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15 pages, 2256 KiB  
Article
In Vivo Wear Analysis of Leucite-Reinforced Ceramic Inlays/Onlays After 14 Years
by Ragai-Edward Matta, Lara Berger, Oleksandr Sednyev, Dennis Bäuerle, Eva Maier, Werner Adler and Michael Taschner
Materials 2025, 18(15), 3446; https://doi.org/10.3390/ma18153446 - 23 Jul 2025
Viewed by 288
Abstract
Material wear significantly impacts the clinical success and longevity of dental ceramic restorations. This in vivo study aimed to assess the wear behavior of IPS Empress® glass-ceramic inlays and onlays over 14 years, considering the influence of different antagonist materials. Fifty-four indirect [...] Read more.
Material wear significantly impacts the clinical success and longevity of dental ceramic restorations. This in vivo study aimed to assess the wear behavior of IPS Empress® glass-ceramic inlays and onlays over 14 years, considering the influence of different antagonist materials. Fifty-four indirect restorations of 21 patients were available for comprehensive wear analysis, with complete follow-up data for up to 14 years. Three-dimensional measurements relied on digitized epoxy resin models produced immediately post-insertion (baseline) and subsequently at 2, 4, and 14 years. The occlusal region on the baseline model was delineated for comparative analysis. Three-dimensional superimpositions with models from subsequent time points were executed to assess wear in terms of average linear wear and volumetric loss. Statistical analyses were conducted in R (version 4.4.1), employing Mann–Whitney U tests (material comparisons) and Wilcoxon signed rank tests (time point comparisons), with a significance threshold of p ≤ 0.05. During the entire study period, an increase in wear was observed at each assessment interval, gradually stabilizing over time. Significant differences in substance loss were found between the follow-up time points, both for mean (−0.536 ± 0.249 mm after 14a) and integrated distance (−18,935 ± 11,711 mm3 after 14a). In addition, significantly higher wear was observed after 14 years with gold as antagonist compared to other materials (p ≤ 0.03). The wear behavior of IPS Empress® ceramics demonstrates clinically acceptable long-term outcomes, with abrasion characteristics exhibiting stabilization over time. Full article
(This article belongs to the Special Issue Advanced Dental Materials: From Design to Application, Second Volume)
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13 pages, 2438 KiB  
Article
The Integration of Micro-CT Imaging and Finite Element Simulations for Modelling Tooth-Inlay Systems for Mechanical Stress Analysis: A Preliminary Study
by Nikoleta Nikolova, Miryana Raykovska, Nikolay Petkov, Martin Tsvetkov, Ivan Georgiev, Eugeni Koytchev, Roumen Iankov, Mariana Dimova-Gabrovska and Angela Gusiyska
J. Funct. Biomater. 2025, 16(7), 267; https://doi.org/10.3390/jfb16070267 - 21 Jul 2025
Viewed by 560
Abstract
This study presents a methodology for developing and validating digital models of tooth-inlay systems, aiming to trace the complete workflow from clinical procedures to simulation by involving dental professionals—dentists for manual cavity preparation and dental technicians for restoration modelling—while integrating micro-computed tomography (micro-CT) [...] Read more.
