated measurements, whereas a reduction in residual intensity modulation improves the signal-to-noise ratio and the sensitivity of wavelength-modulated measurements. Full article

Tunable laser spectroscopy (TLS) with infrared (IR) imaging is a powerful tool for gas leak detection. This study focuses on direct absorption spectroscopy (DAS) that utilizes wavelength modulation to extract gas information. A tunable interband cascade laser (ICL) with an optical power of 5 mW is periodically modulated by a sawtooth injection current at 10 Hz across the methane absorption around 3271 nm. A fast and sensitive thermal imaging camera for the mid-infrared range between 3 and 5.7 µm is operated at a frame rate of 470 Hz. Offline processing of image stacks is performed using different algorithms (DAS-F, DAS-f and DAS-2f) based on the Lambert–Beer law and the HITRAN database. These algorithms analyze various features of gas absorption, such as area (F), peak (f) and second derivative (2f) of the absorbance. The methane concentration in ppm*m is determined on a pixel-by-pixel analysis without calibration. Leak localization for methane leak rates as low as 0.25 mL/min is accurately displayed in a single concentration image with pixelwise sensitivities of approximately 1 ppm*m in a laboratory environment. Concentration image sequences represent the spatiotemporal dynamics of a gas plume with high contrast. The DAS-2f concept demonstrates promising characteristics, including accuracy, precision, 1/f noise rejection, simplicity and computational efficiency, expanding the applications of DAS. Full article

Quartz-Enhanced Photoacoustic Spectroscopy (QEPAS) is a technique in which the sound wave is detected by a quartz tuning fork (QTF). It enables particularly high specificity with respect to the excitation frequency and is well known for an extraordinarily sensitive analysis of gaseous samples. We have developed the first photoacoustic (PA) cell for QEPAS on solid samples. Periodic heating of the sample is excited by modulated light from an interband cascade laser (ICL) in the infrared region. The cell represents a half-open cylinder that exhibits an acoustical resonance frequency equal to that of the QTF and, therefore, additionally amplifies the PA signal. The antinode of the sound pressure of the first longitudinal overtone can be accessed by the sound detector. A 3D finite element (FE) simulation confirms the optimal dimensions of the new cylindrical cell with the given QTF resonance frequency. An experimental verification is performed with an ultrasound micro-electromechanical system (MEMS) microphone. The presented frequency-dependent QEPAS measurement exhibits a low noise signal with a high-quality factor. The QEPAS-based investigation of three different solid synthetics resulted in a linearly dependent signal with respect to the absorption. Full article

The Tibet Plateau is known as the “third pole” of the world, and its environmental change profoundly impacts East Asia and even the global climate. HDO is the stable isotope of water vapor, which acts as an ideal tracer for studying the water cycle, and which is commonly used for atmospheric circulation and climatic studies. To monitor the water vapor isotopic abundance in the Tibetan Plateau, a portable laser heterodyne radiometer was operated in Golmud in August 2019. The radiometer utilizes a narrow-linewidth 3.66 μm distributed feedback interband cascade laser as the local oscillator, the heterodyne module is been optimized and the radiometer performs with high resolution and stability in obtaining spectral data. Furthermore, the absorption spectra of atmospheric HDO and H₂O are obtained, and the retrieval method for water vapor isotopic abundance is discussed. The optimal estimation method is adopted to retrieve the density of HDO and H₂O. The average column density of H₂O was 1.22 g/cm², and the HDO/H₂O ratio in Golmud was 178 ± 15 × 10⁻⁶ during the observation. For a better understanding of the retrieval, the retrieval errors are analyzed and compared. The results indicate that the smoothing error is significantly higher than the measurement error in this work. The backward trajectory analysis of atmospheric transport is used to investigate the relationship between water vapor density and atmospheric motion. The results indicate that the variation of H₂O column density and HDO/H₂O ratio have a relationship with atmospheric movements. Full article