This study presents a methodology for developing and validating digital models of tooth-inlay systems, aiming to trace the complete workflow from clinical procedures to simulation by involving dental professionals—dentists for manual cavity preparation and dental technicians for restoration modelling—while integrating micro-computed tomography (micro-CT) imaging with finite element analysis (FEA). The proposed workflow includes (1) the acquisition of high-resolution 3D micro-CT scans of a non-restored tooth, (2) image segmentation and reconstruction to create anatomically accurate digital twins and mesh generation, (3) the selection of proper resin and the 3D printing of four typodonts, (4) the manual preparation of cavities on the typodonts, (5) the acquisition of high-resolution 3D micro-CT scans of the typodonts, (6) mesh generation, digital inlay and onlay modelling and material property assignment, and (7) nonlinear FEA simulations under representative masticatory loading. The approach enables the visualisation of stress and deformation patterns, with preliminary results indicating stress concentrations at the tooth-restoration interface integrating different cavity alternatives and restorations on the same tooth. Quantitative outputs include von Mises stress, strain energy density, and displacement distribution. This study demonstrates the feasibility of using image-based, tooth-specific digital twins for biomechanical modelling in dentistry. The developed framework lays the groundwork for future investigations into the optimisation of restoration design and material selection in clinical applications. Full article
(This article belongs to the Section Dental Biomaterials)
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11 pages, 28340 KiB  
Article
Self-Adapting Foot Orthosis Inlay Facilitates Handling and Reduces Plantar Pressure Compared to Vacuum-Based Technology
by Alexander Milstrey, Carolin Horst, Stella Gartung, Ann-Sophie Weigel, Richard Stange and Sabine Ochman
J. Clin. Med. 2025, 14(10), 3384; https://doi.org/10.3390/jcm14103384 - 13 May 2025
Viewed by 407
Abstract
Background/Objectives: Orthoses are commonly used in the treatment of various foot and ankle injuries and deformities. An effective technology in foot orthoses is a vacuum system to improve the fit and function of the orthosis. Recently, a new technology was designed to [...] Read more.
Background/Objectives: Orthoses are commonly used in the treatment of various foot and ankle injuries and deformities. An effective technology in foot orthoses is a vacuum system to improve the fit and function of the orthosis. Recently, a new technology was designed to facilitate the wearing of the foot orthoses while maintaining function without the need for vacuum suction. Methods: A plantar dynamic pressure distribution measurement was carried out in 25 healthy subjects (13 w/12 m, age 23–58 y) using capacitive measuring insoles in two differently designed inlays within the VACOpedes® orthosis (Group A: vacuum inlay vs. Group B: XELGO® inlay) and a regular off-the-shelf shoe (Group C, OTS). The peak plantar pressure, mean plantar pressure and maximum force were analyzed in the entire foot and in individual regions of the medial and lateral forefoot, the midfoot and the hindfoot. Finally, the wearing comfort was compared using a visual analog scale from 1 to 10 (highest comfort). Results: The peak pressure of both inlays was significantly lower than in the OTS shoe (A: 230.6 ± 44.6 kPa, B: 218.0 ± 49.7 kPa, C: 278.6 ± 50.5 kPa; p < 0.001). In a sub-analysis of the different regions, the XELGO® inlay significantly reduced plantar pressure in the medial forefoot compared to the vacuum orthosis (A: 181.7 ± 45.7 kPa, B: 158.6 ± 51.7 kPa, p < 0.002). The wearing comfort was significantly higher with the XELGO® inlay compared to the vacuum inlay (A: 5.68/10, B: 7.24/10; p < 0.001). Conclusions: The VACOpedes® orthosis with a new XELGO® inlay showed at least equivalent relief in all pressure distribution measurements analyzed and greater relief in the forefoot area than the VACOpedes® orthosis with a vacuum inlay, as well as increased wearing comfort. Full article
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24 pages, 26458 KiB  
Article
An Innovative Tube Hydro-Joining Process Combining Piercing, Hole Flanging and Nut Inlaying
by Yeong-Maw Hwang, Hong-Nhan Pham, Ze-Wei Ho and Yu-Jen Wang
Materials 2025, 18(9), 1990; https://doi.org/10.3390/ma18091990 - 28 Apr 2025
Viewed by 481
Abstract
This paper proposes a novel tube hydro-joining process, which combines piercing, hole flanging, and nut inlaying. The nut punch shape design proposed by this paper can deliver three advantages of no scrap, no oil leakage, and longer flange length, which can achieve stronger [...] Read more.