Nitrous oxide (laughing gas, N₂O) is a relevant greenhouse gas. Agriculture contributes significantly to its emissions. As nitrogen fertilization has been identified as one of the main sources of N₂O, controlled application and reduction of the amount of fertilizer adapted to crop demand is essential to reduce N₂O emissions. This requires detailed studies of the local distribution of the N₂O emission fluxes on different croplands. Consequently, frequent spatially resolved field measurements of N₂O concentrations are needed. A precision in the ppb range close to the ambient N₂O level of 333 ppb is necessary. Tunable laser absorption spectroscopy using quantum-cascade lasers (QCL) as a light source is an established technique for the measurement of N₂O traces. We present the development and validation of a compact portable setup for on-site measurement of N₂O emissions from the soil. The setup differs from previous solutions by using an interband cascade laser (ICL), which has significantly lower power consumption compared to a QCL. The portable measurement setup allows N₂O emission fluxes to be determined with a precision of 3.5% with a measuring duration of 10 min. The developed system enables the detection of increased N₂O emissions because of the fertilization of fields. High N₂O emission fluxes are indicators of the overfertilization of the field. Directly after fertilization, N₂O fluxes between 2.9 and 5.3 µL m⁻² min⁻¹ depending on the gas acquisition site are measured during the field tests. Over time, the fluxes decrease. The obtained results compare well with data from more precise but also more complex and maintenance-intensive instruments for atmospheric research. With this system, the soil moisture as well as the air humidity and air temperature are recorded. Strong influences on N₂O fluxes by soil moisture were observed. The presented measurement system is a contribution to the establishment of mobile N₂O screening systems that are robust in the field and suitable for comprehensive and routine detection of N₂O emissions from soil. Full article

Gas detection based on photoacoustic spectroscopy (PAS) has attracted extensive attention due to its high sensitivity and large range of linearity. Herein, to achieve the simultaneous detection of the light carbon gases (CH₄, C₂H₄, and C₂H₆), a gas detection system was constructed using a single mid-infrared tunable diode laser (central wavelength 3345 nm) source based on differential Helmholtz resonance spectroscopy (DHRS). The detection parameters (driving current, modulation depth, phase angle, etc.) were optimized under ambient pressure using the 1f demodulation method. With an integration time of 2 s, the detection limit reached 98.8 ppb, 252 ppb, and 33 ppb for methane, ethylene, and ethane, respectively. The validation test of the three-component mixture shows that the cross-interference can be effectively reduced by multiwavelength linear regression, and single wavelength linear regression causes large errors in the quantification of methane and ethylene. Full article

A tunable diode laser absorption spectroscopy (TDLAS)-based spectrometer employing a mid-infrared (Mid-IR) interband cascade laser (ICL) was developed and used to determine pressure broadening coefficients of two NO absorption transitions at 1914.98 cm⁻¹ and 1915.76 cm⁻¹ in the fundamental (1←0) band (R11.5 Ω1/2 and Ω3/2) for CO₂, N₂, Ar, O₂, He, and H₂. For the first time, a reliable and consistent set of six different pressure-broadening coefficients for the NO line has been measured by a consistent approach covering pressures from 100 to 970 mbar at a temperature of 294 K. Air pressure broadening has been calculated based on N₂ and O₂ coefficients. The stated pressure-broadening coefficients for N₂, CO₂, Ar, H₂, O₂, He, and Air have relative errors in the 0.5–1.5% range. For CO₂ and H_2, broadening results of NO (1←0) band (R11.5 Ω1/2 and Ω3/2) lines are reported for the first time. The results are also compared to previously available literature data. It was found that the broadening coefficients for O₂ and Air are in agreement with literature values, whereas results for Ar and He show larger differences. Full article