This paper proposes a novel tube hydro-joining process, which combines piercing, hole flanging, and nut inlaying. The nut punch shape design proposed by this paper can deliver three advantages of no scrap, no oil leakage, and longer flange length, which can achieve stronger clamping force and accordingly increase the pull out load. First, we use the finite element analysis to investigate the elasto-plastic deformation of the aluminum alloy A6063 tube during the hydro-joining process. A punch-shaped nut with a tapered locking part is designed to increase the elasto-binding strength of the pierced tube and the pull out load of the inlayed nut. The effects of hydro-joining loading paths on the formability of the A6063 tubes and punch-shaped nuts are examined. Additionally, the effects of fit zone size, nut punch stroke length, internal pressure, nut diameter, and the die hole diameter on the pull out load and twisting torque are explored. Finally, experiments on hydro-joining of A6063 tubes are conducted to validate the finite element modeling and the simulation results. Full article
(This article belongs to the Collection Welding and Joining Processes of Materials)
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12 pages, 1620 KiB  
Article
Comparison of Marginal and Internal Fit of CAD/CAM Ceramic Inlay Restorations Fabricated Through Model Scanner, Intraoral Scanner, and CBCT Scans
by Ayben Şentürk, Bora Akat, Mert Ocak, Mehmet Ali Kılıçarslan and Kaan Orhan
Appl. Sci. 2025, 15(9), 4626; https://doi.org/10.3390/app15094626 - 22 Apr 2025
Viewed by 645
Abstract
Background and Objectives: CBCT images have been successfully used for CAD/CAM crown restorations; however, their use for ceramic inlay restorations remains unclear. This study aimed to evaluate the marginal and internal fit of CAD/CAM ceramic inlay restorations fabricated using intraoral scanner, model [...] Read more.
Background and Objectives: CBCT images have been successfully used for CAD/CAM crown restorations; however, their use for ceramic inlay restorations remains unclear. This study aimed to evaluate the marginal and internal fit of CAD/CAM ceramic inlay restorations fabricated using intraoral scanner, model scanner, and CBCT data. Materials and Methods: Inlay preparations were performed on 11 mandibular molar typodont teeth. The teeth were scanned using an intraoral scanner, an extraoral scanner, and CBCT (0.075 mm voxel size). CBCT-generated DICOM data were converted to STL format with dedicated software. All scan data were transferred to CAD software, and a total of 33 restorations were designed. Feldspathic ceramic blocks were used for milling. Micro-CT was employed to measure marginal and internal gaps, with 60 measurement points taken from three cross-sections per sample. Data were analyzed using ANOVA and Bonferroni tests (p < 0.05). Results: CBCT exhibited greater marginal and internal gap dimensions (mean: 169.27 ± 38.64 μm), which were approximately 60–70 μm higher than those of the intraoral (97.00 ± 10.1 μm) and model scanner groups (109.67 ± 9.72 μm), exceeding clinically acceptable limits (≤120 μm) (p < 0.05). Intraoral and model scanners showed similar, clinically acceptable results. Conclusions: CBCT was less accurate for inlay restorations, likely due to their complex geometry. Nevertheless, fabrication was possible, and further research may improve its clinical applicability. Full article
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10 pages, 677 KiB  
Article
An Assessment of the Micro-Tensile Bond Strength of Composites for Indirect Restoration to Enamel and Dentin
by Viktoria Petrova, Janet Kirilova and Sevda Yantcheva
J. Funct. Biomater. 2025, 16(4), 138; https://doi.org/10.3390/jfb16040138 - 12 Apr 2025
Viewed by 672
Abstract
This study aimed to evaluate the micro-tensile bond strength (µTBS) of two types of composites for indirect restoration, luted to enamel and dentin with self-adhesive cement. Moreover, it aimed to evaluate the impact of thermocycling on bond strength. Sixteen flat enamel and dentin [...] Read more.
This study aimed to evaluate the micro-tensile bond strength (µTBS) of two types of composites for indirect restoration, luted to enamel and dentin with self-adhesive cement. Moreover, it aimed to evaluate the impact of thermocycling on bond strength. Sixteen flat enamel and dentin surfaces of human molars were cemented to equal flat specimens of the laboratory composite Signum ceramis and the CAD/CAM block Cerasmart. Half of the specimens of the group underwent thermocycling. After that, the samples were cut into 80 beams for µTBS analysis. The data were analyzed using Levene’s test and the independent sample t-test. The micro-tensile bond strength tests revealed that thermocycling significantly reduced the adhesive bond. Dentin bonds better to conventional laboratory composites. Enamel bonds are better than composite blocks for milling. Full article
(This article belongs to the Special Issue Biomechanical Studies and Biomaterials in Dentistry)
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18 pages, 58403 KiB  
Article
Modeling and Simulation of Standing Wave Configurations for Outflow Improvement and Minimizing Undesired Recirculation
by Julien Schwalbe, Bogac Tur, Stefan Kniesburges, Nicolas Neuss, Michael Stingl, Thorsten Keck, Joachim Buff and Michael Döllinger
Appl. Sci. 2025, 15(6), 3127; https://doi.org/10.3390/app15063127 - 13 Mar 2025
Viewed by 571
Abstract
River surfing has evolved from natural rivers to artificial standing waves, like the Fuchslochwelle in Nuremberg, where optimizing wave quality and safety remains a challenge. Key issues include recirculation zones that pose risks, particularly at higher inflows. This study addresses safety and performance [...] Read more.
River surfing has evolved from natural rivers to artificial standing waves, like the Fuchslochwelle in Nuremberg, where optimizing wave quality and safety remains a challenge. Key issues include recirculation zones that pose risks, particularly at higher inflows. This study addresses safety and performance improvements by introducing geometric modifications to reduce recirculation zones. Using STAR-CCM+ simulations, 16 configurations of baffles and inlays were analyzed. A 3D-CAD model of the Fuchslochwelle was developed to test symmetrical and asymmetrical configurations, focusing on reducing vorticity. Results showed that baffles placed 2 m from the inlay reduced recirculation zones by over 50%. Asymmetrical setups, combining wall and inlay baffles, also proved effective. Following simulations, a baffle was installed at 3 m, enhancing safety and quality. Previously, inflows above 7.5 m3/s caused dangerous backflow, requiring surfers to swim or dive to escape turbulence. With the baffle, safe operation increased to 9 m3/s, a 20% improvement, making the system suitable for surfers of all skill levels. These finding provide a novel approach to enhancing flow dynamics, applicable to a wide range of artificial standing waves. The valuable insights gained enable operators to optimize the dynamics and accessibility through geometric modifications while ensuring safety for users. Full article
(This article belongs to the Special Issue Computational Fluid Dynamics and Modeling for Hydraulic Engineering)
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21 pages, 4853 KiB  
Article
Outside the Palaces: About Material Culture in the Almoravid Era
by Sophie Gilotte and Yasmina Cáceres Gutiérrez
Arts 2025, 14(2), 26; https://doi.org/10.3390/arts14020026 - 3 Mar 2025
Viewed by 1408
Abstract
The material legacy of the Almoravid dynasty is evident in a limited number of public and military works promoted by the authorities, reflecting their policies on territorial expansion and urban planning. Other aspects, such as its integration into the Mediterranean economy, its ideological [...] Read more.
The material legacy of the Almoravid dynasty is evident in a limited number of public and military works promoted by the authorities, reflecting their policies on territorial expansion and urban planning. Other aspects, such as its integration into the Mediterranean economy, its ideological spread, and the vitality of its productive sectors, are well represented through coinage, inscriptions, and sumptuary arts. However, understanding everyday material culture beyond aristocratic circles remains elusive. This paper explores the influence of the Almoravid period on al-Andalus’s material culture, identifying antecedents and impacts on later periods. We analyze artifacts from the Albalat site (Romangordo, Cáceres, Spain), contextualized in the first half of the 12th century, comparing them with contemporary and earlier examples across the Almoravid empire. Emphasis is placed on ceramics, highlighting their diverse nature with inherited traits from the Taifa period, and innovations that persisted into Almohad culture, considering the role of production centers in disseminating these models. The transition from Almoravid to Almohad is also examined through everyday items like a casket adorned with bone inlays, representing a link in Andalusian ivory handicraft evolution. This analysis aims to deepen understanding of Almoravid heritage in the Iberian Peninsula. Full article
(This article belongs to the Special Issue Islamic Art and Architecture in Europe)
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15 pages, 1708 KiB  
Review
The Inlay Technique in Alveolar Ridge Augmentation: A Systematic Review
by Carlo Barausse, Subhi Tayeb, Gerardo Pellegrino, Lorenzo Bonifazi, Edoardo Mancuso, Stefano Ratti, Andrea Galvani, Roberto Pistilli and Pietro Felice
J. Clin. Med. 2025, 14(5), 1684; https://doi.org/10.3390/jcm14051684 - 2 Mar 2025
Viewed by 1815
Abstract
Background/Objectives: Vertical ridge augmentation remains a critical challenge in implant dentistry for addressing inadequate alveolar bone height. The inlay technique, or sandwich osteotomy, has gained attention for its potential to improve graft vascularization and predictability. This systematic review aimed to evaluate the [...] Read more.