During industrial operations and in confined places, carbon monoxide (CO) may collect in harmful proportions if ventilation is insufficient or appliances are not properly maintained. When the concentration of CO is too high, it might result in suffocation, coma, or even death. The detection of tiny concentrations of CO plays an important role in safe production. Due to the selective absorption of specific wavelengths of light by gas molecules, lasers have a wide range of applications in the field of gas detection. In this paper, a tunable diode laser absorption spectroscopy (TDLAS) system for CO detection was constructed using an interband cascaded laser (ICL) with a central wavelength of 4.625 μm. The modulated signal generated by the FPGA module was output to the laser controller to modulate the laser. The signal received by the detector was input to the FPGA module. After lock-in amplification, the second harmonic signal of high frequency modulation was output. Several concentrations of CO that were dispersed via static gas distribution were identified. A CO detection system with an open optical path was constructed, and the detection distance was about 8 m. The minimum detectable concentration is around 10.32 ppmm. The concentration of CO in the open optical path was 510.6 ppmm, according to the calibration of the detected concentration. The remote detection system based on TDLAS using an ICL can be used to monitor CO in the open optical path. Full article

Given the exquisite capability of direct, non-destructive label-free sensing of molecular transitions, IR spectroscopy has become a ubiquitous and versatile analytical tool. IR application scenarios range from industrial manufacturing processes, surveillance tasks and environmental monitoring to elaborate evaluation of (bio)medical samples. Given recent developments in associated fields, IR spectroscopic devices increasingly evolve into reliable and robust tools for quality control purposes, for rapid analysis within at-line, in-line or on-line processes, and even for bed-side monitoring of patient health indicators. With the opportunity to guide light at or within dedicated optical structures, remote sensing as well as high-throughput sensing scenarios are being addressed by appropriate IR methodologies. In the present focused article, selected perspectives on future directions for IR spectroscopic tools and their applications are discussed. These visions are accompanied by a short introduction to the historic development, current trends, and emerging technological opportunities guiding the future path IR spectroscopy may take. Highlighted state-of-the art implementations along with novel concepts enhancing the performance of IR sensors are presented together with cutting-edge developments in related fields that drive IR spectroscopy forward in its role as a versatile analytical technology with a bright past and an even brighter future. Full article

In this work, we experimentally investigate the nonlinear dynamics of an interband cascade laser (ICL) under variable-aperture optical feedback implemented by a gold mirror combining with a ring-actuated iris diaphragm (RAID). By continuously varying the diameter of RAID (D_R), the evolution of the dynamical state of ICL with the aperture of the optical feedback can be inspected. The characteristics of each dynamical state are characterized by time series, power spectra, phase portraits, and Lyapunov exponents. The results show that, with the decrease of D_R, the dynamical state of the ICL under variable-aperture optical feedback presents an evolution from complex, simple to stable. Diverse dynamical states including period one state (P1), period two state (P2), multi-period state (MP), quasi-period state (QP), low-frequency fluctuation (LFF), chaotic state (C), and hyperchaos have been observed. Through mapping the evolution of dynamical states with D_R for the ICL biased at different currents, different evolved routes of the dynamical states are revealed. Full article

Remote sensing of HDO and CH₄ could provide valuable information on environmental and climatological studies. In a recent contribution, we reported a 3.53 μm distributed feedback (DFB) inter-band cascade laser (ICL)-based heterodyne radiometer. In the present work, we present the details of measurements and inversions of HDO and CH₄ at Dunhuang, Northwest of China. The instrument line shape (ILS) of laser heterodyne radiometer (LHR) is discussed firstly, and the spectral resolution is about 0.004 cm⁻¹ theoretically according to the ILS. Furthermore, the retrieval algorithm, optimal estimation method (OEM), combined with LBLRTM (Line-by-line Radiative Transfer Model) for retrieving the densities of atmospheric HDO and CH₄ are investigated. The HDO densities were retrieved to be less than 1.0 ppmv, while the CH₄ densities were around 1.79 ppmv from 20 to 24 July 2018. The correlation coefficient of water vapor densities retrieved by LHR and EM27/SUN is around 0.6, the potential reasons for the differences were discussed. Finally, in order to better understand the retrieval procedure, the Jacobian value and the Averaging Kernels are also discussed. Full article