Background/Objectives: Vertical ridge augmentation remains a critical challenge in implant dentistry for addressing inadequate alveolar bone height. The inlay technique, or sandwich osteotomy, has gained attention for its potential to improve graft vascularization and predictability. This systematic review aimed to evaluate the clinical outcomes of the inlay technique. Methods: A systematic search was conducted in Cochrane Library and Medline databases for studies published from 2015 to 2025 to capture the most recent studies and advancements specifically focusing on the inlay technique. Inclusion criteria encompassed observational and interventional studies, including randomized controlled trials (RCTs) and cohort and case series with a focus on outcomes related to the inlay technique. Key outcomes were extracted and analyzed, including implant survival rates, MBL, vertical bone gain, and surgical complications. Results: Eleven studies involving 352 patients and more than 612 implants were included, with a mean follow-up of 2.27 ± 2.69 years (range: 4 months to 8 years). The implant survival rates ranged from 84.5% to 100%. Mean vertical bone gain varied from 2.69 to 4.4 mm. Complications were fewer with the inlay technique compared to onlay and other grafting methods, with significantly reduced graft-related failures and soft tissue issues. Conclusions: The inlay technique shows good vertical bone augmentation with high implant survival rates and fewer complications compared to other reconstructive techniques. Longer follow-up studies are needed to support its value in managing vertically deficient ridges. Moreover, further studies with extended follow-up are required to evaluate long-term marginal bone loss. Full article
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12 pages, 4779 KiB  
Article
Influence of Proximal-Cervical Undermined Enamel Areas on Marginal Quality and Enamel Integrity of Laboratory and CAD/CAM Ceramic Inlays and Partial Crowns
by Roland Frankenberger, Katharina Friedrich, Marie-Christine Dudek, Julia Winter, Norbert Krämer and Matthias J. Roggendorf
J. Funct. Biomater. 2025, 16(3), 82; https://doi.org/10.3390/jfb16030082 - 1 Mar 2025
Viewed by 1040
Abstract
(1) The aim of this in vitro study was to investigate the handling of proximal-cervical undermined enamel margins on the adhesive performance of differently fabricated and differently cemented ceramic inlays and partial crowns (2) Methods: 192 extracted third molars received MOD (n [...] Read more.
(1) The aim of this in vitro study was to investigate the handling of proximal-cervical undermined enamel margins on the adhesive performance of differently fabricated and differently cemented ceramic inlays and partial crowns (2) Methods: 192 extracted third molars received MOD (n = 96) and partial crown (n = 96) preparations. A mesial 2 × 2 × 4 mm cervical groove was created in dentin to simulate a deeper (dentin) caries excavation. This dentin groove was either left (G/groove), filled with composite (F/filling), or completely removed (D/dentin). Distal proximal boxes did not receive a groove and served as controls within the same tooth. Labside (e.max Press) restorations additionally went through a temporary phase. Labside and chairside (e.max CAD) inlays and partial crowns were then adhesively luted with Syntac/Variolink Esthetic (SV) or Adhese Universal/Variolink Esthetic (AV). Initially, and again after thermomechanical loading (TML: 1 million cycles at 50 N, 25,000 thermocycles at 5 °C/55 °C), specimens were molded and the resulting 24 groups of epoxy replicas (n = 8) were gold-sputtered and examined for marginal gaps using scanning electron microscopy (200× magnification). Light microscopy (10× magnification) was used to measure proximal cervical crack propagation in adjacent enamel. (3) Results: Regardless of the adhesive system, D groups generally showed significantly lower marginal quality (79–88%; p < 0.05), with the universal adhesive performing better than the multi-step adhesive system (p < 0.05). Subgroups G and F were similar in marginal quality (94–98%; p > 0.05) and not worse than the controls (p > 0.05) regardless of the adhesive system, but showed less cracking in F than in G (p < 0.05). In general, fewer cracks were observed in chairside CAD/CAM restorations than in laboratory-fabricated restorations (p < 0.05). Partial crowns showed better marginal quality (96–98%) and less cracking than inlays (p < 0.05). (4) Conclusions: If the dentin level is lower than the enamel level in ceramic preparations after caries excavation in the proximal box, the resulting undermined enamel should not be removed. In terms of enamel integrity, partial crowns outperformed inlays. Full article
(This article belongs to the Special Issue Advances in Restorative Dentistry Materials)
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19 pages, 4591 KiB  
Article
Enhancing Orthotic Treatment for Scoliosis: Development of Body Pressure Mapping Knitwear with Integrated FBG Sensors
by Ka-Po Lee, Zhijun Wang, Lin Zheng, Ruixin Liang, Queenie Fok, Chao Lu, Linyue Lu, Jason Pui-Yin Cheung, Kit-Lun Yick and Joanne Yip
Sensors 2025, 25(5), 1284; https://doi.org/10.3390/s25051284 - 20 Feb 2025
Cited by 2 | Viewed by 1244
Abstract
Bracing is a widely used conservative treatment for adolescent idiopathic scoliosis (AIS) patients, yet there is no consensus on the optimal amount of force applied. Although a number of different sensors have been developed to continuously monitor the applied pressure and force, they [...] Read more.
Bracing is a widely used conservative treatment for adolescent idiopathic scoliosis (AIS) patients, yet there is no consensus on the optimal amount of force applied. Although a number of different sensors have been developed to continuously monitor the applied pressure and force, they have several limitations, including inadequate overall force distribution and displacement. They also cause discomfort with limited wearability. In this study, body pressure mapping knitwear (BPMK) integrated with fourteen silicone-embedded fiber Bragg grating (FBG) sensors is developed to monitor immediate and overall changes in force during the bracing treatment. A wear trial of the BPMK is conducted by using a validated soft AIS mannequin, and prediction equations have been formulated for the FBG sensors at individual locations. The findings indicate that the measured forces are in good agreement with those obtained from clinical studies, with peak forces around the padding regions reaching approximately 2N. This was further validated by using finite element (FE) models. When comparing X-ray images, the estimated differences in Cobb angles were found to be 0.6° for the thoracic region and 2.1° for the lumbar region. This model is expected to provide valuable insights into optimal force application, thus minimizing the risk of injury and enhancing bracing compliance and efficacy. Ultimately, this innovative approach provides clinicians with data-driven insights for safer and more effective bracing applications, thus improving the quality of life of AIS patients. Full article
(This article belongs to the Special Issue Advances in Optical Fiber-Based Sensors)
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19 pages, 12490 KiB  
Article
Feasibility Exploration and Research Examples of On-Site Metallographic Inspection Methods in the Analysis of Bronze Artifacts—A Case Study of Ming Jiajing Bronze Lions and the Shang Bronze Tripod Vessel with Cicada Designs
by Kaige Zhang, Cheng Liu, Siyu Zhang, Ruihua Cui and Yi Li
Metals 2025, 15(2), 209; https://doi.org/10.3390/met15020209 - 17 Feb 2025
Cited by 1 | Viewed by 835
Abstract
This study explores a new microdestructive on-site metallographic inspection technique for analyzing metal artifacts. In the current archeometrical work, the metallographic analysis of metal artifacts requires mechanical sampling, which not only damages the integrity of the artifacts but also brings cold working effects [...] Read more.
This study explores a new microdestructive on-site metallographic inspection technique for analyzing metal artifacts. In the current archeometrical work, the metallographic analysis of metal artifacts requires mechanical sampling, which not only damages the integrity of the artifacts but also brings cold working effects to the metallographic structure during the sampling process, making the information inaccurate. This study designed a set of detailed on-site metallographic inspection methods for bronze artifacts, including grinding, sealing, polishing, etching, replicating, cleaning, and other steps. After verifying its safety through simulation experiments, the method was applied to several precious bronze artifacts, including two Ming Dynasty bronze lions from the Xi’an Beilin Museum and a Shang Bronze Tripod Vessel with Cicada Designs from the China Bronze Ware Museum. The metallographic findings show that the in situ metallographic technique can flexibly and accurately reveal the metallographic texture and process information of each localized part of the bronze artifacts, e.g., the heat-affected zone of the coins on the surface of the Ming Dynasty bronze lions proved the casting-inlay process, and the different heat texture of each foot of the Shang Bronze Tripod Vessel with Cicada Designs proved the chronological sequence of its two historical restorations. This study provides a novel approach to the process analysis of bronze artifacts, a method that can provide significant advantages in analyzing the processing techniques of precious and intact artifacts. Full article
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24 pages, 7283 KiB  
Article
Analysis of Cultural Perceptions of the Intangible Cultural Heritage of Chinese Porcelain Inlay: An Investigation Based on Social Media Data
by Yanyu Li and Yile Chen
Information 2025, 16(2), 124; https://doi.org/10.3390/info16020124 - 8 Feb 2025
Cited by 1 | Viewed by 2043
Abstract
Cultural heritage is a precious treasure left to mankind by history. With the development of the times and the improvement of people’s education, more and more people are becoming aware of the importance of protecting cultural heritage. Chinese porcelain inlay is a type [...] Read more.
Cultural heritage is a precious treasure left to mankind by history. With the development of the times and the improvement of people’s education, more and more people are becoming aware of the importance of protecting cultural heritage. Chinese porcelain inlay is a type of architectural decoration born out of the specific historical, geographical, and cultural conditions of Fujian and Guangdong, and was included in the second batch of The National List of Intangible Cultural Heritage of China published in 2008 and the third batch of The National List of Intangible Cultural Heritage of China—Expanded Projects in 2011. It represents an important part of the complex traditional culture of Fujian and Guangdong, acting as the essence of national culture, a symbol of national wisdom, and the refinement of national spirit. Using targeted analysis and making changes based on negative reviews, organizations that protect cultural heritage can improve their actions and find new ways to spread cultural heritage. The craft of Chinese porcelain inlay is used as an example in this paper. It combines Python Octopus crawler technology, data analysis, and sentiment analysis methods to perform a cognitive social media visualization analysis of Chinese porcelain inlay, which is a form of national intangible cultural heritage in China. Then, by looking at network text data from social media, it seeks to find out how the Chinese porcelain inlay culture is passed down, what its main traits are, and how people feel about it. Finally, this study summarizes the public’s understanding of inlay porcelain and proposes strategies to promote its future development and dissemination. This study found that (1) as a form of national intangible cultural heritage in China and a unique traditional architectural decoration craft, Chinese porcelain inlay has widely recognized cultural and artistic value. (2) The emotional evaluation of Chinese porcelain inlay is mainly positive (73 and 60.76%), while negative evaluations account for 12.62 and 20.79% of responses, mainly reflected in regret regarding the gradual disappearance of old buildings, the lament that Chinese porcelain inlay is highly regional and difficult to popularize, the regret that the individual has not visited locations with Chinese porcelain inlay, a feeling of helplessness with regard to inconvenient transportation links to these places, and discontent with the prohibitively high prices of Chinese porcelain inlay products. These findings offer valuable guidance for the future dissemination and development of Chinese porcelain inlay as a form of intangible cultural heritage. (3) The LDA topic model is used to divide the perception of Chinese porcelain inlay into nine major themes: arts and crafts, leisure and entertainment, cultural travel, online appreciation, heritage protection, dissemination scope, prayer and blessing, inheritance and innovation, and collection and research. This also provides a reference for the future direction of the inheritance of Chinese porcelain inlay cultural heritage. Full article
(This article belongs to the Special Issue Recent Advances in Social Media Mining and Analysis)
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21 pages, 7878 KiB  
Article
Carboxyethylsilanetriol-Functionalized Al-MIL-53-Supported Palladium Catalyst for Enhancing Suzuki–Miyaura Cross-Coupling Reaction
by Yucang Liang, Xin Ning and Yanzhong Zhen
Molecules 2025, 30(3), 656; https://doi.org/10.3390/molecules30030656 - 1 Feb 2025
Viewed by 1128
Abstract
The application of metal–organic frameworks (MOFs) has attracted increasing attention in organic synthesis. The modification of MOFs can efficiently tailor the structure and improve the property for meeting ongoing demand in various applications, such as the alteration of gas adsorption and separation, catalytic [...] Read more.
The application of metal–organic frameworks (MOFs) has attracted increasing attention in organic synthesis. The modification of MOFs can efficiently tailor the structure and improve the property for meeting ongoing demand in various applications, such as the alteration of gas adsorption and separation, catalytic activity, stability, and sustainability or reusability. In this study, carboxyethylsilanetriol (CEST) disodium salt was used as a dual-functional ligand for modified Al-MIL-53 to fabricate CEST-functionalized Al-MIL-53 samples through a hydrothermal reaction of aluminum nitrate, terephthalic acid, and CEST disodium salt by varying the molar ratio of CEST to terephthalic acid and keeping a constant molar ratio of Al3+/-COOH of 1:1. The structure, composition, morphology, pore feature, and stability were characterized by XRD, different spectroscopies, electron microscopy, N2 physisorption, and thermogravimetric analysis. With increasing CEST content, CEST-Al-MIL-53 still preserves an Al-MIL-53-like structure, but the microstructure changed compared with pure Al-MIL-53 due to the integration of CEST. Such a CEST-Al-MIL-53 was used as the support to load Pd particles and afford a catalyst Pd/CEST-Al-MIL-53 for Suzuki–Miyaura C-C cross-coupling reaction of aryl halides and phenylboronic acid under basic conditions. The resulting Pd/CEST-Al-MIL-53 showed a high catalytic activity compared with Pd/Al-MIL-53, due to the nanofibrous structure of silicon species-integrated CEST-Al-MIL-53. The nanofiber microstructure undergoes a remarkable transformation into intricate 3D cross-networks during catalytic reaction, which enables the leachable Pd particles to orientally redeposit and inlay into these networks as the monodisperse spheres and thereby effectively preventing Pd particles from aggregation and leaching, therefore demonstrating a high catalytic performance, long-term stability, and enhanced reusability. Obviously, the integration of CEST into MOFs can effectively prevent the leaching of active Pd species and ensure the re-deposition during catalysis. Moreover, catalytic performance strongly depended on catalyst dosage, temperature, time, solvent, and the type of the substituted group on benzene ring. This work further extends the catalytic application of hybrid metal–organic frameworks. Full article
(This article belongs to the Section Inorganic Chemistry)
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16 pages, 24312 KiB  
Article
Fast Terahertz Reflection Imaging for In-Line Detection of Delaminations in Glass Fiber-Reinforced Polymers
by Peter Fosodeder, Michael Pfleger, Kausar Rahman, Tom Dutton, Sophie Cozien-Cazuc, Sandrine van Frank and Christian Rankl
Sensors 2025, 25(3), 851; https://doi.org/10.3390/s25030851 - 30 Jan 2025
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Abstract
Terahertz (THz) is an emerging technology particularly well suited for the non-destructive investigation of inner structures in polymers. To realize its full potential, THz imaging systems adapted to industrial constraints as well as more application studies in areas of interest are needed. In [...] Read more.
Terahertz (THz) is an emerging technology particularly well suited for the non-destructive investigation of inner structures in polymers. To realize its full potential, THz imaging systems adapted to industrial constraints as well as more application studies in areas of interest are needed. In this work, we present a fast and flexible THz imaging system comprising hardware and software and demonstrate its capabilities for the investigation of defects in glass fiber-reinforced polymers (GFRPs), particularly for the detection of drilling-induced delaminations. Measurement data obtained by raster scanning of GFRP samples are gathered in 3D volumetric images. THz images of the drilled holes are then compared to reference images of the same holes obtained from X-ray computed tomography measurements. We show that THz imaging is capable of identifying not only artificial defects in the form of aluminum and Teflon inlays, but also real defects such as delaminations generated by drilling operations, and is suitable for non-destructive testing in industrial conditions. Full article
(This article belongs to the Special Issue Recent Advances in THz Sensing and Imaging)
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